Kosters, E. C., and A. Bailey, A., 1983, Louisiana peat resources. Final technical report, 1 April 1981-15 April 1983. Report prepared for the U. S. Department of Energy Division of Energy Technology under Contract DE-FG18-81FE05113. Louisiana geological Survey, Louisiana State University, Baton Rouge, Louisiana. 63 pp.
Kosters, E. C., and A. Bailey, A., 1983, Louisiana peat resources. Final technical report, 1 April 1981-15 April 1983. Report prepared for the U. S. Department of Energy Division of Energy Technology under Contract DE-FG18-81FE05113. Louisiana geological Survey, Louisiana State University, Baton Rouge, Louisiana. 63 pp.
Kosters, E. C., and A. Bailey, A., 1983, Louisiana peat resources. Final technical report, 1 April 1981-15 April 1983. Report prepared for the U. S. Department of Energy Division of Energy Technology under Contract DE-FG18-81FE05113. Louisiana geological Survey, Louisiana State University, Baton Rouge, Louisiana. 63 pp.
for the Period 1 April 1981 through 15 April 1983 Elisabeth C. Kosters August 1983 Work Performed under Contract DE-FG18-81FE05113 Department of Natural Resources Louisiana Geological Survey University Station, Box G Baton Rouge, Louisiana 70893 DOE/ FE/ 05113 DISCLAIMER This report was prepared as an account of work sponsored by the United States Government. Neither the United States nor the United States Department of Energy, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by trade name, mark, manufacturer, or otherwise, does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or any agency thereof. The views and opinions of authors expressed herein do not necessarily state or reflect those of the United States Government or any agency thereof. Available from the National Technical Information Service, U.S. Department of Commerce, Springfield, Virginia 22161: Price: Printed Copy A04 Microfiche AO 1 LOUISIANA PEAT RESOURCES Final Technical Report for the Period 1 April 1981 through 15 April 1983 Elisabeth C. Kosters with a contribution by Alan Bailey Department of Geology University of Southwestern Louisiana Lafayette. Louisiana Department of Natural Resources Louisiana Geological Survey University Station. Box G Baton Rouge, Louisiana 70893 August 1983 Prepared for the U. S. Department of Energy Division of Energy Technology under Contract DE-FG18-81FE05113 DOE/FE/05113 Abstract Introduction Classification and Properties Clas sifica tion Depositional Setting s Ash Content and Btu Bulk Density CONTENTS Relationships between Percent Moisture and Percent Organic Matter , Mineral Content Average Values , History of Assessment Study and Overview of Prospect Areas History of Assessment Gueydan Prospect, Avery Island Prospect Sale-Cypremort Prospect Barataria Prospect Lake Pontchartrain Prospect Methods Sampling ,. , Determination of Percent Moisture and Ash Bulk Density Calculation of Peat Tonnage Status of Survey Future Plans Pu blica tions Acknowledg ments , References Appendices Distribution List iii vii 1 4 4 4 5 6 8 11 12 13 13 13 17 17 33 46 46 46 48 48 49 50 50 51 52 53 57 63 FIGURES Figure 1. Location map showing peat research areas. . . 2 2. Plot showing relationship between bulk density and percent organic matter. ........ 7 3. 4. 5. 6. 7. 8. 9. 10. II. 12. 13. 14. 15. 16. 17. 18. 19. Linear plots showing relationship between (3a) bulk density and depth for samples taken from the top 80 cm of section and between (3b) bulk density and depth for all samples. .. Log-linear plot showing relationship between percent moisture and percent organic matter in Sale-Cypremort and Barataria.
Gueydan prospect. Approximate depths to the Pleistocene.
Gueydan prospect. Location and analysis of the two most important cores.
Avery I.sland prospect. L o c a ~ i o n map. Avery Island prospect. Dip sections A-A' and B-B'. Avery Island prospect. Strike section C-C'.
Avery Island prospect. Isopach map of lowermost peat bed. . .
Avery Island prospect. Isopach map of upper peat bed. . .
Avery Island prospect. Isopach map of org anic-rich cypress swamp deposit.
42 30. Barataria prospect. Contoured section E-E'. 43 31. Barataria prospect. Frequency distribution plot. 44 32. Barataria prospect. Map showing depth to the 30% org anic matter isopleth. . .
45 33. Lake Pontchartrain prospect. Location map. core locations. and core descriptions. .
47 TABLES Page Table 1- Average properties of Louisiana peat.
3 2. Classification of org anic sediments. with clayey inorganic texture. . . . . . . . ..
4 3. Typical veg eta tion by marsh type.
14 ABSTRACT Five peat prospect areas--Gueydan, Avery Island, Sale-Cypremort, Barataria, and Lake Pontchartrain--are representative of different types of South Louisiana peat deposits. Together, the prospects are estimated to contain about 20 x 10 6 metric tons of peat. Because these areas occupy only a small portion of the deltaic and chenier plains, there is potentially much more peat present in South Louisiana. Approximately 2000 samples, taken from about 200 auger holes and vibracores, were analyzed. Average values of Louisiana peat are 90% moisture, 80% organic matter (20% ash), a bulk density of 0.12 g/cm 3 , and a Btu of 8515. The relationships between percent moisture and organic matter and between bulk density and depth indicate that compaction during the first few thousand years was minimal. Freshwater peats contain primarily kaolinite and quartz, whereas marine-influenced peats contain kaolinite, quartz, and water-soluble salts. vii INTRODUCTION The Louisiana Geological Survey (LGS) has been investigating peat distribution in South Louisiana since April 1981. The objectives of this project were to map mineable fuel-grade peat deposits at least 3 km 2 in area and 1.5 m thick and to evaluate their qualitative and quantitative properties. The American Society for Testing and Materials (ASTM) defines peat as organic material containing more than 75% organic matter by dry weight. Little peat meeting this specification has been found in Louisiana. Although many organic deposits are primarily hemic and sapric and often do not contain more than the required 75% organic matter, the study of peats in the Mississippi River Deltaic Plain can provide useful information about modern coal-forming environments. Selection of the four prospect areas (Fig. 1) was based on resource assessment conducted through a literature search (Kress, 1980). One prospect, Avery Island, was added. Most of the prospects are located in basins formed by cyclic deltaic sedimentation of the Holocene Mississippi River. Outline of a prospect is based on natural boundaries, whenever possible. However, since virtually all of South Louisiana's swamps and marshes can be designated as a peat resource area, these boundaries are, in places, arbitrary. The total amount of peat in all prospects is about 20 x 10 6 metric tons; Louisiana peat has an average of 90% moisture, 80% organic matter, and a bulk density of 0.12 g Icm 3 (Table 1). All units of measurement in this report are metric. SCALE 10 0 10 20 30 40 50 MI 10 0 20 40 60 80 100 KM ! I ... )' I GUEYDAN 2 AVERY ISLAND 3 SALE CYPREMORT 4 BARATARIA 5 LAKE PONTCHARTRAIN --PLEISTOCENE LIMITS - Figure 1. Location map showing peat research areas. 2 Table 1. Average properties of Louisiana peat. A VERAGE QUALITY ORGANIC BULK MOISTURE PROSPECT (%) Gueydan 92.2% Avery Island (I) 89.2 Avery Island (II) 89.2 Avery Island (swamp) Sale-Cypremort 89.0 Barataria 89.4 Lake Pontchartraintt 90.2 AVERAGE 90% * Figure based on one sample. t Average for all areas. MATTER (%) 78.3% 79.4 79.4 81.6 79.4 81.1 80% See p. 25 for respective thicknesses. ** Figures not established. DENSITY (g/ cm3) 0.12 g/cm 3 t 0.12 g/ cm3 tt Figures for average quantity are AVERAGE QUANTITY AREA THICKNESS METRIC TONS Btu (km 2 ) (m) (x 10 6 ) 9227* 3.43 km 2 1.20 m 0.49 x 10 6 8328 9.65 0.60 0.69 8328 7.68 0.40 0.36 34 8485 87.12
