DESTILACION

Presin de vapor
KN/m2
(mm.Hg)

Temperatura (K)
C5H12
C6H14

1.3
2.6
5.3
8
13.3
26.6
53.2
101.3

223.1
233
244
251
260.6
275.1
291.7
309.3

10
20
40
60
100
200
400
760

248.2
259.1
276.9
279
289
304.8
322.8
341.9

curvas de Presiones

110
100
90

y = 0.0001x3 - 0.0893x2 + 22.5358x - 1,904.7182

R = 0.9996

80
70
3

70
y = 0.0002x3 - 0.1143x2 + 26.4305x - 2,048.8115
R = 0.9999

60
50
40
30
20
10
0
0

50

100

150

200

250

* Con analisis de Datos para el n-Pentano

n-pentano
Presion de vapor
KN/m2
mmHg
1.3
2.6
5.3
8
13.3
26.6
53.2
101.3

10
20
40
60
100
200
400
760

t
223.1
233
244
251
260.6
275.1
291.7
309.3

Temperatura K
t2
49773.61
54289
59536
63001
67912.36
75680.01
85088.89
95666.49

t3

11104492.39
12649337
14526784
15813251
17697961.02
20819570.75
24820429.21
29589645.36

Hallando la presin de vapor a su respectivo intervalo de temperatura

T
251
256
261
266
271
276
279

2
P= 8.0 KN/m
Pentano PA

8
10.271215
13.2851302
17.0810121
21.7833354
27.5165748
31.5031396

P=53.2 KN/m2
T

Pentano PA

291.7
297.7
303.7
309.7
315.7
321.7
322.8

53.2
67.39312987
83.62205409
102.5077505
124.2653114
149.109829
154.0164865

300

350

* Con analis de datos para el n-Hexano

Presin de Vapor
KN/m2
mmHg
1.3
10
2.6
20
5.3
40
8
60
13.3
100
26.6
200
53.2
400
101.3
760

t
248.2
259.1
276.9
279
289
304.8
322.8
341.9

Temperatura
t2
t3
61603.2400 15289924.1680
67132.8100 17394111.0710
76673.6100 21230922.6090
77841.0000 21717639.0000
83521.0000 24137569.0000
92903.0400 28316846.5920
104199.8400 33635708.3520
116895.6100 39966609.0590

Hallando la Presion de Vapor a su respectivo intervalo de Temperatura

P=8 KN/m2
T
251
256
261
266
271
276
279

Hexano PB

P=53.2KN/m2
T

Hexano PB

1.3
2.14186363
2.84052104
3.71514691
4.8546218
6.34782627
8

291.7
297.7
303.7
309.7
315.7
321.7
322.49

14.3255
19.10386709
25.07509818
32.39274145
41.21038251
51.68160697
53.19164288

a.4 Hallar el equilibrio liquido-vapor

XA= (PT-PB)/(PA-PB)

T
251
256
261
266
271
276
279

YB= PA.XA/PT

P=

PA

PB

XA

YA

8
10.271215
13.2851302
17.0810121
21.7833354
27.5165748
31.5031396

1.3
2.14186363
2.84052104
3.71514691
4.8546218
6.34782627
8

1
0.72061547
0.49398487
0.3205818
0.18580137
0.07804778
0

1
0.925199555
0.820331674
0.684482695
0.505921699
0.268450932
0

X=Y
1
0.72061547
0.49398487
0.3205818
0.18580137
0.07804778
0

Curva de equlibrio Liquido-Vapor X-Y*

1

0.9

0.9

0.8

0.8
0.7

0.7

0.6

0.6

0.5
0.4

Series1

0.5

xy

0.4

0.3

0.3

0.2

0.2

0.1

0.1

0
0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

251

XA= (PT-PB)/(PA-PB)
P=
T
291.7
297.7
303.7
309.7
315.7
321.7
322.5

YB= PA.XA/PT

53.2
PA

PB

XA

YA*

53.2
67.3931299
83.6220541
102.50775
124.265311
149.109829
154.016486

14.3255
19.1038671
25.0750982
32.3927414
41.2103825
51.681607
53.1916429

1.00
0.71
0.48
0.30
0.14
0.02
0.00

1.00
0.89
0.76
0.57
0.34
0.04
0.00

Curva de equilibrio Liquido-Vapor X-Y*

1.00
0.90

X=Y
1.00
0.71
0.48
0.30
0.14
0.02
0.00

0.90
0.80
0.70
X-Y*

0.60

X=Y

0.50
0.40
0.30
0.20
0.10
0.00
0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

