12

th
ABCD (Date: 17-07-2011) Review Test-3
PAPER-2
Code-B
ANSWER KEY
CHEMISTRY
SECTION-2
PART-A
Q.1 A,B
Q.2 A,B,D
Q.3 B,D
Q.4 A,B,C,D
Q.5 A,D
Q.6 A,B,D
Q.7 A,D
Q.8 B
Q.9 D
Q.10 B
Q.11 A
PART-B
Q.1 (A) P,S or P,S,T
(B) Q,R or Q,R,T
(C) T
(D) P,S
PART-C
Q.1 0150
Q.2 2313
Q.3 0003
Q.4 1800
Q.5 0003
Q.6 0002
MATHS
SECTION-1
PART-A
Q.1 C
Q.2 D
Q.3 D
Q.4 A
Q.5 D
Q.6 C
Q.7 A, C
Q.8 D
Q.9 A
Q.10 B
Q.11 A
PART-B
Q.1 (A) R
(B) S
(C) T
(D) P
PART-C
Q.1 0011
Q.2 0135
Q.3 0011
Q.4 0013
Q.5 0003
Q.6 0016
PHYSICS
SECTION-3
PART-A
Q.1 B
Q.2 A,C,D
Q.3 A,B,D
Q.4 A,B,C
Q.5 A
Q.6 A,B,C
Q.7 A,B,C
Q.8 C
Q.9 A
Q.10 B
Q.11 D
PART-B
Q.1 (A) P,R,T
(B) P,R
(C) Q,R
(D) R,S,T
PART-C
Q.1 0012
Q.2 0007
Q.3 0016
Q.4 0002
Q.5 0018
Q.6 1250
MATHEMATICS
Code-B Page # 1
PART-A
Q.1
[Sol.
mb
We have, 2 (a + 2b) = a + (2a + b) a = 3b ......(1)
and (ab + 5)
2
= (a + 1)
2
(b + 1)
2
......(2)
Using (1) in (2), we get
( )
2
2
5 b 3 +
= (3b + 1)
2
(b + 1)
2
3b
2
+ 5 = (3b + 1) (b + 1)
3b
2
+ 5 = 3b
2
+ 4b + 1 b = 1 or 3b
2
+ 5 = 3b
2
4b 1

0 . Disc
2
0 3 b 2 b 3
<
= + + . so b e R
So b = 1, a = 3. Hence (a + b) = 4. Ans.]
Q.2
[Sol.
mb
Given that
G(x) = x
2
g(x) ........(1)
Differentiable both sides of equation (1) with respect to x, we get
2
f(2)=1
g = f
1
f
G'(x) = x
2
g'(x) + 2x g(x)
G'(1) = g'(1) + 2 g(1) =
) 2 ( ' f
1
+ 2 f
1
(1) = 2 + 2 (2) = 6. Ans.]
Q.3
[Sol.
mb
Let g(x) = x, where x < 2, then g(x) is strictly increasing.
let h(x) = x
2
2x + 4, where x > 2, then h(x) is also strictly increasing.
Since, f(x) is strictly increasing at x = 2,
so k x Lim
2 x
s

s ( ) 4 x 2 x Lim
2
2 x
+
+

2 s k s 4 k e [2, 4]
Aliter:
x=2
x
O
(0, 4)
y
(0, 2)
y

=

x
y = x
2
2x + 4
Clearly, 2 s f(2) = k s 4. Ans.]
Q.4
[Sol.
MB
As sgn (x + 1) = 1, x e (1, 2]
So, f(x) =

s < +
s s

2 x 1 , bx ) 2 x 2 cos( a
1 x 0 , e x
2
) 1 x ( 2 2
By definition of continuity of f(x) at x = 1, we get
1 = (a + b) .......(1)
And by definition of differentiability of f(x) at x =1, we get
f '(1

) = 4 and f '(1
+
) = 2b
2b = 4 b = 2 a = 1. Ans.]
MATHEMATICS
Code-B Page # 2
Q.5
[Sol. Given,
}

) x ( f
1
1
dt ) t ( f =
( ) 8 x
3
1
2 3

Differentiating both sides with respect to x, we get

f
1
(f(x)) f '(x) =
2
x
x f '(x) =
2
x
f '(x) =
2
1
x
1/2
Now, integrate both side with respect to x, we get
f(x) = x + C
Given f(1) = 0 C = 1
Hence, f(x) = x 1 f(9) = 3 1 = 2. Ans.]
Q.6
[Sol.
MB
We know that if k (x) = f(x) g(x), where f(x) is differentiable at x= a and f(a) = 0 but g(x) is continuous
at x = a then k (x) is also derivable at x = a.
In options (A) , (D), functions are differentiable at x = 1.
For option (B),
f ' (1
+
) = 0
h
h sin
Lim
0 h
=

f ' (1

) =
0
h
h sin
Lim
0 h
=

f(x) = sin ( ) 1 x 1 x is derivable at x = 1.

