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Convective transport at low & high pressure. Free convection effects in Supercritical Fluids
Chapter Five
One of the most important parameters needed in the design of packed bed systems is the particle-to-fluid transport coefficients. In the past six decades, a substantial amount of work has been devoted to the study of these parameters. Particle-to-fluid mass transfer studies were first carried out by Gamson et al. (1943), and Hurt (1943). They obtained mass transfer coefficients from measurements of the rates of evaporation of water from wet porous particles. Hurt (1943) also reported mass transfer coefficients derived from the measurement of rates of naphthalene sublimation. Since their pioneering work, a large number of experimental studies have been carried out on mass transfer coefficients in packed bed systems. Theoretical work has also been in progress. Pfeffer (1964) and Pfeffer and Happel (1964) applied a free surface cell model to the creeping flow region. LeClair and Hamielec (1968, 1970) proposed a zero vorticity cell model, and El-Kaissy and Homsy (1973) applied the free surface cell model, zero vorticity cell model and distorted cell model to a multiparticle system at low Reynolds number. Nishimura and Ishii (1980) also applied the free surface cell model to the study of mass transfer at high Reynolds numbers. These models which are based on different assumptions, generally give different and inconsistent values of particle-to-fluid mass transfer coefficients. Therefore, theoretical prediction of mass transfer coefficients is far from satisfactory. For the design and analysis of packed bed catalytic reactors, it is necessary to know the temperatures of the fluid and the catalyst particles in which the chemical reactions are taking place. In general, fluid temperature is measured with little difficulty, but the measurement of the solid surface temperature is not easy. This is particularly true of packed bed reactors. The particle temperature or temperature drop at the particle surface then has to be estimated in terms of the heat transfer coefficient between the particle and the fluid. Because of the importance of the particle-to-fluid heat transfer coefficient in packed bed reactors, a considerable effort has been made to evaluate this parameter. Experimental determinations of heat transfer coefficients for a wide variety of systems have been made using various experimental techniques, under either steady-state or unsteady-state conditions. An extensive review on experimental/theoretical works on particle-to-fluid mass and heat transfer can be found in Wakao and Kaguei (1982). Although there is broad information available of published experimental data for particle-tofluid forced convection heat and mass transfer at low pressure (see e.g. Wakao and Kaguei, 1982), scarce data are available for high pressure situations or supercritical packed bed reactors. Many authors have studied catalytic reactions using a supercritical fluid as a solvent (Poliakoff et al., 1996; Ramirez et al., 2004), but main interest has been centered in kinetics of chemical reactions under supercritical conditions. Other authors have studied mass transfer in packed beds under supercritical conditions applied to supercritical extraction (Debenedetti and Reid, 1986; Stber et al., 1996). The recent study and development of new compact packed bed supercritical nuclear reactors opens a branch for the study of heat transfer phenomena under high pressure conditions (see e.g. Oka et al., 1994). In the following sections, analytical solutions of the steady-state temperature and composition profiles in a packed bed will be shown. In addition, a CFD simulation strategy for the estimation of forced convection mass and heat transfer coefficients at low pressure is discussed. Estimated transport parameters are compared to broadly accepted correlations. Mixed convection mass and heat transfer at high pressure is modeled and analyzed, and numerical results obtained are compared to previously published experimental data (Stber et al., 1996), and a correlation for predicting heat transfer parameters in a supercritical packed bed reactor is presented (Guardo et al., 2006). The obtained numerical results validates the idea that the modified correlation presented by Guardo et al. (2006) can be used to describe heat transfer
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Chapter Five
phenomena in a supercritical packed bed reactor under mixed convection regime at high pressures.
5.1.
To properly design a mesh capable of capturing the transport mechanisms present in the study in detail, a dimensionless analysis of Navier-Stokes equations under simulation conditions was developed. The dimensionless equations corresponding to continuity, mass, momentum, and energy balances are detailed in Chapter two. The orders of magnitude of the dimensionless groups were estimated by taking physical-chemical property values for air from experimental data and empirical correlations available in the literature (Reid et al., 1987; Yaws, 1999; Poling et al., 2000). Reynolds number was calculated using particle diameter as characteristic length. Reynolds analogy was used to estimate values of Prt from Ret (White, 1991). For first analysis purposes, Prt was assumed as a constant value within the bed, justified in the fact that majority of experimental results shows a range of variations between 0.75 < Prt < 2 for air and water (Kays, 1994). Boundary (operating) conditions for each analyzed situation are shown in Table 5.1. Details on the dimensionless numbers used can be found in Appendix C. Results of the order of magnitude of the dimensionless groups are shown in Table 5.2.
Boundary condition
Circulating fluid C7H8 concentration at inlet, mol/m3 C7H8 concentration at particle surface (equilibria), mol/m3 Pressure, Pa Mass flow at the inlet, kg/m2 s Velocity at the inlet, m/s
Low pressure
High pressure
In the case of particle-to-fluid transport at low pressure, dimensionless analysis allows identifying the problem as forced convection in laminar or turbulent flow. For the momentum balance it becomes clear that viscous forces decrease their contribution as Re increases. Inertial gravity forces increase their contribution as Re decreases, and pressure drop together with turbulent forces become the most important terms in the momentum balance at high Re. In energy and species balances, the convective and the diffusive term become important for the balances. For both balances, steady state analysis can be used.
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Chapter Five
When analyzing a mass/heat transfer case at high pressure, the problem is identified as mixed (free + forced) convection in laminar or transitional flow. Body forces and pressure drop become the most important terms in the momentum balance. Turbulence forces contribution to all balance equations is negligible. In order to couple species/energy and momentum balance, unsteady state analysis is required.
Low Pressure
Re Sr Ma Eu Fr Pr Sc Ec ReT PrT ScT
Table 5.2. 100 102 10-6 103 - 104 10-4 10-1 100 10-10 101 10-1 103 101 101 10-5 101 - 103 10-4 - 10-2 10-1 100 10-10 - 10-8 100 10-1 102 102 100 10-4 10-1 - 101 10-2 - 100 10-1 100 10-8 - 10-6 100 10-1 101 103 10-1 10-3 10-1 100 10-1 100 10-6 100 10-1 100
High Pressure
100 105 10-6 106 10-10 100 100 10-16 101 10-1 103 101 104 10-5 104 10-8 100 100 10-14 100 10-1 102
In order to define the computational domain, a 44 spheres stacking with a sphere-to-tube diameters ratio of 3.923 was chosen for the geometrical model. Modeled geometry was constructed following the bottom-up technique (generating surfaces and volumes from nodes and edges) in order to control mesh size around critical points (i.e. particle-to-particle and particle-to-wall contact points). In this study, to include real contact points, the spheres were modeled overlapping by 0.5 % of their diameters with the adjacent surfaces in the geometric model. For further details on the geometrical model please refer to Guardo et al., (2004) and Chapter Four of this thesis.
5.2.
Navier-Stokes equations together with species/energy balance were solved using commercially available finite volume code software Fluent 5.x/6.x. For the low pressure models the fluid was taken to be incompressible, Newtonian, and in a laminar or turbulent flow regime. CO2, air and toluene at standard conditions were chosen as the simulation fluids. Incompressible ideal gas law for density, power law for viscosity and appropriated mixing rules were applied to the model for making these variables temperature and composition dependent. For the high pressure simulations, the fluid was taken to be Newtonian, in laminar flow regime and with variable density. CO2 and toluene were chosen in this case as the simulation fluids, and its
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Chapter Five
properties at high pressure were incorporated to the solver code through User Defined Functions (UDF) and User Defined Equations (UDE). Peng-Robinson equation of state was used to calculate fluids density and heat capacity, Lucas method was used to calculate the viscosity, and thermal excess method was used to calculate the thermal conductivity (Reid et al., 1987). Appropriate mixing rules were applied to the model for making all variables compositiondependant. Details on the implementation of these UDEs and UDFs can be found in Appendix D. Under-relaxation factors for pressure, momentum and energy were initially set to 0.05, 0.1 and 0.2, respectively (Gunjal et al., 2005), and increased progressively after convergence until values of 0.2, 0.4 and 0.8, respectively. In the case of turbulent flow simulations, under-relaxation factors for turbulent quantities were set in 0.4. A first order discretization scheme for pressure, momentum and energy equations was used until convergence was achieved, and the results obtained were used as initial solution for a new simulation applying a second order discretization scheme for momentum and energy equations. Simulations were run in a Dell Precision 380 and Hewlett Packard Proliant DL385 workstations, and simulation times ranged from 1 to 240 hours depending on the studied case. Numerical convergence of the model was checked based on a suitable diminution of the normalized numerical residuals of all computed variables. For a more complete convergence checking the average static temperature or average species concentration at the bed outlet were also chosen as monitors depending on the case.
5.3.
5.3.1.
The main purpose of this set of simulations was to test CFD capabilities in a particle-to-fluid transport packed bed model. Standard correlations for Nu and Sh, and experimental data were selected as reference values to compare against the numerical results generated (Wakao et al., 1979, 1982). For each simulation, inlet velocity was varied (0.2 < Re < 1800), and the transport coefficients (Nu, Sh) were obtained. For the modeling in the turbulent flow region (Re > 300), previous experience shows that the Spalart-Allmaras turbulence model is a good choice (Guardo et al., 2005). In packed beds with constant temperature or species concentration at particle surface, the transport resistance resides only on the fluid side. If axial dispersion is taken into consideration, then the balance equations for steady-state analysis are as shown in Table 5.3. For each simulation, variable profiles along the bed were recorded and analyzed. With the collected numerical results, the transport coefficients (kc, h) were obtained from Equations [5.3-1] and [5.3-2]. From the obtained values for kc and h, Sh and Nu were computed and compared with the broadly accepted correlations and experimental data. Results for mass transfer are shown in Figure 5.1. Results for heat transfer are shown in Figure 5.2. In both mass and heat transfer simulation sets, four meshes were used. It can be noticed that for both mass and heat transfer situations, in the laminar and transition flow zone (Re < 300) the results do not show dependence on the mesh density. The refinement of the mesh is expressed in terms of Vcell / Vp ratio.
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Chapter Five
Mass balance
2 dC 6k c (1 ) (C f C ps ) = ax d C + u dx d p dx 2 [5.3-1]
Energy balance
d 2T f 6h (1 ) (T f T p ) = ax 2 u + dx d p C p dx [5.3-2] dT f
Boundary conditions
u (C C 0 ) = ax
at x = 0 (inlet)
dC dx
[5.3-1a]
u (T f T0 ) = ax dT f =0
dT f dx
[5.3-2a]
at x = 0 (inlet) [5.3-1b]
dC =0 dx
at x = L (outlet) Table 5.3.
dx
[5.3-2b]
at x = xL (outlet)
Mass and energy balance equations applied to the packed bed model
At lower Reynolds numbers (Re < 10), mass and heat transfer results obtained shows that the fitting against Wakao et al. correlations (1979, 1982) is not good. This is particularly noticeable in the case of the heat transfer simulations (see Figure 5.2). For a single velocity condition, different meshes give results in a wide range of Nu and no relation with mesh density can be established in any case. Experimentally, one-shot measurements have demonstrated that no definite Nu values can be obtained at low Re (Wakao, 1976). The fact that any Nu value within the obtained ranges yields approximately the same value of ax suggests that at this low Re, particle-to-fluid heat transfer makes little contribution to the overall heat transfer in the system, which analytically has been reflected in an increased confidence range for the selected correlation at low Re (Shent et al., 1981). Using a laminar model, a good accuracy for Sh and Nu values was obtained within 10 < Re < 100, reinforcing the idea that a similar methodology can be applied to model mixed convection heat transfer at high pressure in the same Re range.
100
Sh
10
Sc = 1.3
1 1
VSerie10 cell / V p = 5.77 x 10
= 5.74 x 10-4 Vvcell/vp cell / V p = 3.04 x 10
-4 -5
10
100
1000
Serie12 V cell / V p = 3.21 x 10 Ranz & Marshall (1952)
10000
-5
Re
-4 VSerie11 cell / V p = 2.09 x 10
Wakao et al.)
Figure 5.1.
Sherwood number vs. Reynolds number for the low pressure convective mass transfer packed bed model
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Chapter Five
100
Nu
10
1 0.1 1
Pr = 0.9
Re
-4
10
100
1000
Figure 5.2.
Nusselt number vs. Reynolds number for the low pressure convective mass transfer packed bed model
For higher values of Re there is a divergence between the results obtained for tested meshes in both heat and mass transfer simulations, probably due to the fact that at higher Re, turbulent transport term in the transport equation becomes more important. In RANS modeling, the balance equations possess a smooth exact solution, and the numerical solution approaches that solution as we refine the grid. The aim of grid refinement is numerical accuracy (Spalart, 2000; Shur et al., 2005). Therefore, for our specific study case, an accurate turbulence modeling requires a denser mesh around the particles surface in order to capture the involved turbulence phenomena and its related mixing enhancement in the boundary layer (Guardo et al., 2005). The results obtained with the finer meshes fit better the prediction of Wakao et al. (1979) for heat transfer, and Wakao and Kaguei (1982) for mass transfer in the turbulent flow zone (Re > 300), probably due to a better capture of the vorticity energetic scales associated effects.
5.3.2.
A numerical modeling of a packed bed where mixed convection mass and heat transfer phenomena appear was also made. The same geometrical model as the aforementioned case was used but now the circulating fluid and the values of pressure and velocity were modified. The effects of density, flow rate and flow direction on mass and heat transfer are presented. Obtained numerical results for mass transfer were compared against the experimental results and the correlation presented by Stber et al. (1996). Obtained numerical results for heat transfer were fitted, and a novel correlation based on the convective mass transfer correlation presented by Stber et al. (1996) is proposed (Guardo et al., 2006a). An analogy between the obtained numerical data and previously reported heat transfer data (Guardo et al., 2006b) is also presented.
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Chapter Five
Two simulation sets (upflow and downflow operation) were done, and for each simulation, inlet velocity was varied and Sh and Nu were obtained for 9 < Re < 100. A laminar flow model was used as viscous model for all simulations. Gravitational acceleration was added to the operating conditions of the model. Under-relaxation factors were set as previously explained for the aforementioned low pressure models. A first order discretization scheme for momentum and energy equations and a second order discretization scheme for pressure were used until convergence was achieved, and the results obtained were used as initial solution for a new simulation applying a second order discretization scheme for momentum and energy equations. Equations [5.3-1] and [5.3-2] were used to obtain the values of Sh and Nu for each studied case (see Table 5.3). Boundary conditions for the model are described in Table 5.1. The presence of high density gradients lead to the formation of hydrodynamical instabilities (i.e., stream differentiation, countercurrent flow, recirculation) caused by buoyancy effects (Benneker et al., 1998). In order to compute correctly the flow fields and the heat transfer phenomena in these zones, the optimal grid used for the prior model was locally refined for each case studied around the zones where high density gradients were found. Dimensionless analysis indicated that for the studied velocity range, laminar or transitional flow could be expected. For different mass and heat transfer simulations, local values of Gr, Pr, Sc and Re were calculated various points inside the boundary layer around the spheres in order to corroborate the transport mechanism present in the packed bed. Obtained values were compared with Metais-Eckert maps (Metais and Eckert, 1964) and are shown in Figure 5.3. As it can be observed, the main transport mechanism inside the packed bed under the different simulation conditions is the free convection in laminar/transitional flow regime.
1E+4
1E+3
Re
1E+2 Free Convection / Laminar flow 1E+1
1E+0 1E+2
1E+3
1E+4
1E+5 or
1E+6
1E+7
1E+8
1E+9
Gr (Pr
Figure 5.3.
Sc) (d/L)
Churchill (1983) suggests that in a mixed convection heat transfer situation the transition between laminar and turbulent flow can be found at 1 109 < GrH < 1 1010. In order to corroborate this idea, the numerical results obtained for Nu for the different heat transfer situations analyzed were plotted in a flow map according to Churchills criteria (see Figure 5.4).
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Chapter Five
It can be noticed that the results obtained follow the expected behavior according to the dimensionless analysis, and transition between laminar and turbulent flow shows up in the results by means of a high increase in Nu for alike values of GrH.
20
Laminar Flow Transition Turbulent Flow
15
Nu
10
Gr H
Assisting Flow
Figure 5.4.
Opposing Flow
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Chapter Five
clear that despite the fact a small density gradient is present in the results, flow field is controlled by the inlet velocity.
Figure 5.5.
Velocity field (scale colored by density, kg/m3) in an axial cut of the packed bed. (A) CO2 at 1 107 Pa and Re = 41; (B) Air at 101 325 Pa and Re = 531
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Chapter Five
Figure 5.6.
Toluene mass fraction contour plot in an axial cut of the packed bed for [A] opposing flow and for [B] assisting flow with Re 20
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Chapter Five
3.50E-05 3.00E-05
Time [s] Re = 13
Figure 5.7.
Re = 20
Re = 36
Re = 78
Cumulative toluene extracted at the bed outlet vs. time for different Re in opposing flow regime
Assisting flow
Cumulative toluene extracted at the bed outlet vs. time for different flow directions
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Chapter Five
When analyzing heat transfer at high pressure, results obtained show a similar behavior than the aforementioned, reflecting that heat transfer coefficient values are significantly greater in assisting flow cases than those obtained for opposing flow cases (see figure 5.9). The heat transfer rising in assisting flow is favored by the temperature gradient direction (the same as flow direction), which increases flow mixing and heat transfer rates. The presence of an adverse density gradient (when temperature gradient direction is opposed to flow direction) diminishes heat transfer rates and lower coefficients are obtained.
20 16 12
Nu
8 4 0 40 50 60 70 80 90 100
Re
Assisting flow
Figure 5.9.
Opposing flow
Nusselt number vs. Reynolds number for assisting and opposing flow simulations
In a similar way, flow velocity has a directly proportional effect over heat transfer when forced convection takes place. An increase on flow velocity leads to an increase on kinetic energy. This fact generates a better mixing and a greater heat transfer coefficient (see Figure 5.2). When analyzing a mixed convection case, the obtained results indicate that despite the fact that the forced convection component of the phenomena follows this behavior, free convection component is almost constant for all cases (see Figure 5.10). Is clear that free convection component is intrinsically related to density and temperature fields and it is not affected by velocity. Therefore, the dominant dimensionless group describing this phenomenon will be GrH rather than Re. Independently of flow direction, for the covered range of Re the heat transfer coefficient value increases almost linearly with velocity (see Figure 5.9). This increase in the overall heat transfer is due exclusively to the increase of the contribution of forced convection to the total heat transfer rate.
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Chapter Five
100
Nu
10
1 1 10 100
Re
Free Convection Forced Convection
Figure 5.10.
Nusselt number vs. Reynolds number for free and forced convection in assisting flow
Sh
10
1 10
Re
CFD Experimental Stber et al.
100
Figure 5.11.
CFD obtained Sherwood number vs. Reynolds number for both upflow and downflow operations, and comparison against experimental data and correlations presented by Stber et al. (1996).
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Chapter Five
The contributions of free and forced convection to mass transfer could be evaluated following the indications of Stber et al. (1996), finding also concordance between the numerically obtained results and the experimental results reported in that paper (see Figures 5.12 and 5.13).
100
Shfree/Sh (%)
10 10
Re
Assisting flow
100
Opposing flow
Figure 5.12.
CFD obtained contribution of free convection to total mass transfer vs. Reynolds number and comparison against experimental data presented by Stber et al. (1996).
0.3
100
10
1 10 100
Re
Opposing flow
Figure 5.13.
Assisting flow
CFD obtained contribution of forced convection to total mass transfer vs. Reynolds number and comparison against experimental data presented by Stber et al. (1996).
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Chapter Five
100
Nufree / Nu (%)
10 1
Re
Assisting Flow Opposing Flow
10
100
Figure 5.14.
