Mark Scheme (Results) Summer 2010

IGCSE

IGCSE Chemistry (4335) Paper 1F

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IGCSE CHEMISTRY 4335/1F SUMMER 2010 SECTION A Question Mark Acceptable answers Notes Total

i ii iii iv v i ii

b c

M1 M2 M3 M1 M1 M1 M1 M1 M1

neutron proton electron nucleus 12 5 2.3 Accept any punctuation (eg , / )) or none helium / beryllium / magnesium / calcium / strontium / barium / radium / He / Be / Mg / Ca / Sr / Ba / Ra hydrogen / helium / H / He Accept H2 it has isotopes / atoms have different numbers of neutrons / it Reject different numbers of protons / is an average electrons

1 1 1 1 1 1 1 1 1 1

Question

Mark

Acceptable answers

Notes

Total

i ii

M1 M1 M3 M1 M2 M1 M2 M3

air / atmosphere

i ii iii

re any reference to method natural gas / North Sea gas / hydrocarbons / named fraction / Ignore methane water / steam iron / Fe Ignore reference to oxide(s) / oxidation states II and III 350 - 500 100 - 350 cross in box 3 cross in box 4 cross in box 5

1 1 1 1 1 1 1 1

Question

Mark

Acceptable answers

Notes

Total

a b i ii

M1 M2 M1 M1

phosphorus potassium cross in box 1 cross in same box as in bi

Accept answers in either order Ignore symbols Consequential marking from bi

1 1 1 1

Question

Mark

Acceptable answers

Notes

Total

a b c d

M1 M1 M2 M1 M1 M2

denser than air / greater molar mass than air or nitrogen or oxygen limewater / aqueous calcium hydroxide / Ca(OH)2(aq) milky / cloudy /chalky / white precipitate / white solid copper(II) carbonate copper(II) oxide + carbon dioxide green black

Accept heavier than air/nitrogen/oxygen Accept (aq) / solution / dissolved in water as equivalent to aqueous Ignore bubbles Both (II) needed Reject any other substances Ignore heat Ignore qualifiers such as light / dark Reject all other colours

1 1 1 1 1 1

Question

Mark

Acceptable answers

Notes

Total

a b c

M1 M2 M1 M1 M2

cross in box 1 cross in box 4 filter or filtration / centrifuge and decant wash (with water) / add water and filter dry / heat / warm / evaporate / leave in warm place / spread onto filter paper / place in (warm) oven

Accept description of process Reject any wrong method Accept description of process Accept description of process Ignore wrong consequence (eg heat to remove sodium nitrate) If M1 and M2 in wrong order, award1/2 Reject any wrong method in both M1 and M2

1 1 1 1 1

Question

Mark

Acceptable answers

Notes

Total

a b

M1 M1 M2 M3 M1 M2

covalent low weak molecules shared pairs of electrons between O and both H atoms two electrons in O inner shell AND four more electrons in O outer shell AND no extra electrons in H

If high given for M1, then accept strong Mark b independently except that if high given for M1, then accept strong for M2 Electrons can be shown as dots / crosses / e / any combination of these Accept these electrons paired or unpaired

1 1 1 1 1 1

M1 M2

ii iii

M1 M1

M2 dependent on M1 blue Ignore qualifiers such as light / dark Reject all other colours white / grey / pale(r) blue Accept all combinations of these Reject all other colours anhydrous copper(II) sulphate (II) not needed becomes blue / heat produced / temperature rises / forms If different colour given in di(M1), accept this hydrated copper(II) sulphate / goes back to original colour colour here

1 1 1 1

Question

Mark

Acceptable answers

Notes

Total

i ii

M1 M1 M2

propene / propylene yellow / orange / brown (goes) colourless / decolourised

M1 M2

(contains) hydrogen and carbon / H and C (atoms) only

Accept prop-1-ene Accept any combination of these colours Reject red Ignore clear Ignore discoloured Do not award mark for single colour if not clear whether start or finish Reject molecules / ions Accept other words with equivalent meaning, such as purely / solely / entirely Award M2 only if correct elements mentioned in M1 M2 dependent on M1 Accept in either order Ignore state symbols Award 1 mark for both correct formulae but incorrect coefficients Accept H4C2 and OH2 SECTION A TOTAL: 55 MARKS