5.50 8189 127 ** 2.51 8620 81 1.08 10.53 8515 TOTAL: 20.08 x 10 6 CLASSIFICATION AND PROPERTIES Classification Sediments in the upper 4 m of the Mississippi River Deltaic Plain are highly variable in organic matter content. In order to log sediments properly, a special classification was developed (Kearns, 1982, personal commun.) (Table 2): Table 2. Classification of organic sediments, with clayey inorganic texture. Organic Matter (%) <5% 5-15% 15-35% 35-55% 55-75% > 75% Type clay mucky clay clayey muck muck peaty muck peat NOTE: The term "organic-rich material" is used to describe material containing more than 35% organic matter by dry weight. Depositional Setting s There are several types of peat deposits in the delta and chenier plains of South Louisiana. The two major kinds are blanket peats and interdistributary peats; of lesser importance are channel fill and detrital peats. Blanket peats form atop slowly subsiding abandoned delta lobes. Often, several depositional cycles can be recog nized . Organic-rich deposits represent periods when active delta deposition took place at a considerable distance from the area of organic accumulation; deposits with little organic matter (clays and mucky clays) represent periods when a depocenter was located in proximity to the area (Coleman and Smith, 1964). Blanket peats experience little detrital influx, are laterally continuous, and display a relatively uniform thickness. The upper peat deposit in the Sale-Cypremort prospect is an example of a blanket peat. Interdistributary peats form in relatively low-lying basins between distributaries during periods of active delta deposition. The basins are susceptible to the influx of fine-grained detrital material by overbank flooding. In these basins, stratig raphic correlations are usually difficult to establish; however, pockets of organic-rich material up to 4 m thick may exist. The Barataria prospect is an example of interdistributary-peat accu mula tion The Gueydan prospect is characterized by a third kind of peat accumulation, that of channel fill. Pleistocene channels, or abandoned meander belts of the Mississippi or one of its distributaries, provide the setting for these peats. Compared to that of other types, the aerial extent is small; although detrital influx is minimal, organic matter content is similar to that of other peats (Table 1). Lastly, there are detrital peats. These originate by shoreline erosion of marshland, after which the eroded marsh material is deposited in the shallow offshore zone. These peats were not investigated. Blanket peats, interdistributary peats, and detrital peats can be preserved in the fossil record and should therefore be considered examples of modern coal-forming environments. Ash Content and Btu The ash content of Louisiana peats averages 20% (Table 1) as a result of the following factors: 1) Intermittent interruption of marsh growth due to detrital influx. such as crevasse splays and flooding events. 5 . 2) Botanical orlgm of peats, which are composed mainly of cypress swamp and marsh material (Table 3). Sphagnum vegetation yielding low-ash peats is not present. Determination of botanical origin of peats was done visually. Microtome analysis has not yet been done. 3) Subsidence. A certain amount of subsidence is necessary to enable the marsh to continue growing upward. When the optimal subsidence rate is exceeded, inundation begins, resulting in the influx of detrital matter. Ash percentages, as determined by the Grand Forks Energy Technology Center, were, in 81.5% of all cases, slightly lower than those established by LGS for the same samples. The difference ranges from 0.2 to 13.1% (ash content), with an average of 3.9%. This discrepancy is thought to be due to the fact that, at Grand Forks, samples are ground prior to analysis. Grinding loosens the sediment, thus freeing more particles for combustion. In the remaining 18.5% of all cases, ash percentages determined by Grand Forks were slightly higher than those at LGS. The reason for this is unknown. Values for Btu range from 7431 to 9227, with an average of 8515 for all prospects (Table 1; App. A). Bulk Density For organic-rich material, bulk density values range from 0.07 to 0.20 g/cm 3 , with an average of 0.12 g/cm 3 for all depths. The botanical origin of the different peats may account for the rather wide range of bulk density values (Cohen, 1982, personal commun.). Fifty-three samples were analyzed (App. B). The results show (Fig. 2) that a relationship between organic matter content and bulk density does not exist. Neither is there any difference between values for different areas. Because of this, the average of all bulk density values for organic-rich material has been taken as the overall average for Louisiana. 6 p E R C E N T 100 90 . 60 70 60 SO
____ T-__ ____ __ __ __ __ __ __ __ __ __ __ __ ____ __ 0.05 0.06 0.07 0.06 0.09 0.10 0.11 0.12 0.13 0. 15 0.16 0.17 0.1 6 0.19 0.20 0.21 0.22 0. 23 808 6ULK DENSITY IN GRRMS PER CENTIMETER CU6EO Figure 2. Plot showing relationship between bulk density organic matter. and percent 7 0 R G A N I C t.I A T T E R With respect to the relationship between bulk density and depth, there is an indication of sharp increase in bulk density from the surface to -80 cm depth (Fig. 3a). At depths greater than -80 cm, a relationship does not seem to exist (Fig. 3b). A verage bulk density increases from 0.11 g/ cm 3 for depths less than -1 m to 0.15 g/ cm 3 for depths greater than -3 m, but correlations are poor. These results probably indicate that, in the first few thousand years after deposition, most compaction took place immediately after the accumulation of the root mat (Coleman, 1982, personal commun.); after this, compaction was minimal. It has been reported (Boelter, 1969) that when the degree of decomposi- tion increases, the average bulk density also increases. Observations of the degree of decomposition fall primarily in the hemic and sapric ranges; these observations, related to Boelter's results, show that bulk density values of Louisiana peats are typical of hemic and sapric peats. The relatively high degree of decomposition of peats is possibly due to the slightly alkaline pH which allows for greater biological activity affecting the breakdown of plant fibers (Renton and others, 1979). Relationships between Percent Moisture and Percent Organic Matter Relationships between percent moisture and percent organic matter were established for Sale-Cypremort and Barataria (Fig. 4; Apps. C and D). It appears that the relationship is a log-linear one. However, correlations are generally not very good. Regression equations were established for the following depths: less than -1 m, -1 to -3 m, and greater than -3 m. For 80% organic matter, material at depths greater than -3 m contains slightly less moisture than material at depths less than -1 m. The difference in moisture content, which is 4.4% in Sale-Cypremort and 3% in Barataria, is attributed to 8 a 10 20 30 C 40 H 50 60 70 LI NEAR REGRESS ION, y. -437.27 'i\. 