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s
,) at
the pinch-point can be found.
m.,(h1 . ,-h2 . ,) '" mex'(H1-H2)
.. , '" -
(1 )
(2)
(3)
If constant specific-heat is assumed for the exhaust gas, the steam
temperature at the pinch-point can be found more easily.
(4)
However, for this study the formulation for variable specific heat is
applied. It should be noted that when applying Eq. (1) caution must
be made when evaluating the specific heat (Cp2.
s
') for steam near the
critical temperature. The specific heat changes very rapidly as the
function of temperature above and near the critical point. For a
supercritical stage with reheating, the same procedure can be applied
except for Eq. (2) which has to be rewritten and an extra heat balance
equation needs to be added (Eq. 6).
(h1 . ,-h2 . ,HH 1-H3) '" (H1-H2)'(h 1 . ,-h3 ... ) (5)
mex'(H1-H3) '" ms,(h1.s,-h3 . ,) + mreh(hl.reh-h3.reh) (6)
The HRSG heat transfer area calculation is carried out by an
integration method for each type of heat exchanger (superheater,
evaporator, economizer and preheater). Acounterflow heat exchanger
model is applied. The integration model ensures that the effect of
variable specific heat capacities is taken into account. This is
important for high pressure superheated steam and water near
saturation. A counterflow heat exchanger model may not be accurate
in all cases, but when comparing heat transfer areas as in this study,
-Waier ai supercritical pressure can hardly be defined as either water or steam,
but is here referred to as steam.
5
such a model should be sufficient.
The steam turbine expansion is broken into a number of sections
which correspond to the number of HRSG pressure stages. Each
section is computed by an individual dry isentropic step efficiency.
The efficiency for the LP section is corrected for moisture if the
expansion crosses into the wet region. The LP expansion is broken
into steps, and the efficiency for each step is corrected for moisture
when the exit quality is below that for the onset of condensation. This
"Wilson line" quality is normally between 0.95-0.98. The efficiency
degradation is assumed to be an exponential function (7) of mean
step steam quality.
(7)
The exponent c is typically in the range 1 .0-1 .3, and is chosen to be
1.15 for this study. That means the penalty for moisture is a decrease
in isentropic efficiency with a factor typically in the range 0.63-0.75
for every extra percent of moisture. The steam turbine model also
takes into account a throttle valve loss, steam leakages through the
steam turbine seais, LP section leaving loss and steam turbine and
generator auxiliary power requirements.
The condenser model is a water-cooled counterflow heat exchanger.
The cooling water pressure drop and the required pump work are
calculated.
Heat and exergy balances are carried out for all components in the
model. To ensure that there are no errors in the model, an overall
system heat balance is carried out as well as an overall exergy
balance.
The net efficiency of the CC is here defined by Eq. (8).
Tlcc '"
W
Gr
+ W
sc
- W
AlJX
m,.LHV
WGPW
SC
'" power output at the generator terminals
W NJX auxiliary power demand and pump work
EXERGY ANAL YSIS
(8)
Traditional first-Iaw cycle analysis based upon component
performance characteristics coupled with energy balances invariably
lead to a correct final answer. However, such analysis cannot locate
and quantify the sources of loss which lead to that result. This is
because the first lawembodies no distinction between work and heat,
no provision for quantifying the Quality of energy. These limitations
are not a serious drawback when dealing with familiar systems, since
an intuitive understanding of the different parametric influences on
system performance and a second-Iaw qualitative appreciation of
"grade-of-heat" and effect of pressure loss can be developed. When
analyzing novel and complex thermal systems, however, such an
understand ing must be supplemented by more rigorous quantitative
methods. Second-Iaw analysis, or exergy analysis, provides these
tools. Second-Iaw analysis is no substitute for first-Iaw analysis,
rather, a supplement.
The quantity energy can be split into exergy and anergy.
Energy '" Exergy + Anergy
Anergy is energy in equilibrium with the ambient conditions and
cannot be converted to work, while exergy is the proportion of energy
which theoretically can be converted to work. The exergy of a flow
stream for a given pressure Pl and temperature t
1
can be computed
by the following expression:
(9)
where,
ha = h(p.,t.)
Sa = s(P.,t.)