1 1 1

1 1

ii iii c d

M1 M1 M2 M1 M2 M1 M2

only single bonds / no double bonds / no multiple bonds double bond between two carbon atoms each carbon bonded to two hydrogen atoms cross in box 1 cross in box 5 C2H4 / CH2CH2 / CH2=CH2 H2O

1 1 1 1 1 1 1

SECTION B Question Mark Acceptable answers Notes Total

i ii

M1 M1 M1 M1 M1 M2

b c

i ii

i ii

M1 M2 M1

bubbles / fizzing / effervescence / metal gets smaller / white Ignore metal dissolves / gas produced trail Reject all answers in a(ii) melts / forms a ball / darts / moves (on surface) / floats Ignore reference to flames Reject all answers in a(i) calcium hydroxide NaOH hydrogen / H2 Ignore H (squeaky) pop with burning splint /burns with a (squeaky) pop Accept other words such as explosion / lighted spill or taper Reject glowing splint Ignore references to air/splint extinguished No CONSEQ from wrong gas blue / purple Ignore qualifiers such as light / dark / bright OH / hydroxide yellow / orange Ignore hydroxyl Ignore qualifiers such as light / dark / golden / bright Reject all other colours

1 1 1 1 1 1

1 1 1

Question

Mark

Acceptable answers

Notes

Total

a b c d

i ii

M1 M2 M1 M1 M1 M2 M1 M2

hydrogen peroxide manganese(IV) oxide / manganese dioxide (gas) syringe catalyst / to speed up the reaction / lower activation energy (s) for both PbS and PbSO4 (aq) for H2O2 and (l) for H2O PbS / lead sulphide / sulphide ion / S2 / sulphur in lead Ignore oxidation numbers if given sulphide only award if M1 correct or sulphur gains oxygen/O/O2 ignore loss of electrons increase in oxidation state S + O2 SO2 acidic / (forms) H+ (ions) / sulphurous acid / sulphuric(IV) acid orange green Ignore state symbols Accept S2 or S8 Reject sulphuric acid / sulphuric(VI) acid Accept blue-green

1 1 1 1 1 1 1 1 1 1 1 1

i ii iii

M1 M1 M1 M2

Question

Mark

Acceptable answers

Notes

Total

10

M1 M2 M3

electron transfer from magnesium/Mg to chlorine/Cl Mg loses two electrons and (each) Cl gains one electron

All marks can be scored from suitably annotated diagrams Award 0/3 if any reference to sharing electrons Ignore covalent M3 dependent on M2

1 1 1

b c

M1 M2 M1 M2 M3

Ignore number of electrons M2 independent of M1 + and ions / oppositely charged ions / Mg2+ and Cl Need idea of + and - charge strong (electrostatic) attractions (within lattice) accept strong (ionic) bonds reject covalent bonds / molecular attraction lot of energy needed to overcome attractions / break bonds / Do not accept loosening bonds separate ions Ignore hard to break any mention of intermolecular or intramolecular loses M1 and M2 So strong intermolecular forces need lots of energy to overcome scores M3

magnesium / Mg loss of electrons / increase in oxidation state

1 1 1 1 1

Question 11 a i ii

Mark M1 M1 M2 M3 M4

Acceptable answers fractional distillation / fractionation crude oil heated (vapour) passed into column/tower

Notes

Total 1 1 1 1 1 1 1 1 1 1 1 1 1

M1 given even if describe laboratory process. Only M1 possible if describe lab process or mention cracking/breaking bonds If crude oil heated in fractionating column, then give only 1 mark for M1 and M2

i ii iii iv

M1 M1 M1 M1 M2 M1 M2 M3

fractions collected at different heights correct reference to boiling point / molecular size / Do not award if specified temperature temperature gradient/hot at bottom cooler at top gradient is wrong way round All marks can be gained from suitable diagram bitumen gasoline bitumen Accept answers in either order refinery gases Accept naphtha in place of either fuel oil oxygen Ignore air Accept answers in either order carbon dioxide Accept steam in place of water water All marks in c are independent Ignore heat

i ii

M1 M1 M2 M3

CnH2n+2 same/similar chemical properties / same functional group gradation in physical properties / gradation in specified physical property (eg boiling point) neighbouring members differ by CH2

Accept other letters/symbols such as x accept CnH2(n+1) reject trend in chemical properties reject same/similar physical properties Ignore references to general formula and references to saturation/unsaturation/specific functional group Accept any two for 1 mark each SECTION B TOTAL: 45 MARKS PAPER TOTAL: 100 MARKS

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