13

th
VXY (Date: 18-12-2011) Review Test-5
PAPER-1
Code-A
ANSWER KEY
CHEMISTRY
SECTION-2
PART-A
Q.1 D
Q.2 D
Q.3 C
Q.4 A
Q.5 A
[Only V-Group Batch]
Q.6 C
[Only XY Batch]
Q.6 A
Q.7 C
Q.8 B
Q.9 A
Q.10 A,B,C,D
Q.11 A,C,D
[Only V-Group Batch]
Q.12 A,B,C,D
[Only XY Batch]
Q.12 A,D
PART-B
(Only V-Group Batch)
Q.1 (A) P,Q,R,S,T
(B) P,Q,R,S
(C) P,S
(D) P,R,S,T
(Only XY Batch)
Q.1 (A) Q,T
(B) P,T
(C) P,S
(D) R,S
PART-C
Q.1 3006
[Only V-Group Batch]
Q.2 2345
[Only XY Batch]
Q.2 9890
Q.3 3049
Q.4 0004
PHYSICS
SECTION-1
PART-A
Q.1 C
Q.2 B
Q.3 D
Q.4 A
Q.5 B
Q.6 A
Q.7 D
Q.8 B
Q.9 A
Q.10 A,B
Q.11 C
Q.12 B,C,D
PART-B
Q.1 (A) P,Q
(B) P,S
(C) P,S
(D) R
PART-C
Q.1 0500
Q.2 0006
Q.3 0001
Q.4 0005
MATHS
SECTION-3
PART-A
Q.1 D
Q.2 B
Q.3 B
Q.4 D
Q.5 D
Q.6 B
Q.7 B
Q.8 D
Q.9 D
Q.10 B,C,D
Q.11 B,C
Q.12 B,D
PART-B
Q.1 (A) S
(B) P,Q
(C) P
(D) Q
PART-C
Q.1 0002
Q.2 0006
Q.3 0002
Q.4 0010
PHYSICS
Code-A Page # 1
PART-A
Q.1
[Sol. P =
R
q
2
R =
A
P

R 8
q
' P
2
= R' =
4 A/
) 2 ( l
= 8R ]
Q.2
[Sol. T
2
=
GM
4
2
t
r
3
G =
s R
3
4
T
4
3 2
2
t
t
R
3
=
2
T
3

t
]
Q.3
[Sol. Let T be final temp.
V
1
S(T T
1
) + V
2
S(T T
2
) = 0
T =
2 1
2 2 1 1
V V
V T V T
+
+
]
Q.4
[Sol. ms
dt
dT
= ocA (T
4
T
0
4
)

dt
dT

m
1
Lesser mass cools faster and hollow sphere is having less mass. ]
Q.5
[Sol. PV = nRT
V
n
=
RT
P
Since temperature in all are same.
One having more pressure has heightest particle density. ]
Q.6
[Sol. P T
3
P = k
3
nR
PV
|
.
|

\
|
P
2
V
3
= const.
PV
3/2
= const. Y = 3/2 ]
PHYSICS
Code-A Page # 2
Paragraph for question nos. 7 to 9
[Sol. Q.No. 7 & Q.No. 8
i
R
27O iR
) 27 R ( i +
= O ..... (1)
R
3
ni
(n i)i
i
iR = 3(n 1)i R = 3(n 1) ...... (2)
From (1) and (2)
(R + 27) = R
(

+1
3
R
R = 9O and n = 4 ]
Q.9
[Sol.
378V
40A
8 A
9O 27O 3O
30O
32A 40A 10A
9O
9O
]
Q.10
[Sol. g =

>
<
R r
r
GM
R r
R
GMr
2
3
(A) r, r
2
< R
2
1
F
F
=
2
1
r
r
(B) r, r
2
> R
2
1
F
F
=
2
1
2
2
r
r
]
Q.11
[Sol.
3F 5F
30V
56.25+q
1
56.25+q
30V
7F
q = 56.25 C
i
q
q
2
3
q 25 . 56
7
q
1 2
+
=
..... (1)
PHYSICS
Code-A Page # 3
5
q q 25 . 56
7
q
2 1 2
+ +
+
= 30 ..... (2)
q
2
= 70 ; q
1
= 26.25
q = 43.75 ]
Q.12
[Sol.
A
10V
2.5O
10O
i = 4A
Maximum
A
10V
2.5O
5O
i = 2A
Minimum
5O
]
PART-B
Q.1
[Sol. (A)
. const
P
T
1 y
y
=