CFD obtained contribution of free convection to total heat transfer as a function of Reynolds number
The aforementioned idea of a high pressure mixed convection heat transfer correlation can be noticed explicitly in Figure 5.14 and Figure 5.15. Figure 5.14 shows the contribution of free convection to the total Nusselt number as a function of the Reynolds number. As expected, low Re numbers correspond to transport dominated by natural convection, but for Re around 100, still 30% of transport is due to natural convection (for both assisting and opposing flow). Figure 5.15 shows a reduction of the numerical data points to a natural convection-free basis only depending on the Re numbers. While the contribution of free convection to total heat transfer rate decreases with Re (as its value remains almost a constant), forced convection increases, leading to greater heat transfer coefficients.
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Chapter Five
10.00
0.3
1.00
0.10 1
Re
Assisting Flow Opposing Flow
10
100
Figure 5.15.
CFD obtained contribution of forced convection to total heat transfer as a function of Reynolds number
After validating the numerical results obtained against experimental data and empirical correlations (see Figures 5.11, 5.12 and 5.13), an analogy between mass transfer data presented in this work (CFD and experimental) and numerical heat transfer data reported (Guardo et al., 2006) can be done, establishing a relationship between the selected data. It can be noticed that with a similar simulation methodology heat and mass transfer coefficients at high pressure can be obtained, because the CFD code applies the same mathematical procedure to estimate transport of any scalar quantity (such as mass or energy). Results obtained for heat and mass transfer simulations show a good fitting when compared to the prediction of the aforementioned correlations for heat and mass transfer. The parity plot for predicted vs. obtained Nusselt and Sherwood numbers is given in Figure 5.16. In summary, the correlations recommended are:
[5.3-3]
Taking Nu0 = 2 (Wakao and Kaguei, 1982), the correlations for free and forced convection are:
Nu free = Nu 0 + 0.001(GrH Pr )
Nu forced = 0.269 Re 0.88 Pr 0.3
0.33
Pr 0.244
[5.3-3a] [5.4-3b]
Valid for the following ranges of dimensionless numbers: 9 < Re < 96; 2.2 < Pr < 3.3; 1 108 < GrH Pr < 4 1010.
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Chapter Five
An advantage of this correlation is that a single set of parameters predicts heat transfer for assisting flow free convection (with the minus sign in Equation [5.3-3]) as well as opposing flow free convection (with plus sign in Equation [5.3-3]). Predicted values for Nusselt number show that estimation error is within that obtained with original mass transfer correlation, that showed an AARD = 18.9% (see Figure 5.17).
20
15
10
0 0 5 10 15 20
Mass transfer
Comparison of numerically obtained vs. predicted heat and mass transfer coefficients using the proposed correlations
25
20
15
NuT
10
0 1 2 3 4 5 6 7 8 9 10 11
Simulation run
CFD Correlation [Eq. 5.3-3]
Figure 5.17.
Estimated error for the high pressure mixed convection correlation against simulation runs
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Chapter Five
CONCLUSIONS
CFD proves to be a reliable tool when modeling convective mass and heat transfer phenomena in packed beds. It allows to analyze either free or forced convection situations and the obtained results can be compared qualitatively and quantitatively against previous published data. Forced convection at low pressure in a packed bed was simulated, and the influence of velocity over mass and heat transfer could be analyzed. For values of Re > 10 it was obtained a good agreement with the correlations presented by Wakao and Kaguei (1982) for mass transfer, and Wakao et al. (1979) for heat transfer. At lower Reynolds numbers (Re < 10), results shows that the fitting against correlation is not good. This situation is especially notorious when analyzing heat transfer. For a single velocity condition different meshes give results in a wide range of Nu and no relation with mesh density can be established in any case. No mesh sensitivity was noticed for the laminar and transition flow zones, but in the turbulent flow zone a good definition of the mesh around the particles surface is of primal importance in order to capture the turbulence vorticity energetic scales associated effects. Mixed (free+forced) convection at high pressure in a packed bed was also analyzed. For a supercritical fluid in laminar flow regime it was possible to study the effects of the density gradient, flow direction and velocity over mass and heat transfer. It was noticed that the presence of large density gradients conditioned the mesh influence over the numerical results when computing the mixing and the mass/heat transfer within the computed domain. An adverse density gradient generates hydrodynamical instabilities that produce an increase of the axial dispersion and a diminished mass/heat transfer rates. This fact caused numerical instability in the simulation process. In order to eliminate numerical instability, the mesh was locally refined in each case trying to avoid the presence of high density and velocity gradients along the bed. Influence of flow direction over mass/heat transfer was also analyzed and it was noticed that in assisting flow regime, greater heat transfer rates are obtained. The rising in the density along the bed height due to the adverse density gradient helps the axial dispersion to grow, obtaining less mixing within the bed and smaller heat transfer coefficients. Flow velocity also affects the heat transfer rate. The value of Sh and Nu increases almost linearly with flow velocity and this increase is due exclusively to the increase in the contribution of forced convection to the overall mass/heat transfer. Free convection is independent of flow velocity and its value remains almost constant within the studied velocity range. A novel correlation (Eq. [5.3-3]) is presented for estimating the free and forced convection effects and Nu from Re, Pr and GrH . Presented correlations are valid for 9 < Re < 96, 2.2 < Pr < 3.3, and 1 108 < GrH Pr < 4 1010. The obtained numerical results validates the idea that the modified correlation presented (Guardo et al., 2006), based on the one proposed by Stber et al. (1996) for mixed convection mass transfer under supercritical conditions in packed beds, can be used to describe heat transfer phenomena in a supercritical packed bed reactor under mixed convection regime at high pressures.
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Chapter Five
REFERENCES
Benneker, A., Kronberg, A., Westerterp, K., (1998). Influence of buoyancy forces on the flow of gases through packed beds at elevated pressures. AIChE Journal, 44, 263 270. Churchill, S., (1983). Single phase convective heat transfer. In: Schlnder, E. et al. (Eds.): Heat Exchanger Design Handbook. Hemisphere publishing corporation, New York, NY, USA. (Sections 2.5.7 to 2.5.10) Debenedetti, P., and Reid, R.C., (1986). Diffusion and mass transfer in supercritical fluids. AIChE Journal, 32, 2034 2046. El-Kaissy, M.M., and Homsy, G.M., (1973). A theoretical study of pressure drop and transport in packed beds at intermediate Reynolds numbers. Industrial & Engineering Chemistry Fundamentals, 12, 82 90. Gamson, B.W., Thodos, G., Hougen, O.A., (1943). Heat, mass and momentum transfer in the flow of gases through granular solids. Transactions of the American Institute of Chemical Engineers, 39, 1 35. Germain, J., del Valle, J., de la Fuente, J., (2005). Natural convection retards supercritical CO2 extraction of essential oils and lipids from vegetable substrates. Industrial & Engineering Chemistry Research, 44, 2879 2886. Guardo, A., Coussirat, M., Larrayoz, M.A., Recasens, F., Egusquiza, E., (2004). CFD Flow and heat transfer in nonregular packings for fixed bed equipment design. Industrial & Engineering Chemistry Research, 43, 7049 7056. Guardo, A., Coussirat, M., Larrayoz, M.A., Recasens, F., Egusquiza, E., (2005). Influence of the turbulence model in CFD modeling of wall-to-fluid heat transfer in packed beds. Chemical Engineering Science, 60, 1733 1742. Guardo, A., Coussirat, M., Recasens, F., Larrayoz, M.A., Escaler, X., (2006a). CFD study on particle-to-fluid heat transfer in fixed bed reactors: Convective heat transfer at low and high pressure. Chemical Engineering Science, 61, 4341 4353. Guardo, A., Coussirat, M., Recasens, F., Larrayoz, M.A., Escaler, X., (2006b). CFD studies on particle-to-fluid mass and heat transfer in packed beds: free convection effects in supercritical fluids. Chemical Engineering Science (submitted in revision). Gunjal, P., Ranade, V., Chaudhari, R., (2005). Computational study of a single-phase flow in packed beds of spheres. AIChE Journal, 51, 365 378. Hill, S., (1952). Channeling in packed columns. Chemical Engineering Science, 1, 247 253. Homsy, G.M., (1987). Viscous fingering in porous media. Annual Reviews of Fluid Mechanics, 19, 271 311. Hurt, D.M., (1943). Principles of reactor design. Industrial & Engineering Chemistry, 35, 522 528. Kays, W.M., (1994). Turbulent Prandtl number. Where are we? Journal of Heat Transfer, 116, 284 295.
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Chapter Five
Lakshminarayana, B., (1991). An assessment of computational fluid dynamic techniques in the analysis and design of turbomachinery. The 1990 Freeman scholar lecture. Journal of Fluids Engineering, 113, 315352. LeClair, B.P., and Hamielec, A.E., (1968). Viscous flow through particle assemblages at intermediate Reynolds numbers. Steady-state solutions for flow through assemblages of spheres. Industrial & Engineering Chemistry Fundamentals, 7, 542 549. LeClair, B.P., and Hamielec, A.E., (1970). Viscous flow through particle assemblages at intermediate Reynolds numbers. Steady-state solutions for flow through assemblages of cylinders. Industrial & Engineering Chemistry Fundamentals, 9, 608 613. Manickam, O., and Homsy, G.M., (1995). Fingering instabilities in vertical miscible displacement flows through porous media. Journal of Fluid Mechanics, 288, 75 102. Nishimura, Y., and Ishii, T., (1980). An analysis of transport phenomena for multi-solid particle systems at higher Reynolds numbers by a standard KarmanPohlhausen methodI Mass transfer. Chemical Engineering Science, 35, 1205 1209. Oka, Y., Koshizuka, S., Jevremovic, T., Okano, Y., (1994). Systems design of direct-cycle supercritical-water-cooled fast reactors. Nuclear Technology, 109, 1 10. Pfeffer, R., (1964). Heat and mass transport in multiparticle systems. Industrial & Engineering Chemistry Fundamentals, 3, 380 383. Pfeffer, R., and Happel, J., (1964). An analytical study of heat and mass transfer in multiparticle systems at low Reynolds numbers. AIChE Journal, 10, 605 611. Poliakoff, M., George, M.W., Howdle, S.M., (1996). Inorganic and related chemical reactions in supercritical fluids. In: Van Eldik, R. (Ed.), Chemistry under Extreme and Non-classical Conditions. Spektrum, Heidelberg, pp. 189218 (Chapter 5). Poling, B., Prausnitz. J., OConnell, J., (2000). The properties of gases and liquids. McGraw-Hill, New York. pp. 3.1 10.56. Ramrez, E., Recasens, F., Fernndez, M., Larrayoz, M.A., (2004). Sunflower oil hydrogenation on Pd/C in SC propane in a continuous recycle reactor. AIChE Journal, 50, 1545 1555. Reid, R., Prausnitz, J., Poling, B., (1987). The properties of gases and liquids. McGraw-Hill, Boston. pp. 95 205. Saiz, S., Larrayoz, M.A., Trabelsi, F., Recasens, F., (2000). Procedimiento para la extraccin de lanolina de la lana y planta para la realizacin de dicho procedimiento. Spain patent No. P200002461. Shent, J., Kaguei, S., Wakao, N., (1981). Measurements of particle-to-gas heat transfer coefficients from one-shot thermal responses in packed beds. Chemical Engineering Science, 36, 1283 1286. Shur, M., Spalart, P., Squires, K., Strelets, M., Travin, A., (2005). Three dimensionality in Reynolds-averaged NavierStokes solutions around two-dimensional geometries. AIAA Journal, 43, 1230 1242. Sovov, H., Kuera, J., Je, J., (1994). Rate of the vegetable oil extraction with supercritical CO2 II. Extraction of grape oil. Chemical Engineering Science, 49, 415 420.
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Chapter Five
Spalart, P.R., (2000). Strategies for turbulence modelling and simulations. International Journal of Heat and Fluid Flow, 21, 252 263. Stber, F., Vzquez, A.M., Larrayoz, M.A., Recasens, F., (1996). Supercritical fluid extraction of packed beds: external mass transfer in upflow and downflow operation. Industrial & Engineering Chemistry Research, 35, 36183628. Wakao, N., (1976). Particle-to-fluid transfer coefficients and fluid diffusivities at low flow rate in packed beds. Chemical Engineering Science, 31, 1115 1122. Wakao, N., Kaguei, S., Funazkri, T., (1979). Effect of fluid dispersion coefficients on particle-tofluid heat transfer coefficients in packed beds: correlation of Nusselt numbers. Chemical Engineering Science, 34, 325 336. Wakao, N., and Kaguei, S., (1982). Heat and mass transfer in packed beds. Gordon and Breach Science Publishers, New York. pp. 138 160; 264 295. White, F., (1991). Viscous fluid flow. McGraw-Hill, New York. pp. 482 542. Yaws, C., (1999). Chemical properties handbook. McGraw-Hill, New York. pp. 1 55.
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CHAPTER SIX
Verdrink niet in je eigen inspiratie en verbeelding; wordt geen slaaf van je eigen model
Chapter Six
Partial hydrogenation of fats and oils is an important process in the food industry because not only increases oxidative stability of the final product when compared to raw materials, but also changes the physical characteristics of it, according to their final application (e.g. margarines or shortenings). In the conventional process, low reaction rates and the formation of undesirable by-products (such as trans fatty acids content about 40 wt%) are consequences of the low solubility of H2 in the oil and the high mass transfer resistance for the hydrogen in the liquid phase (Farrauto and Bartholomew, 1997). Supercritical technology has proven to be a reliable alternative to the conventional hydrogenation process (Hrrod et al., 2001; Tacke et al., 2003) resulting increasing the rate of reaction and reduced trans isomer levels. It also provides a clean, economic and environmental friendly process. Porous solid catalysts used for gas catalytic reactions have specific surface areas of tens to hundreds of square meters per gram. This enormous amount of surface area results mainly from the fine interconnecting pores in the catalyst pellets. If a chemical reaction is very fast, it proceeds at the external surface of the pellet. If, however, the reaction is very slow, the reactant gas may diffuse deep into the pores of pellet, even to the center of the pellet, and the chemical reaction takes place everywhere uniformly in the pellet. In the laboratory, reaction rate determined directly by measurements using a differential reactor, for example, is the overall rate. The overall rate constant does not necessarily mean the intrinsic chemical reaction rate constant. For the design of industrial packed bed reactors, one needs to know the overall reaction rate, not the intrinsic chemical reaction rate. The overall rate is governed not only by the chemical reaction, but also by the diffusion rate through the pores inside the catalyst pellet as well as at the pellets external surface. If we simply measure activation energy from the overall reaction rate constants, the activation energy may differ from that of the intrinsic chemical reaction. The importance of diffusion is often underestimated by some catalyst chemists. Wheeler (1951, 1955) made an extensive study on the role of pore diffusion in catalysis. Also, Petersen (1965), Smith (1970), Satterfield (1970), Jackson (1977), and Dullien (1979) have reviewed the subject of pore diffusion associated with chemical reaction well. The review article of Youngquist (1970) will also help readers understand the basic principles of diffusion and reaction in a porous catalyst. In previous work done by our research group (Ramrez et al., 2004), an experimental design methodology and a response surface methodology were used to achieve optimum hydrogenation conditions for Pd catalyst in supercritical propane in a continuous well-mixed reactor. The results showed that it is possible to obtain a hydrogenated fat with 2 3 wt% trans C18:1 content and an iodine value (IV) of about 70 (starting from an initial value of 130). External resistance to mass transfer was made negligible using a high flow velocity over the catalyst bed (Re 6000). Furthermore, studies applying the Hashimoto et al. (1971) scheme provided information on the kinetics for the supercritical hydrogenation on a commercial-size Pd/C catalyst. In later studies (Ramrez et al., 2006), the intra-particle diffusion mechanisms of the triglycerides and hydrogen in the hydrogenation were studied using supercritical propane for 2 % Pd on activated carbon. The method of measuring the effective diffusion coefficients was first to obtain the intrinsic kinetic constants on small-size catalyst particles ( 0.5 mm) in the absence of diffusional limitation and then using the intrinsic kinetic constants, to derive the diffusivities in diffusion-limited reaction runs using larger catalyst sizes (up to 2 mm). The results showed that while hydrogen is transported by bulk pore diffusion, the oil seem to diffuse by surface diffusion. Diffusivity for H2 is about 10 times greater than that for triglycerides.
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Chapter Six
The aim of the work presented in this chapter was to apply Computational Fluid Dynamics (CFD) to the study of the catalytic hydrogenation of sunflower oil in the presence of a supercritical solvent. A 2D CFD model of a single Pd-based catalyst pellet is presented. Intraparticle concentration profiles for all species present in the mixture (oil triglycerides and hydrogen) are obtained and compared against experimental results. Different particle sizes are studied and external mass transfer and intra-particle diffusional effects are analyzed. Verified kinetic constants and intra-particle diffusion coefficients were fed into a 3D packed bed reactor model, and conversion profiles are obtained.
6.1.
To properly design a mesh capable of capturing the transport mechanisms present in the study in detail, a dimensionless analysis of Navier-Stokes equations under simulation conditions was developed. The dimensionless equations corresponding to continuity, mass, momentum, and energy balances are detailed in Chapter Two. The orders of magnitude of the dimensionless groups were estimated by taking physical-chemical property values for air from experimental data and empirical correlations available in the literature (Reid et al., 1987; Yaws, 1999; Poling et al., 2000). Reynolds number was calculated using particle diameter as characteristic length. Reynolds analogy was used to estimate values of Sct and Prt from Ret (White, 1991). Boundary (operating) conditions for each analyzed situation are shown in Table 6.1. Values for operating conditions were taken from experimental data published by Ramrez et al., (2006). Details on the dimensionless numbers used can be found in Appendix C. Results of the order of magnitude of the dimensionless groups are shown in Table 6.2.
Boundary condition
Circulating fluid Mixture proportions (wt %) Temperature, K Pressure, Pa Flow model Velocity at the inlet, m/s Particle diameter, mm L inlet concentration, mol/m3 O inlet concentration, mol/m3 E inlet concentration, mol/m3 S inlet concentration, mol/m3 H2 inlet concentration, mol/m3
Table 6.1.
0.217710 0.171589 0.094676 0.057084 0.018240 0.023614 0.056489 0.120502 1.5590 1.450727
- 118 -
Chapter Six
Magnitude order
Re Sr Ma Eu Fr Pr Sc Ec ReT PrT ScT
Table 6.2. 100 10-1 10-6 1010 10-2 100 10-1 10-10 10-3 103 102 101 10-2 10-5 108 10-1 100 10-1 10-8 10-2 103 102 102 10-3 10-4 106 100 100 10-1 10-6 10-1 103 102 103 10-4 10-3 104 101 100 10-1 10-4 100 103 102 104 10-3 10-3 104 100 100 10-1 10-4 101 103 102
In the case of particle-to-fluid transport, dimensionless analysis allows identifying the problem as forced convection in laminar or turbulent flow. For the momentum balance it becomes clear that viscous forces decrease their contribution as Re increases. Inertial gravity forces increase their contribution as Re decreases, and pressure drop together with turbulent forces become the most important terms in the momentum balance at high Re. In energy and species balances, the convective and the diffusive term become important for the balances. For both balances, steady state analysis can be used. In order to define the computational domains, 2 geometrical models were created. A 2D axisymmetric simplification of a single spherical catalyst pellet (see Figure 6.1) was built to study mass transfer and intra-particle diffusional effects. 4 different particle sizes were selected for this study (Dp = 0.1, 0.47, 0.9205 and 2 mm). A simple cubic sphere stacking (see Figure 6.2) was selected as the base unit cell in order to simulate a packed bed reactor. For the simulations the fluid was taken to be Newtonian, isothermal (457 - 473 K) and in a laminar (10 < Rep < 100 for the packed bed model) or turbulent flow regime (u = 1.3 m/s for the single sphere model). A mixture of propane, hydrogen and sunflower oil (95 : 4 : 1) was chosen as the simulation fluid.
Figure 6.1. Mesh detail for the 2D single pellet geometrical model
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Chapter Six
Figure 6.2.
Mesh detail for the 3D packed bed unit cell geometrical model
6.2.