72 IWHERE R:O. SOl o E p T H e O ~ ~ ~ ~ ~ ~ ~ __ - r ~ ~ ' - ~ __ r - ~ ~ ~ ~ ~ ~ ~ ~ 0.01 0.09 0.11 O.ll 0.1; 0.1/ 0.19 0.21 0.23 Figure 3a. BO BULK DENSI" IN DARNS rCR CENTIMfTER CUBED Linear plot showing relationship between bulk density and depth for all areas for samples taken from the top 80 cm of section. 0 50 100 150 200 C 250 M 300 350 400 450 sao 0.0 Figure 3b. o. I 0.2 80 BULK 0[NS\11 IN GAAMS PER CENTIMeTER CUBED 0.3 o E p T H Linear plot showing relationship between bulk density and depth for all samples. Average bulk density for samples taken at depths less than -1 m, between -1 and - 3 m, and greater than -3 m is 0.11, 0.13, and 0.15 g / cm 3 . respectively. ... o P E A C E (A) SALE-CYPREMORT < I METEA, POINTS AAE HASHES' AEGAESSION IS SOLID 1-3 METEAS, POINTS AAE STAAS' AEGAESSION IS DASHED > 3 METERS, POINTS ARE TAIANGLES , AEGRESSION IS LONG-SHORT 2 < I METER AEGRESSION, T_12.0SLNX-3B.20 WHEAE O.BO-A 2 1-3 METER REGAESSION, T-S.36LNX'41.Be WHEAE O.Se-A 2 > 3 METEA REGRESSION, T_B .91LNX41.93 WHEAE 0.43-A 100 1 90 ." 10 DASH .. o I S T U R E N 60 C o N T E N T T SO 40 3 D ~ ~ I ~ ~ ~ ~ ~ - r __ ~ ~ ____ r y - ~ ~ ~ ~ __ T-__ ~ 30 40 50 Figure 4. 60 10 eo PEACENI Log -linear plot percent organic prospects. 90 100 showing relationship between Sale-Cypremort matter in (A) (B) BARATARIA < I "ETER, POINTS AAE HASHES' AEGAESSION IS SOLID 1-3 "ETEAS, POINTS AAE STAAS' AEGAESSION IS DASHED > 3 "ETEAS, POINTS ARE TAIANGLES , REGAESSION IS SHOAT-LONG DASH P E R C E IUu 90 eo 10 N 60 T 50 40 30 < I HETEA AEGAESSION, Y.47.91'9.61LNX WHEAE 0.42-/ 1-3 "ETEA REGAESSION, Y-44.24'10.32LNX WHERE 0.64_R 2 > 3 METCR AEGRESSION, T-50.49e.41LNX WHERE 0.50./ .' 30 40 50 60 10 eo so PEACENT ORGRNIC "ATTER percent moisture and and (B) Barataria 100 .. o I 5 T U R E C o N T E N T natural compaction. The fact that compaction is somewhat higher in Sale- Cypremort than in Barataria may be due to two factors. of detrital matter in Sale-Cypremort are putting First, cyclic deposits more weight on the organic-rich sediments underneath; this is not the case in Barataria. Also, Sale-Cypremort was sampled to a depth of -9 m, whereas Barataria was sampled to a depth of -5 m. Data on samples taken from Sale-Cypremort between -5 and -9 m may affect the curve. Both bulk density and moisture-versus-organic matter behavior seem to suggest the same general pattern discussed in the previous section; a slight increase in bulk density with depth and a slight decrease in moisture with depth indicate a small amount of compaction during the first few thousand years after deposition. Ingram and Otte (1982), however, found the converse to be true in the North Carolina peats of the Pamlimarle Peninsula: moisture content increases and bulk density decreases with depth; they attributed these results to differences in drainage, elevation, and degree of decomposition. In all of the Louisiana prospect areas, the water table is permanently at the surface and near mean sea level. Most Louisiana peats are hemic and sapric, and vertical trends have not been observed. This situation is the reverse of that in North Carolina, where two distinct peat types are present in the subsurface. The entirely different setting of Louisiana peats is thus responsible for the distinct pattern of moisture and bulk density found here. However, one should keep in mind that, in all cases, correlations are poor, and a detailed analysis of the botanical parent material of the peats has not yet been taken into account. Mineral Content In addition to high-temperature ashes, some samples from the Gueydan and Avery Island prospects were subjected to low-temperature ashing in order to 11 examine the mineralogy. Low-temperature ashes (LTA's) were analyzed using X-ray diffraction (XRD) and scanning electron microscopy (SEM). In the XRn work, both the original bulk LTA's and the clay-sized portions of the LTA's are being examined. Bulk LTA's from Gueydan samples are composed primarily of quartz and kaolinite, whereas bulk LTA's from Avery Island samples contain salts, such as hydrated calcium sulfates, hexahydrite, and polyhalite in addition to quartz and kaolinite. These salts appear to make up 30 to 50% by weight of the LTA's. Samples are being leached with distilled water for future XRn and SEM work. Clay fractions from the LTA's are composed of illite, kaolinite, quartz, and smectites. The Gueydan samples appear to contain less illite relative to quartz and less smectite clays than the Avery samples. In the Avery samples, the underlying, nonorganic material is much richer in smectitic clays than the clay portion of the LTA's from the organic-rich material. Ratios of kaolinite to quartz appear to be greater in the organic-rich material. SEM examination shows the presence of quartz (clastic and some euhedral crystals), framboidal pyrite, salts, clays (illite, kaolinite, gibbsite?), siliceous spicules, and the trace minerals rutile, biotite, and pyroxene. Average Values The average values of peat in each prospect are given in Table 1. Peat in South Louisiana averages 90% moisture, 80% organic matter, and a bulk density of 0.12 g / cm 3 , the latter two based on dry weight. Tonnage could be calculated for Gueydan and Avery Island. Calculations of tonnages for Sale- Cypremort and Barataria are statistical averages. For Lake Pontchartrain, only a rough estimate could be given. 12 HISTORY OF ASSESSMENT ST UDY AND OVERVIEW OF PROSPECT AREAS History of Assessment The LGS began a literature study of Louisiana peat resources in 1979. This study resulted in a report (Kress, 1980) recommending four areas for further investigation (Fig. 1). Field sampling for the program funded by the U.S. Department of Energy (DOE) was begun in September 1981. Sale-Cypremort was primarily surveyed during the fall of 1981; Avery Island, Gueydan, and Pontchartrain, in the spring of 1982; and most of Barataria, during the summer of 1982. The A very Island prospect was added to the areas originally recommended by Kress after additional information was obtained. Gueydan Prospect The G:ueydan prospect is located south of Gueydan in Vermilion Parish (Fig. 1) on the edge of the Pleistocene terrace. The peat originated as a fill in a Pleistocene river channel that cuts the terrace. South of the deposit, the Pleistocene becomes completely covered by Holocene marsh. The area is classified as fresh marsh (Chabreck and Linscombe, 1978) (Table 3). In the eastern part of the area, the channel cut is less than -2 m deep (Fig. 5), and only muck and clayey muck were encountered. In the western part, the bayou reaches depths of more than -6 m, but peat has not yet developed; most of the area is covered with a mat of floating vegetation. Surveys in the area, aided by the study of aerial photographs dating back to the 1930's, suggest that high-quality peat is present only in the center of the bayou between depths of -1 and -2.2 m (Fig. 6), where it is currently being mined. 