For an ideal gas, the term S,-S. can be wrilten:
S,-Sa = - (10)
a a
To quantify the loss of exergy for a component, an exergy balance
is applied. Fig. 4 shows a counterflow heat exchanger and the
quantities related to an exergy balance. The loss of exergy for the
heat exchanger is
(11 )
EH 2 PH,2 l2 SH,2
HEAT
EH,I PH,1 TH,I SH,1
Ec,1 PC.I li SC,I
EXCHANGER
EC,2 PC,2 TC.2 SC,2
/
Figure 4 Exergy balanee of a counterflow heat exchanger
The steam cycle is a closed loop. Exergy in a stream leaving a
component is transferred to the next component, and is therefore not
lost from the system. The exception is at points where exergy is
deliberately rejected from the system sueh as the HRSG stack and
the condenser cooling water. The loss of exergy for all other
components in the steam eycle can be calculated in a similar way as
shown in the above example. When adding up all losses of exergy
plus the generated work, this should equal the exergy of the gas
turbine exhaust gas entering the HRSG. At this point the exergy.
efficiency can be defined
Wnet,out EHASG,ln - L Ela ..
'I1exergy = -E-- = E
HASG,in HRSG,ln
(12)
and further, the maximum thermal effieieney referred to the exhaust
gas is given by
where,
llthermal,max =
EHASG,ln
HASG,in
0HRSG,in = mex ' (H HRSG,in -Ha)
(13)
(14)
and where, HHRSG,in is referred to ambient conditions which means
Ha = O
The maximum thermal efficiency deseribes the thermodynamic
limitation for the conversion of heat to work. The exergy efficiency
accounts for internal steam cycle "imperfeetions", such as heat
6
exchanger temperature differences, "mismatched" heat exchanger
temperature profiles, heat losses, pressure losses, mixing losses,
mechanical losses, generation of entropy in compression and
expansion processes and rejection of exergy to the surroundings. By
eombining Eqs. (12) and (13) a relation belween work and heat is
obtained
W net,out = 0HASG,ln' 'I1therrrel,max' 'fJexel1lY
(15) .
RESULTS AND DISCUSSION
Parametric studies were carried out for combined cycles us ing the
Siemens V94.2 and V94.3 gas turbines (representing eurrent "state
of the art" and advanced technology, respeetively). Thermodynamic
eycle data for the gas turbines were presented earlier, and the
Appendix contains additional partieulars for the various cyele
components.
Net exergy effieieneies (Eq. 12) and net combined eycle effieieneies
(Eq. 8) were calculated for the various combined cycles. These
efficiencies are presented in Figs. 5 and 6 as tunetions of the design
HP-pressure for the HRSG, using the V94.3. At eaeh HP-pressure
the other live-steam pressures (RH,IP,LP) are optimized with respect
to cycle efficieney. Figs. 7 through 9 com pare the effeets of the two
gas turbines on net cyele efficiency, staek temperature, and the
required HRSG heat transfer area in eaeh of the cycles.
Introducing reheat improves the efficiency by 0.2-0.4 percentage
points compared to the non-reheat cyeles, both for the dual and triple
pressure cycles. The difference in efficiency belween dual and triple
pressure cycles is about 0.5-0.6 percentage points except for smal/er
HP-pressures where this difference tends to decrease. Supercritical
reheat cycles give a higher efficiency than the subcritieal eycles.
There is also a significant difference in effieiency between the dual
and triple pressure supercritical reheat cycles, which is about 0.5
percentage point.
The variation in exergy efficiency is from 65 % for the dual pressure
cycle at 60 bar HP-pressure and up to nearly 71 % for the triple
pressure supereritical reheat cycle. The differenees in exergy
effieiency eorrespond, of eourse, to what has been explained for Fig.
5. It is interesting here to make a comparison between the steam
eycle and the Kalina-cyele, where in the latter eyele a mixture of
ammonia and water is used as working fluid. For the Kalina-cycle,
Steeco and Desideri [12) have calculated the exergy effieiency to be
63.2 % when utilizing exhaust gas heat at 577C. It should be
emphasized, however, that the assumptions used in the present work
differ from those of the reference [12).
In Figs. 5 and 6 the graphs are marked in order to represent a
"reasonable" choiee of HP-pressure for eaeh type of eyele. These
ehoices are mainly based on the steam turbine exit quality for the
non-reheat eyeles. For the subcritical reheat eycles the HP-pressures
are chosen to be 140 bar. Increased live-steam pressures normally
implies higher HRSG eost, but for the subcritieal reheat cycles the
HRSG HP-stage has a smaller mass flow and also a smaller
volumetric flow compared to the non-reheat cycles. The increased
tube thickness (and weight) due to higher pressure will be opposed
by smaller tube diameters. Table 2 summarizes the results from the
calculations with the chosen HP-pressures which are marked in Figs.