P
T
y
1 y
TP

= const. R
(B) E =
2 / 3 2 2
) R x (
kQx
+
E
x
(C)
U
V
R.O.
R.I.
R.O.
V.I.
(D) Speed decreases as infinity does not exist. ]
PART-C
Q.1
[Sol. E =
y 2
0
tc

sin u =
y 2
0
tc

2 2
h y
h
+
u
u
Y
Z
h
h
(y,0)
=
h 8
0
tc

y = h ]
PHYSICS
Code-A Page # 4
Q.2
[Sol. T = (l x)g ...... (1)
T = xg ...... (2)

l
x
=
1

+
]
Q.3
[Sol. More the resistance less will be power dissipated.
One should connecte the battery is 6O resistor.
2O 4O 6O
11V
]
Q.4
[Sol.
u =
u
K
d
Id
2
2

2
m
12
1

(e
2
u) = Ku
K =
12
1
ml
2

2
T
2
|
.
|

\
| t
= 5 ]
CHEMISTRY
Code-A Page # 1
PART-A
Q.1
[Sol. 2C (graphite) + O
2
(g) 2CO (g) A
r
H = 110.5 2
CO
2
(g) C(graphite) + O
2
(g) A
r
H = 393.5
C(diamond) C (graphite) A
r
H = 2
__________________________________________________
CO
2
(g) + C(diamond) 2CO(g) A
r
H = + 170.5 kJ/mol Ans. ]
Q.2
[Sol. CH
2
= CH CH
2
I
) excess ( HI
I I
| |
CH CH CH
2 3

2
I
CH
3
CH=CH
2
HI
I
|
CH CH CH
3 3
]
Q.3
[Sol. A : Cr
3+
in [Cr(H
2
O)
6
]
3+
Hyb : d sp
= 3.89 B.M.
2 3

eff
3d
4s
4p
B : Cu
+
in [Cu(CN)
4
]
3
Hyb : sp
= 0
3

eff
3d
4s
4p
C : V
+++
in [V (H
2
O)
6
]
3+
Hyb : d sp
= 2.83 B.M.
2 3

eff
3d
4s
4p
D : Co
++
in [Co(H
2
O)
6
]
++
Hyb : sp d
= 3.89 B.M.
3 2

eff
3d
4s
4p
]
CHEMISTRY
Code-A Page # 2
Q.4
[Sol. A CO
2
5600 counts 2800 1400
B CO
2
1400 counts
2 half lives. ]
Q.5
[Sol. NO
2
will show I, but OMe will show +M.

NO
2
NO
2
OMe NO
2
NO
2
CH CO
CH
CH
O O
O
O
+ OH
+
OH
CH OH
2
]
[Only V-Group Batch]
Q.6
[Sol. H
3
PO
2


A
H
3
PO
4
+ PH
3
H
3
PO
3


A
H
3
PO
4
+ PH
3
H
3
PO
4


A
P
4
O
10
+ H
2
O
HNO
2


A
NO + HNO
3
H
3
PO
4
doesn't undergoes disproportionation ]
[Only XY Batch]
Q.6
[Sol. (A)
C
Cl Cl
Cl
H
(B)
C
C
O O
H
Cl Cl
Cl
H H
Chloral (CCl
3
CHO) Chloral hydrate CCl
3
CHO . H
2
O
(C)
H
H
O
O
C (D)
H
O
Cl
Ortho hydroxy benzaldehyde ortho chlorophenol ]
CHEMISTRY
Code-A Page # 3
Paragraph for question nos. 7 to 9
[Sol.(7) M = 0.1
M =
2 . 11
strength volume
0.1 =
2 . 11
V
volume strength = 1.12 Ans.
(8) [Sol. H
2
O
2
+ 2KI I
2
n
f
= 2 n
f
=1 n
f
=2
I
2
+ hypo 2I