CFD has proven to be a reliable tool when modeling chemical reactors. Several reviews on the applicability of CFD methodology to chemical reactors design have been published in the last years (Bode, 1994; Harris et al., 1996; Kuipers and van Swaaij, 1998; Ranade, 2002). In this chapter, in order to study the transport and reaction mechanisms present in the supercritical hydrogenation of sunflower oil, Navier-Stokes equations together with the - turbulence model (when necessary) and a convection/diffusion mass balance were solved using a CFD commercially available finite element code software, Comsol Multiphysics 3.x. Simulations were run under isothermal (457 473 K) conditions. Steady state analysis was chosen for the simulations, following the guidelines obtained with the dimensionless analysis. The kinetic and diffusional models proposed by our research group (Ramrez et al., 2004, 2006) for the supercritical hydrogenation of sunflower oil were also incorporated within the equations set of the CFD solver. A schematic representation of the kinetic model used is shown in Figure 6.3. Kinetic constants used for simulations can be seen in Table 6.3. Values of molecular and effective intra-particle diffusivities applied to the CFD model can be seen in Table 6.4. For further insight in the kinetic and diffusional model, please refer to Ramrez (2005).
Figure 6.3.
Schematic representation of the kinetic model used for the supercritical hydrogenation of sunflower oil
- 120 -
Chapter Six
Parameter k12
mol-0.5 m4.5 (kg Pd)-1 s-1
Temperature, K 457
0.071 1 x 10-6 0.352 0.603 6.77 x 10-3 7.13 x 10-3
473
0.1 1 x 10-6 0.426 0.933 0.116 0.02
k13
mol-0.5 m4.5 (kg Pd)-1 s-1
k23
mol-0.5 mol-0.5 m4.5 m4.5 (kg Pd)-1 s-1 (kg Pd)-1 s-1
k32 k24
mol-1 m6 (kg Pd)-1 s-1
k34
mol-1 m6 (kg Pd)-1 s-1 Table 6.3.
457 K Oil
Particle diameter, mm
Molecular diffusivity, m2/s Effective diffusivity, m2/s Molecular diffusivity, m2/s Effective diffusivity, m2/s
0.47
2.94 x 10-8 2.94 x 10-8 6.4 x 10-8 6.4 x 10-8
0.9205
2.94 x 10-8 1.76 x 10-8 6.4 x 10-8 3.84 x 10-8
2
2.94 x 10-8 8.82 x 10-9 6.4 x 10-8 1.92 x 10-8
H2
473 K Oil
Particle diameter, mm
Molecular diffusivity, m2/s Effective diffusivity, m2/s Molecular diffusivity, m2/s Effective diffusivity, m2/s
0.47
9.8 x 10-8 9.8 x 10-8 3 x 10-7 3 x 10-7
0.9205
9.8 x 10-8 5.88 x 10-8 3 x 10-7 1.8 x 10-7
2
9.8 x 10-8 2.94 x 10-8 3 x 10-7 9 x 10-8
H2
Table 6.4.
Fitted molecular and effective diffusion coefficients for hydrogenation species on 2% Pd/C catalyst (Dp range = 0.47 - 2 mm)
Simulations were run in a Dell Precision 380 workstation, and simulation times ranged from 1 to 4 hours depending on the studied case. Numerical convergence of the model was checked based on a suitable diminution of the normalized numerical residuals of all computed variables. Concentration contour fields (see Figure 6.4) for all species present in the model were obtained and the numerical data recorded in order to analyze conversion, reaction velocities and mass transfer.
- 121 -
Chapter Six
Figure 6.4.
(A) Concentration contour plot for Linoleic fatty acid (C18:2) in a single 2 % Pd catalyst pellet model (Dp = 0.9205 mm); (B) Concentration contour plots for fatty acids in a 3D packed bed model (Re = 100). Concentrations expressed in mol/m3
- 122 -
Chapter Six
6.3.
6.3.1.
In order to validate the numerical results obtained, a set of 2D simulations of particle-to-fluid mass transfer and reaction in a single catalyst pellet (emulating the experimental conditions proposed by Ramrez et al. (2006)) was made, and the results obtained were compared against the experimental results aforementioned. Intra-particle concentration profiles and intra-particle reaction rates were obtained for Dp = 0.47, 0.9205 and 2 mm, for which validation was possible due to the availability of experimental data. First of all, it was necessary to verify the absence of gradients in the catalyst surface, since the experimental data was obtained in a Robinson-Mahoney gradientless reactor (Ramrez et al., 2004, 2006). For all particle diameters studied, concentrations (see Figure 6.5) and reaction velocity profiles (see Figure 6.6) along the surface arc were recorded. In all cases analyzed, flat variables profiles were obtained, assuring the absence of gradients along the catalyst surface.
0.24
1.6
0.18
1.2
0.12
0.8
0.06
0.4
Dp = 0.47 mm
0 -1.00 -0.50 0.00 0.50 0 1.00
Oleic
Elaidic
Stearic
Hydrogen
Verification of the gradientless condition at the catalyst surface. Species concentration on catalyst surface for Dp = 0.47 mm
Once verified the aforementioned, intra-particle concentration profiles and intra-particle reaction rates were obtained and compared against experimental data previously published by our research group (Ramrez et al., 2006), obtaining for all cases a good agreement between the numerical and the experimental data (see Figures 6.7 and 6.8). Magnitude of relative errors was evaluated for the developed simulations, finding that this value was within the magnitude order of the experimental error previously reported by our research group. A trial for minimizing the relative error by means of optimizing the kinetic constants of the model and the effective diffusivities was also made, but an appreciable change was not observed in the concentration profiles obtained, remaining the magnitude order of the relative errors similar to those obtained when the original kinetic and diffusional model was used (Guardo et al., 2006).
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Chapter Six
0.03
-0.08
0.015
-0.11
-0.14
-0.015
-0.17
Dp = 2 mm
-0.03 -1 -0.5 0 0.5 1 -0.2
Oleic
Elaidic
Stearic
Hydrogen
Verification of the gradientless condition at the catalyst surface. Reaction rates on catalyst surface for Dp = 2 mm
0.25 0.2
[mol/m ]
Coil
0.4
Dp = 0.47 mm
0 -1 -0.5 0 0.5 [dimensionless]
Elaidic Elaidic - EXP
0.2 0 1
Particle radius
Linoleic Linoleic - EXP Hydrogen Oleic Oleic - EXP Hydrogen - EXP
Figure 6.7.
Validation of numerical data obtained. Intra-particle species concentration profile for Dp = 0.47 mm. Experimental data taken from Ramrez et al. (2006)
- 124 -
CH 2
0.6
[mol/m ]
Chapter Six
0.0045 0.003
-0.005 -0.01
[mol/m s]
0.0015 0 -0.0015
roil
Dp = 2 mm
-0.003 -1
Linoleic Linoleic - EXP Hydrogen
Particle radius
Oleic Oleic - EXP Hydrogen - EXP
Figure 6.8.
Validation of numerical data obtained. Intra-particle reaction rates for Dp = 2 mm. Experimental data taken from Ramrez et al. (2006)
Coil
0.1 0.05 0
Figure 6.9.
Comparison of the intra-particle concentration profiles for Dp = 0.1 mm (numerical) and Dp = 0.47 mm (experimental Ramrez et al., 2006) in a single 2 % Pd catalyst pellet
- 125 -
CH 2
r H2
[mol/m s]
-0.015
Chapter Six
6.3.2.
Due to the difficulty for obtaining experimental data at very low particle sizes, a CFD simulation extrapolating the catalyst evaluation for Dp = 0.1 mm was also made in order to corroborate the catalyst effectiveness. It can be seen in Figure 6.9 that for a particle with Dp = 0.1 mm, numerically obtained concentration profiles were almost identical to those reported experimentally for Dp = 0.47 mm (Ramrez et al., 2006), reassuring the idea that for a particle diameter of 0.47 mm or lower, the effectiveness factor of the catalyst is close to the unity.
6.3.3.
For each simulation, species concentration contour plots (Figure 6.4) were analyzed, and mass flux through the particle surface was recorded. With this data the surface local mass transfer coefficients (k) could be determined:
J i = k i Ae (C i , surface C i , )
[6.3-1]
Figure 6.10 shows the surface local mass transfer coefficients for oil and Figure 6.11 shows the surface local mass transfer for H2 obtained by means of the CFD simulations. It can be seen that the obtained mass transfer coefficient values are almost constant in the upstream surface sector, while in the downstream surface sector the mass transfer coefficient value is strongly diminished. This fact must be related with the formation of an stagnation/recirculation flow point downstream the catalyst pellet, affecting specially the mass fluxes over the catalyst surface.
0.05
0.10 mm
0.04
[m/s]
0.03
0.47 mm
koil, local
0.02
0.9205 mm
0.01
2 mm
0
-1.00
-0.50
0.00
0.50
1.00
- 126 -
Chapter Six
0.09
0.07
0.10 mm
0.05
0.47 mm
0.04
0.9205 mm
0.02
2 mm
0.00
-1.00
-0.50
0.00
0.50
1.00
From the values of k, the Sherwood number (Sh) was computed (see Table 6.5) and compared with the theoretical solution proposed by Ranz and Marshall (1952) for particle-to-fluid mass transfer in a single sphere (gas at low pressure), finding that obtained values for the Sherwood number are higher than those predicted by the aforementioned theoretical correlation (see Figure 6.12). When comparing the obtained results with an extrapolation for the correlation proposed by Tan et al. (1988) for supercritical extraction in packed beds or with an extrapolation of the experimental results obtained by Brunner (1985) for a high pressure bubble column, it can be noticed that the obtained values are lower than the extrapolation predictions. The absence of experimental data at such high Reynolds numbers difficult the validation tasks of the obtained numerical data. Nevertheless, the obtained numerical data suggests that the particle-to-fluid mass transfer coefficients for the supercritical hydrogenation of sunflower oil lie within the values for a gas (Ranz and Marshall, 1952) and a liquid (Brunner, 1985), which is coherent with the definition of a supercritical fluid (Guardo et al., 2006).
Dp, mm
0.10 0.47 0.9205 2.00
Table 6.5.
Re
Sherwood number O E S
647 44.16 44.16 44.18 44.18 27.61 3044 113.43 113.47 113.56 113.78 64.11 5962 208.14 208.32 207.11 209.28 119.85 12954 628.94 621.55 622.79 620.35 360.41
Computed values for Sherwood number for oil fatty acids and hydrogen in the supercritical hydrogenation of sunflower oil at 20 MPa and 473 K at different particle sizes
- 127 -
Chapter Six
100000 10000 1000 Tan et al. (1988) 100 10 Ranz & Marshall (1952) 1 10 100 1000 10000 100000 Brunner (1985)
Sh
THIS WORK
Re p
HYDROGEN OIL
Figure 6.12.
Sherwood number vs. Reynolds number for different particle diameters on the supercritical hydrogenation of sunflower oil at 20 MPa and 473 K
6.3.4.
In order to evaluate the temperature effects on the external mass transfer coefficients for the supercritical hydrogenation of sunflower oil, a simulation set at two different temperatures (457 and 473 K) was done. Particle size of Dp = 0.47 mm was chosen for the simulations because of being considered the optimal particle size for the hydrogenation reaction, as proven with the diffusional model and the intra-particle concentration profiles described in prior sections of this chapter. Values for the kinetic parameters and the values for the diffusion coefficients were set as show in Table 6.3 (for the kinetic model) and Table 6.4 (for the diffusional model). From the numerical results obtained, surface local mass transfer coefficients (see Figure 6.13) and Sherwood numbers (see Table 6.6) for the temperatures selected were estimated, following a procedure similar to that explained priory on this chapter. It can be noticed that a temperature increase is reflected in a direct increase of the surface local mass transfer coefficients. When expressing these numerically obtained mass transfer coefficients in a dimensionless way, it can also be noticed that mass transfer coefficients increase with Reynolds.
Temperature, K
457 473
Table 6.6.
Re
Sherwood number O E S
3972 202.41 202.24 198.86 196.80 139.30 3044 113.43 113.47 113.56 113.78 64.11
Computed values for Sherwood number for oil fatty acids and hydrogen in the supercritical hydrogenation of sunflower oil at different temperatures (particle size, Dp = 0.47 mm)
- 128 -
Chapter Six
0.03
0.045
473 K
0.0225
457 K
0.0075
H2 OIL 0.01125
Dp = 0.47 mm
0 -1.00 -0.50 0.00 0.50 0 1.00
Re
Sherwood number O E S
H
5.73 12.72 17.54 63.89 64.11 64.89
30 8.75 8.75 8.75 8.75 152 19.54 19.54 19.54 19.54 304 30.40 30.24 30.43 30.33 1522 111.76 111.61 111.78 111.69 3044 113.43 113.47 113.56 113.78 6077 114.63 114.43 114.68 114.54
Computed values for Sherwood number for oil fatty acids and hydrogen in the supercritical hydrogenation of sunflower oil at different inlet flow velocities (particle size, Dp = 0.47 mm)
- 129 -
H2
0.03375
Chapter Six
From the numerical results obtained, surface local mass transfer coefficients (see Figures 6.14 and 6.15) and Sherwood numbers (see Table 6.7) for the temperatures selected were estimated, following a procedure similar to that explained priory on this chapter.
0.045
0.03
0.015
0 -1 -0.5 0 0.5 1
Surface velocity effects on the hydrogen local mass transfer coefficients for the supercritical hydrogenation of sunflower oil.
0.025 0.02
-0.5
0.5
Figure 6.15.
Surface velocity effects on the oil fatty acids local mass transfer coefficients for the supercritical hydrogenation of sunflower oil
- 130 -
Chapter Six
From Figures 6.14 and 6.15 and the numerical data shown in Table 6.7 it can be concluded that for high superficial velocities (u > 0.66 m/s), there is no significant effect of the superficial velocity over mass transfer phenomena. This behavior is in complete agree with the expected behavior for a well-stirred reactor. A similar situation has been studied experimentally by Ramrez et al., (2004) and Ramrez (2005), who reported for a CSTR supercritical hydrogenation reactor that an increase in operating stirrer speed (and in consequence, an increase in superficial velocity) from 52 rad/s to 262 rad/s produces no significant increase in the reaction rates of the hydrogenation. When taking a look at the surface local mass transfer coefficients (shown in Figures 6.14, 6.15 and Table 6.7) at low superficial velocities (similar velocities to those used in supercritical packed bed reactors) it can be noticed that there is a clear effect of velocity over mass transfer. Obtained mass transfer coefficients are significantly lower than those obtained for a well-stirred reactor. It was noticed that surface reaction velocities decreased with surface velocity, and that the total mass flux over particle surface increased with the surface velocity. The diminution of the surface reaction rates and the increase of the surface mass fluxes can significantly affect the surface mass transfer coefficients.
Sh = a Re x Sc y
[6.3-2]
Following the aforementioned model, numerically obtained Sherwood numbers (shown in Tables 6.5, 6.6 and 6.7) were correlated as a function of Reynolds and Schmidt numbers, in order to present a simple set of equations capable to predict mass transfer coefficients in the supercritical hydrogenation of sunflower oil. Figure 6.16 shows the obtained correlations for the numerically obtained mass transfer data. In summary, suggested correlations for predicting the oil fatty acids and hydrogen mass transfer coefficients in the supercritical hydrogenation of sunflower oil are as follows:
[6.3-3]
[6.3-4]
- 131 -
Chapter Six
1000
100
Sh oil = 0.5192 Re
0.69
Sc
0.33
[6.3-3]
Sh
10 Sh H 2 = 0.4796 Re 1 1 10 100 1000
0.6765
Sc
0.33
[6.3-4]
Re
10000
100000
- 132 -
Chapter Six
Figure 6.17.
Linoleic fatty acid concentration contour fields for different stages of the packed bed reactor model (T= 473 K; Re = 100)
150
100
50
Re = 40
Re = 70
Re = 100
Re = 150
Re = 200
Conversion profile along the packed bed length for different inlet velocities at 457 K
- 133 -
Chapter Six
As it is important to minimize the presence of trans C18:1 (elaidic fatty acid) in the hydrogenation product due to its health implications (Ramrez, 2005), oil fatty acids mass fraction in the hydrogenated product was also obtained (see Figure 6.19). It can be seen that an increase in the reaction temperature makes the reaction move primarily to the formation of stearic fatty acid, reducing the formation of elaidic fatty acid. An increase in the reaction temperature produces an increase of the reaction rates, favoring the formation of stearic fatty acid.
0.6
Mass fraction
0.4
0.2
O S E
100
0 120
80
60
E - 457 K E - 473 K
Figure 6.19.
L - 457 K L - 473 K
O - 457 K O - 473 K
S - 457 K S - 473 K
Oil fatty acids mass fraction in the hydrogenated product (Re = 200)
CONCLUSIONS
Computational Fluid Dynamics proves to be a useful tool when applied to the study of the catalytic hydrogenation of sunflower oil in the presence of a supercritical solvent. This computational technique allows to obtain in a fast and economical way information that otherwise is extremely complicated and expensive to obtain experimentally. Numerical simulations for the supercritical hydrogenation of sunflower oil were validated against experimental data previously published by this research group (Ramrez et al., 2006), obtaining a good agreement in every case analyzed. Magnitude of relative errors was evaluated for the developed simulations, finding that this value was within the magnitude order of the experimental error previously reported by our research group. Due to the difficulty for obtaining experimental data at very low particle sizes, a CFD simulation extrapolating the catalyst evaluation for Dp = 0.1 mm was also made in order to corroborate the catalyst effectiveness. It can be seen in Figure 6.9 that for a particle with Dp = 0.1 mm, numerically obtained concentration profiles were almost identical to those reported experimentally for Dp = 0.47 mm (Ramrez et al., 2006), reassuring the idea that for a particle diameter of 0.47 mm or lower, the effectiveness factor of the catalyst is close to the unity.
- 134 -
Chapter Six
Obtained numerical data allowed analyzing local mass transfer coefficients over the catalyst surface. Sherwood number for the process was also evaluated, and it was found that its value lies in between those expected for a gas and those expected for a liquid. Particle size, temperature and superficial velocity effects on external mass transfer were analyzed. It was found that mass transfer coefficients increased with an increase in temperature and in particle size. When analyzing the effects of the superficial velocity over the mass transfer coefficients, it was found that for high superficial velocities the system shows the behavior of a well-stirred reactor. It was observed that at high superficial velocities there is no effect over mass transfer coefficients. Numerically obtained Sherwood numbers were correlated as a function of Reynolds and Schmidt numbers, in order to present a simple set of equations capable to predict mass transfer coefficients in the supercritical hydrogenation of sunflower oil. Correlations presented are valid for predicting mass transfer in a range of 30 < Re < 12954 and 0.7 < Sc < 2.1, whit an AARD = 2.8 %. The validation of a single particle model allowed creating a 3D heterogeneous packed bed model in order to study the hydrogenation reaction in a semi-industrial scale, obtaining concentration and conversion profiles along the packed bed. Reaction rates obtained in the first 10 % of the length of the reactor are extremely high in every case analyzed (approximately 1000 times higher than for the traditional biphasic hydrogenation process). Further work must be done in the study of a packed bed reactor configuration in order to find optimal design and operation conditions for the industrial development of the supercritical hydrogenation process.
REFERENCES
Bode, J., (1994). Applications of computational fluid dynamics in the chemical industry. Chemical Engineering & Technology, 17, 145 148. Brunner, G., (1985). Mass transfer in gas extraction, a supercritical fluid technology. In: J.M.L. Penninger, M. Radosz and M.A. McHugh (Eds.). Elsevier Science Publishers, Amsterdam. Dullien, F.A.L., (1979). Porous media: Fluid transport and pore structure. Academic Press, New York. Farrauto R.J., and Bartholomew C.H., (1997). Fundamentals of Industrial Catalytic Processes. London, UK: Chapman & Hall. Guardo, A., Casanovas, M., Magaa, I., Martnez, D., Ramrez, E., Larrayoz, M.A., Recasens, F., (2006). CFD modeling on external mass transfer and intra-particle diffusional effects on the supercritical hydrogenation of sunflower oil. Chemical Engineering Science (submitted). Harris, C.K., Roekaerts, D., Rosendal, F.J.J., Buitendijk, F.G.J., Daskopoulos, Ph., Vreenegoor, A.J.N., Wang, H., (1996). Computational fluid dynamics for chemical reactor engineering. Chemical Engineering Science, 51, 1569 1594. Hrrd, M., Van den Hark, S., Macher, M.B., Moller, P., (2001). Hydrogenation at supercritical single-phase conditions. In: Bertucco, A., and Vetter, G., (Eds.). High Pressure Process Technology: Fundamentals and Applications. Elsevier Science Publishers, New York.