B. PARA CADA PRESION, CALCULE LAS VOLATILIDADES RELATIVAS Y DETERMINE SU VALOR PROMEDIO
volatilidad

P=
PA
8
10.271215
13.2851302
17.0810121
21.7833354
27.5165748
31.5031396

8
PB
1.3
2.14186363
2.84052104
3.71514691
4.8546218
6.34782627
8
promedio

PA/PB

Volatilidad
6.15384615
4.79545703
4.67700469
4.59766802
4.48713336
4.33480276
3.93789245
4.71197207

x
0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1

y
0.0000
0.3436
0.5409
0.6688
0.7585
0.8249
0.8761
0.9166
0.9496
0.9770
1.0000

C5H12
C6H14

Resumen
Estadsticas de la regresin
Coeficiente de correlacin
0.99996911mltiple
Coeficiente de determinacin
0.99993822 R^2
R^2 ajustado 0.99989189
Error tpico
0.36190279
Observaciones
8
ANLISIS DE VARIANZA
Grados de libertad
Suma de cuadrados
Promedio de los cuadrados F
Valor crtico de F
Regresin
3 8479.57611 2826.52537 21580.8742 7.1561E-09
Residuos
4 0.52389451 0.13097363
Total
7
8480.1
Coeficientes Error tpico
Intercepcin -2048.81147
146.69935
Variable X 1
26.4304647 1.67606591
Variable X 2 -0.11431226 0.00634625
Variable X 3
0.00016597 7.9628E-06

Estadstico t Probabilidad Inferior 95%

-13.9660569 0.00015246 -2456.11416
15.7693469 9.4481E-05 21.7769597
-18.0125799 5.5844E-05 -0.13193226
20.8428031 3.1311E-05 0.00014386

T-PB)/(PA-PB)

Resumen
Estadsticas de la regresin
Coeficiente de correlacin
0.99980884mltiple
Coeficiente de determinacin
0.99961771 R^2
R^2 ajustado
0.999331
Error tpico
0.9002534
Observaciones
8
ANLISIS DE VARIANZA
Grados de libertad
Suma de cuadrados
Promedio de los cuadrados F
Valor crtico de F
Regresin
3 8476.85818 2825.61939 3486.45548 2.7398E-07
Residuos
4 3.24182472 0.81045618
Total
7
8480.1
Coeficientes
Intercepcin -1904.71817
Variable X 1
22.5357861
Variable X 2 -0.08927194
Variable X 3
0.00011851

Error tpico
392.900128
4.05277028
0.01385515
1.5697E-05

Estadstico t Probabilidad Inferior 95%

-4.8478431 0.00835246 -2995.58381
5.56058808 0.00512137 11.2834919
-6.44323096 0.00298556
-0.12774
7.54967129 0.00164921 7.4925E-05

Diagrama de t-XY*
1
0.9
0.8
0.7
0.6
T-X

0.5

T-Y*

0.4
0.3
0.2
0.1
0
251

253

255

257

259

261

T-PB)/(PA-PB)

DIAGRAMA T-XY*

1.00
0.90
0.80

263

265

267

269

271

273

275

277

279

0.80
0.70
0.60

X-Y*

0.50
0.40
0.30
0.20
0.10
0.00
291 293 295 297 299 301 303 305 307 309 311 313 315 317 319 321 323