For option (C)
f '(1
+
) = 2
h
h h tan
Lim
0 h
=
+

and f'(1

) =
2
h
h h tan
Lim
0 h
=

f(x) = tan ( ) 1 x + 1 x is non-derivable at x = 1. Ans.]

Q.7
[Sol.
gk
Let f(x) = x
2
+ ax a
Clearly, f(2) < 0 4 + 2a a < 0 a < 4 ......(1)
and f(3) < 0 9 + 3a a < 0 a < 9/2 ......(2)
So, (1) (2) gives
2 3
x
f(x) = x + ax - a
2
a e
|
.
|

\
|

2
9
,
Ans.]
MATHEMATICS
Code-B Page # 3
Paragraph for question nos. 8 to 11
[Sol.
(i) g(x) = x k, where k =
}
1
0
dt ) t ( f
f(x) =
3
x
3
+ 1 x
}

x
0
dt ) k t ( =
2
x
3
+ 1 x
(

kx
2
x
2
= 1 + kx
2
k =
}
+
1
0
2
dt ) kt 1 ( = 1 +
3
k
|
.
|

\
|
0 ,
2
3
|
.
|

\
|
2
3
, 0
g(x) f(x)
O
(0, 1)
x
y
P(x , y )
1
1

|
.
|

\
|
=
3
5
,
3
4
terval in the in which lies
2
3
k
.
Hence f(x) = 1 +
2
3
x
2
; g(x) = x
2
3
(ii) Now, minimum vertical distance between f(x) and g(x) is
min
) x ( g ) x ( f =
(
(

|
.
|

\
|

|
|
.
|

\
|
+
2
3
x 1
2
x 3
2
= |
.
|

\
|
+
2
3
5
3
x 2
x
2
3
=
(
(

+
|
.
|

\
| 1

9
14
3
x
2
3
2
Hence,
min
) x ( g ) x ( f =
9
14
2
3

=
3
7
. Ans.
(iii) Since, perpendicular distance is the minimum distance.
Hence, distance of the point P(x
1
, y
1
) on the curve y = f(x) from the curve y = g(x) is least when tangent
line at P is parallel to y = x
2
3
.

P
dx
dy
= 1 3x
1
= 1 x
1
=
3
1
. Ans.
(iv) Since vertex lies of y-axis. Hence f(|x|) = f(x).
So, no points of non-derivability, as f(|x|) = f(x) is derivable for all real x. Ans.]
PART-B
Q.1
[Sol.
(A) Use
}
b
a
dx ) x ( f =
}
+
b
a
dx ) x b a ( f
add to get 2I =
}
10
4
dx
I = 3 Ans.
(B) Clearly, f(u) = 2 sin
2
u 1 = cos 2u
f(u) = 0 cos 2u = 0 u =
4
7
,
4
5
,
4
3
,
4
t t t t
So, number of solution are 4. Ans.
MATHEMATICS
Code-B Page # 4
(C) Let u =
x
c
, so du = dx
x
c
2

, so
}
c
1
dx
x
) x ( f
=
}
|
|
.
|

\
|

c
c
2
du
c
x
c
) u ( f u
=
}
c
c
du
u
) u ( f
Therefore,
}
c
1
dx
x
) x ( f
=
}
c
1
dx
x
) x ( f
+
}
c
c
du
u
) u ( f
= 3 +3 = 6 Ans.
(D) Clearly, point of intersection is P (1, 1).
Now,
| ( ) ( ) x n 1 x x
dx
d
m
x x
P 1
l + = =
= 1 and
| ( ) x n 1
dx
d
m
P 2
l + =
=
x
1
= 1.
As, m
1
= m
2
So, two curves touches each other at P
u = 0, so secu = sec 0 = 1. Ans.]
PART-C
Q.1
[Sol.
dkm
Let
,
L
1
= }
+