13 Table 3. Typical vegetation by marsh type (from Chabreck and Linscombe, 1978). FRESH MARSHES Panicum hemitomoR (maiden cane) Hydrocotyl sp. Eichhornia crassipes (water hyacinth) Pontederia cordata (pickerelweed) Alternan thera p hiloxeroides (alligatorweed) S agit taria s p (bulltongue) BRACKISH MARSHES S partina patens (wireg rass) S cirpus olneyi (three-cornered grass) Scirpus robustus (coco) Ruppia maritima (widg eong rass) INTERMEDIA TE MARSHES S partina patens (wireg rass) Vigna repens (deer pea) Sagittaria sp. (bull tongue) Echinochloa walteri (wild millet) Scirpus californicus (bullwhip) Cladium jamaicense (sawgrass) SALINE MARSHES Spartina alternif/ora (oysterg rass) Salicornia sp. Juncus roemerianus (black rush) Batis maritima Avicennia nitida (black mangrove) Distichlis spicata (saltg rass) Figure 5. 1 KM r------- ----- --- --- I i I I i I LAKE CHARLES. STUDY AREA LEGEND ~ <1.5 M !III] 1.5 - 3 M ~ 3 - 4.5 M [] 4.5 - 6 M III > 6 M ~ UNKNOWN --- --------7 BATON ROUGE Gueydan prospect. Approximate depths to the Pleistocene. (After F. Shutt & Sons, Civil Engineers, Lake Charles, La.) Figure 6. a:: I ~ 1 KILOMETER 3 3.5 a:: I ~ o 50 100 - 100% OM Gueydan prospect. Location and analysis of the two most impor- tant cores. Histograms show percent organic matter versus depth (OM = organic matter). High-grade peat is present in the center of Latanier Bayou between depths of -1 to -2.2 m. 16 Peat is hemic, of reed sedge origin. and averages 92.2% moisture and 78.3% organic matter. Elemental analyses indicate that sulfur content is less than 1% (Bailey, 1982. personal commun.). Total estimate is 0.49 x 10 6 metric tons (Table 1). Avery Island Prospect The Avery Island prospect, which is located south and southwest of the Avery Island salt dome in Iberia Parish (Fig. 7). represents a blanket peat-forming environment. The size of the area is approximately 50 km 2
Four auger holes and five vibracores. each about 4 m deep. were drille'd. Stratigraphic interpretation of cross sections is shown in Figures 8 and 9. A cypress swamp deposit, about 2 m thick (-1 to -3 m deep), is present in most cores. This deposit is characterized by organic-rich sediments with abundant cypress wood frag ments. Within this deposit, two peat beds can be recog nized. Isopachs of the peat and swamp deposits are shown in Figures 10 to 12. The swamp deposit possibly correlates with a marsh deposit at the same depth at Sale-Cypremort (Kearns. 1982. personal commun.). The subsurface swamp horizon originated in a freshwater environment. and the present surface is classified as a saline marsh (Chabreck and Linscombe, 1978) (Table 3). tonnage of both peat beds is 1.05 x 10 6 metric tons. Calculated The presence of pyrite, together with a sulfur content of +3%, indicates that postdepositional inundation by saltwater greatly influenced the sulfur content of the peat (Bailey, 1982, personal commun.). Sale-Cypremort Prospect The Sale-Cypremort prospect is located south of Franklin. St. Mary Parish (Figs. 1 and 13). and represents primarily a blanket peat-forming environment. Several organic-rich horizons present in the subsurface were first shown by 17 Figure 7. ----------------- Avery Island prospect. cross sections. 1 KM LEGEND _ LINES INDICATE CROSS SECTIONS CORE LOCATIONS Location map showing core locations and 18 5 o -1 -2 -3 -4M--- 100% OM 7 LAGOONAL CLAYS ? 100% OM p. A' 8 100% OM o KM 5 KM a o -1 -2 -3 -4 M--- 2 100% OM --- LAGOONAL CLAYS? a' 4 o KM 5 KM Figure 8. LEGEND ~ SPOIL ~ MUCK ~ CLAY tl] PEATY MUCK EJ MUCKY CLAY
PEAT [Z] CLAYEY MUCK ~ WOOD THIN LENS OF ORGANIC MATTER VERTICAL EXAGGERATION: 500 Avery Island prospect. Dip sections A-A' and B-B'. Two peat beds are present within a cypress swamp deposit. 19 C 5 3 o - 1 - 2 ------ ----... DEPOSIT -3 LAGOoNAL CLAYS - 4 M --- -100% OM I o KM I 5 KM LEGEND C8J SPOIL ~ MUCK ~ CLAY 121 PEATY MUCK El MUCKY CLAY
PEAT EZ1 CLAYEY MUCK 5] WOOD VERTICAL EXAGGERATION: 500 Figure 9. Avery Island prospect. Strike section C-C' Two peat beds (I and II) are present within a cypress swamp deposit. CYPIlESS PEAT I 9 C' -100% OM I 0 -1 --- - 2 --- - 3 --- - 4 M 10 KM 6 ( !( o I / Q) 0 \ \ : g cf \ \ \ ( ( ~ (0 \ I"" ( / to. 0 ( \ ~ 9 ----1KM
AREA FOR WHICH VOLUME HAS BEEN CALCULATED CORE LOCATIONS CONTOUR INTERVAL: 10 CM IlIIIII1l > 30 eM THICK Figure 10. A very Island prospect. Isopach map of lowermost peat bed (I). Pattern indicates peat with a thickness of 30 to 60 cm. Eastern part of the area was not included in the calculation of volume because core 9 was isolated. I ~ / N 5 / j
/ / '\0 I O ~ 3 \ 1 ~ \
I ) N \ N 7 0 9 fl,0 / I I ~ AREA FOR WHICH VOLUME .8 HAS BEEN CALCULATED
CORE LOCATIONS [llill) 30 CM THICK CONTOUR INTERVAL: 10 CM 1 KM Figure 11. A very Island prospect. Isopach map of upper peat bed (II). ~ I 8
5.1-___ _
____ 1 KM \ \ \ \ ~ CP o \ \ \ \ ~ o o \ AREA FOR WHICH VOLUME HAS BEEN CALCULATED CORE LOCATIONS \ CONTOUR INTERVAL: 10 CM Figure 12. Avery Island prospect. Isopach map of organic-rich cypress swamp deposit. in which peat beds are developed. \ \ WEST COTE BLANCHE BAY 8' CORE LOCALITY t N Figure 13. Sale-Cypremort prospect. Location map showing cores and cross sections.. - 1 KILOMETER 1 MILE Coleman (1966) and in more detail during the LGS project (interpretation by Kearns, 1982, personal commun.) (Figs. 14-16). The area is a slowly subsiding interdistributary basin between Bayous Sale and Cypremort. These bayous were distributaries of the Maringouin and Teche delta lobes, two of the oldest Holocene Mississippi delta systems (Frazier, 1967). Depth to the Pleistocene ranges from -5 to -19 m (Coleman, 1966). Organic-rich horizons are intercalated with organic-poor beds. This cyclicity is mostly due to delta lobe switching. Three depositional cycles can be recognized in the upper 9.5 m of the subsurface. The tops of each of the organic-rich horizons occur at approximately -1.2, -4.3, and -6.4 m with respective thicknesses of 1.2, 0.4, and 0.8 m (Kearns, Autin, and Gerdes, 1982) . Only the uppermost organic-rich horizons contain material of peat quality. The peat is mostly hemic and sapric and of reed sedge origin. The lowermost horizon probably represents a swamp environment (Kearns, 1982, personal commun.). Due to extreme variation and discontinuity of the beds, isopaching techniques were not expected to be reliable. Instead, contouring techniques were used (Figs. 17-19). Boreholes reached a depth of about -8 m, but contouring was executed to a depth of about -4.5 m in order to be able to analyze the relationship between the different settings of the Sale-Cypremort and Barataria basins. Analysis of the distribution curves (Fig. 20) shows that about 15% of the total volume is peat, which amounts to 58.8 x 10 6 m 3 With a bulk density of 0.12 g/ cm 3 , this amounts to 7 x 10 6 metric tons. The contoured cross sections are based on the assumption that the entire area is marshland. An estimated 20%, however, is open water. Recalculation results in a total of 5.5 x 10 6 metric tons of peat, most of which is present in the updip part of the basin along strike section A-A'. 