n
f
= 2 n
f
= 1
Eq. H
2
O
2
= Eq. of I
2
= Eq. Hypo .....(1)
Eq. Hypo = 200 0.1 = 20
KIO
3
+ KI I
2
n
f
= 5 n
f
= 1 n
f
= 5/3
5 mm of KIO
3
=
3
5
mm of I
2
....(2)
from equation (1) 2 mm of I
2
= 20
mm of I
2
= 10
mm of KIO
3
=
3
5 2
=
3
10
Ans.
(9) N
1
V
1
= N
2
V
2
V 0.1 2 = 0.1 200
V = 100 ml ]
Q.10
[Sol. (A)
+
H

exp
ring



ring
exp.
OH


O H
2

(B)
+
H

O H
2
OH
(C)
+
H
then same as (A)
(D)
+
H

O H
2
OH
]
CHEMISTRY
Code-A Page # 4
Q.11
[Sol. (A) Due to high value of Z
eff
in Ir
+3
, which belongs to III
rd
transition series (P < A
0
)
(B) Due to higher oxidation state of Cobalt in
+ 3
6 2
III
] ) O H ( Co [ , P < A
0
, also H
2
O lies towards
stronger ligand side in spectrochemical series.
(C) CO is a strong field ligand hence P < A
(D) Due to high value of Z
eff
of Pd
2+
, which belongs to 2
nd
transition series , (P < A) ]
[Only V-Group Batch]
Q.12
[Sol.

N N
+ N=NNH
NHN=N
Me
Me
H O
3
+
OH OH NH
2
NH
2
Me
Me
+ + +
H O
3
+
]
[Only XY Batch]
Q.13
[Sol.
NH
2

2
HNO

N N

2
N

H


~
H

ring
exp.

H O
2
HO
Possible products
OH
and
HO
]
CHEMISTRY
Code-A Page # 5
PART-C
[Only V-Group Batch]
Q.2
[Sol. (a)
Me Me
CMe
3
CMe
3
+ E

E
(2)
(b)
NO
2
NO
2
+ E

E
(3)
(c)
NHCMe NHCMe
O O
+ E

E
(4)
(d)
O O
O O
C C
Me Me Me Me
+ E

E
(5) ]
[Only XY Batch]
Q.2
[Sol. (a)
O
| |
CH C CH
3 3
+
O
D
Me
H CH CH
2

OH
Cross aldol
O
| |
CH C CH
2 3

O
D
Me
H CHCH +
CHEMISTRY
Code-A Page # 6
Products:
O
CH
| |
|
CH C CH C CH
|
OH
3
3 2 3
(1)
H
D
O
Me
CH
2
CHCH CCH
2 3
OH
*
(2)
*
CH C CH
3
CH
3
CHO

OH
Me
D
H (2) H H
D D
Me Me
CH
2
CHCH
OH
*
*
CHO

(4)
Total 9
(b) 8
(c) Other than first all are diastereomers therefore 9
(d) No enantiomers are formed therefore 0
9890 ]
Q.3
[Sol. t
1/2
= 30 min
in 90 min, total 3 half lives
Volume of H
2
O
2
consumed = 28 +
2
28
+
2
14
= 49 ml Ans. ]
Q.4
[Sol. C
5
H
10
O
5
ROH + CH CCl
3
O O
ROCCH
3
MW 1 + 43
MW + 42
C
5
H
10
O
5
MW = 150
Remaining MW = 318 150
= 168
4 42 4 OH
Structure
CHO
CH OH
2
OH
OH
OH
H
H
H
]
MATHEMATICS
Code-A Page # 1
PART-A
1. Using L Hospital's rule, we get
L =
4
1
x
x sin
4
1
0 x
Limit
) x sin 2 ( 2
x sin x
0 x
Limit
x 2 cos 2 2
x sin x
0 x
Limit
2