5 and 6.
Figs. 7-9 are graphical presentations of the data in Table 2. When
comparing the CC performance with respeet to gas turbine technology
(V94.2 versus V94.3), the differences in effieieney (Fig. 7) are about
2.0-2.1 percentage points. These differences are larger than anyof
the differenees between the cycles with a given gas turbine. The
potential for CC effieiency improvement therefore mainly relies on gas
'*
>-
U
Z
W
[)
CL
CC
UJ
i
ru
Z
HP -PF1ESSlJRE bal
Figure 5 Combined Cyele net errieieney as funetion of HP--
pressure for the V94.3 gas turbine
)-
u
z
w
Cl
CL
LI
IJJ
)-
C)
rr:
CCI
x
W
i--
UJ
:7
DUAL Pf-1ESSUf1E Flfii[AT (YCLE
HP -PFiESSURt'. bal
Figure 6 Steam cyele net exergy affieieney as function of HP-
pressure for tlJe V94.3 gas turbine
55.5
>-
550
U
Z
W
u
IL
6-1.0
UJ
[-
UJ
tJ3,5
Z
lLi
_J
U
()
Cj
Ul
:2
LlJ
L
o
U
r----------------------------- ------.. -------------- -- --'- .-.----,
1m SiEM[N:; V94.2
llII SIfM[US V94.J
DUAl PRESSURF. DUAl PRESSUHE DUAL PRESSVkE fRI?l E Pf1ESSlJRE mIP!...L H\hSI,"lF T;1IPI c PF1f:SSlJRf
CYCLE REH[AT CyeLf SUPfRCRITICAt CYCI_E RcrlfA.T CYCLE S0PI::I;C!-1lfICAl
C'leLE n[flf:A,r (yeU'
Figure 7 Combined Cyele net efficieney for spee/fjely ehosen HP-
pressure for t/le V94.2 and V94.3 gas turbin es
7
aU
UJ
II
:::J
f-
-
CC
W
CL
2:
W
i--
v'
U
f--
U)
CYCLE
DUAL PRESSUliE lfllf.'LE PRE:SSURE TI1iiU: PRESSURE -f"HIi'LE PFiES$UR[
Rc:HEAT CYCI t: CYC! E AEHEAT CYCI i::: SIJPEHCR:TICAL
CYCLE REHEA)
Figure 8 Stack !PflYln,1r.',,,rlln,,,
(tJr specificiy et/osen NP-pressures
gas turbines
for the V94.2 and
turbine doveloprnents. \Nith the new generation oT gas lurbines, in lhis
study represented the Siemens V94.3, it is likely to have CC net
efficiencies reaching 54-55 %.
Fig. 8 S!lOWS the slack temperatures for the different cydes. As can
be seen thore are only minor differences in stack temporatures when
comparing the Iwo of gas turbines. Thore is no obvious
connection belwoen slack temperature and efficiency. This means
that the CC efficiency is no! soiely dependent on ho.'tLfllUCh of the
exhaust gas energy Wflictl is utilized, bu! it is also a question of ho.w
Itle exhaust gas energy is utiiized.
In Fig. 9 and Table 2 the HRSG he al transfer areas are given in a
nondimensional form, which is
(16)
where is Ille steam cycla ne! power output
for all cases. (16) defines a parameter relating
to the net power output of the steam cycla. Fig. 9 SllOWS Ihere is
very littlo difference in Ihe HR SG heat transfer area berNeen the twa
gas turbines. As can be seen when camparing Figs. and 9,
increased efficieney comes al the expense of a larger heat transfer
area. The supererilieai eyeles, especially, require a large heat transfer
area for a given gain in It is interesting lo note iha! the
!riple pressure subcritical reheat cyde requires less heat transfer area
than the triple pressure non-reheat cyclo. The reason for this is thal
<f
LLJ
<f
Cl
LU
CL
<1:
er
i-
1--
<f
LI!
T
DUAL PRESSURE DUAL PRI"SSLJnf :JUAl_ PRr.SSUI-1[C 1fliPtE ,PiPU:::: PRESSIJR[ THIPLE DRf:S;,\!Rf'
(yelF. fWHEAT CyeLr ;;IJPEJ1CRITir;p,L CYClf: m'HE;AT ned: SUPERCRrTIC/lL
(yeLl" m:Hf:A, CYCLl:-
Figure 9 HRSG relativt) heat transfer areas for the V94.2 and
V94.3 gas turbines
the relle8! results in less mass ilow going the Hp
eeonomizer and whieh eonslilule most of the heat
transfer area for a nonreheat eycle. Besieles, Ihe condensate flow
rate is less for a rehea! cycie compareel lo a non-mhea! cycle, wllieh
n1eans less heal lransfer and heat lransfer area at thH cold end of U,e
HRSG.
