Southwestern University College of Arts and Sciences Deparment of Chemistry Chem 5 Lecture Final Exam: Organic Chemistry Lab

Group No. Name: Date: Test 1 Seat 2 Multiple choices. Shade the box that corresponds to the letter of the correct/best answer. Two points each number. An answer with erasure is 1 point only if correct. Shaded answers using pencil will be erase. [1] The general formula of ester is: A B C D [A] R-COO-R [B] R-CO-R [C] R-CO-OH [D] R-CO-NH2 [2] The reaction between alcohol and carboxylic acid to make esters. It is also the opposite of hydrolysis of esters. [A] Esterification [B] Condensation [C] Hydrolysis [D] Neutralization [3] Copper(II) sulfate solution contains blue hexaaquacopper(II) ion. Addition of excess of ammonia or diethylamine will form a darker shade of blue. The ammonia or diethylamine acts as a base. What type of base? [A] Arrhenius base [B] Bronsed-lowry base [C] Lewis base [D] None of the above. [4] Amides are present in nature and technology as structural materials. The amide linkage is easily formed, confers structural rigidity, and resists hydrolysis. Which of the following material is not an amide? [A] Aramid [B] Twaron [C] Kevlar [D] None of the above [5] In preparing dye bath, what is added to the dye in dyeing silk or wool? [A] salt [B] venigar [C] water [D] alcohol [6] In preparing dye bath, what is added to the dye in dyeing cotton or linen fabric? [A] salt [B] venigar [C] water [D] alcohol [7] What is the color of precipitate of the reaction of ammonia or diethylamine with FeCl3? [A] Blue [B] Red [C] Yellow [D] None of the above [8] Copper(II) sulfate solution contains blue hexaaquacopper(II) ion. The formula of hexaaquacopper(II) ion is: [A] [Cu(H2O)6]2+ [B] [Cu(H2O)6]+ [C] [Cu(OH)6]2+ [D] [Cu(H)6]2+ 3+ [9] The reaction of Fe and OH will form hydrate ferric oxide [A] Fe2O3.H2O [B] Fe2O3 [C] Fe2O3.2H2O [D] Fe2O3.3H2O [10] In the hydrolysis of amide, what is produced? [A] ammonia and alcohol [B] alcohol and carboxylic acid [C] ammonia and carboxylic acid [D] amine and alcohol A B C D

A A

B B

C C

D D

[11] The dissociation of FeCl3 to ions will form: [A] Fe3+ and Cl[B] Fe2+ and Cl2 + [C] Fe and Cl [D] Fe3+, Fe2+ and Cl[12] Copper(II) sulfate solution contains blue hexaaquacopper(II) ion. Addition of small amount of ammonia or diethylamine will form a darker shade of blue. The ammonia or diethylamine acts as a base: What type of base? [A] Arrhenius base [B] Bronsed-lowry base [C] Lewis base [D] None of the above. [13] Ammonia water reacts with water and partially dissociates into ions. What is the reaction of litmus paper with this ammonia water solution? [A] red to blue [B] blue to red [C] red to red [D] depends on the concentration of the solution [14] Ammonia partially dissociate in solution because it is a weak base. What are the primary ions present when ammonia dissociates? [A] NH3 and H2O [B] NH3 and NH4+ [C] H2O and OH [D] OH- and NH3 [15] In the hydrolysis of urea and acetamide, the product that is responsible for the change in color of red litmus paper to blue. [A] OH[B] NH3 [C] N2 [D] NH4+ [16] The odor of ammonia and diethylamine is: [A] Fishy pungent [B] Wintergreen oil [C] Sweet [D] Solvent [17] What type of reaction is this: CH3COOCH2CH3 + H2O = CH3COOH + CH3CH2OH [A] Hydrolysis of ethanamide under neutral condition. [B] Esterification of ethyl acetate under alkaline condition [C] Hydrolysis of ethyl acetate under alkaline condition [D] Hydrolysis of ethyl acetate under acidic condition [18] Heating urea will form a white residue, what is the name of the residue? [A] Urea nitrate [B] Urea oxalate [C] Biuret [D] None of the above [19] Which of the following is a secondary amine? [A] [B]

A A

B B

C C

D D

A A

B B

C C

D D

[C]

[D] None of the above

[20] Which of the following does not belong to the group? [A] NH3 [B] R-NH2 [C] R-NH-R [D] R-N-(R)2 [21] In Biuret test with a heated urea, the color of the solution changes to violet with the addition of copper solution. The result of this color change is due to the presence of [A] peptide bonds of the formed compound.

