11

th
J-BATCH (Date: 16-10-2011) Review Test-4
PAPER-2
Code-A
ANSWER KEY
CHEMISTRY
SECTION-1
PART-A
Q.1 A
Q.2 B
Q.3 B
Q.4 C
Q.5 A
Q.6 C
Q.7 A
Q.8 B
Q.9 B
Q.10 A,B,D
Q.11 A,B,C
Q.12 B,C
Q.13 B,C,D
PART-B
Q.1 (A) P
(B) Q,R
(C) S
PART-C
Q.1 1222
Q.2 1211
Q.3 0021
Q.4 6221
PHYSICS
SECTION-3
PART-A
Q.1 A
Q.2 D
Q.3 B
Q.4 A
Q.5 C
Q.6 C
Q.7 C
Q.8 A
Q.9 D
Q.10 A
Q.11 B,D
Q.12 A,B,C,D
Q.13 B,D
PART-B
Q.1 (A) P,Q,S
(B) P
(C) Q,R,S
PART-C
Q.1 0060
Q.2 0005
Q.3 0019
Q.4 0010
MATHS
SECTION-2
PART-A
Q.1 C
Q.2 A
Q.3 A
Q.4 A
Q.5 A
Q.6 B
Q.7 B
Q.8 C
Q.9 B
Q.10 AB
Q.11 A,C
Q.12 A,B,C
Q.13 A,B,C,D
PART-B
Q.1 (A) P,Q,R,S
(B) P,Q,R,S
(C) P
PART-C
Q.1 0010
Q.2 0006
Q.3 0008
Q.4 1026
CHEMISTRY
Code A Page # 1
PART-A
Q.1
[Sol.
RT
PV
n
OF SF
5
=
=
300 0821 . 0
821 . 0
760
76

=
300
1
1000
1
300
1
100
30
n
2 5
ONF SF
= =
gm 195 . 0
1000
195
W
2 5
ONF SF
= =
]
Q.2
[Sol. 4 ( extended conjugation
1 ( Back - bonding)
3 ( Low I effect of oxygen)
2 (High I effect of oxygen) ]
Q.3
[Sol. For alkaline IE
3
>> IE
2
because of inert gas configuration only 'B' is suitable for that. ]
Q.4
[Sol. (A) < more benzenoid structure, so must have high R.E.
(B) > R.E. is equal because they are resonating structures.
(C) < Extended conjugation so, have more R.E.
(D)
+ +
R.E. is equal because they are resonating structures. ]
Q.5
[Sol. 100 ml given 44800 ml O
2
or 0.2 mole
Now 100 ml can give 11200 ml O
2
or 0.05 mole
so O
2
given in that duration = 0.2 0.05 = 0.15 mole
= 0.15 32 = 4.8 gm ]
CHEMISTRY
Code A Page # 2
Q.6
[Sol. w (single bond) ,
z (Double Bond) ,
y, x (Single bond character as well as double bond character, because of resonance. But, x have more
single bond character, while y have more double bond character due to more contributing non polar
resonating structure.]
Paragraph for question nos. 7 to 9
[Sol
(7) PV = nRT
M =
PV
wRT
=
16 4
320 08 . 0 100

= 40 Ans
(8) Volume of cylinder
v n or
2
1
2
1
n
n
V
V
=
80
100
x
16
=
x =
100
80 16
= 12.8 L Ans.
(9) As T = constant
P
1
V
1
= P
2
V
2
4 16 = P
2
12.8
P
2
= 5 atm Ans. ]
Q.10
[Sol. for any hydrocarbon : C
x
H
y
+
|
.
|

\
|
+
4
y
x
O
2
xCO
2
+
2
y
H
2
O ]
Q.11
[Sol. (A*)
N
+ I,
N
N
I of N
(B*)
Cl
|
COOH CH CH
3

more (I),
Cl
|
COOH CH CH
2 2

Less (I)
(C)
CH
2
NO
2

more (I),
CH
2
CH
3

more (+I),
(D)
COOH
|
) CH (
|
COOH
3 2
COOH
|
COOH
more I. ]
CHEMISTRY
Code A Page # 3
Q.12
[Sol. Ag
2
A Ag
2
108
54
A 108 2
152
=
+
4 152 = 2 108 + A
A = 392
Ag
2
A = 392 + 216 = 608 gm /mole
H
2
A = 392 + 2 = 394 gm / mole ]
Q.13
[Sol. (A) + KOH Na + RX
(B)
O
+ H
2
SO
4