+
]
2. The equation of plane containing A, B and C is
2 1 2
0 1 1
1 z 1 y 1 x


= 0
A(1,1,1)
M( , 2, 1)
C
(3,0,1)
B(2,2,1)
P(x,yz)
2x + 2y 3z + 3 = 0 ........(1)
Clearly, M (o, 2, 1) satisfy equation (1), so
2o + 4 3 + 3 = 0 o = 2. Ans.]
3. Given x
3
3x = c
Let y = x
3
3x and y = c
Now,
dx
dy
= 3x
2
3
1 1 O
y = c
2
2
x
y
(1,2)
(1, 2)
x = 1 or 1 (Graph of y = x
3
3x is as shown)
Clearly, for 3 distinct roots, we have
c e ( 2, 2)
number of integers = { 1, 0, 1} 3 Ans.
4. For real roots D > 0
k
2
4(k
2
+ 2k 4) > 0 3k
2
8k + 16 > 0 3k
2
+ 8k 16 s 0 3k
2
+ 12k 4k 16 s 0
3k (k + 4) 4(k + 4) s 0 k e
(

3
4
, 4
.
Also, o
2
+ |
2
= (o + |)
2
2o| = k
2
2(k
2
+ 2k 4) = k
2
4k + 8 = 12 (k + 2)
2
Maximum value is 12 when k = 2. Ans.]
5.
1
c
z
b
y
a
x
2
2
2
2
2
2
= +
.....(1)

1
c
z
b
y
a
x
2
2
2
2
2
2
= +
......(2)
1
c
z
b
y
a
x
2
2
2
2
2
2
= + +

.....(3)
(1) + (2) + (3)
3
c
z
b
y
a
x
2
2
2
2
2
2
= + +
.....(4)
MATHEMATICS
Code-A Page # 2
From (1) and (4),
1
c
z
2
2
=
z = c
Hence, x = a, y = b, z = c.
So, number of solution (x, y, z) = 2 2 2 = 8. Ans.
6. I =
}
t
+
6
0
dx
x cos
x sin 1
=
}
t

+ 6
0
2 2
dx
2
x
sin
2
x
cos
2
x
sin
2
x
cos
=
}
t

6
0
2
x
sin
2
x
cos
dx
=
}
t
|
.
|

\
| t
+
6
0
4 2
x
cos 2
dx
=
}
t
|
.
|

\
| t
+
6
0
dx
4 2
x
sec
2
1
=
6
0
2
x
4
tan
2
x
4
sec n 2
t
(

|
|
.
|

\
|
|
.
|

\
|
+
t
+
|
.
|

\
|
+
t
l
=
|
|
.
|

\
|
+
+
1 2
3 2
n 2 l
=
( ) 3 4 6 8 n 2 + l
. Ans.]
Paragraph for question nos. 7 to 9
Sol. We have
L
1
:
1
4 z
1
7 y
3
6 x
=

= r
1
(say) ........(1)
and L
2
:
4
2 z
2
9 y
3
x
=
+
=

= r
2
(say) .......(2)
Clearly, any point P on line L
1
is (3r
1
+ 6, r
1
+ 7, r
1
+ 4) and any point Q on line L
1
is
( 3r
2
, 2r
2
9, 4r
2
+ 2).
So, direction ratios of PQ are 2 r r 4 , 16 r r 2 , 6 r 3 r 3
1 2 1 2 1 2
+ .
The points on the lines (1) and (2) which are nearest to each other will lie on line of shortest distance
which will be perpendicular to both the given lines. If PQ is the line of shortest distance, then
3( 3r
2
3r
1
6) 1(2r
2
+ r
1
16) + 1(4r
2
r
1
2) = 0
i.e., 7r
2
11r
1
4 = 0 ........(3)
and 3( 3r
2
3r
1
6) + 2(2r
2
+ r
1
16) + 4(4r
2
r
1
2) = 0
i.e., 29r
2
+ 7r
1
22 = 0 .......(4)
On solving ((3) and (4) ,
We get r
1
= 1, r
2
= 1
Point P(3, 8, 3) and Q( 3, 7, 6)
7. The distance between P and Q =
( ) ( ) ( )
2 2 2
3 6 8 7 3 3 + +
=
9 225 36 + +
=
30 3
.
8. Equaton of plane OPQ, is

6 7 3
3 8 3
0 z 0 y 0 x


= 0
P(3,8,3) Q( 3,7,6)
O(0, 0, 0)
P(x, y, z)
23x 9y + z = 0 Ans.
MATHEMATICS
Code-A Page # 3
9. The value of parallelopiped formed by
OQ , OP
and
OR
where O is origin and R (1, 1, 0)
= | | |
0 1 1
6 7 3
3 8 3
| | OR OQ OP |

= = | 3(0 + 6) 8(0 6) + 3(3 + 7) | = 30 48 18 + + = 96. Ans.]