26 A A' 2 3 5 6 7 8 o - 1 - 1 - 2 - 2 - 3 - 3 - 4 100"4 OM - 4 - 5 ____ _ ------- ------------------- _____ --------- -------- ------- LEGEND - 5 - 6M-- 0 SPOIL D o - 35l1. ORGANICS
PEAT CJ WOOD VERTICAL EXAGGERATION - 500 o KM 5 KM 10 KM 15 KM Figure 14. Sale-Cypremort prospect. Strike section A-A' (Interpretation by Kearns, 1982, personal commun.) o --- -1 -2 -3 -4 -5 -6 -7 -8 -9M-- Figure 15. I I I I I ------------------------------------------------------------______ I ----------- 100% OM LEGEND 1iiOi'Ci'M - - - - - - - - - - - - - - - 7 ~ 10 KM [g] SPOIL l CLAY r;] MUCKY CLAY I2l CLAYEY MUCK I5B MUCK ~ PEATY MUCK PEAT [3j WOOD o 0 - 35% ORGANICS 035 - 100% ORGANICS VERTICAL EXAGGERATION = 500 15 KM I I I I I I I ~ -- 0 ---1 ---2 ---3 ---4 ---5 ---6 ---7 ---8 I I I I I I I I I I I ---9M Sale-Cypremort prospect. Dip section B-B' (Interpretation by Kearns, 1982, personal commun.) 27 .., 011 0 0 -- - 1 -- -2 - 3 -4 -- - 5 -6 -- - 7 - 8 -- _ - - - - - - - - - - - - - - - - - - - - ~ : ; : : ~ - - - - - - - - - - - - - - - --'"""'-- _--- 100l!. OM - 9M-- ----- - - - - - - ~ ~ ~ ~ ~ ~ - - - - - - - - - - - - OKM 5 KM 23 0' 24 LEGEND SPOIL CLAY o MUCKY CLAY t{]" CLA YEY MUCK ~ MUCK
~ PEATY MUCK PEAT WOOD o 0 - 35% ORGANICS ~ 35 - 100% ORGANICS VERTICAL EXAGGERATION 500 10KM Figure 16. Sale-Cypremort prospect. Strike section D-D' (Interpretation by Kearns, 1982, personal commun.) A 2 3 4 5 6 7 8 9 A' 0 -- - 1 - 2 - 3 - 4 ~ CC - 5 -- D 0 - 10% OM III 10 - 30% OM - 6M-- IillJ 30 - 70% OM f?$jJ 70 - 100% OM I I I I I I I I o KM 2 3 4 5 6 7 8 9 10 11 12 13 Figure 17. Sale-Cypremort prospect. Contoured section A-A'. interval is 10% organic matter. Contour 8 0 7 11 12 -1 - 2 -3 - 4 - 5 [] 0 - 10% OM .. , - 6 M [l]]]]] 10 - 30% OM co 0 30 - 70% OM 0 ~ 70 -100% OM I I I I o KM 2 3 4 5 Figure 18. Sale-Cypremort prospect. Contoured section B-B'. val is 10% organic matter. Dashed line indicates -4.5 m) to which planimetering was carried out. I 6 I 7 Contour inter- depth (about 13 I I 8 9 14 8' 0 -1 -2 -3 -4 -5 -6 -7 -8 - 9 M 10 0 - 1 - 2 - 3 - 4 - 5 - 6 Co) ... - 7 - 8 - 9 M Figure 19. 0 0' 19 20 13 21 22 ! ! I ! i ! i ! l ! ! ! l I I ! I ! l l i i i : ; ! ! I I I ! ! ! I I ! ! ! ! ! l I I I I I I I ! ! I ! ! ! l I I I I I ! I ! ! l I ! ! ! ~ ~ ~ ~ LEGEND o 0 - 10% OM o KM 2 3 4 5 6 Sale-Cypremort prospect. Contoured section D-D'. Contour inter- val is 10% organic matter. Dashed line indicates depth (about -4.5 m) to which planimetering was carried out. !IIlID 10 - 30% OM Cill 30 - 70% OM ~ 70 - 100% OM 7 8 r % FREOUENCY 60 ~ - - - - - - - - - - - - l I I I I I I I I I I I I I I I I : 'Il 50 40 30 20 .............................. _. _( 10 o 20 40 60 80 100 +- % ORGANIC MATTER Values for each Cross Section: 0-10% OM 10-30%OM 30-70%OM 70-100%OM A-AI .......... .. ... 19. 36 14 45.29 21.08 8-8' ----- 8 . 56 20. 97 61 .80 8.67 0-0 1 . . .. . . . 20.02 32.00 34.93 12.94 Average 16.07 22.32 47.34 14.23 Figure 20. LOUISIANA GEOLOGICAL SURVEY Sale- Cypremort prospect. Frequency distribution plot for quantities of material resulting from the planimetering of contoured cross sections. Values for cross sections are quantities in percentage of the total. 32 Barataria Prospect Barataria Basin, located southeast of Lake Salvador in Jefferson and Lafourche Parishes, is a rapidly subsiding interdistributary basin (Figs. 1 and 21) exemplifying an interdistributary peat-forming environment. Depth to the Pleistocene ranges from -20 to -50 m (McFarlan, 1961). Organic-rich deposits are formed during periods of rapid deltation. Hence, due to highly varying degrees of subsidence and detrital influx, an extremely high variability in the amount of organic matter, both horizontally and vertically, is present. Variation is such that separate peat beds cannot be mapped (Figs. 22-26). Cross section C-C', a dip section along Bayou Barataria (Fig. 24), shows the following stratigraphy: levee clay in the lower portions is overlain by organic-poor sediments with numerous clay lenses. This unit is interpreted as "incipient marsh," which implies that the activity of Bayou Barataria as a distributary declined and marsh started to grow. Marsh growth was still frequently interrupted by overbank flooding, resulting in organic-poor sediment and clay lenses. When Bayou Barataria became inactive, flooding stopped, and the organic-rich "recent marsh" developed as the upper unit. After the cross sections were planimetered and quantified (Figs. 27-30), the frequency distribution of sediments in the Barataria prospect shows that about 5% of the total amount of material is pBat (Fig. 31), compared to 15% at Sale-Cypremort. Barataria prospect contains less peat than Sale-Cypremort for the following reasons: 1) difference in depth to the Pleistocene surface, causing variations in subsidence rates; 2) different depositional setting; and 3) larger influx of detrital matter in the form of crevasse splays and small distributaries in Barataria Basin. The total volume of the basin, from the surface until the 30% organic matter isopleth (Fig. 32), is 317 x 10 6 m 3 Five percent of the total 38
U D I .ltto4,." I . I
I I O.
: . \ : I I c:7' ;).p. ()
I
'U !J : " I
I . . .. . I I I I ---===' 2KM SOUTHEAST LOUISIANA Figure 21. Barataria prospect. Location map showing cores and cross sections. 34 w Z ::::; :I: U f-- < ::; o -1 -- -2 -- -3 -- - 4M--- 35 Figure 22. 9 100"' OM o KM 39 10 KM ~ ~ [;J EZl ~ rll
~ 40 BAYOU PEROT r-----1 26 41 LEGEND SPOIL ~ SILTY CLAY CLAY ~ SILT MUCKY CLAY PALEOSOL CLAYEY MUCK W ROOTLETS MUCK MUDCRACKS 16 5 KM 15 KM PEATY MUCK THIN LENS OF ORGANIC MATTER PEAT REED CHUNKS WOOD VERTICAL EXAGGERATION :500 Barataria prospect. Dip section A-A'. 36 42 A' w z ::::; --- 0 --- 1 ---2 --- 3 ---- 4 M s 29 6 26 36 21 6 o -1 -2 -3 -4M-- o KM 5 KM 10 KM LEGEND ~ SPOIL E!l WOOD ~ CLAY EJ SHELL BED ~ MUCKY CLAY ~ SILT CZJ CLAYEY MUCK THIN LENS OF ORGANIC MATTER ~ MUCK (THICKER LENS OF) REED CHUNKS rl1 PEATY MUCK 0 SAND
PEAT VERTICAL EXAGGERATION: 500 s' 14 22 23 46 25 46 o -1 - 2 -- -3 -- -4M 15 KM 20 KM Figure 23. Barataria prospect. Dip section B-B'. 36 o - 1 -2 - 3 -4 M--- Figure 24. C 19 NCPENT MARSH LEVEE CLAYS o KM 2 10 RECENT MARSH lEVEE CLAYS [gJ SPOIL
CLAY
MUCKY CLAY .- CREVAS ---......... 5 KM LEGEND PEAT WOOD ------- LEVEE CLAYS SILTY CLAY 45 El
CLAYEY MUCK MUCK ALTERATION OF LITH. ON LAMIN. SCALE (THICKER LENS OF) REED CHUNKS
PEATY MUCK VERTICAL EXAGGERATION: 500 Barataria prospect. Dip section C-C'. (Levee clays: clays with less than 5% organic matter, occasional rootlets, and oxidation colors. Incipient marsh: mucky clays, clayey mucks, and mucks with numerous clay lenses. Recent marsh: mucks and peaty mucks without clay lenses. Crevasse splay: silty clays.) C' 44 --- 0 ----1 ----2 ----3 ----4 M 100% OM 10 KM o o -1 -2 -3 -4 M--- Figure 25. LAKE INTRACOASTAL SALVADOR W'WAY ., 28 100% OM OKM BAYOU PEROT ENTRANCE 15 Barataria prospect. BAYOU PEROT 21 100% OM 5 KM LEGEND ~ SPOIL ~ MUCK ~ CLAY 121 PEATY MUCK r;J MUCKY CLAY