OH
6 (A) t
HSO
4
(C) + 2K
:
:
K
K
6 (A) t
(D) + 2Na
10 (A) t
:
:
]
PART-B
Q.1
[Sol. 2NH
3
(g) +
2
5
O
2
(g) 2NO (g) + 3H
2
O (g)
N
2
(g) + 3H
2
(g) 2NH
3
(g)
C
3
H
8
(g) + 5O
2
(g) 3CO
2
(g) + 4H
2
O (l)
2 HI H
2
(g) + I
2
(g) ]
CHEMISTRY
Code A Page # 4
PART-C
Q.1
[Sol. (a)
(I)
Extended conjugation;
(II)
cross conjugation
(b)
(I)
Isolated system;
(II)
conjugation
(c)
(I)
Less - t bonds;
(II)
More - t bonds
(d)
(I)
Less - t bonds;
(II)
More - t bonds]
Q.2
[Sol. (a)

O
(I)
Octet of all atoms are complete ;

O
(II)
Octet of C-atom is incompete.
(b)
N
H
(I)
Unlike charges are farer.
N
H
(II)
Unlike charges are closer
(c) (I)CH
2
= CHCH=CH
2
Non-polar (II)
2 2
H C CH CH H C

=

Polar
(d) (I)
2
CH CH O =

Negative charge on more EN atom

(II)
2
H C CH O

=
Negative charge on less EN atom. ]
Q.3
[Sol. (a) But compound must be cyclic planer and conjugated also
(b) Becouse extent of overlap i.e.
F (2p - 2p) 3, Cl (3p2p), Br (4p2p), I(5p2p) ]
Q.4
[Sol. (a) Aromatic = 6
(b) Non Aromatic = 2
(c) Anti-Aromatic = 2
(d) quasi aromatic = 4 ]
MATHEMATICS
Code-A Page # 1
PART-A
Q.1
[Sol. We have 2B = A + C B = 60
Now,
2
3
c
b
= sin C =
2
1
ZC = 45
ZA = 180 (60 + 45) = 75. Ans.]
Q.2
[Sol. Discriminant D = 16b
2
(4)(3a)(c) = 4(4b
2
3ac)
Let three terms be (r d), (r), (r + d)
a = r d b = r c = r + d
= 4 [4r
2
3(r
2
d
2
)]
= 4 [r
2
+ 3d
2
]
So D > 0
as 'r' and 'd' cannot be simultaneously zero. So the equation has two distinct solutions. ]
Q.3
[Sol. We have, 3 (sin x + cos x) 2 (sin
3
x + cos
3
x) = 8
3 (sin x + cos x) 2 [(sin x + cos x)

(sin
2
x + cos
2
x sin x cos x)] = 8
(sin x + cos x)
|
|
.
|

\
|
|
.
|

\
|

2
x 2 sin
1 2 3 = 8
(sin x + cos x) (1 + 2 sin x cos x) = 8
(sin x + cos x) (1 + sin 2x) = 8
(sin x + cos x)
3
= 8
sin x + cos x = 2 (not possible). Ans.]
Q.4
[Sol. a = k
2
+ 1 ; d = 1
S =
2
1 k 2 +
[(k
2
+ 1) + (k
2
+ 2k + 1)]
S = (2k + 1) (k
2
+ k + 1) = k
3
+ k
3
+ 3k
2
+ 3k + 1 = k
3
+ (k + 1)
3
Ans.]
Q.5
[Sol. Put D = 0 and sin o > 0
4cos
2
o 4
2
1
sin o (cos o + sin o) = 0 2cos
2
o sin o cos o sin
2
o = 0
(2cos o + sin o) (cos o sin o) = 0
Either, tan o = 2 or tan o = 1.
Now, tan o = 1 Also, tan o = 2
o =
4
t
,
4
5t
(Reject) o = t tan
1
2 or o = 2t tan
1
2
As,
4
5
sin
t
< 0 o = t tan
1
2
MATHEMATICS
Code-A Page # 2
o =
4
t
.]
Q.6
[Sol. We have, (1 sin
2
x) +
|
|
.
|