x
0
2
0 x
dt ) t cos 1 (
x
1
Lim
=
( )
2
0 x
x cos 1 Lim +

= 4
and L
2
= }
+

x
0
2
x
dt ) t cos 1 (
x
1
Lim
= }
|
.
|

\
| +
+ +

x
0
x
dt
2
t 2 cos 1
t cos 1
x
1
Lim
= }
|
.
|

\
|
+ +

1
0
x
dt t 2 cos
2
1
t cos 2
2
3
x
1
Lim
=
2
3
Hence, 2(L
1
+ L
2
) = 2 |
.
|

\
|
+
2
3
4
= 2
|
.
|

\
|
2
11
= 11. 1. Ans.]
Q.2
[Sol.
mkj
As, f(x) =
16 bx x
4 ax x
2
2
+ +
+ +
is defined for all x e R, so
0
16 bx x
4 ax x
2
2
>
+ +
+ +
x e R.
which is possible if only if
x
2
+ ax + 4 > 0 x e R and x
2
+ bx + 16 > 0 x e R
a
2
16 s 0 and b
2
64 < 0 4 s a s 4 and 8 < b < 8
So, number of integral values of a = 9 and number of integral values of b = 15
Hence, number of ordered pairs (a, b) = 135. Ans.]
Q.3
[Sol.
dkm
When x > 2 :
( )
}
+
x
0
dt 1 t 2 5
=
( ) ( ) ( ) ( )
} }
+ + +
x
1
1
0
dt 1 t 2 5 dt 1 t 2 5
= ( ) ( )
} }
+ +
x
1
1
0
dt t 2 3 dt t 2 7 = 6 + (3x 3) + x
2
1 = x
2
+ 3x + 2
MATHEMATICS
Code-B Page # 5
f(x) =

s +
> + +
2 x , bx ax
2 x , 2 x 3 x
2
2
By solving we get, 2a = 1, b = 5 2a + 2b= 1 + 10 = 11 Ans.]
Q.4
[Sol. Consider I =
}
+
t
1
3 2
x 1
dx
(put, x = y
3
)
So, I =
}
+
3 1
t
1
2
2
dy
y 1
y 3
=
}
+
+
3 1
t
1
2
2
dy
y 1
3 ) 1 y ( 3
I = (3t
1/3
3) 3 ( )
4
3
t tan
3 1 1
t
+

Now, L = ( )
|
.
|

\
|

t
+


b 3 1 1 3 1
t
at
4
3
t tan 3 3 t 3 Lim
For L to exist, a = 3 and b =
3
1
and hence L =
2
3
4
t

t 3
3 =
4
t 3
3
So, 4L = 3t 12 12 = 4L 3t
Hence, ab 4L 3t = 1 + 12 = 13. Ans.]
Q.5
[Sol. As y = f(x) is polynomial hence it is differentiable.
f '(x) = k (x 1) (x 2) (x 3)
f '(0) = 6k
6 = 6k k = 1
Hence f '(x) = (x 1) (x 2) (x 3) = (x
3
6x
2
+ 11x 6)
f(x) =
(

1
+ x 6
2
x 1
3
x 6
4
x
2 3 4
+ C
2 1
D I D I
3

As, f(0) = 1, hence C = 1
So, f(x) = 1
(

1
+ x 6
2
x 1
3
x 6
4
x
2 3 4
Hence, f(2) = 1 4 + 16 22 + 12 = 3. Ans.]
MATHEMATICS
Code-B Page # 6
Q.6
[Sol. Given ( )
}
+

x
0
King
2
dt t x sin t = x
2

}

x
0
2
dt t sin ) t x ( = x
2
x
2

}
x
0
dt t sin 2x
}
x
0
t sin t +
}
=
x
0
2 2
x t sin t
x
2
(1 cos x) 2x ( x cos x + sin x) + ( x
2
cos x + 2 x sin +cos x 1) = x
2
cos x = 1
So, x = 2nt ; n e I
Hence, number of values of 0, 2t, 4t,......, 30t equals 16. Ans.]
CHEMISTRY
Code-B Page # 1
PART-A
Q.1
[Sol.(A) t =
|
|
.
|

\
|
1
2
T
T
log
k
303 . 2
k = 4 10
2
sec
=
|
.
|

\
|
298
600
log
10 4
303 . 2
2
= 17.5 sec
(B) t =
|
.
|

\
|
298
1192
log
10 4
303 . 2
2
=
4 log
10 4
303 . 2
2

= 35 sec.]
Q.2
[Sol. (A) CH
3
CCH

+ 2
Hg
CH C = CH
3
Hg
2+
Cl

CH C=CH
3
Hg

Cl



H
2 3
CH C CH
|
Cl
=
(B) CH
3
CCH

+ 2
Hg
CH C = CH
3
Hg
2+
H O
2
H
2 3
CH C CH
|
OH
=

3 3
CH C CH
| |
O

(C)