- 135 -
Chapter Six
Hashimoto, K., Muroyama, K., Nagata, S., (1971). Kinetics of the hydrogenation of fatty oils. Journal of the America Oil Chemists Society, 48, 291 295. Jackson, R., (1977). Transport in porous catalysts. Elsevier, New York. Kuipers, J. A. M., and Van Swaaij, W. P. M., (1998). Computational fluid dynamics applied to chemical reaction engineering. In: Wei, J., Anderson, J., Bischoff, K., Denn, M., Seinfield, J., Stephanopoulos, G., (Eds.); Advances in Chemical Engineering 24; Academic Press: San Diego, CA; pp. 227 328. Petersen, E.E., (1965). Chemical reaction analysis. Prentice-Hall, New Jersey. Poling, B., Prausnitz. J., OConnell, J., (2000). The properties of gases and liquids. McGraw-Hill, New York. pp. 3.1 10.56. Ramrez, E., Recasens, F., Fernndez, M., Larrayoz, M.A., (2004). Sunflower oil hydrogenation in Pd/C in SC propane in a continuous recycle reactor. AIChE Journal, 50, 1545 1555. Ramrez, E., (2005). Contribution to the study of heterogeneous catalytic reactions in SCFs: Hydrogenation of sunflower oil in Pd catalysts at single-phase conditions. Ph.D. Thesis. Chemical Engineering Department, Universitat Politcnica de Catalunya, Barcelona. Ramrez, E., Larrayoz, M.A., Recasens, F., (2006). Intraparticle diffusion mechanisms in SC sunflower oil hydrogenation on Pd. AIChE Journal, 52, 1539 1553. Ranade, V., (2002). Computational flow modeling for chemical reactor engineering. Academic press, New York, pp. 244 422. Ranz, W.E., and Marshall Jr., W.R., (1952). Evaporation from drops, part 1. Chemical Engineering Progress, 48, 173 180. Reid, R., Prausnitz, J., Poling, B., (1987). The properties of gases and liquids. McGraw-Hill, Boston. pp. 95 205. Satterfield, C.N., (1970). Mass transfer in heterogeneous catalysis, 2nd ed., McGraw-Hill, New York. Tan, C.-S., Liang, S.-K., Liou, D.-C., (1988). Fluid-solid mass transfer in a supercritical fluid extractor. Chemical Engineering Journal, 38, 17 22. Tacke, T., Wieland, S., Panster, P., (1996). Hardening of fats and oils. In: Rudolf von Rohr, P., and Trepp, Ch., (Eds.); Proceedings of the 3rd International Symposium on High-Pressure Chemical Engineering. Zurich, Switzerland. Elsevier Science Publishers; pp. 17 - 22. Tacke, T., Wieland, S., Panster, P., (2003). Selective and complete hydrogenation of vegetable oils and free fatty acids in supercritical fluids. In: De Simone, J.M., (Ed.) Green Chemistry Using Liquid and Supercritical Carbon Dioxide. Oxford, UK: Oxford Univ. Press. Wheeler, A., (1951). Advances in catalysis, Vol. 3. Academic Press, New York. Wheeler, A., (1955). In: P.H. Emmett (Ed.), Catalysis, Vol. 2. Reinhold, New York. White, F., (1991). Viscous fluid flow. McGraw-Hill, New York. pp. 482 542.
- 136 -
Chapter Six
Yaws, C., (1999). Chemical properties handbook. McGraw-Hill, New York. pp. 1 55. Youngquist, G.R., (1970). SYMPOSIUM ON FLOW THROUGH POROUS MEDIA: Diffusion and flow of gases in porous solids. Industrial & Engineering Chemistry, 62 (8), 52 63.
- 137 -
CHAPTER SEVEN
conclusions
and future work
Conclusions
CFD proves to be a useful tool when modeling mass and heat transfer and chemical reactions in packed bed equipment. It allows obtaining velocity, pressure, temperature and species concentration contour plots inside the bed, reaching information almost impossible to get by means of experimental work. Using CFD commercially available codes (a Finite Element code, Comsol 3.x, and a Finite Volume code, Fluent 5.x/6.x) allowed us to simulate and validate velocity and temperature profiles around simple geometries, and to study mass and heat transfer phenomena and heterogeneous reaction at low and high pressure in packed beds. A summary of the conclusions reached in each section of this thesis work is presented in this chapter.
7.1.
Validation models
Two computational flow models were developed to validate flow and heat transfer around spheres (single or stacked). For the flow validation test, flow around a simple cubic stack of spheres was used as validation model to test the capabilities of the solver reproducing experimental data. The model predictions were verified by comparing the simulation results with the published experimental and computational results. Predicted results showed excellent agreement with the experimental data of Suekane et al., (2003). Mesh sensitivity was established and optimal average mesh density for flow problems could be obtained. For the heat transfer validation test, a sphere suspended in an infinite fluid was used as validation tool to test the capabilities of the solver reproducing an analytical solution. Drag coefficient over particle surface was recorded and compared against the Stokes law and the graphical correlation presented by Lapple and Shepherd (1940), obtaining an overall good agreement between the compared sets of data, and a neglectable mesh dependency on the results. In the case of the prediction of heat transfer parameters, mesh sensitivity tests were performed, and optimal average mesh density over the heat transfer surface was established. Numerical results obtained were compared against the theoretical answer for estimating the heat transfer coefficient obtained by Ranz and Marshall (1952), obtaining a good agreement between numerical and theoretical answers.
7.2.
CFD proves to be useful in the wall to fluid heat transfer parameter estimation, and also for calculation of pressure drop along the bed in packed bed equipment. It was possible to model a realistic case of a packed bed of spheres including contact points within the surfaces involved in the geometry. The calculated velocity profiles fitted qualitatively the expected results, and the calculated values of pressure drop along the bed adjust quite well with previously published and accepted correlations. Flow structures within the bed (i.e., wall channeling, stagnant points, eddy flows) were easily identifiable. Obtained temperature profiles inside the bed allowed estimating wall heat transfer parameters such as Nuw and kr/kf . The results obtained for all of the cases studied (laminar and turbulent) agree among themselves and with the selected empirical and semi-empirical correlations when analyzing pressure drop and effective radial conductivity. This can be explained by the similarity in the
- 141 -
Conclusions
velocity field obtained for each simulation. The calculation of these parameters is more closely related to velocity fields than to mixing parameters. The prediction of the mixing rate within the bed along with the near-wall treatment appreciably affects the estimate of Nuw. Flow regime zones can be identified using the heat transfer coefficient estimate. A laminar solution overestimates the value of this coefficient in the turbulent flow zone, and turbulent solutions tend to underestimate the value of the coefficient in the laminar transition zone. Turbulence models used for simulations do not predict the transition regime well, and this can be seen in the discrepancy between numerically obtained results and correlations in the low Re and transition range. The definition of a good mesh allows calculations of fluid dynamics variables, as velocity and pressure. However, in our case, the proposed geometry governs mesh density and element size in the near-wall area, and this fact affects the definition of an appropriate y+ parameter in order to apply a correct near-wall treatment for certain turbulence models (e.g. the family models). To define an adequate y+ for a correct coupling for the two-equation models at the near-wall treatment is not an easy task. Therefore, the y+ parameter is crucial during the selection of the appropriate turbulence model to apply within the simulation. A good near-wall modeling is fundamental to obtain more accurate results in pressure drop and heat transfer calculations and the selection of the right turbulent model will depend on the geometry proposed and the values obtained for y+ in the wall. Results obtained with the SpalartAllmaras turbulence model show better agreement than the two-equation RANS models for pressure drop and heat transfer parameter estimation. This could be due to the fact that this model uses a coupling between wall functions and damping functions for near-wall treatment, does not include additional diffusion or dissipation terms in its formulation and does not present the stagnation point anomaly. Factors such as the misestimating of , or t can lead to differences in flow and temperature profiles that can be translated into miscalculation of heat transfer parameters. Therefore, the Spalart Allmaras model could be a good tool for these kinds of flows because the y+ problem is solved automatically in spite of the necessity of checking the upper values of y+ (less than 120). Turbulence models used for simulations do not properly predict the transition regime and this can be observed in the discrepancy between numerically obtained results and correlations in the low Re and transition range. Results present slower ratios of convergence at low Re than at high Re.
7.3.
Particle-to-fluid convective mass and heat transfer at low and high pressure
CFD proves to be a reliable tool when modeling convective mass and heat transfer phenomena in packed beds. It allows to analyze either free or forced convection situations and the obtained results can be compared qualitatively and quantitatively against previous published data. Forced convection at low pressure in a packed bed was simulated, and the influence of velocity over mass and heat transfer could be analyzed. For values of Re > 10 it was obtained a good agreement with the correlations presented by Wakao and Kaguei (1982) for mass transfer, and Wakao et al. (1979) for heat transfer. At lower Reynolds numbers (Re < 10), results shows that the fitting against correlation is not good. This situation is especially notorious when analyzing heat transfer. For a single velocity condition different meshes give results in a wide range of Nu and no relation with mesh density can be established in any case. No mesh sensitivity was
- 142 -
Conclusions
noticed for the laminar and transition flow zones, but in the turbulent flow zone a good definition of the mesh around the particles surface is of primal importance in order to capture the turbulence vorticity energetic scales associated effects. Mixed (free+forced) convection at high pressure in a packed bed was also analyzed. For a supercritical fluid in laminar flow regime it was possible to study the effects of the density gradient, flow direction and velocity over mass and heat transfer. It was noticed that the presence of large density gradients conditioned the mesh influence over the numerical results when computing the mixing and the mass/heat transfer within the computed domain. An adverse density gradient generates hydrodynamical instabilities that produce an increase of the axial dispersion and a diminished mass/heat transfer rates. This fact caused numerical instability in the simulation process. In order to eliminate numerical instability, the mesh was locally refined in each case trying to avoid the presence of high density and velocity gradients along the bed. Influence of flow direction over mass/heat transfer was also analyzed and it was noticed that in assisting flow regime, greater heat transfer rates are obtained. The rising in the density along the bed height due to the adverse density gradient helps the axial dispersion to grow, obtaining less mixing within the bed and smaller heat transfer coefficients. Flow velocity also affects the heat transfer rate. The value of Sh and Nu increases almost linearly with flow velocity and this increase is due exclusively to the increase in the contribution of forced convection to the overall mass/heat transfer. Free convection is independent of flow velocity and its value remains almost constant within the studied velocity range. A novel correlation (Eq. [5.3-3]) is presented for estimating the free and forced convection effects and Nu from Re, Pr and GrH . Presented correlations are valid for 9 < Re < 96, 2.2 < Pr < 3.3, and 1 108 < GrH Pr < 4 1010. The obtained numerical results validates the idea that the modified correlation presented (Guardo et al., 2006), based on the one proposed by Stber et al. (1996) for mixed convection mass transfer under supercritical conditions in packed beds, can be used to describe heat transfer phenomena in a supercritical packed bed reactor under mixed convection regime at high pressures.
7.4.
Computational Fluid Dynamics proves to be a useful tool when applied to the study of the catalytic hydrogenation of sunflower oil in the presence of a supercritical solvent. This computational technique allows to obtain in a fast and economical way information that otherwise is extremely complicated and expensive to obtain experimentally. Numerical simulations for the supercritical hydrogenation of sunflower oil were validated against experimental data previously published by this research group (Ramrez et al., 2006), obtaining a good agreement in every case analyzed. Magnitude of relative errors was evaluated for the developed simulations, finding that this value was within the magnitude order of the experimental error previously reported by our research group. Due to the difficulty for obtaining experimental data at very low particle sizes, a CFD simulation extrapolating the catalyst evaluation for Dp = 0.1 mm was also made in order to corroborate the catalyst effectiveness. It can be seen in Figure 6.9 that for a particle with Dp = 0.1 mm, numerically obtained concentration profiles were almost identical to those reported
- 143 -
Conclusions
experimentally for Dp = 0.47 mm (Ramrez et al., 2006), reassuring the idea that for a particle diameter of 0.47 mm or lower, the effectiveness factor of the catalyst is close to the unity. Obtained numerical data allowed analyzing local mass transfer coefficients over the catalyst surface. Sherwood number for the process was also evaluated, and it was found that its value lies in between those expected for a gas and those expected for a liquid. Particle size, temperature and superficial velocity effects on external mass transfer were analyzed. It was found that mass transfer coefficients increased with an increase in temperature and in particle size. When analyzing the effects of the superficial velocity over the mass transfer coefficients, it was found that for high superficial velocities the system shows the behavior of a well-stirred reactor. It was observed that at high superficial velocities there is no effect over mass transfer coefficients. Numerically obtained Sherwood numbers were correlated as a function of Reynolds and Schmidt numbers, in order to present a simple set of equations capable to predict mass transfer coefficients in the supercritical hydrogenation of sunflower oil. Correlations presented are valid for predicting mass transfer in a range of 30 < Re < 12954 and 0.7 < Sc < 2.1, whit an AARD = 2.8 %. The validation of a single particle model allowed creating a 3D heterogeneous packed bed model in order to study the hydrogenation reaction in a semi-industrial scale, obtaining concentration and conversion profiles along the packed bed. Reaction rates obtained in the first 10 % of the length of the reactor are extremely high in every case analyzed (approximately 1000 times higher than for the traditional biphasic hydrogenation process). Further work must be done in the study of a packed bed reactor configuration in order to find optimal design and operation conditions for the industrial development of the supercritical hydrogenation process.
7.5.
Future work
Further work on the study of heat and mass transfer phenomena in packed beds can be done applying a CFD methodology, especially when dealing with supercritical fluids. The advantages of CFD simulations (low cost, fast and reliable information) can be applied to situations where obtaining experimental data is technically complex and not cost effective. When dealing with supercritical fluids, materials and equipment needed to deal with the high pressures and high temperatures required for the experimentation are extremely expensive, limiting sometimes the experimentation possibilities. Further work can be done in this subject, using CFD to simulate complex situations involving supercritical fluids, as radial effects in packed beds or axial dispersion studies when natural convection is involved into the heat/mass transfer phenomena. Further research can be done for studying the effects of the configuration of the packing structure in the efficiency of the transport process, and the effects of the geometrical configuration (particle size, pore size and pore distribution) on transport and reaction parameters.
REFERENCES
Guardo, A., Coussirat, M., Recasens, F., Larrayoz, M.A., Escaler, X., (2006). CFD study on particle-to-fluid heat transfer in fixed bed reactors: Convective heat transfer at low and high pressure. Chemical Engineering Science, 61, 4341 4353.
- 144 -
Conclusions
Lapple, C.E., and Shepherd, C.B., (1940). Calculation of particle trajectories. Industrial & Engineering Chemistry, 32, 605 617. Ramrez, E., Larrayoz, M.A., Recasens, F., (2006). Intraparticle diffusion mechanisms in SC sunflower oil hydrogenation on Pd. AIChE Journal, 52, 1539 1553. Ranz, W.E., and Marshall Jr., W.R., (1952). Evaporation from drops, part 1. Chemical Engineering Progress, 48, 173 180. Suekane, T., Yokouchi, Y., Hirai, S., (2003). Inertial flow structures in a simple-packed bed of spheres. AIChE Journal, 49, 10 17. Stber, F., Vzquez, A.M., Larrayoz, M.A., Recasens, F., (1996). Supercritical fluid extraction of packed beds: external mass transfer in upflow and downflow operation. Industrial & Engineering Chemistry Research, 35, 36183628. Wakao, N., Kaguei, S., Funazkri, T., (1979). Effect of fluid dispersion coefficients on particle-tofluid heat transfer coefficients in packed beds: correlation of Nusselt numbers. Chemical Engineering Science, 34, 325 336. Wakao, N., and Kaguei, S., (1982). Heat and mass transfer in packed beds. Gordon and Breach Science Publishers, New York. pp. 138 160; 264 295.
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APPENDICES
APPENDIX A
BIBLIOGRAPHIC REVIEW
Appendix A
Extract
Oil Oil Essential oil Total extract Carvone, Limonene Oil Oil Total extract - Amyrin - Sitosterol Oil Limonene Total extract
T [K]
313 282 308 303 323 313 305 348 308 315 323 343 308 338 293 323 313 323 295 323 311 323 313 333 303 313 330 303 313
P [M Pa]
12 6 10 15 30 10 35 7.5 30 20 30 30 25 35 15 45 8 28 25 30 7 30 20 30 20 30 10 20 25 20 25
Solvent
CO2 CO2 + ethanol CO2 CO2 + caprylic acid methyl ester CO2 CO2 CO2 + ethyl alcohol CO2 Ethane CO2 CO2 CO2 CO2 + ethanol CO2 + ethanol CO2 + ethanol CO2 CO2 CO2 + ethanol CO2 + propanol CO2 CO2 CO2 + H2O CO2 Propane CO2 CO2 CO2 CO2 CO2 CO2 Propane CO2 + ethanol CO2 + ethanol CO2
References
Doneanu and Anitescu, 1998 Badalyan et al., 1998 Ferreira et al., 1999 Daukas et al., 2002 Baysal and Starmans, 1999 Ills et al., 2000 Rnyai et al., 1998 de Azevedo et al., 2003 Simndi et al., 2002 Mira et al., 1999
Total extract - carotene Oleoresin Terpene lactones and flavonoids Pyrethrins Caffeine Total extract Oleoresin Total extract Antioxidants Essential oil Essential oil Oil Oleoresin Total extract Oil Oil
Ginkgo leaves Ground pyrethrum flowers Guaran seeds Hiprose fruit Jalapeo peppers (Capiscum annuum L.) prepelletised Lemon balm (Melissa Officinalis L.) Lemongrass (Cymbopogon citratus) Lovage (Levisticum officinale Koch.) Nutmeg (Myristica fragans Houttuyn) Pungent spice paprika powder Shells of the bacuri fruit (Platonia insignis Mart) Soybeans Summer savory (Satureja hortensis L.)
333 393 293 313 313 343 298 308 313 308 313 296 323 313 323 296 308 328 289 323 333 353 313
24 31 7 25 10 40 5 25 12 32 10 18 8.5 12 8 35 9 10 40 6.3 20 16 69 12 18
Chiu et al., 2002 Kiriamiti et al., 2003 Saldaa et al., 2002 Ills et al., 1997 del Valle et al., 2003 Ribeiro et al., 2001 Carlson et al., 2001 Daukas et al., 1999 Spricigo et al., 1999 Daood et al., 2002 Monteiro et al., 1997 Montanari et al., 1999 Esquvel et al., 1999
Table A-1.
- 151 -
Appendix A
Raw material
Atlantic mackerel (Scomber scombrus) Black scabbardfish (Aphanopus carbo) Cow brain Dried egg yolk Pigskin Raw wool Sheepskin Wool scour wastes
Extract
Oil PCB, chlorinated pesticides Cholesterol Phospolipids Fat Natural wax Fat Wax
T [K]
308 309 337 323 - 343 313 293 313 303 - 353 318 313 353
P [M Pa]
34.5 10 - 24 23 27 51.7 10 - 60 7 - 20 10 24 10.4 24 25
Solvent
CO2 CO2 CO2 CO2 CO2 CO2 + ethanol CO2 CO2 + toluene
References
Dunford et al., 1998 Antunes et al., 2003 Vedaraman et al., 2005 Boselli and Caboni, 2000 Vaquero et al., 2006 Eychenne et al., 2001 Marsal et al., 2000a Marsal et al, 2000b Lpez-Mesas et al., 2005
Table A-2.
Raw material
Extract
T [K]
333
P [M Pa]
25
Solvent
CO2 + methanol, acetyl acetone, methylisobutyl ketone, Tributyl phosphate CO2 + ethanol/water CO2 + methanol
References
Uranyl nitrate
14.7 - 23 51.6
Table A-3.