The effeet of in front or the HRSG for three
different types eyeles is shown Fig. 10. The seleded cyclas are
the dual pressum cyele, the lripie pressure reheat eycle and the dual
pressure supercritical rehea! eyde. All three eyclas are ealculaled WiUl
the V94.3 gas lurbine. The !WO subcriticai cyeles are caleulated with
different along with an optimization of the oUler live-
steam pressures. As can be seen from Fig. 10
does no! improve lhe of the subcritieal cyc!es irrespective
of the HPpressure wilhin the range stated in Fig. 10. On Ule alher
Iland, the is sJighlly improved by Ule
of the dual pressure supercriiical
The differenee be!ween the wilh respecl to efficieney is
described by rneans of firsl-Iaw method of analysis. A secondlaw
or exergy analysis provides information aboul wby lrlere are
differences in cycle performance. Fig. 11 shows a breakdown of
exergy losses for different components in the steam cycle wllh the
V94.2 gas turbine, as well as the steam cycle ne! exergy efficiencies.
The main for differences in efficiency between Ihe cycles is
the decrease in HRSG exergy losses, The steam turbine exergy
IOSS8S do no! differ significan!ly be!ween the cycles. The varialions
ean be explained the fae! that different mass fiows are expanded
in !h lurbines Ula! the efficiencies vary because of differonces
in exit quality, especially between reheal and non-rehea! cycles. The
candenser has also rather small variations in exergy losses; bu! Ihe
CYCI[
DUAl_ Pil!" SSUl1F SUPEflCfUI iCAI
64.6
54.4
580 690 eoo 610 620 610
SIJPflLHM::NTAlW fiRING t
Figure 10 Combined Cyele nel as funetion of
supplementary firing temperature
f,40
reheat eycles have sli()hlly less condenser losses. Even if reheat
cyc!es a higher steam turbine exit Ihe reduc!ion
eondenser steam mass flow implies a loss of exergy, The
slack exergy loss is a funclion of slack tm perature , and as can be
seen the triple pressure cyeles have mueh smeller losses Itlan Ule
dual prcssure eyeles. The exergy losses from pipes and valves 8110wn
in Fig. 11 are obviously funelion of cycle eomplexity and steam
mass flow.
2i-\1 DU!'\L RH--1EAT
:..:: DUAL PRESSURE SUPt=SCRITICAL RtHE,t\,!
:lP mlc'l.f: PRESSURE CYCLE
3PR "TRIPL!: PRESSUF,E IlEHEAT CYCI.E
JPHS c TRiPLE PHESSURE SUPERCRITIC!\I. 11F:fjC:IIl CYCI
Figure '/1 Exergy effiency and exergy loss breakdown for the considered cyeles
8
CONCLUSIONS
The combination of the first-Iaw and second-Iaw approach provides
a good tool for the analysis of power cycles. The exergy balanee
method of analysis enables all loss sources to be J.QQaied and
QlliIDillled. When different steam cyele configurations are compared,
the exergy analysis gives a very useful understand ing of wlnl
thermodynamical performanee difters from ane type of eyele to
anolher.
The lriple pressure supercritical reheat steam eyele gives the largest
increase in efticiency compared to a "state of Ihe art" dual pressure
subcritical steam eyele. On the olher hand, the inerease .in required
heat transfer area is large compared to Ihe gain in efficiency. The
triple pressure subcritical reheat steam cycle seems to be very
interesting. Compared to the dual pressure non-reheat cyele, the
increase in efficiency is approximately one percentage point
Supplementary firing is not very interesting as a measure to increase
CC efficiency with the types of gas !urbine used in this study, except
for the supercritical cycles. However, supplementary firing provides
flexibility with respect to load control, and from a design point of view,
flexibility is added to power output without having to make significantly
less effiden! cycles.
When com paring the CC effieiency of the !WO gas turbines used in
this study, il is obvious U'lat the new generation of gas turbines now
being introduced to the market will increase the CC efficiency by
aboul 2 percentage points. This new generation of gas lurbines
together with some of the proposed steam cycle configurations will
make it possible to reaeh neI efficiencies in the range 54-55 % for
large combined eycles.
ACKNOWlEDGEMENT
The discussions he Id with Dr. Maher EImasri wme invaluable during
the course of this work.