\
|
+
2
1 3
sin x
4
3
1 = 0
sin
2
x
|
|
.
|

\
|
+
2
1 3
sin x +
4
3
= 0
4 sin
2
x 2 3 sin x 2sin x + 3 = 0
On solving, we get sin x =
2
1
,
2
3
x e [t, t] are
6
t
,
6
5t
,
3
t
,
3
2t
. Ans.]
Q.7, 8, 9
[Sol. Given g
1
g
5
= 15 a ar
4
= 15 ......(1)
g
1
+ g
3
= 20 a + ar
2
= 20 ......(2)
) 2 ( ) 1 ( 1 r
2
=
4
3
r
2
=
4
1
r =
2
1
or
2
1
(reject, as terms of G.P are positive)
Hence r =
2
1
a = 16
Hence G.P. is 16, 8, 4, 2, 1,
2
1
,............
g
5
= 1
Now
=
5
1 i
i
g
= (16 + 8 + 4 + 2 + 1) = 31 Ans.(i)
Given g
5
= 1, lies between the roots of the equation (k
2
+ 4k + 5)x
2
+ (k 2)x + k
2
16k + 2 = 0
Hence (k
2
+ 4k + 5) + (k 2) + k
2
16k + 2 < 0
2k
2
11k + 5 < 0 (2k 1)(k 5) < 0
Hence k e
|
.
|

\
|
5 ,
2
1
Hence largest integral value of k is 4 Ans.(ii)
Now g
3
= 4
(g
3
1), (g
3
), (g
3
+ 1) = 3, 4, 5
Hence triangle is right triangle.
r =
s
A
=
6
6
= 1 , R =
2
5
Hence R r =
2
3
Ans.(iii) ]
MATHEMATICS
Code-A Page # 3
Q.10
[Sol. We know that
(A) tan A + tan B + tan C = tan A tan B tan C = 0
Either tan A, tan B or tan C is equal to zero, which is not possible.
(B) Let
2
A sin
=
2
B sin
=
1
C sin
= k (say) a = 2k, b = 3k, c = k
b = a +c, whic is not possible.
(C) (a + b)
2
= c
2
+ ab
ab 2
c b a
2 2 2
+
=
2
1
= cos C
ZC =
3
2t
.
Also, (sin A + cos A) =
2
3
1 + sin 2A =
2
3
sin 2A =
2
1
2A = 30 A = 15
(D) We know that
c b
a
+
=
C sin B sin
A sin
+
=
|
.
|

\
|
|
.
|

\
| +
2
C B
cos
2
C B
sin 2
2
A
cos
2
A
sin 2
=
|
.
|

\
|
2
C B
cos
2
A
sin
>
2
A
sin
As, 0 < |
.
|

\
|
2
C B
cos
s 1
because 0 s | B C | < 180. Ans.]
Q.11
[Sol. A =
3 10
, s = 10 r = 3
s
=
A
and r = (s b) tan
2
B
s b = 3 b = 7.
a + c = 13 .......(1)
ac = 40 .......(2)
A
B C
60
a
b c
3 10 60 sin ac
2
1
=
From (2), a
2
13a + 40 = 0
a = 5, a = 8
c = 8 and c = 5.
Hence, a = 8; b = 7 and c = 5 (As a > b > c)
r
1
=
a s
A
, r
2
=
b s
A
, r
3
=
c s
A
will give
15
1
:
13
1
:
12
1
Also, R 2
B sin
b
= 2R =
2
3
7
R =
3
7
. Ans.]
Q.12
[Sol. From figure we see that both roots are positive and a <
0
o + | =
( ) positive
a
2
and o| =
a
c
= (positive)
MATHEMATICS
Code-A Page # 4
a < 0 and c < 0
i.e., both a and c have same sign (A) is correct.
Difference between roots 2 < | o
( ) 2 4
2
< o| | + o (B) is correct.
Also f ( 1) < 0 a + c < 2 (C) is correct.
Both roots are real and distinct D > 0 4 4ac > 0 ac < 1 (D) is incorrect. ]
Q.13
[Sol. Clearly, area of quadrilateral ABCD = area (AABC) + area(AACD)
=
2
1
ab sin B +
2
1
cd sin D
Area of quadrilateral ABCD =
2
1
(ab + cd) sin B (C) is correct
[As, B + D = 180 D = 180 B]
By cosine rule in AABC, we have
a
2
+ b
2
2ab cos B = AC
2
.........(2)
d
a
h
1
h
2
b
c
D
B
C
A
Similarly, by cosine rule in AACD, we get
c
2
+ d
2
2cd cos D = AC
2
.........(3)
From (2) and (3), we get
a
2
+ b
2
2ab cos B = c
2
+ d
2
+ 2cd cos B.
cos B =
( ) cd ab 2
d c b a
2 2 2 2
+
+
........(4)
(A) is correct.
Also, area of quadrilateral ABCD = area (AABC) + area (AACD)
=
2
1
AC h
1
+
2
1
AC h
2
=
2
1
(h
1
+ h
2
) AC =
2
1
(ab + cd) sin B (Using equation (1))
(ab + cd) = (h
1
+ h
2
)
B sin
AC
..........(5)
Now, using sine law in AABC, we get