Removal efficiency
70 90 %
T [K]
313
P [M Pa]
10
Solvent
CO2 CO2 CO2 + methanol Acetone Hexane Methanol Toluene CO2 CO2 + methanol CO2
References
Brady et al., 1987
~ 100 %
313 423
40
327 353
37.8 34
Table A-4.
- 152 -
Appendix A
Catalyst type
Zeolite Zeolite Deloxan
Solvent
T [K] ALKYLATION
323 473 323 413 433 573
P [MPa]
3.5 5 3.4 15.5 15 20
References
Fan et al., 1997a Clark and Subramaniam, 1998 Hitzler et al., 1998
CRACKING
Zeolite 598 3.4 Dardas et al., 1996
DISPROPORTIONATION
Zeolite Zeolite Zeolite Benzene n-pentane Butane Pentane CO2 593 598 533 573 673 3.36 5.6 20 5 Collins et al., 1998 Tiltscher et al., 1984 Tiltscher and Hofmann, 1986 Niu and Hoffmann, 1995, 1997 Vieville et al., 1993 Yokota et al., 1990, 1991a, 1991b Snavely and Subramaniam, 1997 Clark and Subramaniam, 1996 McCoy and Subramaniam, 1995 Dooley and Knopf, 1987 Fan et al., 1997b
ESTERIFICATION
Sulfonic Ru/Al2O3 Co/SiO2 Fe > 823 0.95 1.3
ISOMERIZATION
1-hexene 1-hexene to olefinic oligomers Toluene to benzaldehyde Isobutane to tert-butyl alcohol Fats and oils Acetophenone Cyclohexene Cyclohexene Unsaturated ketones Fatty acid methyl esters - pirene Palm oil Soybean oil Sunflower oil Pt/Al2O3 Pt/Al2O3 CO2+n-pentane CO2+n-hexane 291 300.7 18 27.7
OXIDATION
Co/Al2O3 Pd/C CO2 281 426 8 4.4 5.4
HYDROGENATION
Deloxan Deloxan Pd/C Pd/Al2O3 Cu Pd/C Pd/C Ni Pd/C CO2 - Propane CO2 - Propane CO2 CO2 Propane CO2 Propane CO2 Propane Dimethyleter 323 433 313 593 343 323 493 473 573 323 338 - 408 393 - 413 428 - 488 8 16 6 12 13.6 12 17.5 15 14 15 14 20 Tacke et al., 2003 Hitzler and Poliakoff, 1997 Arunajatesan et al., 2001 Bertucco et al., 1997 van den Hark et al., 1999, 2000, 2001 Chouchi et al., 2001 Macher and Holmqvist, 2001 King et al., 2001 Ramirez et al., 2004 Ramirez, 2005
Table A-5.
Survey of heterogeneous catalytic reactions carried out under supercritical conditions (Baiker, 1999; Ramirez et al., 2002)
- 153 -
Appendix A
A-4.
and
Typical process equipment, key design issues, and perspectives on the current status of CFD for simulating flows of practical interest in chemical engineering are summarized in Tables A-6 to A-11. (Joshi and Ranade, 2003). Typical equipment Design issues / applications
Pipes, pipe fittings, T mixers, valves, flow meters, membrane modules, heat exchangers, monoliths, etc. Pressure drop, heat transfer coefficient, mixing, residence time distribution, identification of hot spots/dead regions, influence of non-uniform material properties, extrapolation to non-standard configurations, end effects.
Experiments
Influence of small-scale features performance (Liou et al., 2002). on
Physical models
Influence of curvature and severe changes in flow direction on turbulence or complex fluids (Suga, 2003). Constitutive equations based on molecular structure (van Ruymbeke et al., 2002). Turbulence models adaptable to the resolution requirements (Speziale, 1998). Understanding the role of unsteady flows (spatially or temporally) in mixing and other transport processes (Jana et al., 1994).
Behavior of complex fluids in nonrheometric flows (Rothstein and McKinley, 2001). Data at the onset of turbulence (Palikaras et al., 2002). Measurement of wall transport rates for model discrimination (Vogel, 1984). Measurement of local concentration and segregation profiles (Verschuren et al., 2002).
Table A-6.
Typical process equipment, key design issues, and perspectives on the current status of CFD for simulating single-phase flows through conduits/channels (Joshi and Ranade, 2003)
- 154 -
Appendix A
Knowledge of physics
Falling film evaporators, fiber spinning, spray coating, multiphase flow through monoliths, etc. Shape of free surface/film thickness, influence of surface characteristics (roughness/wetting), non-uniform material properties, heat/mass transfer coefficients, hot spots, learning tool for developing macroscopic closure models. CURRENT STATUS Basic models to capture the role of surface forces on the shape of the interface between immiscible phases are available. Understanding of surface characteristics, contact angle, and wetting and wall adhesion is not adequate. Quantitative prediction of instabilities and regime transitions is not yet adequately possible. Commercial CFD codes allow simulating free surface flows with the volume of fluid (VOF) approach or other front tracking methods. Demands on grid resolution/computing resources are high: usually threedimensional simulations are needed; small time step and several iterations per time step are needed for simulating transients accurately; convergence behavior is sensitive to the grid quality VOF-based codes are relatively robust compared to those with surface tracking; simulations require expert intervention. CFD simulations are used more as a learning tool than as a design tool; in some instances, calibrated models may be used for design. PATH FORWARD Wetting and wall adhesion: hysteresis in contact angle, grid quality, curvature effects. Transport at interface: capturing small-scale features of the interface, computation of gradients at the interface. Flow regimes: grid quality, transport of the interface, computational resources. Prediction of die-swell and other peculiar characteristics of viscoleastic fluids. Experiments Physical models Characterization of wetting and drop Models for wetting characteristics dynamics on different surfaces (Ted (Fukai et al., 1995) Mao et al., 1997). Influence of gradients of surface Data on mass and heat transfer through tension on transport rates the interface (Gulawani, 2002). Characterization of film flows and Capturing small-scale structures on associated instabilities (Ambrosini et al., the interface. 2002). Data on the influence of viscoelasticity Interface models to capture regime on evolution of free surfaces (Coopertransitions. White et al., 2002). Constitutive equations suitable for practical flows of interest. Typical process equipment, key design issues, and perspectives on the current status of CFD for simulating free surface flows (Joshi and Ranade, 2003)
Table A-7.
- 155 -
Appendix A
Rotating disk contactors, stirred reactors/mixers, pumps/turbines, screw extruders, rotary kilns/dryers, ball mills, centrifuges, etc. Number, shape, size, location and speed of impellers or rotating walls, mixing/residence time distribution, heat and mass transfer, scale-up/scale-down
CURRENT STATUS
Adequate for single-phase flows in stirred vessels.
Knowledge of physics
Models for simulating dispersion or suspension of multiphase flows are inadequate. Models for granular flows in kilns/ball mills are inadequate. Commercial CFD codes/models allow simulations of rotating elements with either quasi-steady or sliding mesh approaches. Fine resolution is needed to capture vortices around rotating elements; full transient simulations based on the sliding mesh approach are very computation intensive.
Prediction of mean flow is reasonably good. Quantitative prediction of turbulence characteristics is still not good. A priori prediction of multiphase flows in stirred vessels or rotary kiln is not possible; regime-specific models with calibrated parameters may provide useful design information. CFD simulations are used for understanding different design configurations mainly to assist engineering decision making.
Experiments
Data near the top free surface (Desai and Joshi, 1996). Measurement of turbulence kinetic energy, stresses and energy dissipation rate (Joshi et al., 2001) Characterization of unsteady flow and its impact on the performance (Kresta and Wood, 1993). Characterization of cavities formed behind rotating blades (Lu and Ju, 1989). Local measurements of phase fractions, phase velocities, and particle sizes at higher phase fractions (Bomba et al., 1997). Local measurements of heat transfer coefficients at different coil/jacket configurations (Karcz, 1999). Measurements of angle of internal friction, coefficient of restitution, granular pressure, and temperature for solidliquid flows.
Physical models
Calibration of parameters of the turbulence models. Influence of the free surface/vortex on flow in the stirred vessels (Ciofalo et al., 1996) Turbulence models/wall functions for nonNewtonian fluids (Son and Singh, 2002). Ways of capturing low-frequency flow structures. Modified wall functions to capture heat transfer near walls with complex curvatures (Churchill and Zajic, 2002). Interface closures and coalescence/breakup models for high phase factions. Improved models for estimating the frictional viscosity of solid particles sliding on each other. Models for simulating formation of gas cavities behind the blades
Table A-8.
Typical process equipment, key design issues, and perspectives on the current status of CFD for simulating stirred or rotating vessels (Joshi and Ranade, 2003)
- 156 -
Appendix A
Bubble/slurry columns fluidized beds, spray columns/extraction columns, cyclones, settling tanks, crystallizers/precipitators, distillation trays, condensers/evaporators, furnace/boilers, mist eliminators. Distributor design, flow regime, minimal fluidization/suspension velocity, sensitivity with hardware changes, distribution of dispersed phase and interfacial area, mass and heat transfer, entrainment, scale-up, erosion.
CURRENT STATUS
Reasonable for dilute multiphase flows.
Knowledge of physics
Inadequate for dense multiphase flows; closures for interface coupling for turbulent, dense dispersions are not adequate. Models involve several parameters, which have to be obtained from experimental data. Eulerian-Lagrangian and Eulerian-Eulerian approaches are used for simulating diluted and dense flows respectively; several particle trajectories need to be simulated for an adequate picture.
A priori prediction of flow regimes is still not possible. Models are often calibrated without obtaining grid-independent results; ad hoc models to simulate the influence of turbulence or other particles are used. Though basic solvers for Eulerian-Lagrangian and Eulerian-Eulerian approaches are available in commercial CFD codes, user-defined functions are needed to implement problem-specific sub-models and closures. Use in practical design is often indirect: for qualitative screening and for assisting engineering decision making rather than for quantitative simulations.
Experiments
Unambiguous experimental data to determine drag, lift and virtual mass coefficients under different conditions (Tomiyama et al., 2002). Experiments allowing separation of dispersion effects from lift and other effects. Data on Lagrangian quantities (Cassanello et al., 2001). Experiments to quantify the fraction of energy dissipated in the bulk of the continuous phase (away from the interface). Local measurements of size distribution to track evolution of it within the vessel (Buwa and Ranade, 2002). Measurement of the interfacial area and local mass transfer coefficients (Sun et al., 2003).
Physical models
Direct numerical simulation (lattice Boltzmann or surface tracking) of multiphase flows to provide theoretical basis to empirical correlations of drag, lift and virtual mass transfer coefficients (Sankaranarayanan and Sundaresan, 2002). Models to ensure correct Lagrangian correlations (Gouesbet and Berlemont, 1999). Improved models for the interface momentum, energy and mass transfer. Better understanding of the formation of agglomeration/clusters and their influence of transport rates (Harris et al., 2002). Models to estimate the effective dispersion coefficients as a function of particle size and local turbulence length scales. Guidelines to select appropriate coalescence/break-up kernels.
Table A-9.
Typical process equipment, key design issues, and perspectives on the current status of CFD for simulating multiphase flows (Joshi and Ranade, 2003)
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Appendix A
Reactors for fast reactions (comparable time scales of mixing and reactions), combustors, burners, etc. Selectivity and yield, complete combustion and energy efficiency, NOx formation, nozzle designs, etc.
CURRENT STATUS
Reasonable for single phase laminar flow.
Knowledge of physics
Closures for turbulent reactive mixing are available only for simple reaction schemes. Inadequate models for interfacial area limit modeling of multiphase reactive flows. Single phase reactive mixing models may be solved using the existing framework with additional closure models (probability density function/phenomenological approaches); user defined functions are needed for implementing specific phenomenological closures.
Particle level reactions may be simulated with the Eulerian-Lagrangian approach. Simulations of reactive flows are computationally very demanding, and it is difficult to eliminate the influence of numerical issues completely. CFD simulations are used to address design issues of equipment involving single phase or dilute multiphase reactive flows. Capability of simulating multiphase reactive systems with the Eulerian-Eulerian or VOF approach is still in the primitive stages.
Experiments
Measurements of reduction in striation thickness with time under wellcharacterized flows for complex fluids (Fourcade et al., 2001).
Physical models
Better understanding of interaction between turbulent, mixing and reaction for cases with one of the reactants or products existing in a different immiscible phase (Marchisio et al., 2001). Quantification of the role of complex rheology on stretching and folding to create large interfacial areas. Closure models for simulating complex reaction schemes. Models/correlations for interface transport rates from drops/particles with phase change. Models of cluster formation and to predict their influence on reaction rates.
Experiments to quantitatively measure the reduction in scale of mixing and intensity of mixing (Buchmann and Mewes, 2000). Measurements of cross correlations of concentrations for improved closures. Measurements of local interfacial area and transport coefficients from agglomerated particle clusters (van der Bosch, 1998). Measurements of transport coefficients under evaporation or condensation. Single particle combustion data under controlled flow situations.
Table A-10.
Typical process equipment, key design issues, and perspectives on the current status of CFD for simulating reactive flows (Joshi and Ranade, 2003)
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Appendix A
Monoliths, fixed beds, packed columns, trickle-bed reactors, filters, etc. Pressure drop, flow maldistribution and channelling, mixing and residence time distribution, heat/mass transfer coefficients, scale-up.
PATH FORWARD
Representing void space in packed beds: grid quality, computing resources.
Closures for multiphase flow through packed beds: interfacial area, drag. Simulation of flow regimes/transition and unsteady flows. Mixing and liquid dispersion: role of capillary forces/wetting.
Experiments
Measurements of porosity distribution (with different length scales) within a packed bed (mean, axially averaged, standard deviation and so on) with quantification of the way of packing (Sharma et al., 2001). Pressure drop measurements along with local turbulence characteristics (Niven, 2002). Local phase distributions and velocity measurements for gas-liquid flow through well-characterized packed beds (Gladden et al., 2002). Detailed measurements of unsteady flow regimes (quantification of key spatial and temporal scales). Experimental data (global as well as local measurements) on liquid dispersion, bypass and channelling (Tsochatzidis et al., 2002).
Physical models
Direct numerical simulations or VOF simulations are needed to guide the development of closures.
Models to simulate different packing possibilities (Spedding and Spencer, 1995). Interface closure models for estimating gassolid, gas-liquid and liquid-solid phases under different flow regimes (Jiang et al., 2002). Models to represent transient or low Re turbulent flow through complex geometry with severe curvature. Quantification of the role of gradients of porosity and capillary forces on liquid dispersion (Yin et al., 2000). Quantitative representation of the role of wetting and hysteresis on contact angle.
Table A-11.
Typical process equipment, key design issues, and perspectives on the current status of CFD for simulating flow through packed beds (Joshi and Ranade, 2003)
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Appendix A
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Appendix A
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Appendix A
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APPENDIX B
Transport equations, turbulent quantities and convective heat and mass transfer modeling
TURBULENCE MODELS
Appendix B
~ ~ 2 1 ~ ~ ~ Y + S~ ( ) + ( u i ) = G + ( + ) + C b 2 x t x i x ~ x j j j
[B-1] where G is the production of turbulent viscosity and Y is the destruction of turbulent ~ and viscosity that occurs in the near-wall region due to wall blocking and viscous damping. ~ is a user-defined source term. C b 2 are constants and is the molecular kinematic viscosity. S Note that since the turbulence kinetic energy is not calculated in the Spalart-Allmaras model, the last term in Eq. [2.1-8] is ignored when estimating the Reynolds stresses.
~f t = v1
where the viscous damping function, f v1 , is given by
[B-2]
f v1 =
3 3 + C v31
[B-3]
[B-4]
~~ G = C b1 S
[B-5]
~ ~ + 2 2 f v2 d
[B-6]
- 171 -
Appendix B
f v2 = 1
1 + f v1
[B-7]
C b1 and are constants, d is the distance from the wall, and is a scalar measure of the
2 ij ij
where ij is the mean rate-of-rotation tensor and is defined by
[B-8]
ij =
u 1 u i j 2 x j xi
[B-9]
~ Y = C w1 f w d
[B-10]
1
1+ C6 f w = g 6 w3 6 g + C w3
[B-11]
g = r + C w2 r 6 r
[B-12]
~ r ~ 2 2 d
C w1 , C w2 and C w3 are constants, and is given by Eq. [B-6].
[B-13]
C b1 = 0.1355; C w1 = C b1
C b 2 = 0.622;
~ = ;
2 3
C v1 = 7.1;
1 + Cv 2
C w 2 = 0.3;
C w3 = 2.0;
= 0.4187;
[B-14]
- 172 -
Appendix B
u ut d = ut
[B-15]
If the mesh is too coarse to resolve the laminar sublayer, it is assumed that the centroid of the wall-adjacent cell falls within the logarithmic region of the boundary layer, and the law-of-thewall is employed:
ut d 1 u = ln 9.793 u t 0.4187
where u is the velocity parallel to the wall and
[B-16]
C p t (E ) + [ui (E + p )] = k+ t xi x j Prt
where k is the thermal conductivity, tensor, defined as
T x + u i ( ij )eff + S h j
[B-17]
( )
ij eff
u j u i = eff + x i x j
2 eff u i ij 3 xi
[B-18]
( )eff
Prandtl number is 0.85. Turbulent mass transfer is treated similarly, with a default turbulent Schmidt number of 0.7. Wall boundary conditions for scalar transport are handled analogously to momentum, using the appropriate "law-of-the-wall''.
- 173 -
Appendix B
the method of calculating turbulent viscosity the turbulent Prandtl numbers governing the turbulent diffusion of and . the generation and destruction terms in the equation.
The transport equations, methods of calculating turbulent viscosity, and model constants are presented separately for each model. The features that are essentially common to all models follow, including turbulent production, generation due to buoyancy, accounting for the effects of compressibility, and modeling heat and mass transfer.
t ( ) + ( u i ) = + (Prt ) t xi x j t ( ) + ( u i ) = + (Prt ) t xi x j
x + G + S j
[B-19]
2 ( ) + C G + C G C + S 1 3 b 2 k x j
[B-20]
In these equations, G represents the generation of turbulence kinetic energy due to the mean velocity gradients, Gb is the generation of turbulence kinetic energy due to buoyancy, Ym represents the contribution of the fluctuating dilatation in compressible turbulence to the overall dissipation rate, C1 , C 2 , and C 3 are constants, and S and S are user-defined source terms.
and as follows:
- 174 -
Appendix B
t = C
[B-21]
where C is a constant.
C1 = 1.44;
C 2 = 1.92;
C = 0.09;
(Prt )
= 1.0;
(Prt )
= 1.3;
[B-22]
These default values have been determined from experiments with air and water for fundamental turbulent shear flows including homogeneous shear flows and decaying isotropic grid turbulence. They have been found to work fairly well for a wide range of wall-bounded and free shear flows.
+ G + Gb YM + S ( ) + ( ui ) = eff t xi x j x j
[B-23]
2 ( ) + ( u i ) = ( ) + C G + C G C R + S 1 3 b 2 eff t xi x j x j
[B-24] In these equations, G represents the generation of turbulence kinetic energy due to the mean velocity gradients, Gb is the generation of turbulence kinetic energy due to buoyancy, and Ym represents the contribution of the fluctuating dilatation in compressible turbulence to the overall dissipation rate. The quantities and are the inverse effective Prandtl numbers for and , respectively. S and S are user-defined source terms.
- 175 -
Appendix B
2 d
= 1.72 d 3 1 + C v
[B-25]
eff
[B-26]
C 100
[B-27]
Eq. [B-25] is integrated to obtain an accurate description of how the effective turbulent transport varies with the effective Reynolds number (or eddy scale), allowing the model to better handle low-Reynolds-number and near-wall flows . In the high-Reynolds-number limit, Equation [B-25] gives
t = C
[B-28]
with C = 0.0845, derived using RNG theory. It is interesting to note that this value of C is very close to the empirically-determined value of 0.09 used in the standard model.