PEAT 121 CLAYEY MUCK I SILTY CLAY -- ~ AL TERA TION OF LITH. ON LAMIN. SCALE VERTICAL EXAGGERATION: 500 Strike section D-D'. 13 -- BAYOU RIGOLETTES ---- - BAYOU BARATARIA 0' o --- -1 --- -2 --- -3 --- - 4M 10 KM E 36 o - 1 - 2 - 3 - 4 M--- o KM Figure 26. 35 14 [8J ~ El [Z] ~ rl1 SPOIL CLAY MUCKY CLAY CLAYEY MUCK MUCK PEATY MUCK BAYOU PEROT 5 KM LEGEND PEAT Erl WOOD ~ SILTY CLAY 15 100'11> OM THIN LENS OF ORGANIC MATTER (THICKER LENS OF) REED CHUNKS VERTICAL EXAGGERA liON: 500 Barataria prospect. Strike section E-E'. 4 BAVOU RIGOlETTES ./ ./ /' ./ ( lEVEE --- 2 ABANX>tO MEAhOEA OF BAYOU BARATARIA ,.--, E' /1 / \ / \ / \ / \ I \ \ --- 0 ----1 --- - 2 --- - 3 ----4 M ------ 10 KM A 31 9 28 16 0 - 1 - 2 -3 -- - 4M-- \ I o KM 2 j j I 4 I 3 I w IZ 1- 1-' I:x; 1(.) I f- 1< 35 39 40 4 1 I 1 14 I j I I ,I, I 8KM 10 1 1 13 LEGEND D 0 - 10% OM .. , []]]]]] 10 - 30% OM [] 30 - 70% OM ~ 70 - 100% OM Figure %7. Barataria prospect. Contoured section A-A'. is 10% organic matter. Dashed line indicates -4.5 m) to which planimetering was carried out. 40 Wi Z :::i :x; (.) f- < 34 ::;; I 7 A' 42 --0 ---1 --- 2 --- 3 --- 4M 1 Contour interval depth (about I UJ Z :::; 11 B 29 o KM Figure 28. 12 8 7 I 3 13 14 15 26 I 4 5 16 LEGEND [J 0 - 10% OM IIIlIll 10 - 30% OM lEI 30 - 70% OM ~ 70 -100% OM 38 6 7 17 18 Barataria prospect. Contoured section B-B'. 21 I 19 is 10% organic matter.. Dashed line indicates -4.5 m) to which planimetering was carried out. 41 I 8 9 20 Contour depth UJ Z :::; :t () >- 6
::; 10 --0 ---1 ---2 ---3 ---4M interval (about D 28 15 21 o - 1 -2 - 3 - 4 - 5 M--- Figure 29. o KM 2 3 4 LEGEND D 0 - 10% OM [llll]] 10 - 30% OM E] 30 - 70% OM ~ 70 -100% OM 5 Barataria prospect. Contoured section D-D'. . is 10% organic matter. Dashed line indicates -4 5 m) to which planimetering was carried ou t. Contour interval depth (about D' 6 7 8 E o - 1 - 2 - 3 - 4M-- Figure 30. E' 36 35 ~ ~ I I _ " ____ - -" 14 o KM 2 3 4 5 LEGEND D 0 - 10% OM !II 10 - 30% OM IEl 30 - 70% OM ~ 70 - 100% OM Barataria prospect. Contoured section E-E'. is 10% organic matter. Dashed line indicates -4.5 m) to which was planimetering was carried ou t. 6 7 Contour interval depth (about 8 9 10 fr' FREQUENCY 60 r'-'- '-'- '-'- '- ' -I o 20 40 60 80 100 +-% ORGANIC MATTER Values for each Cross Section 0-10% OM 10-30% OM 30-70% OM 70-100% OM A-A' ----- - - - B-B' 0-0' E-E' - '-'-'- Average ~ Figure 31. C 9 . 7O 25.45 47.35 7.50 20.49 28.99 43.02 7.50 19.12 19.25 56.73 4.91 34.15 25.61 36.28 3.96 23.88 16.96 58.26 0.89 23.47 23.25 48.33 4.95 LOUISIANA GEOLOGICAL SURVEY Barataria prospect. Frequency distribution plot for quantities of material resulting from the planimetering of contoured cross sections. Values for each cross section are quantities in percentage of the total. 44 270
Figure 32. Barataria prospect. Map showing depth to the 30% organic matter isopleth. Number next to core locations indicates actual depth (m). volume, including the bottom clays, is peat. Because construction of the isopleth map on the top of the clay was possible, the amount of peat above that surface is higher, namely 6.6%, which amounts to 20.95 x 10 6 m 3 , resulting in 2.51 x 10 6 metric tons (Table 1). Lake Pontchartrain Prospect The Lake Pontchartrain prospect, located between Lakes Pontchartrain and Maurepas (Fig s. 1 and 33), represents a delta flank depression, covered mostly with freshwater swamp and marsh. Access to the prospect and coring was extremely difficult because there are very few bayous and canals in the area. An attempt was made to penetrate the area by marsh buggy , but even with this vehicle, access was very limited. This area has been discarded as a possible prospect so as not to disturb the delicate cypress swamp environment. High-grade peat is present at or near the surface in a zone along Interstate 55 (I-55). In addition, peat was found in the eastern part of the area (Fig. 33). Comparing these results with infrared U-2 aerial photographs, one can assume that there is, on either side of I-55, a roughly rectangular area, totaling 82 km 2 , that contains peat. The average thickness of the peat is 1.08 m, resulting in a total of 10.53 x 10 6 metric tons (Table 1). METHODS Sampling Most sampling was done with a vibracore, and some was carried out with a McCauley peat sampler. The vibracore has two advantages over the auger: First, it allows for precise logging and correlation of boreholes. This is especially advantageous in the South Louisiana marshes, where much compaction takes place during coring. Also, if field work consists entirely 46 SCALE LEGEND SCALE FOR CORE DESCRIPTION r-r--, o 1 2km PEAT OTHER D "organics TANGIPAHOA ST. TAMMANY ASCENSION _J __ - I _.... I ST. JOHN //- I THE BAPTIST '\ / ST. I - CHARLES I JEFF. Figure 33. Lake Pontchartrain prospect. prospect area and cores. 47 Location of 22 24 ,:p ,j 25 '" '" .00 of coring, the vibracore enables one to drill holes without the necessity of logging them in the field. Field trip costs are thus reduced. Taking all this into account, we prefer vibracoring to augering; about 90% of all holes drilled were vibracores. Determination of Percent Moisture and Ash About 2000 samples were taken from every logged core or auger unit and analyzed. The cores were logged according to sedimentologic features and the classification system given in Table 2. Three samples of 20 g each were taken from every logged unit, and moisture and ash percentages were determined. Moisture was determined by leaving the sample in a porcelain crucible in a moisture oven at 105C for 24 hours. Ash percentage was established by putting the sample, after the moisture procedure was completed, in a muffle oven at 555C for the same amount of time. T he average value based on the three samples per unit was then calculated. Bulk Density Only vibracore samples were used for bulk density measurements; after the core was split lengthwise and logged, a half-core sample 5 cm long was taken from an organic-rich unit in the core. The sample was then placed in a graduated cylinder, which was previously filled with 150 ml water. The volume of the displaced water was taken as the volume of the sample. The contents of the cylinder were put in a beaker and placed in a moisture oven at 105C for 24 hours, after which dry weight was calculated. The method has an estimated +5% standard error. Results have been compared against depth and percent organic matter (Figs. 2 and 3, App. A). Because bulk density correlated reasonably well with moisture content, we believe that the method is reliable. 