OH is weaker base than CH
3
C

C ]
Q.3
[Sol. [Co(C
2
O
4
)(en)Cl
2
]
1
Oxidation state of Co
x 2 + 0 2 = 1
x = + 3
C
2
O
4
2
and en = bidentate ligand
Cl

= monodentate ]
Q.4
[Sol. For adiabatic reversible process , q = 0
For reversible cyclic prcess , AU = 0
W = 0
Also AH = 0
Also, for any system, q
sys
+ q
surr
= q
total
= 0 and W
sys
+ W
surr
= W
total
= 0 ]
Q.5
[Sol.
(A) CH
3
CCH
THF / BH
3
(CH
3
CH-CH)
3

A

3
AgNO
CH
3
CH=CHCH=CHCH
3
(B)
Me
Me
A

COOH CH ) ii (
THF / BH ) i (
3
3
(cis)
Me Me
) anti (
4
CCl
2
Br

Me
Me
Br
Br H
H
(Erythro)
+ Enantiomer
CHEMISTRY
Code-B Page # 2
(C)
Ph H

A


OH /
2
O
2
H ) ii (
THF / BD ) i (
3
OH
|
CH CD Ph = PhCHDCHO
(D)

THF / BH
3 3 B
A

COOH CH
3
]
Q.6
[Sol. AG = AH TAS
(A) AS = 0 and AH < 0 AG < 0
so the process will be spontaneous
(B) AS
univ.
= AS
sys
+ AS
surr
For adiabatic process AS
surr
= 0
Given that AS
sys
> 0 AS
univ
> 0 (So process is spontaneous)
(D) AG
P,T
< 0, so process will be spontaneous ]
Q.7
[Sol.

HBr

Br
Peroxide
HBr

Br


HBr
Br

HBr
Peroxide
]
Paragraph for question nos. 8 to 11
[Sol.(i)
OH
OH
OH
HO
OH
OH
Sol.(ii)

NBS

Br
CHEMISTRY
Code-B Page # 3
Sol.(iii)

HI

I

I
Sol.(iv)

HOCl H O
2

Cl

Me
OH
Cl
+
Me
Cl
HO
]
PART-B
Q.1
[Sol. (Compound) (Final major product during hydrolysis)
PCl
5
H
3
PO
4
(tribasic acid)
PCl
3
H
3
PO
3
(dibasic acid
BCl
3
H
3
PO
3
(monobasic)
P
4
O
10
H
3
PO
4
(tribasic) ]
PART-C
Q.1
[Sol. Given that v
avg
= 4.6 10
2
m/s =
M
RT 8
t
v
rms
=
M
RT 3
M
RT 8
10 6 . 4
M
RT 3
v
2
rms
t

v
rms
= 4.610
2

8
3t
2
rms
v = 24.93 10
4
(m/s)
2
Total translational KE of gas molecules =
) molecules of . no ( mv
2
1
2
rms
|
.
|

\
|
=
22 4 26
10 2 10 93 . 24 10 6
2
1

= 149.58
~
150 Ans.]
Q.2
[Sol. (a)

O H / Zn / O
2 3
O O
(b) CH
2
=CHCH
2
CH+CHCH
3

O H / Zn / O
2 3
CH
2
=O+OCHCH
2
CHO+CH
3
CHO
CHEMISTRY
Code-B Page # 4
(c)

O H / Zn / O
2 3
O
O
H
(d)

O H / Zn / O
2 3
O
+
O
O
+ CH
2
= O ]
Q.3
[Sol. BeCl
2
, HgCl
2
and I
3

have linear shape. ]

Q.4
[Sol. A + B C + D
K
eq
=
b
f
K
K
AG = RT ln K
eq
= 2 300 ln 20 = 1800 cal
magnitude of AG = 1800 cal Ans.]
Q.5
[Sol. BeCO
3
< BaCO
3
(Thermal Stability),
AgI > AgCl (Intensity of color),
BeO > BeF
2
(Covalent character) ]
Q.6
[Sol. 2A 3B + 5 C [For constant T and V
K =
|
|
.
|