MINE SU VALOR PROMEDIO

P=
PA
53.2
67.3931299
83.6220541
102.50775
124.265311
149.109829
154.016486

53.2
PB
14.3255
19.1038671
25.0750982
32.3927414
41.2103825
51.681607
53.1916429
promedio

Volatilidad
3.71365746
3.52772188
3.33486447
3.16452841
3.01538845
2.8851624
2.89550159
3.21954638

x
0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1

y
0
0.26347511
0.44594857
0.57979761
0.68217284
0.7630077
0.82845339
0.88252259
0.92794447
0.96663989
1

or crtico de F

Superior 95% Inferior 95.0%Superior 95.0%

-1641.50878 -2456.11416 -1641.50878
31.0839697 21.7769597 31.0839697
-0.09669226 -0.13193226 -0.09669226
0.00018807 0.00014386 0.00018807

or crtico de F

Superior 95% Inferior 95.0%Superior 95.0%

-813.852538 -2995.58381 -813.852538
33.7880803 11.2834919 33.7880803
-0.05080387
-0.12774 -0.05080387
0.00016209 7.4925E-05 0.00016209

T-X
T-Y*

T (C)
44.4
71.6
84.9
99.3
115.4
125.8
139.9
161.2
185.8
210.6

Pv (mmHg)
1
5
10
20
40
60
100
200
400
760

800
700
600
y = 0.0003x3 - 0.0760x2 + 6.1964x
R = 0.9991

500
400
300
200
100
0
40
-100

T (C)
45
50

Pv (mmHg)
71.97
92.65

800

60

80

100

120

800

55
60
65
70
75
80
85
90
100

118.23
149.61
187.83
234.03
289.49
355.63
434.04
526.41
760

700
600
500
400
300
200
100
0
45

utilizando el analisis de datos para el nitrobenceno

PV
1
5
10
20
40
60
100
200
400
760

T
44.4
71.6
84.9
99.3
115.4
125.8
139.9
161.2
185.8
210.6

T2
1971.36
5126.56
7208.01
9860.49
13317.16
15825.64
19572.01
25985.44
34521.64
44352.36

T3
87528.384
367061.696
611960.049
979146.657
1536800.26
1990865.51
2738124.2
4188852.93
6414120.71
9340607.02

t
45
50

t2
2025
2500

t3
91125
125000

para agua
Pv (mmHg)
71.97
92.65

50

55

60

65

118.23
149.61
187.83
234.03
289.49
355.63
434.04
526.41

55
60
65
70
75
80
85
90

3025
3600
4225
4900
5625
6400
7225
8100

166375
216000
274625
343000
421875
512000
614125
729000

a)calculamos la temperatura de destilacion

T
97.80
98.00
98.20
98.40
98.60
98.80
99.00
99.26
99.40
99.60
99.80
100.00

PA

PB

PT

19.5337079
8381414.38
8432813.9
8484423.13
8536242.49
8588272.43
8640513.36
8708742.7
8745629.9
8798506.38
8851595.55
8904897.85

699.104869
704.051062
709.023973
714.023684
719.05028
724.103841
729.184451
735.829817
739.427147
744.589399
749.779029
754.996121

718.638577
8382118.43
8433522.92
8485137.15
8536961.54
8588996.53
8641242.54
8709478.53
8746369.33
8799250.97
8852345.33
8905652.85

+ 6.1964x - 157.4363
R = 0.9991

120

140

160

180

200

220

y = 0.0019x3 - 0.2041x2 + 10.976x - 180.84

R = 1

65

70

75

80

85

90

95

100

Resumen
Estadsticas de la regresin
Coeficiente de correlacin
0.99955922mltiple
Coeficiente de determinacin
0.99911864 R^2
R^2 ajustado 0.99867796
Error tpico
8.89481016
Observaciones
10
ANLISIS DE VARIANZA
Grados de libertad
Suma de cuadrados
Promedio de los cuadrados F
Valor crtico de F
Regresin
3 538129.694 179376.565 2267.21306 1.4972E-09
Residuos
6 474.705887 79.1176478
Total
9
538604.4