1.3929 0 1.3929
0.6321
+ 2.3929 0 + 2.3929
0.3679
mol eff
[B-29]
where 0 = 1.0. In the high-Reynolds-number limit ( mol / eff << 1), = 1.393
B-2.2.4. The
The main difference between the RNG and standard models lies in the additional term in the equation given by
C 3 1 2 0 R = 3 1 +
[B-30]
- 176 -
Appendix B
V / , 0 = 4.38,
= 0.012.
[B-31]
The effects of this term in the RNG equation can be seen more clearly by rearranging Eq. [B24]. Using Eq. [B-30], the third and fourth terms on the right-hand side of Eq. [B-24] can be merged, and the resulting equation can be rewritten as
2 * ( ) + ( u i ) = ( ) + C G + C G C 1 3 b 2 eff t xi x j x j
[B-32]
* C2 C 2
C 3 1 0 + 3 1 +
[B-33]
* In regions where < 0 , the R term makes a positive contribution, and C 2 becomes larger
* than C 2 . In the logarithmic layer, for instance, it can be shown that 3.0, giving C 2 2.0, which is close in magnitude to the value of C 2 in the standard model (1.92). As a result, for weakly to moderately strained flows, the RNG model tends to give results largely comparable to the standard model.
In regions of large strain rate ( > 0 ), however, the R term makes a negative contribution,
* making the value of C 2 less than C 2 . In comparison with the standard model, the smaller destruction of augments , reducing and, eventually, the effective viscosity. As a result, in rapidly strained flows, the RNG model yields a lower turbulent viscosity than the standard model.
Thus, the RNG model is more responsive to the effects of rapid strain and streamline curvature than the standard model, which explains the superior performance of the RNG model for certain classes of flows.
C1 = 1.42;
C 2 = 1.68;
[B-34]
U 2 u 2 = 2 t x 3
[B-35]
- 177 -
Appendix B
Using Eq. [B-21] for t t / , one obtains the result that the normal stress, u 2 , which by definition is a positive quantity, becomes negative, i.e., non-realizable, when the strain is large enough to satisfy
U 1 3 .7 x 3C
Similarly, it can also be shown that the Schwarz inequality for shear stresses ( u u
2
[B-36]
2 2 u u ; no
summation over and ) can be violated when the mean strain rate is large. The most straightforward way to ensure the realizability (positivity of normal stresses and Schwarz inequality for shear stresses) is to make C variable by sensitizing it to the mean flow (mean deformation) and the turbulence ( , ). The notion of variable C is suggested by many modelers including Reynolds (1987), and is well substantiated by experimental evidence. For example, C is found to be around 0.09 in the inertial sublayer of equilibrium boundary layers, and 0.05 in a strong homogeneous shear flow. Another weakness of the standard model or other traditional models lies with the modeled equation for the dissipation rate. The well-known round-jet anomaly (named based on the finding that the spreading rate in planar jets is predicted reasonably well, but prediction of the spreading rate for axisymmetric jets is unexpectedly poor) is considered to be mainly due to the modeled dissipation equation. The realizable model was intended to address these deficiencies of traditional models by adopting the following: a new eddy-viscosity formula involving a variable originally proposed by Reynolds (1987). a new model equation for dissipation based on the dynamic equation of the meansquare vorticity fluctuation.
x + G + Gb YM + S j
[B-37]
2 + C V C + C C 3 Gb + S 1 2 1 x + j
[B-38] [B-39]
=V
V = 2VijVij
- 178 -
Appendix B
In these equations, G represents the generation of turbulence kinetic energy due to the mean velocity gradients, Gb is the generation of turbulence kinetic energy due to buoyancy, and Ym represents the contribution of the fluctuating dilatation in compressible turbulence to the overall dissipation rate. S and S are user-defined source terms. Note that the equation (Eq. [B-37]) is the same as that in the standard model (Eq. [B19]) and the RNG model (Eq. [B-23]), except for the model constants. However, the form of the equation is quite different from those in the standard and RNG-based models (Eqs. [B-20] and [B-24]). One of the noteworthy features is that the production term in the equation (the second term on the right-hand side of Eq. [B-38]) does not involve the production of ; i.e., it does not contain the same G term as the other models. It is believed that the present form better represents the spectral energy transfer. Another desirable feature is that the destruction term (the next to last term on the right-hand side of Eq. [B-38]) does not have any singularity; i.e., its denominator never vanishes, even if vanishes or becomes smaller than zero. This feature is contrasted with traditional models, which have a singularity due to in the denominator.
2 t = C
[B-40]
The difference between the realizable model and the standard and RNG models is that C is no longer constant. It is computed from
C =
U * Ao + As
[B-41]
where ij is the mean rate-of-rotation tensor viewed in a rotating reference frame with the angular velocity k . The model constants A0 and As are given by
Ao = 4.04;
As = 6 cos
[B-45]
= cos 1 6W ; W =
1 3
VijV jk Vki ~ u 1 j + u i V V V V ; ; = = ~3 ij ij ij 2 xi x j V
[B-46]
- 179 -
Appendix B
It can be seen that C is a function of the mean strain and rotation rates, the angular velocity of the system rotation, and the turbulence fields.
C 1 = 1.44;
C 2 = 1.9;
(Prt )
= 1.0;
(Prt )
= 1.2;
[B-47]
G = u iu j
u j xi
[B-48]
G = tV 2
[B-49]
where V is the modulus of the mean rate-of-strain tensor, defined by Eqs. [B-39] and [B-46].
The standard wall functions are based on the proposal of Launder and Spalding (1974), and have been most widely used for industrial flows.
B-2.5.1. Momentum
The law-of-the-wall for mean velocity yields
U* =
1 ln 9.793 y * 0.4187
)
- 180 -
[B-50]
Appendix B
U
*
U P C 4 P 2
w /
1 1
[B-51]
C 4 P 2 y P y
*
[B-52]
The logarithmic law for mean velocity is known to be valid for 30 < y * < 300. In the FV code, the log-law is employed when y * > 11.225. When the mesh is such that y * < 11.225 at the wall-adjacent cells, the FV code applies the laminar stress-strain relationship that can be written as
U * = y*
[B-53]
It should be noted that, in the FV code, the laws-of-the-wall for mean velocity and temperature are based on the wall unit, y * , rather than y + . These quantities are approximately equal in equilibrium turbulent boundary layers. y + is defined as:
y+ =
u y
[B-54]
B-2.5.2. Energy
Reynolds' analogy between momentum and energy transport gives a similar logarithmic law for mean temperature. As in the law-of-the-wall for mean velocity, the law-of-the-wall for temperature comprises the following two different laws: linear law for the thermal conduction sublayer where conduction is important logarithmic law for the turbulent region where effects of turbulence dominate conduction
The thickness of the thermal conduction layer is, in general, different from the thickness of the (momentum) viscous sublayer, and changes from fluid to fluid. For example, the thickness of the thermal sublayer for a high-Prandtl-number fluid (e.g., oil) is much less than its momentum sublayer thickness. For fluids of low Prandtl numbers (e.g., liquid metal), on the contrary, it is much larger than the momentum sublayer thickness. The law-of-the-wall implemented in the FV code has the following composite form:
- 181 -
Appendix B
T* =
(Tw TP )C p C 4 P 2
1 1
& q
(y
* < yT
)
[B-55]
} (y
* > yT
where
Pr P = 9.24 Prt
[B-56]
* The non-dimensional thermal sublayer thickness, y T , in Eq. [B-54] is computed as the y * value at which the linear law and the logarithmic law intersect, given the molecular Prandtl number of the fluid being modeled.
The procedure of applying the law-of-the-wall for temperature is as follows. Once the physical properties of the fluid being modeled are specified, its molecular Prandtl number is computed. * Then, given the molecular Prandtl number, the thermal sublayer thickness, y T , is computed from the intersection of the linear and logarithmic profiles, and stored. During the iteration, depending on the y * value at the near-wall cell, either the linear or the logarithmic profile in Eq. [B-55] is applied to compute the wall temperature or heat flux (depending on the type of the thermal boundary conditions).
B-2.5.3. Species
When using wall functions for species transport, the FV code assumes that species transport behaves analogously to heat transfer. Similarly to Eq. [B-54], the law-of-the-wall for species can be expressed for constant property flow with no viscous dissipation as
Y
*
(Y
i,w
Yi )C 4 P 2
1 1
J i,w
Sc y * = 1 ln 9.793 y * + Pc Sc t 0.4187
(y (y
* *
* < yc
) >y )
* c
[B-57]
where Yi is the local species mass fraction, Sc and Sct are molecular and turbulent Schmidt
* numbers, and J i , w is the diffusion flux of species i at the wall. Note that Pc and y c are * calculated in a similar way as P and y T (Eq. [B-56]), with the difference being that the Prandtl numbers are always replaced by the corresponding Schmidt numbers.
- 182 -
Appendix B
B-2.5.4. Turbulence
In the models the equation is solved in the whole domain including the wall-adjacent cells. The boundary condition for imposed at the wall is
=0 n
where n is the local coordinate normal to the wall.
[B-58]
The production of kinetic energy, G , and its dissipation rate, , at the wall-adjacent cells, which are the source terms in the equation, are computed on the basis of the local equilibrium hypothesis. Under this assumption, the production of and its dissipation rate are assumed to be equal in the wall-adjacent control volume. Thus, the production of is computed from
G w
w U =w 1 1 y 0.4187 C 4 P 2 y P
[B-59]
P =
C 4 P 2 0.4187 y P
[B-60]
The equation is not solved at the wall-adjacent cells, but instead is computed using Eq. [B60]. Note that, as shown here, the wall boundary conditions for the solution variables, including mean velocity, temperature, species concentration, , and , are all taken care of by the wall functions. Therefore, you do not need to be concerned about the boundary conditions at the walls. The standard wall functions work reasonably well for a broad range of wall-bounded flows. However, they tend to become less reliable when the flow situations depart too much from the ideal conditions that are assumed in their derivation. Among others, the constant-shear and local equilibrium hypotheses are the ones that most restrict the universality of the standard wall functions. Accordingly, when the near-wall flows are subjected to severe pressure gradients, and when the flows are in strong non-equilibrium, the quality of the predictions is likely to be compromised.
- 183 -
Appendix B
T (E ) + [u i (E + p )] = k eff + u i ( ij )eff t xi x j x j
+ Sh
[B-61]
where k eff is the effective thermal conductivity, E is the total energy, and ij deviatoric stress tensor, defined by Eq. [B-18] The term involving ij
( )eff
is the
( )eff
energy equation, depending on the physical models used. See Section 2.1.3 for more details. For the standard and realizable models, the effective thermal conductivity is given by
k eff = k +
C p t Prt
[B-62]
where k is the thermal conductivity. The default value of the turbulent Prandtl number is 0.85. For the RNG model, the effective thermal conductivity is
k eff = C p eff
where is calculated from Eq. [B-29], but with 0 = 1/Pr = k / C p .
[B-63]
The fact that varies with mol / eff , as in Eq. [B-29], is an advantage of the RNG model. It is consistent with experimental evidence indicating that the turbulent Prandtl number varies with the molecular Prandtl number and turbulence (Kays, 1994). Eq. [B-29] works well across a very broad range of molecular Prandtl numbers, from liquid metals (Pr 10-2) to paraffin oils (Pr 103), which allows heat transfer to be calculated in low-Reynolds-number regions. Eq. [B-29] smoothly predicts the variation of effective Prandtl number from the molecular value ( = 1/Pr) in the viscosity-dominated region to the fully turbulent value ( = 1.393) in the fully turbulent regions of the flow. Turbulent mass transfer is treated similarly. For the standard and realizable models, the default turbulent Schmidt number is 0.7. For the RNG model, the effective turbulent diffusivity for mass transfer is calculated in a manner that is analogous to the method used for the heat transport. The value of 0 in Eq. [B-29] is 0 = 1/Sc, where Sc is the molecular Schmidt number.
- 184 -
Appendix B
( ) + ( u i ) = t xi x j x j ( ) + ( u i ) = t xi x j x j
+ G Y + S + G Y + S
[B-64]
[B-65]
In these equations, G represents the generation of turbulence kinetic energy due to mean velocity gradients. G represents the generation of . and represent the effective diffusivity of and , respectively. Y and Y represent the dissipation of and due to turbulence. All of the above terms are calculated as described below. S and S are userdefined source terms.
= +
(Prt ) (Prt )
t
[B-66]
= +
[B-67]
t = *
[B-68]
* + Re t 0 R * * = Re 1+ t R
[B-69]
- 185 -
Appendix B
Re t =
R = 6;
* 0 =
i
3
i = 0.072;
[B-70]
B-3.3.2. Production of
The production of is given by
G =
[B-71]
= *
+ Re t 0 R Re 1+ t R
[B-72]
where R = 2.95. * and Re t are given by Eqs. [B-69] and [B-70] respectively. Note that, in the high-Reynolds-number form of the model, = = 1 .
[B-73]
f*
[B-74]
- 186 -
Appendix B
X =
1 3 x j x j
[B-75]
* = i* [1 + * F (M t )]
4 Re t 4 + R 15 * i* = 4 Re 1+ tR
[B-76]
[B-77]
* = 1.5;
R = 8;
* = 0.09;
[B-78]
B-3.4.2. Dissipation of
The dissipation of is given by
Y = f 2 f = 1 + 70 X 1 + 80 X
[B-79]
[B-80]
X =
ij jk Vki
( )
*
[B-81]
The strain rate tensor, Vij , is defined by Eq. [B-46]. The rotation rate tensor, ij , is defined by Eq. [B-9]. Also,
= i 1
i* * F (M t ) i
[B-82]
0 F (M t ) = 2 2 M t M t0
M t M t0 M t > M t0
[B-83]
- 187 -
Appendix B
M t2 =
2 ; a2
M t 0 = 0.25;
a = RT
[B-84]
* model, i* = . In the
= 0.52;
R = 2.95;
0 = ;
R = 6;
[B-85]
(u * ) + w =
2
+ + = min w ,
[B-86]
i (y + )
[B-87]
50 2 + + w = s 100 + s
s+ < 25
[B-88]
25
+ s
s+ = max 1.0,
s u *
[B-89]
and k s is the roughness height. In the logarithmic (or turbulent) region, the value of + is
+ =
1
*
+ du turb dy +
[B-90]
- 188 -
Appendix B
u*
* y
[B-91]
References
Choudhury, D., Kim, S.-E., Flannery, W.S., (1993). Calculation of turbulent separated flows using a renormalization group based k- turbulence model. American Society of Mechanical Engineers, Fluids Engineering Division (Publication) FED 149, 177 187. Jayatilleke, C., (1969). The Influence of Prandtl number and surface roughness on the resistance of the laminar sublayer to momentum and heat transfer. Progress in Heat and Mass Transfer, 1, 193 321. Kays, W.M., (1994). Turbulent Prandtl number. Where are we?. Journal of Heat Transfer, 116, 284 295. Launder, B.E. and Spalding, D.B., (1972). Lectures in mathematical models of turbulence. Academic Press, London. Launder, B.E. and Spalding, D.B., (1974). The numerical computation of turbulent flows. Computer Methods in Applied Mechanics and Engineering, 3, 269 289. Reynolds, W.C., (1987). Fundamentals of turbulence for turbulence modeling and simulation. Lecture notes for Von Karman Institute, agard report No. 755. Shih, T.-H., Liou, W.W., Shabbir, A., Yang, Z., Zhu, J., (1995). New k- eddy viscosity model for high Reynolds number turbulent flows. Computers and Fluids, 24, 227 238. Spalart, P. and Allmaras, S., (1992). A one-equation turbulence model for aerodynamic flows. Technical Report AIAA-92-0439, American Institute of Aeronautics and Astronautics. Wilcox, D.C., (1998a). Reassessment of the scale-determining equation for advanced turbulence models. AIAA Journal, 26, 1299 1310. Wilcox, D.C., (1998b). Multiscale model for turbulent flows. AIAA Journal, 26, 1311 1320.
- 189 -
APPENDIX C
DIMENSIONLESS NUMBERS
Appendix C
Bi =
Figure C-1. Jean Baptiste Biot
hw L kr
[C-1]
u2 Ec = C p T
[C-2]
Eu =
p u2
[C-3]
- 193 -
Appendix C
Fr =
u g Dp
[C-4]
GrH =
3 g (Ts T )D p
[C-5]
There is an analogous form of the Grashof number used in cases of natural convection mass transfer problems: Figure C-5. Franz Grashof
gD 3 p GrD =
[C-6]
Ma =
u u sound
[C-7]
- 194 -
Appendix C
Nu =
hD p kf
[C-8]
Pe =
D p uC p kf
= Re Pr
[C-9]
Pr =
Figure C-9. Ludwig Prandtl
Cp kf
[C-10]
- 195 -
Appendix C
Ra =
2 D3 p g C p T
kf
= Gr Pr
[C-11]
Re =
D p u
[C-12]
Sc =
D AB
[C-13]
- 196 -
Appendix C
Sh =
kc D p D AB
[C-14]
St =
h Cp u
Nu Re Pr
[C-15]
Sr =
D p
u
[C-16]
- 197 -
Appendix C
Re t =
D p u
t
C p t kt
[C-17]
Prt =
[C-18]
Sc t =
t D AB
[C-19]
constant value within the bed, justified in the fact that majority of experimental results shows a range of variations between 0.75 < Prt < 2 for air and water (Kays, 1994).
References
Kays, W.M., (1994). Turbulent Prandtl number. Where are we? Journal of Heat Transfer, 116, 284 295. White, F., (1991). Viscous Fluid Flow; McGraw Hill, New York, pp. 482 542.
- 198 -
APPENDIX D
FLUID PROPERTIES
Appendix D
D-1. Density
D-1.1. Gas @ atmospheric pressure
In the case of a gas at atmospheric pressure it was chosen to define the density using the ideal gas law for an incompressible flow, which is implemented by default in the FV code (Fluent Inc., 2005). In this case, the density is computed as:
p op M w RT
[D-1]
where R is the universal gas constant, Mw is the molecular weight of the gas and pop is the operating pressure. In this form, the density depends only on the operating pressure and not on the local relative pressure field.
D-1.2. Fluid @ P Pc
In the case of a supercritical fluid it was chosen to define the density using a cubic equation of state (EOS). In this case the density is computed as:
p op M w zRT
[D-2]
where z is the compressibility factor obtained from solving a cubic EOS, which in general form can be expressed as:
z 3 1 + B * uB * z 2 + A* + wB *2 uB * uB *2 z A* B * wB *2 wB *3 = 0
where:
[D-3]
A* =
and
aP R 2T 2
[D-4]
B* =
bP RT
[D-5]
Two cubic EOS were used to estimate the density of a fluid in supercritical conditions during the development of this thesis. Redlich-Kwong EOS (Redlich and Kwong, 1949) was used for estimating the density of a pure substance, and Peng-Robinson EOS (Peng and Robinson, 1976) was applied for estimating the density of a mixture. For these equations, a, b, u and w take the values listed in Table D-1.