A A

B B

C C

D D

[B] ionic bonds of the formed compound. [C] hydrogen bonds of the formed compound. [D] hydrophobic interactions of the formed compound. [22] Common name of pentyl ethanoate is: [A] methyl salicylate [B] ethyl acetate [C] amyl acetate [D] none of the above [23] The formula of urea is: [A] H2N-CO-NH2 [B] H2N-COH-NH2 [C] (H2N)2CO2 [D] H2C-CH-CH2 [24] In the experiment of hydrolysis of esters under alkaline conditions, the final product was added with dilute sodium hydroxide and a few drops of 15% FeCl3. What is the color of the final product after heating? [A] deep yellow color [B] colorless [C] deep red color [D] green [25] Oxalic acid added to urea will form: [A] Uric acid [B] Urea Oxalate [C] Urea nitrate [D] None of the above [26] In the formation of urea nitrate from urea and reagent a white precipitate is formed. What is the name of the reagent used? [A] Nitrate [B] Nitrogen [C] Ammonia [D] Nitric acid [27] Why is the fabric submerged in the dye bath for 20-30 minutes? [A] To remove excess dye [B] So that the color will stick on the fabric evenly. [C] To boil the solution properly. [D] None of the above. [28] Amines are derivative of ammonia. What part or parts of the ammonia is/are replaced to form amines? [A] H2 group [B] H group [C] NH group [D] NH2 group [29] What type of reaction is this: CH3COOCH2CH3 + NaOH CH3COONa + CH3CH2OH [A] Hydrolysis of ethanamide under neutral condition. [B] Esterification of ethyl acetate under alkaline condition [C] Hydrolysis of ethyl acetate under alkaline condition [D] Hydrolysis of ethyl acetate under acidic condition [30] Amides are carboxylic acid derivate. What part of the carboxylic acid is replaced to make an amide? [A] -OH group [B] -COOH group [C] -H group [D] COH group [31] The density of methyl benzoate and methyl-2-hydroxybenzoate are [A] more dense and more dense respectively. [B] less dense and more dense respectively. [C] less dense and less dense respectively. [D] more dense and less dense respectively. [32] Strong acids like nitric acid in aqueous solution will [A] fully dissociate in solution. [B] not dissociate in solution. [C] will partially dissociate in solution. [D] form OH- ions [33] The general formula of amides is: [A] RCOOH [B] RCONH2 [C] RNH2 [D] RCOOR [34] This substance is wide spread in nature and are widely used in industry. In nature, fats are derived from glycerol and fatty acids. [A] Ester [B] Amides [C] Amines [D] Dyes A A A B B B C C C D D D

A A

B B

C C

D D

A A A

B B B

C C C

D D D

[35] Which of the following is not a application of amines? [A] Dyes [B] Drugs [C] Gas treatment [D] None of the above [36] The reaction of ammonia with water is: [A] NH3 + H2O = NH4+ + H+ [B] NH3 + H+ = NH4+ + [C] NH3 + H2O = NH4 + OH [D] NH4+ + H2O = NH4+ + OH[37] A carboxylic acid derivative that is responsible for the aroma of many fruits, including pineapples, bananas, durians, pears and pineapple. [A] Ester [B] Amides [C] Amines [D] Dyes [38] Sodium acetate dissociates into: [A] sodium and acetic acid ions. [B] acetate and sodium acetate ions. [C] sodium and acetate ions. [D] sodium and sodium acetate ions. [39] After immersing the fabric in the dye bath, why is the fabric rinsed in cold water until water is clear? [A] To remove excess dye [B] So that the color will stick on the fabric evenly. [C] To boil the solution properly. [D] None of the above. [40] The odor of amyl acetate and methyl salicylate are [A] pleasant and unpleasant respectively. [B] unpleasant and unpleasant respectively. [C] pleasant and pleasant respectively. [D] unpleasant and unpleasant respectively. [41] Water and esters (amyl acetate, ethyl acetate, methyl benzoate, and methyl salicylate) at equal volume are: [A] miscible [B] immiscible [C] soluble [D] insoluble [42] Esters are carboxylic acid derivative. What part of the carboxylic acid is replaced to make an ester? [A] -OH group [B] -COOH group [C] -H [D] COH group [43] Systematic name of methyl salicylate: [A] methyl benzoate [B] methyl-2-hydroxybenzoate [C] ethyl ethanoate [D] pentyl ethanoate [44] Weak acids like acetic acid in aqueous solution will [A] fully dissociate in solution. [B] not dissociate in solution. [C] will partially dissociate in solution. [D] form OH- ions [45] The product of hydrolysis of esters: [A] ammonia and carboxylic acid [B] alcohol and carboxylic acid [C] alcohol and ammonia [D] carboxylic acid and ammonia

A A A

B B B

C C C

D D D

A A A

B B B

C C C

D D D

Test 2 Essay. Answer the question as best as you can. Partial points are given depending on the weight and accuracy of the answer. (10 points each) [1] Compare and contrast esters, amides and amines in terms of structure, physical properties, and reaction.

[2] Discuss the dyeing method.

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