B sin
AC
= 2R ........(6)
From (5) and (6), we get
ab + cd = 2 (h
1
+ h
2
) R
(B) is correct. .........(7)
As, cos B =
) cd ab ( 2
d c b a
2 2 2 2
+
+
AC
2
= a
2
+ b
2
2ab cos B
= (a
2
+ b
2
) 2ab
(

+
+
) cd ab ( 2
d c b a
2 2 2 2
=
( ) ( )
cd ab
d c ab cd b a
2 2 2 2
+
+ + +
AC
2
=
( ) ( )
( ) cd ab
bc ad bd ac
+
+ +
..........(8)
MATHEMATICS
Code-A Page # 5
Similarly, it could be proved that
BD
2
=
( ) ( )
( ) bc ad
bd ac cd ab
+
+ +
..........(9)
From equation (8) and equation (9), we get
AC
2
BD
2
= (ac + bd)
2
AC BD = ac + bd
ac + bd = d
1
d
2
(D) is correct.
where d
1
and d
2
are the length of diagonals of the quadrilateral. Ans.
Objective approach: Students may verify options by considering a cyclic square.]
PART-B
Q.1
[Sol.
(A) Given, ZA =
3
t
= 60
Now, |
.
|

\
|
+
|
.
|

\
|
+ +
b
a
b
c
1
c
b
c
a
1 = |
.
|

\
| +
|
.
|

\
| + +
b
a c b
c
b a c
=
bc
a ) c b (
2 2
+
=
bc
a bc 2 c b
2 2 2
+ +
=
bc
a ) c b (
2 2 2
+
+ 2 = 2 cos A + 2 = 2
3
cos
t
+ 2 = 2
|
.
|

\
|
2
1
+ 2 = 1 + 2 = 3. Ans.]
(B) Given, 2x y = 5b ........(1)
4x + y = 3b
2
10 b ........(2)
Solving (1) and (2), we get
x =
6
b 5 b 3
2

, y =
6
b 40 b 6
2

.
Now, 2x y > 10
(6b
2
10b) (6b
2
40 b) > 60 30 b > 60 b > 2
The smallest integral value of b = 3. Ans.
(C) Equation of line through (3, 2) with slope
2
3
is (y 2) =
2
3
(x 3)
3x 2y = 5
A (1, 1)
y = x
x
y
y = x
B (5, 5)
O
Here, O (0, 0), A (1, 1), B (5, 5)
Now, OA = 2 , OB = 5 2
Area of AOAB = ( )( ) 2 5 2
2
1
= 5. Ans.]
PART-C
Q.1
[Sol. Given 2 cos 3x(3 4 sin
2
x) = 1
2 cos 3x sin x(3 4 sin
2
x) = sin x (Multiplying both sides by sin x)
2 sin 3x cos 3x = sin x (sin x = 0)
sin 6x = sin x
6x = nt + (1)
n
x, n e I
MATHEMATICS
Code-A Page # 6
if n is odd, say n = (2m 1) then 7x = nt x =
7
) 1 m 2 ( t
, m e I .....(1)
if n is even say n = 2k then 6x = 2kt + x x =
5
k 2 t
, k e I .....(2)
Hence x =
7
t
,
7
3t
,
7
5t
,
7
9t
,
7
11t
,
7
13t
|
.
|

\
| t
= ! think ,
7
7
x
or x =
5
2t
,
5
4t
,
5
6t
,
5
8t
(x = 0, think !)
Total = 10 solutions. Ans.
Note : solution for which sin x = 0 have been rejected. ]
Q.2
[Sol. We have 3x
2
+ x 1 = 0 x =
6
3 1
Clearly, | o | < 1, | | | < 1.
Also, (o + |) =
3
1
and o| =
3
1
( )

=
| + o
1 r
r r
= (o + o
2
+ o
3
+ ...... ) + (| + |
2
+ |
3
+ ...... ) =
|
|
+
o
o
1 1
=
o| + | + o
o| | + o
) ( 1
2
=
3
1
3
1
1
3
2
3
1
+
+