- 201 -
Appendix D
Equation
RedlichKwong
u
1
w
0
b
0.08664 RTc Pc
0.07780 RTc Pc
a
0.42748 R 2Tc2.5 Pc T 0.5
-1
As commercial CFD codes do not offer real-gas equations of state within their default equation system, these equations have to be created and uploaded to the CFD solver if a supercritical fluid has to be modelled. In order to implement the aforementioned EOS within the CFD solver, user-defined functions (UDF) and user-defined equations (UDE) were used. For the UDF creation, an analytical solution of the EOS was compiled using a build-up C++ compiler (incorporated within the CFD software), and included within the equation system of the CFD solver. This strategy allowed the CFD code to compute the density of the fluid as a function of the static pressure and the temperature in every point of the computational grid. An example of a UDF for estimating the density of CO2 using the Redlich-Kwong EOS would be as follows: %UDF EXAMPLE% %PROPERTY TO BE MODIFIED INTO SOLVER: DENSITY% %FLUID: CO2% %Tr: 304.1 K% %Pr: 7380000 Pa% %EOS: REDLICH-KWONG% #include "udf.h" DEFINE_PROPERTY(cell_density, cell, thread) { real ro; real a; real b; real z; real tr; real pr; real a2; real b2; real r; real q; real f; real g; real c; real d; real e; real fi; real z1; real z2; real z3; real t=C_T(cell, thread);
- 202 -
Appendix D
real p=C_P(cell, thread); tr=t/304.1; pr=p/7380000.; a=6456696.46; b=0.02968; a2=0.42747*pr/pow(tr,(5/2)); b2=0.08664*pr/tr; r=a2*b2; q=pow(b2,2.)+b2-a2; f=((-3.*q)-1.)/3.; g=((-27.*r)-(9.*q)-2.)/27.; c=pow((f/3.),3.)+pow((g/2.),2.); if (c>0.0) { d=pow(((-g/2.)+pow(c,0.5)),(1./3.)); e=pow(((-g/2.)-pow(c,0.5)),(1./3.)); z=d+e+(1./3.); } else { fi=a*cos(-6.75*pow(g,2.)/pow(f,3.)); z1=(2*pow((-f/3.),0.5)*cos(fi/3.))+(1/3); z2=(2*pow((-f/3.),0.5)*cos((fi/3.)+2.0944))+(1./3.); z3=(2*pow((-f/3.),0.5)*cos((fi/3.)+4.1888))+(1./3.); if (z1>z2) { if (z1>z3) z=z1; else z=z3; } else { if (z2>z3) z=z2; else z=z3; } } ro=44.*p/(8314.*z*t); } return ro;
For situations where the static pressure could be considered as constant along the computed model, a simplified density model could be used. This simplified model consisted on expressing the density of the fluid (at constant pressure) as a function of temperature, fitting the results obtained with the EOS to a 6th degree polynomial expression. The obtained polynomial expression (which can be written in general form as shown in Eq. [D-6]), can then be fed into the CFD solver as an UDE.
= aT 6 + bT 5 + cT 4 + dT 3 + eT 2 + fT + g
[D-6]
A sample of the obtained coefficients for Eq. [D-6] for estimating the density of supercritical CO2 can be seen in Table D-2, and a graphical representation of the previously stated polynomial fitting is shown in Figure D-1. In order to quantify the round-up error associated
- 203 -
Appendix D
with the numerical solver, a simulation for a density varying flow of supercritical CO2 in a Venturi tube was set, and obtained numerical values were compared with the prediction of the EOS, resulting in a good agreement between the numerical results and the EOS estimation (see Figure D-2).
P [MPa]
8 10 12 14 16 18 20 22 Table D-2.
a
1.13 x 10-9 -4.05 x 10-10 -1.44 x 10-9 -4.78 x 10-10 6.61 x 10-11 1.79 x 10-10 1.43 x 10-10 8.89 x 10-11
b
-2.65 x 10-6 8.77 x 10-7 3.34 x 10-6 1.14 x 10-6 -1.22 x 10-7 -3.98 x 10-7 -3.24 x 10-7 -2.04 x 10-7
c
2.58 x 10-3 -7.80 x 10-4 -3.22 x 10-3 -1.14 x 10-3 8.58 x 10-5 3.65 x 10-4 3.04 x 10-4 1.94 x 10-4
d
-1.33 x 100 3.63 x 10-1 1.65 x 100 6.01 x 10-1 -2.70 x 10-2 -1.77 x 10-1 -1.51 x 10-1 -9.76 x 10-2
e
3.87 x 102 -9.30 x 101 -4.72 x 102 -1.78 x 102 2.75 x 100 4.77 x 101 4.18 x 101 2.73 x 101
f
-5.98 x 104 1.23 x 104 7.17 x 104 2.78 x 104 3.46 x 102 -6.78 x 103 -6.12 x 103 -4.05 x 103
g
3.84 x 106 -6.48 x 105 -4.52 x 106 -1.81 x 106 -6.86 x 104 3.99 x 105 3.72 x 105 2.50 x 105
550 400 250 100 310 330 350 8 MPa 16 MPa 370 390 Temperature [K] 10 MPa 18 MPa 12 MPa 20 MPa 410 430 14 MPa 22 MPa 450
Figure D-1.
255
from CFD
[kg/m ]
3
250 245 240 235 230 230 235 240 245 250 255
Figure D-2.
[kg/m3]
from EOS
Density parity plot for supercritical CO2 (numerical results vs. EOS)
- 204 -
Appendix D
D-1.3. Mixtures
In order to study how the density of a mixture was estimated by the CFD software, a 2dimensional cylinder of 5 m length and 0.2 m diameter was created. From one side of the tube CO2 in laminar flow regime was fed to the model. In order to impose a density gradient along the tube, a flux of 0.01 kg/s of toluene vapor was imposed through the pipe walls. Three temperatures (i.e. 298, 310 and 320 K) and four pressures (i.e. 0.1, 6, 8 and 20 MPa) were taken as study cases. For atmospheric pressure situations, incompressible ideal gas law was used to estimate density. For near-critical and supercritical conditions, Peng Robinson equation of state for density was implemented through a C++ subroutine inside the CFD solver. For each of the simulations it was recorded the C7H8 mass fraction together with the mixture density at the central axis of the tube. The numerical results obtained were compared against the estimation through equations of state (Guardo et al., 2005). Low pressure density was determined by ideal gas law for both of the pure components assuming the flow as incompressible. In such way the density is computed by the CFD solver as shown in Eq. [D-7].
P y R T i Mw
[D-7]
It was expected that for low pressure both methods would give similar results due to the low interaction forces between the molecules. The results obtained at the different temperatures tested (i.e. 298, 310 and 320K) are very similar to the ones shown in Figure D-3. From those results it was checked that the numerical error of the CFD solver when applying the ideal gas law was neglectable.
1.95 Mixture density [kg/m ]
3
0.06
0.08
0.1
Figure D-3.
Density estimation for a binary mixture [C7H8/CO2] at 298 K and 0.1 MPa
In order to study high pressure situations, estimation of the mixture density was checked at 6, 8 and 20 MPa. Peng-Robinson EOS was implemented via UDF in order to obtain the compressibility factors. In such way the density is computed by the CFD solver as shown in Eq. [D-8].
- 205 -
Appendix D
P y z R T i Mw
[D-8]
An example of the results obtained for high pressure situations can be seen in Figure D-4. In general, for all situations simulated, it was noticed that despite the fact that the estimation done by the CFD solver is close to the EOS prediction for low solute mass fractions due to the good pure component density estimation, such a simple mixing rule is not able to predict the mixture critical point or phase changes. For all cases analyzed the divergence between CFD estimated results and the EOS prediction increases as the mass fraction of solute increases. According to this, the greatest numerical errors obtained for the CFD simulations were located at the saturation point (equilibrium conditions at the specified pressure and temperature). Maximum error measured when estimating density was of 6.24%, which is an acceptable value.
300 Mixture density [kg/m3]
275
250
225
EOS estimation
CFD Estimation
Figure D-4.
D-2. Viscosity
D-2.1. Gas @ atmospheric pressure
In the case of a gas at atmospheric pressure it was chosen to define the density using a viscosity power law, which is implemented by default in the FV code (Fluent Inc., 2005). In this case, the viscosity is computed as:
T = 0 T 0
[D-9]
where T0 and 0 are reference values for temperature and viscosity, respectively. Table D-3 shows the values of the coefficients involved in Eq. [D-9] for CO2 and air at moderated pressures and temperatures.
- 206 -
Appendix D
Fluid
CO2 Air Table D-3.
0 [Pa s]
1.37 x 10-5 1.716 x 10-5
T0 [K]
273.11 273.11
n
0.79 0.666
D-2.2. Fluid @ P Pc
In the case of a supercritical fluid it was chosen to define the viscosity following the procedure recommended by Lucas (1980), which first calculates the parameters Z1 and Z2 for the reduced temperature of interest:
0 Z 1 = 0.807Tr0.618 0.357e 0.449Tr + 0.340e 4.058Tr + 0.018 FP0 FQ = 0 0 0
[D-10]
where FP and FQ are low pressure polarity and quantum correction factors determined as shown in Eqs. [D-12] and [D-13] respectively. To obtain the first of the aforementioned correction factors, a reduced dipole moment is required. Lucas defines this quantity as
r = 1.75216 10 29
0
2 Pc
Tc2
[D-11]
FP0 = 1 + 30.55(0.292 z c )
0
F = 1 + 30.55(0.292 z c )
0 P
FP0 = 1
0 r < 0.022
1.72
1.72
[D-12]
The factor FQ is used only for the quantum gases He, H2 and D2.
0 FQ = 1.22Q 0.15 1 + 0.00385 (Tr 12 )
Mw
Tr 12
0
[D-13]
Where Q = 1.38 for He, 0.76 for H2 and 0.52 for D2. For non-quantum gases, FQ = 1. If (1 < Tr < 40) and (0 < PR 100), then
[D-14]
- 207 -
Appendix D
where follows:
is found from Eq. [D-10]. The values of the constants in Eq. [D-14] are defined as
a=
[D-15]
Y=
Z2 Z1
[D-16]
FP =
[D-17]
FQ =
)[
0 Q
[D-18]
Z 2 FP FQ
[D-19]
where
Tc = 0.176 M 3 P4 w c
[D-20]
The aforementioned method for viscosity estimation was implemented into the CFD solver via UDF. An example of a UDF for estimating the viscosity of CO2 using the Lucas method would be as follows:
- 208 -
Appendix D
%UDF EXAMPLE% %PROPERTY TO BE MODIFIED INTO SOLVER: VISCOSITY% %FLUID: CO2% %Tr: 304.1 K% %Pr: 7380000 Pa% %METHOD: LUCAS% #include "udf.h" DEFINE_PROPERTY(cell_viscosity, cell, thread) { real mu; real a; real b; real c; real d; real e; real f; real mu_lp; real tr; real pr; real t=C_T(cell, thread); real p=C_P(cell, thread); tr=t/304.1; pr=p/7380000; a=(0.001245/tr)*exp(5.1726*pow(tr,-0.3286)); b=a*((1.6553*tr)-1.2723); c=(0.4489/tr)*exp(3.0578*pow(tr,-37.7332)); d=(1.7368/tr)*exp(2.2310*pow(tr,-7.6351)); e=1.3088; f=0.9425*exp(-0.1853*pow(tr,0.4489)); mu_lp=((0.807*pow(tr,0.618))-(0.357*exp(-0.449*tr))+(0.340*exp(4.058*tr))+0.018)/39194.92; mu=mu_lp*(1+((a*pow(pr,e))/((b*pow(pr,f))+pow((1+(c*pow(pr,d))), -1)))); } return mu;
For situations where the static pressure could be considered as constant along the computed model, a simplified viscosity model could be used. This simplified model consisted on expressing the viscosity of the fluid (at constant pressure) as a function of temperature, fitting the results obtained with the theoretical method to a 6th degree polynomial expression. The obtained polynomial expression (which can be written in general form as shown in Eq. [D-21]), can then be fed into the CFD solver as an UDE.
= aT 6 + bT 5 + cT 4 + dT 3 + eT 2 + fT + g
[D-21]
A sample of the obtained coefficients for Eq. [D-21] for estimating the viscosity of supercritical CO2 can be seen in Table D-4, and a graphical representation of the previously stated polynomial fitting is shown in Figure D-5. In order to quantify the round-up error associated with the numerical solver, a simulation for a viscosity-varying flow of supercritical CO2 in a Venturi tube was set, and obtained numerical values were compared with the prediction of the Lucas method, resulting in a good agreement between the numerical results and the theoretical estimation (see Figure D-6).
- 209 -
Appendix D
P [MPa]
8 10 12 14 16 18 20 22 Table D-4.
a
2.22 x 10-18 -1.01 x 10-18 -4.11 x 10-18 -4.77 x 10-18 -4.18 x 10-18 -3.32 x 10-18 -2.52 x 10-18 -1.75 x 10-18
b
-5.27 x 10-15 2.10 x 10-15 9.30 x 10-15 1.09 x 10-14 9.57 x 10-15 7.60 x 10-15 5.71 x 10-15 3.89 x 10-15
c
5.21 x 10-12 -1.78 x 10-12 -8.72 x 10-12 -1.03 x 10-11 -9.08 x 10-12 -7.19 x 10-12 -5.36 x 10-12 -3.57 x 10-12
d
-2.74 x 10-9 7.80 x 10-10 4.33 x 10-9 5.17 x 10-9 4.57 x 10-9 3.60 x 10-9 2.66 x 10-9 1.72 x 10-9
e
8.07 x 10-7 -1.84 x 10-7 -1.20 x 10-6 -1.45 x 10-6 -1.28 x 10-6 -1.01 x 10-6 -7.34 x 10-7 -4.61 x 10-7
f
-1.26 x 10-4 2.18 x 10-5 1.77 x 10-4 2.16 x 10-4 1.91 x 10-4 1.49 x 10-4 1.07 x 10-4 6.47 x 10-5
g
8.23 x 10-3 -9.52 x 10-4 -1.07 x 10-2 -1.33 x 10-2 -1.18 x 10-2 -9.12 x 10-3 -6.41 x 10-3 -3.67 x 10-3
9.E-05
Viscosity [Pa s]
6.E-05
2.E-05 310 330 350 8 MPa 16 MPa 370 390 Temperature [K] 10 MPa 18 MPa 12 MPa 20 MPa 410 430 14 MPa 22 MPa 450
Figure D-5.
2.15E-05
2.14E-05
Figure D-6.
Viscosity parity plot for supercritical CO2 (numerical results vs. Lucas method)
- 210 -
Appendix D
D-2.3. Mixtures
To estimate the viscosity of a mixture (at low or high pressure), a similar test to that described in section D-1.3. was developed. In this test, the pure component viscosity was calculated by the aforementioned method of Lucas (1980), imposed to the CFD solver via UDF or UDE. For estimating the viscosity of the mixture, a mass weighted mixing rule was applied:
= Yi i
i
[D-22]
Results obtained with the CFD solver were compared against those obtained using Lucas Method for mixtures (i.e., see Figure D-7). The results are almost identical for the three temperatures tested in atmospheric pressure situations. From Figure D-7 it can be seen that the calculations through CFD are almost exactly the same as the ones done with the contrast method, proving as done for the density that the CFD solver fits the results expected with the selected methods for comparison.
1.57E-05
Viscosity [Pa s]
1.53E-05
1.49E-05
Figure D-7.
Viscosity estimation for a binary mixture [C7H8/CO2] at 310 K and 0.1 MPa
1.E-03
Viscosity [Pa s]
1.E-04
1.E-05
0.025
0.05
0.075
0.1
Figure D-8.
- 211 -
Appendix D
An example of the results obtained for the estimation of viscosity in high pressure situations can be seen in Figure D-8. As happened with density, for all cases analyzed the divergence between CFD estimated results and Lucas estimation increases as the mass fraction of solute increases. According to this, the greatest numerical errors obtained for the CFD simulations were located at the saturation point. Measured errors were lower than 10 %, which is an acceptable range (Guardo et al., 2005).
D-3.2. Fluid @ P Pc
In the case of a supercritical fluid it was chosen to define the thermal conductivity using excess thermal conductivity correlations (Stiel and Thodos, 1964).
(k k )z
0
5 c
5 c 5 c
= 1.22 10 2 e 0.535 r 1
)
) )
r < 0.5
0.5 < r < 2.0 2.0 < r < 2.8
(k k )z
0
(k k )z
0
where
3 Tc M w N 02 = 5 4 R Pc 1 6
[D-26]
The aforementioned method for thermal conductivity estimation was implemented into the CFD solver via UDF. An example of a UDF for estimating the thermal conductivity of CO2 using the thermal excess method would be as follows: %UDF EXAMPLE% %PROPERTY TO BE MODIFIED INTO SOLVER: THERMAL CONDUCTIVITY% %FLUID: CO2% %Tr: 304.1 K% %Pr: 7380000 Pa% %METHOD: THERMAL EXCESS% #include "udf.h" DEFINE_PROPERTY(cell_thermal_conductivity, cell, thread) { real ro=C_R(cell, thread);
- 212 -
Appendix D
ror=ro/468.58; ko=-0.007215+(0.00008015*t)+(0.000000005477*pow(t,2.)(0.00000000001053*pow(t,3.); if (ror<0.5) k=(0.0385*(exp(0.535*ror)-1))+ko; else if (ror<2.) k=(0.036*(exp(0.67*ror)-1.069))+ko; else if (ror<2.8) k=(0.0082*(exp(1.155*ror)+2.016))+ko; } return k;
In order to quantify the round-up error associated with the numerical solver, a simulation for a thermal conductivity-varying flow of supercritical CO2 in a Venturi tube was set, and obtained numerical values were compared with the prediction of the thermal excess method, resulting in a good agreement between the numerical results and the theoretical estimation (see Figure D-9).
0.0337
0.0335
0.0333
0.0331
Figure D-9.
Thermal conductivity parity plot for supercritical CO2 (numerical results vs. thermal excess method)
- 213 -
Appendix D
D-4.2. Fluid @ P Pc
In the case of a supercritical fluid it was chosen to define the heat capacity relating it to the value in the ideal-gas state, at the same temperature and composition:
0 Cp = Cp + C p
[D-27]
where this relation applies to either a pure gas or a mixture at constant composition. C p is a residual heat capacity. For a pressure-explicit equation of state, C p is most conveniently determined by (see Modell and Reid, 1983):
T (P T )V 2P C p = T dV (P V ) R T 2 T
V 2
[D-28]
The aforementioned method for the heat capacity estimation was implemented into the CFD solver via UDF. An example of a UDF for estimating the heat capacity of CO2 using the thermal excess method would be as follows: %UDF EXAMPLE% %PROPERTY TO BE MODIFIED INTO SOLVER: HEAT CAPACITY% %FLUID: CO2% %Tr: 304.1 K% %Pr: 7380000 Pa% %METHOD: RESIDUAL HEAT CAPACITY - EOS% #include "udf.h" DEFINE_PROPERTY(cell_heat_capacity, cell, thread) { real ro=C_R(cell, thread); real t=C_T(cell, thread); real co; real dc; real c; real a; real b; real c; real d; real e; real f; real g; real h; real v; v=0.044/ro; co=19.8+(0.07344*t)-(0.00005602*pow(t,2.)) +(0.00000001715*pow(t,3.)); a=6.46; b=0.0000297; c=0.75*a/(b*pow(t,1.5)); d=log((v+b)/v); e=8.314/(v-b); f=a/(2*v*(v+b)*pow(t,1.5)); g=a*((2*v)+b)/(pow(t,0.5)*pow(v,2.)*pow((v+b),2.));
- 214 -
Appendix D
For situations where the static pressure could be considered as constant along the computed model, a simplified heat capacity model could be used. This simplified model consisted on expressing the heat capacity of the fluid (at constant pressure) as a function of temperature, fitting the results obtained with the theoretical method to a 6th degree polynomial expression. The obtained polynomial expression (which can be written in general form as shown in Eq. [D29]), can then be fed into the CFD solver as an UDE.
C p = aT 6 + bT 5 + cT 4 + dT 3 + eT 2 + fT + g
[D-29]
A sample of the obtained coefficients for Eq. [D-29] for estimating the heat capacity of supercritical CO2 can be seen in Table D-5, and a graphical representation of the previously stated polynomial fitting is shown in Figure D-10.