REFERENCES
1 Bolland,O., Gl.!llEowetPJai:ltA11ernalillesJru:.Nm:wegian
Siemens(KWU)-report Erlangen, FederaJ Republic of Germany, 1987
2 Bolland,O.,and Lken,P.A., Poteotials lo Improvem Steam
in.-'l1LUnlirru:LCrnIlbiruIcLGycill, SINTEF-report STF15 A87053, Trondheim,
Norway, 1987
3 ChinJW.vV.,and Elmasii,M.A., Combined cycles Part 2
Analysis of Journal of Engineering for
Gas Turbines and Power, Vol. 109, pp. 237-243, April 1987
4 EngelkeW., Dampfturbinen Jijr GuD Krafuv1Mke. BWK , Sd. 41, Nr. '7/8 -
July/August, pp. 335-342, 1989
5 Frutschi,H.U.,and Plancherel,A.. Comparison otCQlnblnel:LC)'Cles...witlLSleam
IGTI-vol. 3, ASME Cogen-Turbo, pp. 137-
145, 1988
9
Il Harnann,B.,and Joyce,J.S"
Modem Power Systems, pp. 61-74, May 1989
1 Horlock,J.H., and Power iCliE').
Economks., Pergamon Press, New York, 1987
li Johnson,D.G .. Mbglichkeiten der Kombi Kraf!werke mil Hochtemperatllr-
Gasturbinen, VGS Kraftwerkstechnik 62 , pp. i 67 -173, March 1982
9 Kehlhofer,R., et al., G.as1urilinlmkraftwerlilLKombikraftwerke, Heizkraftwerke
Handbuchreihe Energie Technischer Verlag Resch,
Verlag TUV Rheinland, Band 7, chapter 2, 1984
10 Kotas, T.J., of Butterworths,
London, 1985
11 Rukes,B., Head of Department for Calculation of Heat Cycles and Heat
Removal Systems, Siemens AG - KWU Group, The Federal Republie of
Germany,
12 Steceo, SOS. ,and Desideri, U., of the Kalina
and Perspectils, Presented at the ASME Gas
Turbine and Aeroeogine Congress and Exposition, Toronto, Canada, June i989
APPENDIX
Input not mentioned in the body of the paper but used in the calculations ciled
are:
<lO Ambient temperature = 15 [0C]
.. Ambient pressure = j .Oi 3 [bar]
<& Relative humidity 60 [%]
.. Inlet pressure drop = 10 [mbar]
<lO Outlet (HRSG) pressure drop = 40 [mbar]
.. Auxiliary power for each gas turbine = 400 [kW]
l:IBSG.
.. Pinch-point = 10 [K]
.. Min. steam/exhaust approach temperature = 30 [K]
.. Eeonomizer approach temperature = 2 [K]
.. Pressure drop live-steam pipes
subcritical cycles HP=5 RH=7 IP=7 LP=10 [%]
supercriticaJ cycles HP=4 RH=7 IP=7 LP=lO [%]
.. Heat loss live-steam pipes = 1 [Kl
.. Pressure drep superheaters = 5 [%1
Ol Pressure drop evaporators = 5 [%1
lO Pressure drop economizers = 5 [%1
1/1 Pressure drop feedwater preheater = 4 [bar]
.. Deaerator pressure = 1.2 [bar]
.. Exhaust gas due! heat loss = 2 [K]
.. Max, steam temperature: HP=540 RH=560 [0C]
Steam turbiDe
lO Pressure drop throttle valves = 2 ["lOJ
il> Pressure dro p reheat retum pipe = 3 [%]
<11 Jsentropic efficiencies: HP=92 RH=92 IP=92 LP=89 ["lO] (subcritical)
.. Isentropic efficiencies: HP=91 RH=92 IP=92 LP=89 ["lO] (supercritical)
lO Steam leakages through seais: HP=O.2 RH=0.2 IP=0.2 LP=O.2 ["lO]
.. LP section leaving loss = 30 [kJ/kg]
"Wiison line" quality = 0.975
e Auxiliary power fraction = 0.25 ["lO] (pump work not included)
.. Mechanical/generator-efficiency = 98.2 [%]
Co!1densm
Condenser pressure = 0.04 [bar]
.. Cooling water temperature = 15 [0C]
III Allowed cooling water temperature illcrease = 9 [K]
.. Cooling water pressure drop = 1 [bar]
PJJll1IlS
" Mechanieal efficiency = 92 [%]
fli Isentropie efficiency = 80 [% J