Intercepcin
Variable X 1
Variable X 2
Variable X 3

Coeficientes
-157.436334
6.19642329
-0.07603768
0.00031883

Error tpico
39.7968784
1.12887404
0.00966721
2.5257E-05

Resumen
Estadsticas de la regresin
Coeficiente de correlacin
0.99999875mltiple
Coeficiente de determinacin
0.9999975 R^2
R^2 ajustado 0.99999625
Error tpico
0.29644118

Estadstico t Probabilidad Inferior 95%

-3.95599706
0.007486 -254.815787
5.48902986 0.00153045 3.43416804
-7.86552213 0.00022351 -0.09969249
12.623531 1.5138E-05 0.00025703

Observaciones

10

ANLISIS DE VARIANZA
Grados de libertad
Suma de cuadrados
Promedio de los cuadrados F
Valor crtico de F
Regresin
3 210844.296 70281.4321 799767.098 3.4209E-17
Residuos
6 0.52726424 0.08787737
Total
9 210844.824

Intercepcin
Variable X 1
Variable X 2
Variable X 3

PT = PA +PB

Coeficientes Error tpico

-138.206909 12.2837015
8.91788889 0.57192828
-0.17193939 0.00865629
0.00172081 4.2671E-05

Estadstico t Probabilidad Inferior 95%

-11.2512429 2.9463E-05 -168.264044
15.5926699 4.4053E-06
7.5184308
-19.8629456 1.0564E-06 -0.19312057
40.3272687 1.5542E-08
0.0016164

or crtico de F

Superior 95% Inferior 95.0%Superior 95.0%

-60.0568807 -254.815787 -60.0568807
8.95867854 3.43416804 8.95867854
-0.05238286 -0.09969249 -0.05238286
0.00038063 0.00025703 0.00038063

or crtico de F

Superior 95% Inferior 95.0%Superior 95.0%

-108.149774 -168.264044 -108.149774
10.317347
7.5184308
10.317347
-0.15075822 -0.19312057 -0.15075822
0.00182522
0.0016164 0.00182522

La ecuacion de antoine correlaciona la presiones de vapor de los liquidos puros con La temperatura segn la ecuacin:
logp1=A-B/T+C
Teniendo en cuenta que las constantes de dicha escuacin para el benceno y el tolueno

Benceno
Tolueno

A
6.90565
6.95334

B
1211.033
1343.943

C
220.79
219.377

a) construya el diagrama lquido-Vapor (t-xy*) a presion constante

Encontrar las presiones de vapor
T
80.1
85
90
95
100
105
110
110.62

Benceno
760.00
881.67
1020.99
1176.84
1350.49
1543.23
1756.38
1784.29

Tolueno
292.22
345.10
406.73
476.87
556.32
645.93
746.59
759.89
XA= (P-PB)/(PA-PB)

Calcular la fraccin en el Liquido- vapor

T
80.10
85.00
90.00
95.00
100.00
105.00
110.00
110.62

PT=

760

PA

PB

XA

YA*

760.00
881.67
1020.99
1176.84
1350.49
1543.23
1756.38
1784.29

292.22
345.10
406.73
476.87
556.32
645.93
746.59
759.89

1.000
0.773
0.575
0.404
0.256
0.127
0.013
0.000

1.000
0.897
0.773
0.626
0.456
0.258
0.031
0.000

b) Grafique el diagrama xy*

1.000

0.900
0.800

0.8

0.700
0.600

0.6

0.6

0.600
0.500

T- X

0.400

T- Y*

0.4

0.300
0.2

0.200
0.100
0.000
80.00

0
85.00

90.00

95.00

100.00

105.00

80

110.00

c)Una mezcla liquida contine 55% de benceno y 45% de tolueno en peso calcular :
c.1) L a temperatura de Burbuja
c.2) La composicindel vapor en el Equilibrio
La temperatura de Burbuja

f(TBP)= XA .PA +XB.PB -PT

T (C)

PA

PB

F(TBP)