P [MPa]
8 10 12 14 16 18 20 22 Table D-5.
a
1.24 x 10-7 -9.00 x 10-8 -2.76 x 10-9 1.49 x 10-8 8.67 x 10-9 2.86 x 10-9 3.46 x 10-10 -3.54 x 10-10
b
-2.89 x 10-4 2.08 x 10-4 7.70 x 10-6 -3.40 x 10-5 -2.01 x 10-5 -6.79 x 10-6 -9.59 x 10-7 7.17 x 10-7
c
2.80 x 10-1 -2.01 x 10-1 -8.72 x 10-3 3.21 x 10-2 1.93 x 10-2 6.70 x 10-3 1.08 x 10-3 -5.88 x 10-4
d
-1.44 x 102 1.03 x 102 5.16 x 100 -1.61 x 101 -9.85 x 100 -3.50 x 100 -6.27 x 10-1 2.48 x 10-1
e
4.17 x 104 -2.94 x 104 -1.69 x 103 4.52 x 103 2.81 x 103 1.02 x 103 2.01 x 102 -5.60 x 101
f
-6.41 x 106 4.48 x 106 2.90 x 105 -6.73 x 105 -4.27 x 105 -1.59 x 105 -3.37 x 104 6.29 x 103
g
4.10 x 108 -2.83 x 108 -2.05 x 107 4.15 x 107 2.68 x 107 1.02 x 107 2.32 x 106 -2.59 x 105
Cp [J/kmol K]
7000
4000
1000 310 345 8 MPa 16 MPa 380 Temperature [K] 10 MPa 18 MPa 12 MPa 20 MPa 415 14 MPa 22 MPa 450
Figure D-10.
- 215 -
Appendix D
In order to quantify the round-up error associated with the numerical solver, a simulation for a heat capacity-varying flow of supercritical CO2 in a Venturi tube was set, and obtained numerical values were compared with the prediction of the residual heat capacity method method, resulting in a reasonably good agreement between the numerical results and the theoretical estimation (see Figure D-11). The estimated error for the heat capacity was never superior to 15 %, which was considered to be within an acceptable range.
2100
1900
Figure D-11.
Heat capacity parity plot for supercritical CO2 (numerical results vs. residual heat capacity method)
References
Fluent Inc., (2005). Fluent 6.2 users guide. Fluent Inc. Guardo, A., Oliver, A., Larrayoz, M.A., (2005). Using CFD simulations to estimate properties of a supercritical binary mixture. Proceedings of the 10th meeting on supercritical fluids. Colmar, France. [CD-ROM] Lucas, K., (1980). Phase equilibria and fluid properties in the chemical industry. Dechema, Frankfurt, p. 573. Peng, D.Y. and Robinson, D.B., (1976). A new two constant equation of state. Industrial & Engineering Chemistry Fundamentals, 15, 59 64. Redlich, O. and Kwong, J.N.S., (1949). On the thermodynamics of solutions V: an equation of state. Fugacities of gaseous solutions. Chemical Reviews, 44, 233 244. Reid, R.C., Prausnitz, J.M., Poling, B.P., (1987). The properties of gases and liquids. Forth edition. McGraw-Hill, Boston. Stiel, L.I. and Thodos, G., (1964). The thermal conductivity of nonpolar substances in the dense gaseous and liquid regions. AIChE Journal, 10, 26 30. Yaws, C.L., (1999). Chemical properties handbook. McGraw-Hill, New York.
- 216 -
APPENDIX E
BOUNDARY CONDITIONS
Appendix E
Boundary conditions specify the flow, thermal and species composition variables on the boundaries of a physical model. They are, therefore, a critical component of CFD simulations and it is important that they are specified appropriately.
In this appendix, the boundary conditions listed above will be described, and an explanation of how to set them and when they are most appropriately used will be provided.
- 219 -
Appendix E
u = 0.16 Re DH u
[E-1]
At a Reynolds number of 50,000, for example, the turbulence intensity will be 4%, according to this formula.
- 220 -
Appendix E
l = 0.07 L
[E-2]
where L is the relevant dimension of the duct. The factor of 0.07 is based on the maximum value of the mixing length in fully-developed turbulent pipe flow, where L is the diameter of the pipe. In a channel of non-circular cross-section, you can base L on the hydraulic diameter. If the turbulence derives its characteristic length from an obstacle in the flow, such as a perforated plate, it is more appropriate to base the turbulence length scale on the characteristic length of the obstacle rather than on the duct size. It should be noted that the relationship of Equation [E-2], which relates a physical dimension ( L ) to the turbulence length scale ( l ), is not necessarily applicable to all situations. For most cases, however, it is a suitable approximation. Guidelines for choosing the characteristic length L or the turbulence length scale l for selected flow types are listed below: For fully-developed internal flows, choose the Intensity and Hydraulic Diameter specification method and specify the hydraulic diameter L = D H in the Hydraulic Diameter field. For flows downstream of turning vanes, perforated plates, etc., choose the Intensity and Hydraulic Diameter method and specify the characteristic length of the flow opening for L in the Hydraulic Diameter field. For wall-bounded flows in which the inlets involve a turbulent boundary layer, choose the Intensity and Length Scale method and use the boundary-layer thickness, 99 , to compute the turbulence length scale, l , from l = 0.4 99 . Enter this value for l in the Turbulence Length Scale field.
(Re
layers, shear layers, and fully-developed duct flows. However, at the free-stream boundaries of most external flows, t is fairly small. Typically, the turbulence parameters are set so that
1 < t < 10 .
To specify quantities in terms of the turbulent viscosity ratio, you can choose Turbulent Viscosity Ratio (for the Spalart-Allmaras model) or Intensity and Viscosity Ratio (for the models and the models).
- 221 -
Appendix E
When your velocity inlet boundary condition defines flow entering the physical domain of the model, the CFD code uses both the velocity components and the scalar quantities that you defined as boundary conditions to compute the inlet mass flow rate, momentum fluxes, and fluxes of energy and chemical species. The mass flow rate entering a fluid cell adjacent to a velocity inlet boundary is computed as:
& = u dA m
[E-3]
Note that only the velocity component normal to the control volume face contributes to the inlet mass flow rate. Density at the inlet plane is either constant or calculated as a function of temperature, pressure, and/or species mass fractions, where the mass fractions are the values you entered as an inlet condition.
- 222 -
Appendix E
The adjustment of inlet total pressure might result in a slower convergence, so if both the pressure inlet boundary condition and the mass flow inlet boundary condition are acceptable choices, you should choose the former. It is not necessary to use mass flow inlets in incompressible flows because when density is constant, velocity inlet boundary conditions will fix the mass flow. You will enter the following information for a mass flow inlet boundary: Mass flow rate, mass flux, or (primarily for the mixing plane model) mass flux with average mass flux Total (stagnation) temperature Static pressure Flow direction Turbulence parameters (for turbulent calculations) Chemical species mass fractions (for species calculations)
When mass flow boundary conditions are used for an inlet zone, a velocity is computed for each face in that zone, and this velocity is used to compute the fluxes of all relevant solution variables into the domain. With each iteration, the computed velocity is adjusted so that the correct mass flow value is maintained. To compute this velocity, your inputs for mass flow rate, flow direction, static pressure, and total temperature are used. There are two ways to specify the mass flow rate. The first is to specify the total mass flow rate, & , for the inlet. The second is to specify the mass flux, u n (mass flow rate per unit area). If a m total mass flow rate is specified, the CFD code converts it internally to a uniform mass flux by dividing the mass flow rate by the total inlet area:
un =
& m A
[E-4]
If the direct mass flux specification option is used, the mass flux can be varied over the boundary by using profile files or user-defined functions. If the average mass flux is also specified (either explicitly by you or automatically by the CFD code), it is used to correct the specified mass flux profile, as described earlier in this section. Once the value of u n at a given face has been determined, the density at the face must be determined in order to find the normal velocity. The manner in which the density is obtained depends upon whether the fluid is modeled as an ideal gas or not. Each of these cases is examined below. If the fluid is an ideal gas, the static temperature and static pressure are required to compute the density:
p = R T
[E-5]
If the inlet is supersonic, the static pressure used is the value that has been set as a boundary condition. If the inlet is subsonic, the static pressure is extrapolated from the cells inside the inlet face.
- 223 -
Appendix E
The static temperature at the inlet is computed from the total enthalpy, which is determined from the total temperature that has been set as a boundary condition. The total enthalpy is given by
1 h0 (T0 ) = h(T ) + u 2 2
[E-6]
where the velocity is related to the mass flow rate given by Equation [E-4]. Using Equation [E-5] to relate density to the (known) static pressure and (unknown) temperature, Equation [E-6] can be solved to obtain the static temperature. When you are modeling incompressible flows, the static temperature is equal to the total temperature. The density at the inlet is either constant or readily computed as a function of the temperature and (optionally) the species mass fractions. The velocity is then computed using Equation [E-4]. To compute the fluxes of all variables at the inlet, the flux velocity is used along with the inlet value of the variable in question. For example, the flux of turbulence kinetic energy is u n . These fluxes are used as boundary conditions for the corresponding conservation equations during the course of the solution.
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Appendix E
At pressure outlets, the CFD code uses the boundary condition pressure you input as the static pressure of the fluid at the outlet plane, and extrapolates all other conditions from the interior of the domain.
The boundary conditions used at outflow boundaries are as follows: A zero diffusion flux for all flow variables An overall mass balance correction
The zero diffusion flux condition applied at outflow cells means that the conditions of the outflow plane are extrapolated from within the domain and have no impact on the upstream flow. The extrapolation procedure used updates the outflow velocity and pressure in a manner that is consistent with a fully-developed flow assumption, as noted below, when there is no area change at the outflow boundary. The zero diffusion flux condition applied at outflow boundaries is approached physically in fully-developed flows. Fully-developed flows are flows in which the flow velocity profile (and/or profiles of other properties such as temperature) is unchanging in the flow direction. It is important to note that gradients in the cross-stream direction may exist at an outflow boundary. Only the diffusion fluxes in the direction normal to the exit plane are assumed to be zero.
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Appendix E
all equations). The shear stress and heat transfer between the fluid and wall are computed based on the flow details in the local flow field. You will enter the following information for a wall boundary: Thermal boundary conditions (for heat transfer calculations) Wall motion conditions (for moving or rotating walls) Shear conditions (for slip walls, optional) Wall roughness (for turbulent flows, optional) Species boundary conditions (for species calculations)
When you are solving the energy equation, you need to define thermal boundary conditions at wall boundaries. Five types of thermal conditions are available: Fixed heat flux Fixed temperature Convective heat transfer External radiation heat transfer Combined external radiation and convection heat transfer
For no-slip wall conditions, the CFD code uses the properties of the flow adjacent to the wall/fluid boundary to predict the shear stress on the fluid at the wall. In laminar flows this calculation simply depends on the velocity gradient at the wall, while in turbulent flows one of the approaches described in Appendix B is used. For specified-shear walls, it will compute the tangential velocity at the boundary. If you are modeling inviscid flow, all walls use a slip condition, so they are frictionless and exert no shear stress on the adjacent fluid. In a laminar flow , the wall shear stress is defined by the normal velocity gradient at the wall as
w =
u n
[E-7]
When there is a steep velocity gradient at the wall, you must be sure that the grid is sufficiently fine to accurately resolve the boundary layer. Wall treatments for turbulent flows are described in Appendix B. When a fixed temperature condition is applied at the wall, the heat flux to the wall from a fluid cell is computed as
q = h f (Tw T f ) + q rad
[E-8]
Note that the fluid-side heat transfer coefficient is computed based on the local flow-field conditions (e.g., turbulence level, temperature, and velocity profiles).
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Appendix E
When you define a heat flux boundary condition at a wall, you specify the heat flux at the wall surface. The CFD code uses Equation [E-8] and your input of heat flux to determine the wall surface temperature adjacent to a fluid cell as
Tw =
q q rad + Tf hf
[E-9]
where, as noted above, the fluid-side heat transfer coefficient is computed based on the local flow-field conditions. In laminar flows, the fluid side heat transfer at walls is computed using Fourier's law applied at the walls in its discrete form:
T q = kf n w
where n is the local coordinate normal to the wall.
[E-10]
For turbulent flows, the CFD code uses the law-of-the-wall for temperature derived using the analogy between heat and momentum transfer. See Appendix B for details.
Figure E-1.
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Appendix E
Figure E-2.
The CFD code assumes a zero flux of all quantities across a symmetry boundary. There is no convective flux across a symmetry plane: the normal velocity component at the symmetry plane is thus zero. There is no diffusion flux across a symmetry plane: the normal gradients of all flow variables are thus zero at the symmetry plane. The symmetry boundary condition can therefore be summarized as follows: Zero normal velocity at a symmetry plane Zero normal gradients of all variables at a symmetry plane
As stated above, these conditions determine a zero flux across the symmetry plane, which is required by the definition of symmetry. Since the shear stress is zero at a symmetry boundary, it can also be interpreted as a "slip'' wall when used in viscous flow calculations.
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APPENDIX F
LIST OF PUBLICATIONS
in journals & congresses
Appendix F
F-1.
Articles in journals
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Appendix F
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Appendix F
F-2.
Participation in congresses
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Appendix F
Font, 2001). This software includes modules for geometrical model generation, mesh generation, solution of equations and graphical post-processing of numerical results. Fluid analyzed is taken to be CO2 in supercritial conditions (165 bar, 310 K) and in steady state flow regime, with an uniform velocity at the bed inlet and a fixed velocity condition around the spheres and at the wall. No thermal boundary conditions are applied to the model. Several numerical simulations are developed at different values of Re. Results are presented based on numerical convergency of the method.
Chemical Engineering Science; 2005, 60, 1733 1742 Abstract in prior section. Chicago, USA. June 2004
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Appendix F
7th Italian Conference on Supercritical Fluids and their applications / 9th European Meeting on Supercritical Fluids
CFD simulation of particle-to-fluid heat transfer under supercritical conditions: preliminary results A. Guardo, F. Recasens, M.A. Larrayoz, M. Fernndez Trieste, Italy. June 2004 Abstract Computational Fluid Dynamics (CFD) has proven to be a powerful tool to numerically solve the fluid-flow equations so it gives a further insight into the flow pattern of contacting equipment. There has been a fast growing in the study of applications in fluid flow and heat transfer, and several authors have used it to analyze flow patterns in fixed-bed equipment and to predict heat transfer parameters in studied cases [1-2]. In this work, particle-to-fluid heat transfer is studied in a maximum-occupying-space arrangement of solid spheres in a cylindrical container, in order to simulate via CFD the heat transfer behavior in a supercritical catalytic reactor under steady state conditions. Supercritical CO2 was chosen as circulating fluid; a physical properties database (i.e., density, enthalpy, entropy, Cp, Cv, viscosity, thermal conductivity and sound speed) was created using accepted correlations for high pressure properties estimation [3-4]. Properties database was fed to CFD simulator in order to do properties estimation simultaneously with the mass, momentum and energy calculations. Buoyancy terms were found to be relevant in calculations through a dimensionless analysis done to Navier-Stokes equations, and therefore are used during simulations. C-written programme modules based on the SRK equation of state[4], have been implemented for use with CFD commercial codes. For transport properties, the available correlations have been implemented in the modules. Navier-Stokes equations together with energy balance are solved using a commercially available finite volume-element code (Ansys CFX 5.6 solver). Fluid is taken to be compressible, Newtonian and in laminar or transitional flow regime (10 < Re < 300). So this gives a wider application to SCF cases. Boundary conditions applied to the model are as follows: Constant velocity and temperature of the fluid at the inlet Constant temperature of the particles surface Constant pressure defined within a point of the fluid Adiabatic reactors wall Non-slip condition applied to wall and particle surfaces
Velocity and temperature fields are obtained within the bed, together with physical properties profiles at any point of the fluid domain. Energy balances permit to calculate heat transfer parameters (i.e., hp, Nup, jh) at different operating conditions, and estimated values via CFD are compared with previously published heat transfer correlations estimated under similar conditions applied to simulations [5-6]
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Appendix F
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Appendix F
10th European Meeting on Supercritical Fluids Using CFD simulations to estimate properties of a supercritical binary mixture. A. Guardo, A. Oliver, M.A. Larrayoz Colmar, France. December 2005. Abstract Computational Fluid Dynamics (CFD) has proven to be a powerful tool to numerically solve the fluid-flow equations so it gives a further insight into the flow pattern of contacting equipment. There has been a fast growing in the study of applications in fluid flow and heat and mass transfer. [1-2].
In this work, a prediction of the physical properties of a near-critical or supercritical binary mixture is obtained via CFD simulations in a 2D pipe flow model. Near-critical or supercritical CO2 was chosen as circulating fluid; in order to obtain a composition profile, a mass flux of toluene was imposed through the pipe walls. In order to impose near-critical or supercritical conditions to the fluid, Peng Robinson equation of state was imposed to the CFD model through a C++ subroutine compiled within the solver CFD code. Navier-Stokes equations together with Peng Robinson EOS and species transport and diffusion model are solved using a commercially available finite volume-element code (Fluent 6.2 solver). Fluid is taken to be compressible, Newtonian and in laminar flow regime.
10th European Meeting on Supercritical Fluids CFD flow and mass transfer simulation in a packed bed with supercritical solvent: preliminary results A. Guardo, M. Coussirat, M.A. Larrayoz, F. Recasens Colmar, France. December 2005. Abstract The CFD simulation methodology is applied to the study of the natural convection flow in equipment used in SCF technology that involves a packed bed of particles. The ranges of heat and mass transfer are defined where those free convective effects show themselves. This happens at low particle Reynolds number and large Rayleigh (either GrPr or GrSc) numbers, for both heat and mass transport. Rayleigh number is large in SCF because of liquid-like densities and gas-like viscosities. Free convection effects of heat and mass transfer are of prime importance when modelling the behaviour of supercritical fluids in fixed bed reaction equipment and in solid extractors. Density gradients, caused by temperature or composition variations, tend to control the volume forces and the overall flow pattern of the fluid, making the buoyancy terms of the Navier Stokes equations an important term to model when doing a CFD simulation of a fixed bed under the described conditions. Buoyancy and sinking forces interact with forced flow in extraction with SC fluids, making them sensitive to the gravity field [1-3]
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Appendix F
In order to simulate a supercritical extraction, a Toluene CO2 system is analysed. Mesh sensitivity analysis is done and results of a preliminary simulation are shown. Carbon dioxide in the supercritical conditions has been selected as a flowing fluid. Their transport properties at high pressure are incorporated within a CFD commercial code in order to estimate them online within the simulation process. Particle-to-fluid mass transfer is analysed [4], and flow and composition contour fields are presented, and flow pattern is analysed according to density profiles obtained. Downflow operation regime is modelled.
Chemical Engineering Science; 2006 (Submitted under review) Abstract in prior section.
Potsdam. Germany. September 2006
Chemical Engineering Science; 2006 (Submitted under review) Abstract in prior section.
Potsdam, Germany. September 2006
5th International Symposium on High Pressure Processes Technology and Chemical Engineering
Using CFD to estimate external mass transfer coefficients and intra-particle diffusional effects on the supercritical hydrogenation of sunflower oil A. Guardo, M. Casanovas, E. Ramrez, M.A. Larrayoz, F. Recasens. Segovia, Spain. June 2007 (Submitted) Abstract Hydrogenation of vegetable oil is an important process in the food industry because of its widespread application to produce margarines, shortenings, and other food components. Supercritical technology has proven to be a reliable alternative to conventional hydrogenation process because not only the trans isomer levels can be reduced, but also offers a clean, economic and environmental friendly process. Computational Fluid Dynamics (CFD) modeling applied to the supercritical hydrogenation reaction can be useful in visualizing and understanding the mass transfer phenomena involved. CFD is applied to the study of the catalytic hydrogenation of sunflower oil in the presence of a supercritical solvent. Intra-particle concentration profiles are obtained
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Appendix F
and compared against experimental data. Different temperatures, flow velocities and particle sizes are studied and external and internal mass transfer phenomena is analyzed. The purpose of this work was to visualize the mass transfer phenomena over a single catalyst pellet and the intra-particle diffusional effects associated with particle size for the supercritical hydrogenation of sunflower oil using a 2D CFD modeling strategy. A mix of sunflower oil, hydrogen and supercritical propane (used as a solvent) is the flowing fluid. Their transport properties at high pressure are incorporated within a CFD commercial code in order to estimate them online within the simulation process. A 2D CFD model of a single Pd-based catalyst pellet is presented. Intra-particle and surface concentration profiles and surface mass fluxes for all species present in the mixture (oil triglycerides and hydrogen) are obtained and compared against experimental results. Different temperatures, flow velocities and particle sizes are studied and external and internal mass transfer phenomena is analyzed. External mass transfer coefficients for hydrogen and oil triglycerides are obtained and a correlation for estimating them is presented.
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