\
|

t
o
P P
P P
log
t
303 . 2
P o no. of moles as PV = nRT ]
= |
.
|

\
|

5 . 147 170
80 170
log
700
303 . 2
K = 1.98 10
3
K 100 = 1.98
~
2 Ans. ]
PHYSICS
Code B Page # 1
PART-A
Q.1
[Sol. U = pE cos u
u is max. is cosu is min. in case 3 & 4 U is +ve so angle is obtuse
t = pE sin u max. is angle is closet to 90
pE cos u = V
0
cosu
1
=
PE
V
0
, cosu
2
=
PE
V 7
0
, cosu
3
=
pE
V 3
0
cosu
4
=
pE
V 4
0
]
Q.2
[Sol. If centre is on xy plane,
Q
evc
= tR
2
o = 25 to
| = 50 t
In case c, sphere is above plane
u
evc
= 0 ]
Q.4
[Sol. T cos o = mg
T sin o
2
2
r
kq
mw
2
r T > mg
T > T sin o
2
2
r
kq
+ mw
2
r
T is const. if o is const.
T sin a =
r
mv
2
, prev T sin o =
0
2
2
2
r
mv
r
kq
=
r
mv
r
kq
r
mv
2
2
2 2
0
= +
v should be increased ]
Q.6
[Sol.
6
5
15 2
X
CM
=

=
12
5
10 3
V
CM
=

=
]
Q.8
[Sol. [A] =
| |
2
L
V
=
| |
2
qL
V
=
2
2 2
ATL
T ML

= ML
1
T
3
]
PHYSICS
Code B Page # 2
Q.9
[Sol. E =
i

x
v
c
c

j

x
v
c
c

k

z
v
c
c
= 2x Ai

6Ayy
j

2zAk

=
k

2
A
]
Q.10
[Sol. r =
3
y r
y
u
y
r
= tan u =
3
u = 60 ]
Q.11
[Sol. 1200 = 1 (x
2
3 100 + z
2
)
x
2
+ z
2
= 900 Not possible ]
PART-B
Q.1
[Sol. (A) W = Ak = Positive v |
P = Fv, v| P velocity in positive direction
(B) W = positive v|
P = Fv at x = 2 f = 0 P = 0
(C) F = 0 v = const.
P = Fv = 0 P = const.
(D) F = negative speed is decreasing
P = Fv v+ v+
v +ve ]
PART-C
Q.1
[Sol. E =
j

8 i

6 +
20 j
^
1.6 sec.
t
u
2
m
E
q a

= =
j

8 i

6 +
t a u v

+ =
=
i

t 8 i

t 6 j

20 + +
= (8t 20)
j

+
i

t 6
v
2
= 36t
2
+ 64t
2
+ 400 320t = 100t
2
+ 400 320t
v
2
= 100 (1.6)
2
+ 400 320 1.6
v
min
= 12 m/s ]
PHYSICS
Code B Page # 3
Q.2
[Sol. I
1
= I
0
, I
2
= 4I
0
I = I
1
+ I
2
+ 2
2 1
I I cos
|
.
|

\
|

t
D
dy 2
= I
0
+ 4I
0
+ 2
2
0
I 4
cos
|
|
.
|

\
|

2
10
5
10
10 6
2
3 3
7
= 5I
0
+ 4I
0
cos
|
.
|

\
| t
30
10
= 5I
0
+ 4I
0
cos
|
.
|

\
| t
3
= 7I
0
]
Q.3
[Sol.
x
V
centre
= V
conductor
50 =
x
kQ
R
Q k
surface
+
E
=
2
10 9
10 4
10 11 . 1 10 9

+
x
10 44 . 4 10 9
10 9

25 =
x
4
x = 16 cm ]
Q.4
[Sol.
Q
V
0
V
0
Q
r
at r
max
, v
rel
= 0
2
1
w
rel
2
and
r
kQ
2

=
2
1
0
2
+
x
kQ
2

2
1

m m 2
m 2
2
+
(2v
0
)
2

r
Q
4
1
2
0
e t

=
x
kQ
2

3
m
4
mr 8
Q 3
0
2
e t

r 8
Q
0
2
e t
=
x 4
Q
0
2
e t

x = 2r ]
Q.5
[Sol.
2
1
mv
2
= mgh
R
h
u
N = 0 mg =
R
mv
2
=
R
mgh 2
h =
2
R
= 18 m ]
PHYSICS
Code B Page # 4
Q.6
[Sol.
2
m m
r
G
2 1
=
2
2
r
kq
3
20
10
11
3 10
6
1.8 10
6
= 9 10
9
q
2
q
2
=
9
23
10 9
10 36

= 4 10
32
q = 2 10
16
C = 1.6 10
19
N
N =
6 . 1
10 2
3

=
6 . 1
2000
= 1250 ]