80.1

760.00

292.22

-210.502

XA

100

1350.49

556.32

233.115

90

1020.99

406.73

-15.425

XB
PT

95
92
92.1
92.112

1176.84
1081.28
1084.36
1084.73

476.87
433.72
435.11
435.28

101.855
29.878
32.199
32.477

PA=XA.PA

La composicin del vapor en el equilibrio

PB=XB.PB
PA=
PB=

596.60

mmHg

195.87

mmHg

YA=
YB=

d) Una mezcla liquida contiene 80% de benceno y 20% de tolueno en peso calcular :
d.1) La temperuatura de Rocio
d.2) La composicin del lIquido en el equilibrio
La temperatura de Rocio

0.79
0.26

f(TRP)=YA.P/PA + YB.P/PB -1
T(C)

PA

PB

f(TRP)

80.1

760.00

292.22

0.3202

YA=

100

1350.49

556.32

-0.2766

95

1176.84

476.87

-0.1646

YB=
PT

90
88
88.95

1020.99
963.35
990.40

406.73
381.11
393.11

-0.0308
0.0300
0.0005

La composicin del Liquido

PA'=
PB'=

608
152

PA'=YA.P

XA=PA'/PA

PB'=YB.P

XB=PB'/PB
XA=
XB=

0.614
0.387

emperatura segn la ecuacin:

o y el tolueno

YA*= PA*XA/P

T-X
T-Y*

85

90

0.55
0.45
760

YA=PA/P
YB=PB/P

95

100

105

110

0.8
0.2
760

4. Una Solucin de hiudrocarburos a una presin absoluta de 10 bars, tiene la siguiente composicin expresada como fracc
HidrocarburosFraccin mol
Etano
0.0025
Propano
0.25
I-butano
0.185
N-butano
0.56
I-pentano
0.0025
utilice los coeficientes de distribucin en el equilibrio del monograma de Depriester.
a) calcule el punto de burbuja
b) calcule el punto de rocio

Punto de burbuja :
Primera estimacin
t=

C
60

F
140

Componentes

Xi

mi

ic4

ic4.Xi

Etano
Propano
I-butano
N-butano
I-pentano

0.0025
0.25
0.185
0.56
0.0025

5
1.96
0.93
0.7
0.325

7.14
2.80
1.33
1.00
0.46

0.018
0.700
0.246
0.560
0.001
1.525

segunda iteraccin
C
t=
57.22
Componentes
Etano
Propano
I-butano
N-butano
I-pentano

Punto de Rocio

Xi
0.0025
0.25
0.185
0.56
0.0025

Bar
10

P=

mc4=1/ic4.Xi

Bar
135

P=

mi

ic4
4.8
1.84
0.85
0.65
0.24

ic4.Xi
7.38
2.83
1.31
1.00
0.37

0.018
0.708
0.242
0.560
0.001
1.529

10

Primera iteraccin
C
t=

80

176

Componentes

Xi

mi

ic4

yi/ic4

Etano

0.0025

5.99

6.11

0.000

Propano
I-butano
N-butano
I-pentano

0.25
0.185
0.56
0.0025

2.54
1.4
0.98
0.49

2.59
1.43
1.00
0.50

0.096
0.130
0.560
0.005
0.791

C
68.33

F
155

Xi

mi

ic4

yi/ic4

Etano

0.0025

5.39

6.82

0.000

Propano
I-butano
N-butano
I-pentano

0.2500
0.1850
0.5600
0.0025

2.19
1.09
0.79
0.4

2.77
1.38
1.00
0.51

0.090
0.134
0.560
0.005
0.790

F
P=

Bar
10

P=

Bar
10

Primera iteraccin
t=
Componentes

composicin expresada como fraccin mol:

Psia
145
ic4=mi/mC4
mc4=1/ic4.Xi

mc4=

0.656

Psia
145

mc4=

0.654

Psia
145

ic4=mi/mC4
mc4=ic4.Xi

Psia
145

ic4=mi/mC4
mc4=ic4.Xi