Professional Documents
Culture Documents
2001 Tokyo
Denryoku
t-BuOK
High
180-210 C / Atm
Own Process
High
High
Low
200-250 C / Atm
BCD
High/ Low
300-350 C / Atm
Ebara
High
Low
-1st stage can be applied under 15% PCB concentration. -PCB concentration in 2nd stage should be 200 ppm under. -Cost of t -BtOK is very expensive. -High reaction temperature may cause of fire. -Very difficult to control operation temperature.
Yes L1
Req.
TBD
Yes L1
SD
High Low
Own Process
Low
Med.
-Low Reaction Temp. Yes -Simple Process. -Oil product is easily L1 separated. -Na is produced by himself.
Yes
Cate gory
Method OSD
Description Dechlorination occurs by Dispersed Sodium at low temperature and atmospheric condition. Good reactivity. Products are Biphenyl etc. Dechlorination occurs by Dispersed Sodium at low temperature and atmospheric condition. Good reactivity. PCB and NaOH are solved in Hydrogen donor solution, and UV irradiation. Dechlorination is taken place and Cl will be react with NaOH. In 2nd stage reaction, PCB remained is dechlorinated by Catalyst to Biphenyl.
Company Nuclear Fuel Ind. Ltd. /Sum itomo Corp/Su mitomo Denko Shinko Pantec
Cost
Install Chem
Characteristics -Low reaction temp. -Simple process. -High cost Na, imported from Canad a.
Approval
Tech Plant
Starting Date
Low
High
Yes L1
Yes 1999
Sumitomo
Denko
SP
High
Na dispersed
Low
High
Low 1st React ion 2nd React ion UV/NaOH /IPA Pd/C cat
UV/Catalyst
Toshiba
Own Process
High
Mid.
-Low reaction temp. -Simple process. -High cost Na, imported from Canada -Low reaction temp. -Rapid reaction. -Complicated process. -Safety for Mercury lamp -High catalyst cost.
Yes L3
No
TBD
Yes L3
Req.
Approval: Tech --- Approved Level (L) of technology by authority. L1: Plant is in operation or construction. L3: Bench scale tests have been completed. Plant --- Status of Construction: U/C ; Under Construction Req. ; Requesting
L2: P ilot plant test has been completed. L4: Laboratory tests have been completed
TBD To Be Determined
Cate gory
Company Organo
Cost
Install Chem
Characteristics
Approval
Tech
Plant
Starting
High
Low
-High pressure and Yes high temperature -Corrosion problem L2 by severe condition.
Yes -High pressure and high temperature -Corrosion problem L1 by severe condition.
No
Date TBD
Oxidation reaction by using high temp and high pressure hot water.
Low/ High
MHI
(Mitsubishi
Heavy Industry)
High
Low
Reduction by high temperature hydrogen. 1st Stage, PCB is decomposed by UV. 2nd Stage,PCB is decomposed by Biodegradation
Low/ High
Hydrogen
High Low
Amb/Atm 30 C/ Atm
High
Low
Yes L2
No
TBD
High
Low
Bacteria
Mechanochemical
Low/ High
CaO, SiO2
Amb/Atm
Own process
Low
Low
-Long reaction time for both stages. -Safety for Mercury lamp -Bacteria -Treatment of bacteria sludge. -Low temp/low press. -Easy operation -Low Installation and operation cost.
Yes L3
No
TBD
No
(U/A) L4
No
TBD
Approval : Tech - Approved Level (L) of technology by authority. L1: Plant is in operation or construction. L3: Bench scale tests have been completed. Plant Status of Construction: U/C ; Under Construction Req. ; Requesting
L2: P ilot plant test has been completed. L4: Laboratory tests have been completed
TBD To Be Determined