48 Calculation of Peat Tonnage Estimates of the amount of peat present were made by isopaching the peat bodies, calculating the volume, and multiplying it by the bulk density of the material. In the Sale-Cypremort and Barataria areas, isopaching of the peat beds proved to be an unreliable technique due to extreme horizontal and vertical variations within the organic-rich horizons; instead, the follOWing technique was used there. Values for percent organic matter, as established by lab analyses, were plotted on cross sections at the exact depth on each core location. The cross sections were then contoured at 10% organic matter isopleths (Figs. 17-19 and 27-30). Next, the total range (0-100% organic matter) was divided into four ranges: <10%, 10-30%, 30-70%, and >70% organic matter. Each range roughly represents certain sediment classes (Table 2): the <10% range represents clays; 10-30%, mucky clays and clayey mucks; 30-70%, mucks and peaty mucks; and >70%, peats. Because of the discrepancy in average ash content, as determined by DOE and LGS, 70% organic matter was chosen as representing peat. Each range was then quantified along the cross sections by planimetering its area and calculating the amount of each range in percentages of the total. Frequency distributions of the ranges appear to be very close for different cross sections and significantly different for different prospects for sediments containing more than 70% organic matter (Figs. 20 and 31). This method provides reliable comparisons between peat basins of different depositional settings. Planimetering was done to a depth of -4.5 m. The volume of the prospect area to that depth was calculated, and the amount of peat was calculated based on the percentage that resulted from the cross- sectional planimetering technique. 49 STATUS OF SURVEY This investigation completed the assessment of peat resources under the terms of the DOE contract. All originally proposed prospects and an additional prospect have been surveyed and sampled, and estimates have been established. It should be emphasized that virtually all of the Holocene deltaic and chenier plain of Louisiana can be considered a possible peat prospect. Thus, a complete assessment of Louisiana peat resources would require consideration of this entire area. The surveyed areas do represent, however, examples of the different kinds of peat that can be found in this coastal setting. FUTURE PLANS The state of Louisiana has funded peat research at the Louisiana Geological Survey for another year. Half-cylinder cores of most of the vibracores taken in 1982 have been kept at lDcC. Further research will emphasize the study of modern coal-forming environments. Research will be concentrated in the A very Island/ Sale-Cypremort and Barataria areas. Additional coring will be done in these areas and in offshore detrital peats; furthermore, the LGS will perform X-ray diffraction and radiography of clays and study early diagenetic features in peats. Micropaleontological and botanical analyses will be done in order to determine the original salinity and depositional setting of the peat-forming environments. Radiocarbon dating of the tops and bottoms of organic-rich horizons will be done iT! order to establish rates of accumulation of organic matter over time. 60 PUBLICATIONS Bailey, A., and E. C. Kosters, 1983a, Silicate minerals in organic-rich Holocene deposits in southern Louisiana, in Proc., workshop on mineral matter in peat: Los Alamos Nat. Laboratory, Los Alamos, N. Mex. [in press]. and , 1983b, Inorganic composition of Holocene peats in ----- southern Louisiana and comparisons with coals: Abstracts with Programs, Geol. Soc. America [in press]. Kearns, F. L., W. J. Autin, and R. G. Gerdes, 1982, Occurrence and stratigraphy of organic deposits, St. Mary Parish, Louisiana: Abstracts with Programs, Geol. Soc. America, Northeastern and Southeastern Sec., vol. 14, nos. 1 8. 2, p. 30. Kosters, E. C., and Bailey, A., 1983a, Peat deposits in the Mississippi River Deltaic Plain (abs.): Bull., Am. Assoc. Petro Geol., vol. 67, no. 3, p. 497. and , 1983b, Characteristics of peat deposits in the Mississippi River Delta Plain: Trans., Gulf Coast Geol. Soc., vol. 33 [in press]. 61 ACKNOWLEDGMENTS This project would not have been finished without the assistance of many people. First, I wish to thank those who helped to initiate the program: Robert Gerdes, who led most of the field trips in the fall of 1981; Fonda Kearns, who introduced me to numerous procedures, literature sources, and techniques; Whitney Autin, who headed the first part of the program; Todd Davison; and Robert Kemp. Work during the second part of the program was greatly assisted by David Pominski, who worked in the field, planimetered, and did other office chores; Paul Templet and Michael Halun, who took care of the equipment, designed and built a number of pieces, and assisted in the field; and Peggy Autin, who processed, indexed, and catalogued most laboratory samples. Thanks also go to Rick McCulloh, Laurel Gorman, Paul Kemp, Dianne Lindstedt, David DeBlanc, David Sonnenfeld, and Nameh Salem for field assistance and to Clay Kimbrell and Don Stadter for computer plotting and initial statistical work. Drs. James Coleman, Harry Roberts, and Arthur Cohen provided fruitful discussions and sugg estions. I am also indebted, first, to Raymond Bonin and Edmund Mcilhenny, Jr., of the Mcilhenny Co. of Avery Island for enabling the Survey to core the Avery Island site and, second, to Harvey Oudekerk and Robert Markman of the Markman Peat Co. for permitting the sampling of the Gueydan prospect. Furthermore, I would like to thank Dr. Everett Besch and his colleagues at the LSU School of Veterinary Medicine and Dr. James Gosselink of the LSU Department of Marine Sciences for use of their cooled storage facilities. I also benefited from the Louisiana Geological Survey administrators C.G. Groat, Harry Roland, and especially Don Bebout, who provided discussions, criticism, and moral support. 62 REFERENCES Adams, R. D., B. B. Barrett, J. H. Blackmon, B. W. Gane, and W. G. McIntyre, 1976, Barataria Basin--Geologic processes and framework: La. State Univ., Sea Grant Pub. T 76.00, 117 p. American Society for Testing and Materials, 1969, Standard classification of peats, mosses, humus and related products: Standard D2607-69, Philadelphia, Pa. Bailey, A., 1982, Personal commun.: Univ. Southwestern La., Dept. Geol., Lafayette, La. Boelter, D. H., 1969, Physical properties of peats as related to degree of decomposition: 606-609. Proc., Soil Science Soc. America, vol. 33, no. 4, p. Chabreck, R., and G. Linscombe, 1978, Vegetative type map of the Louisiana coastal marshes: La. Dept. Wildlife and Fisheries, New Orleans, La. Cohen, A. D., 1982, Personal commun.: Los Alamos Nat. Laboratory, Los Alamos, N. Mex. Coleman, J. M., 1966, Coastal sediments and late Recent rise of sea level, Vermilion, Iberia, and St. Mary Parishes, Louisiana: La. State Univ., Center for Wetlands Resources, Coastal Studies Inst., Baton Rouge, La., Rept. TR-17, 73 p. , 1982, Personal commun.: La. State Univ., Coastal Studies -------- Inst., Baton Rouge, La. Coleman, J. M., and W. G. Smith, 1964, Late Recent rise of sea level: Bull., Geol. Soc. America, vol. 75, p. 833-840. 