=
3
1
. Ans.]
Q.3
[Sol. Let f(x) = 5x
2
+ (a + 1) x + a.
Clearly, f(1) f(3) < 0 (2a + 6) (4a + 48) < 0 12 < a < 3. Ans.
Now, checking at end points.
When f(1) = 0 a = 3
Now, f(x) = 0 5x
2
2x 3 = 0 5x
2
5x + 3x 3 = 0 5x (x 1) + (x 1) 3 = 0
(5x + 3) (x 1) = 0
x =
5
3
, 1 (Reject)
Also, when f(3) = 0 a = 12
Now, f(x) = 0 5x
2
11x 12 = 0 5x
2
15 x + 4x 12 = 0 5x (x 3) + 4 (x 3) = 0
(5x + 4) (x 3)
x= 3,
3
4
(Reject)
Hence, we conclude that 12 < a < 3. Ans.]
Q.4
[Sol. S
n
=
.......
2 cos 2 cos 1 cos 2
1
2 cos 1 cos 2
1
1 cos 2
1
2 3 2
+ + +
S
n
= sin 1
(

+ + + .......
8 sin
1
4 sin
1
2 sin
1
= sin 1 [cosec 2 + cosec 4 + cosec 8 + ......]
MATHEMATICS
Code-A Page # 7
As, cosec 2u =
u u =
u u
u u
=
u u
u
=
u
2 cot cot
sin 2 sin
) 2 sin(
sin 2 sin
sin
2 sin
1
cosec 2 = cot 1 cot 2
cosec 4 = cot 2 cot 4
cosec 8 = cot 4 cot 8
cosec 2
10
= cot 2
9
cot 2
10

= cot 1 cot 2
10
S
n
= sin 1 [cot 1 cot 2
10
]
a = 1, b = 1, c = 1024 sum (a + b + c) = 1026. Ans.]
PHYSICS
Code-A Page # 1
PART-A
Q.1
[Sol. Vinegar (higher density) goes up whereas oil (lesser density) comes down resulting in upward movement
of CM. ]
Q.2
[Sol. v
CM
=
2 1
2 2 1 1
m m
v m v m
+
+
>
2 1
1 2 1 1
m m
v m v m
+
+
m and
dt
dT
= k(T
0
4
T
4
) ]
Q.4
[Sol. 50(10) + m(0) = (50 + m) (2.5) ]
Q.6
[Sol. T = 2t
g

T
dT
=
2l
l d
=
u d
2
1
=
) 10 19 (
2
1
6

(25)
dl = l du ]
Q.7
[Sol. No external force COM doesnot move ]
Q.8
[Sol. Initial elongation of spring

u cos

2
1
k
2
cos
|
.
|

\
|

u

=
2
1
2
m
v
r
2
v
r
= l
|
.
|

\
|
u
u
cos
cos 1

m
K 2
]
Q.9
[Sol. v
r
= v + v = 2v =
|
.
|

\
|

37 cos
37 cos 1

m
K 2
v =
m 2
K
4

]
Q.10
[Sol. F =
dx
du
= (

+ |
.
|

\
|

2 2 2 2
a / x
2
a / x 2
xe 2
a
x 2
e x k
]
PHYSICS
Code-A Page # 2
Q.11
[Sol. W
other
is the work done by Non-conservative forces or any other forces for which potential energy can
not be found. ]
Q.12
[Sol. Properties of conservative forces. ]
Q.13
[Sol. Momentum of the system is conserved in every inertial frame of reference. ]
PART-B
Q.1
[Sol. In car's frame of reference
60
a = 2g
net
3 g
m(2g) =

2
min
mv
]
PART-C
Q.1
[Sol. 0.8 30 10
3
30 =
2
1
(400)v
2
= 60 m/s ]
Q.2
[Sol. T = mg
m
rmax
e
2
= T + mg
mr
min
e
2
= T mg
m(r
max
+ r
min
)e
2
= 2mg
r
max
+ r
min
=
2
g 2
e
= 5 m ]
Q.3
[Sol. Area = mv mv
0
42 = 2 (v 2)
21 = v 2
v = 19 m/s ]
Q.4
[Sol. Stress =
Area
Force
=
A
mg
=
A
g ) A (
= lg
8 10
8
= (8 10
3
)l (10) ]