53 Fisk, H. N., 1958, Recent Mississippi River sedimentation and peat accumula- tion, in E. Van Aelst, ed., Congres pour l'avancement des etudes de stratigraphie et de geologie du Carbonifiere, 4th, Heerlen: Maastricht, Netherlands, Compte Rendu, vol. 1, p. 187-199. Frazier, D. E., 1967, Recent deltaic deposits of the Mississippi River: Their development and chronology: Trans., Gulf Coast Assoc. Geol. Soc., vol. 17, p. 287-315. Frazier, D. E., A. Osanik, and W. C. Elsik, 1978, Environments of peat accumulation--Coastal Louisiana, in W. R. Kaiser, ed., Proc., Gulf Coast lignite conference: Geology, utilization, and environmental aspects: Univ. Texas at Austin, Bur. Econ. Geol., Austin, Tex., Rept. Inv. No. 90, p. 5-20. Ingram, R. L., and L. J. Otte, 1982, Peat deposits of Pamlimarle Peninsula-- Dare, Hyde, Tyrrell, and Washington Counties, North Carolina: Prepared for U.S. Dept. Energy, Contract DE-ACI8-79FCI4693, and N Carolina Energy Inst., 36 p. Kearns, F. L., 1982, Personal commun.: La. Geol. Survey, Baton Rouge, La. Kearns, F. L., W. J. Autin, and R. G. Gerdes, 1982, Occurrence and strati- graphy of organic deposits, St. Mary Parish, Louisiana: Abstracts with Programs, Geol. Soc. America, Northeastern and Southeastern Sec., vol. 14, nos. 1 & 2, p. 30. Kress, M. R., 1980, Preliminary assessment of peat resources, Louisiana Gulf Coast region: La. Geol. Survey, Baton Rouge, La., unpub., 45 p. McFarlan, E., Jr., 1961, Radiocarbon dating of Late Quaternary deposits, south Louisiana: Geol. Soc. America, vol. 72, no. 1, p. 129-158. Renton, J. J., C. B. Cecil, R. Stanton, and F. Dulong, 1979, Compositional relationships of plants and peats from modern peat swamps in support of a chemical coal model, in A. C. Donaldson, M. W. Presley, and J. G. Renton, eds., Carboniferous coal short course and guidebook: Volume 3: W. Va. Geol. and Econ. Survey Bull. B-37-3, Supp., p. 57-102. Shutt, F., & Sons, n.d., Florence peat deposits--Approximate thickness interpreted from cross sections and 1968 areal photos: F. Shutt & Sons, Civil Engineers. Lake Charles. La unpub. Weller, J. M., 1959, Compaction of sediments: Bull., Am. Assoc. Petro Geol., vol. 43, no. 2, p. 272-310. Gueydan Prospect (Btu) 9227 A very Island Prospect (Btu) 8365 8292 APPENDIX A Btu Values Sale-Cypremort Prospect (Btu) 8929 9469 8528 8161 8417 8766 8128 8305 7861 8694 8694 8169 8888 7889 7431 8599 7808 8973 8785 7268 8306 9294 9300 9315 8365 8292 67 Barataria Prospect (Btu) 7862 8223 8484 Lake Pontchartrain Prospect (Btu) 8620 8371 9635 9470 8491 8631 7687 7917 8577 8804 APPENDIX B Bulk Density Data Organic Matter Moisture Bulk Density Depth Prospect (%) (%) (g Icm 3 ) (cm) Gueydan 84.7% 92.0% 0.08 g Icm 3 - 30 cm 73.8 91.2 0.09 -148 72.0 92.2 0.10 -188 Avery Island 68.5% 91.7% 0.08 g/cm 3 - 34 cm 73.5 89.2 0.10 -144 Sale-Cypremort 50.2% 87.6% 0.12 g Icm 3 -103 cm 90.3 91.3 0.10 -113 90.3 91.3 0.10 -164 Barataria 70.7% 91.2% 0.09 g/cm 3 - 19 cm 36.5 84.7 0.08 - 23 74.5 90.6 0.10 - 28 73.7 89.8 0.10 - 30 40.2 86.7 0.09 - 33 68.3 89.6 0.12 - 40 89.9 99.8 0.11 - 48 54.0 88.6 0.11 - 48 70.7 87.6 0.14 - 48 74.5 90.5 0.10 - 53 70.9 88.4 0.10 - 53 58.6 87.8 0.12 - 53 83.0 89.4 0.09 - 58 88.6 63.5 0.13 - 58 79.2 89.5 0.10 - 63 62.9 89.7 0.16 - 63 55.3 87.8 0.15 - 68 57.8 85.5 0.16 - 78 56.2 88.3 0.09 - 83 58 APPENDIX B (cont.) Organic Matter Moisture Bulk Density Depth Prospect (%) (%) (gfcm 3 ) (cm) Barataria 82.2% 91.2% 0.13 gfcm 3 - 83 cm (cont. ) 84.6 88.7 0.11 - 85 36.5 84.7 0.12 - 93 81.5 87.2 0.11 -103 70.9 87.3 0.11 -103 76.1 91.4 0.07 -113 71.6 84.7 0.15 -113 53.2 81.6 0.10 -128 59.8 84.2 0.14 -144 78.5 88.3 0.10 -168 64.6 89.2 0.13 -168 49.7 83.3 0.18 -169 80.2 89.0 0.10 -188 40.9 77.9 0.18 -203 65.0 88.2 0.09 -213 79.9 88.8 0.13 -228 42.2 84.5 0.15 -238 77.0 88.7 0.13 -253 65.8 88.2 0.14 -287 56.3 84.2 0.15 -288 65.9 87.0 0.16 -301 43.9 82.0 0.18 -313 44.0 83.2 0.14 -315 65.8 88.2 0.15 -318 51.3 83.7 0.13 -343 Lake Pontchartrain I 78.9% 90.7% 0.12 g fcm 3 -110 cm 69 APPENDIX C Sale-Cypremort Prospect: Percent Moisture and Percent Organic Matter DEPTH: < 1 m DEPTH: 1-3 m DEPTH: > 3 m Organic Organic Organic Moisture Matter Moisture Matter Moisture Matter (%) (%) (%) (%) (%) (%) 88% 58% 91% 76% 86% 47% 90 73 90 73 86 64 87 51 89 76 79 40 88 71 84 39 83 62 82 45 90 86 79 48 89 69 85 58 84 45 90 64 86 76 83 40 87 55 90 88 84 48 80 34 84 45 79 36 83 35 83 60 81 46 89 61 90 79 83 50 87 54 89 80 84 62 87 53 81 35 85 61 90 74 89 72 82 45 81 35 88 77 86 59 87 52 84 44 82 35 90 72 87 50 90 88 88 62 87 74 85 43 86 39 90 74 88 66 87 67 89 83 76 47 88 73 86 72 85 60 88 58 89 84 88 79 60 APPENDIX D Barataria Prospect: Percent Moisture and Percent Organic Matter DEPTH: < 1 m Organic Organic Organic Moisture Matter Moisture Matter Moisture Matter (%) (%) (%) (%) (%) (%) 89.3% 52.8% 86.9% 43.5% 89.6% 72.4% 87.9 42.4 87.7 47.0 88.7 56.8 86.5 49.6 81.1 37.8 87.5 70.7 84.9 36.3 87.2 59.3 88.4 70.9 91.2 70.7 88.7 73.0 89.4 83.0 88.6 54.0 84.7 51.3 90.9 74.9 88.7 56.5 89.0 67.9 85.2 52.5 88.3 51.4 90.5 81.7 90.1 78.1 89.6 68.3 84.1 37.3 87.6 61.5 90.6 69.6 89.9 79.8 92.9 63.6 87.8 58.6 I 91.1 62.7 89.7 62.9 " 88.0 56.0 85.2 60.6 I 76.5 46.6 90.5 70.1 I 91.1 58.6 86.9 67.5 I 89.7 77.9 81.0 38.1 I 91.9 82.2 88.6 63.5 I 89.8 73.7 86.8 76.0 I 85.0 45.8 81.5 45.9 I 86.4 64.1 82.6 55.1 I 86.7 40.1 80.9 44.1 I 83.3 40.2 88.3 56.2 I 88.3 60.6 84.2 38.4 I 88.6 59.2 85.5 57.8 I 88.9 79.4 74.0 51.9 I 85.1 36.1 91.7 77.3 I 87.2 53.7 84.1 52.4 61 APPENDIX D (cont.) DEPTH: 1-3 m DEPTH: > 3 m Organic Organic Organic Moisture Matter Moisture Matter Moisture Matter C%) C%) (%) (%) (%) (%) 87.8% 55.5% 88.9% 57.9% 80.4% 36.7% 83.3 49.7 87.5 71.6 85.6 44.4 87.9 42.4 80.6 43.3 82.5 36.6 90.5 74.6 84.7 71.6 78.9 41.7 87.9 52.5 88.3 77.7 83.7 69.3 87.9 54.6 87.3 70.9 83.2 44.0 89.3 64.6 84.6 37.4 83.7 51.4 87.8 55.3 89.0 80.2 87.0 62.9 87.5 77.1 87.3 76.9 77.0 35.8 84.3 39.6 88.1 65.0 85.8 59.7 83.1 52.9 88.7 77.0 81.9 36.7 88.0 63.5 81.7 35.6 88.9 39.4 82.7 41.4 88.9 79.9 88.3 67.0 87.3 69.6 84.5 42.1 84.0 44.6 77.7 36.7 85.2 43.9 I 84.2 56.3 84.3 48.5 85.4 61.2 I 81.3 39.4 85.7 45.7 82.7 49.2 I 82.0 43.9 83.1 44.7 77.9 40.9 I 80.7 36.7 88.8 72.7 89.8 68.2 I 86.0 56.9 86.6 59.8 87.4 55.0 I 82.6 38.9 84.2 59.6 81.0 62.4 I 81.7 47.5 87.7 69.1 92.1 79.5 I 86.3 68.1 87.4 54.0 82.9 42.3 I 81.9 58.8 88.3 78.5 77.4 36.8 I 84.8 44.6 84.9 40.4 I 89.9 68.8 88.7 84.6 I 83.8 50.2 87.0 65.9 I 81.8 47.5 81.2 47.6 I 84.7 36.5 84.1 54.8 II 89.6 67.3 83.1 55.2 " 91.1 79.6 82.8 40.6 " 87.9 74.5 II 62 REPORTS DISTRIBUTION LIST Contracting Officer Grand Forks Energy Technology Center Box 8213, University Station Grand Forks, ND 58202 Technical Project Manager Mr. Frank I. Honea Grand Forks Energy Technology Center Box 8213, University Station Grand Forks, ND 58202 U.S. Department of Energy Technical Information Center P. O. Box 62 Oak Ridge, TN 37830 Mr. Sam Spadone FE-23, GTN U.S. Department of Energy Germantown, MD 20545 Assistant Chief for Prosecution U. S. Department of Energy California Patent Grou p P.O. Box 808 L-376 Livermore, CA 94550 Gas Research Institute Attn: Mr. John Happe 8600 W. Bryn Mawr Ave. Chicago, IL 60631 63
(Problem Books in Mathematics) Antonio Caminha Muniz Neto - An Excursion Through Elementary Mathematics, Volume III - Discrete Mathematics and Polynomial Algebra (2018, Springer)