10. We have
(B
T
AB)
T
= B
T
A
T
(B
T
)
T
= B
T
A
T
B = B
T
AB, iff A is symmetric.
B
T
AB is symmetric iff A is symmetric.
Also, (B
T
AB)
T
= B
T
A
T
B = B
T
AB, iff A is skew-symmetric matrix. ]
11.
2 O
(0,0)
x=2
x
y
|
.
|

\
|

9
4
, 2 A
y=1
+
x=1
B(2,4)

+
Graph of f(x) =
3 ) 1 x (
) 4 x (
3

Now, verify alternatives. Ans.]

12. Let the line be
1
b
y
a
x
= + , a, b > 0
where 1
b
4
a
1
= +
a
1
1
b
4
=

a
1 a
b
4
=
b =
1 a
a 4

Now, 2A = ab = a
|
.
|

\
|
1 a
a 4
=
1 a
) 1 1 a ( 4
2

+
=
(

+ +
1 a
1
) 1 a ( 4
da
dA
2
= (

2
) 1 a (
1
1 4
= 0
B(0,8)
A(2,0)
O
x
y
a 1 = 1 or 1
a = 2; b = 8, m = 4
MATHEMATICS
Code-A Page # 4
A]
min
=
2
16
= 8
Equation is (y 4) = 4(x 1) y 4 = 4x + 4 4x + y = 8 Ans.
Also, r =
s
A
=
2
68 8 2
8 2
2
1
+ +

=
17 5
8
+
=
17 5
Now verify alternatives. ]
PART-B
1.
(A) S
n
= 33.
2
n
[2 + (n 1) (n 1)] = 33n (n 1)
2
= 64
Hence n = 9. Ans.]
(B) Domain of f(x) is x e [ 1, 1]. Also f(x) is decreasing in its domain.
At x = 1 f
max
(x = 1) = cos
1
( 1) + cot
1
( 1) = t +
4
3t
=
4
7t
At x = 1 f
min.
(x = 1) = cos
1
(1) + cot
1
(1) = 0 +
4
t
=
4
t

4
t
s f(x) s
4
7t
0.8 s f(x) s 5.25 (approx.)
(C) As 1 + sin u > 0, u e R so the given equation becomes cosu = 1 + sin u
cos u sin u = 1.
Clearly, u = 0, 2t,
2
3t
. Ans.
(D) D = 1 + 4a = (Odd No)
2

because of integral roots.

let odd no = 2 + 1 then 1 + 4a = (2 + 1)
2
= 4
2
+ 4 + 1
a = ( + 1) ; so a = 6, 12, 20, 30.
Hence number of possible values of a are four. Ans.]
PART-C
1. Clearly, g'(x) = f(x) =

< <
s < +
2 x 1 , x
1 x 3 , ) 2 x (
3
2
3
g'(x) is a continuous function.
+ +
1 0
Sign scheme of g''(x)
MATHEMATICS
Code-A Page # 5
g'(x) has a local maximum at x = 1 and local minimum at x = 0.
x=2 x= 3 (2,0) x= 1
O(0,0)
Graph of g'(x) = f(x)
x
y
Hence, g'(x) has two extremum points. ]
2. We have
(
(

+ +
+ +
+ +
z 2 y 0 x 4
z 0 y x 2
z 3 y 0 x 3
=
(
(

+
+
+
y 3 4
z 1
y 2 8
Now, on comparing we get system of equations as
3x + 3z = 8 + 2y 3x 2y + 3z = 8 ........(1)
2x + y = 1 + z 2x + y z = 1 ........(2)
4x + 2z = 4 + 3y 4x 3y + 2z = 4 .........(3)
On solving (1), (2) and (3), we get
x = 1, y = 2, z = 3
Hence, (x + y + z) = 1 + 2 + 3 = 6. Ans.]
3. Given, f (x) = 2x
3
+ 3(1 3a)x
2
+ 6(a
2
a)x + b
f ' (x) = 6[x
2
+ (1 3a)x + a(a 1)] .......(1)
As, f (x) has positive point of local maximum, so the equation f ' (x) = 0 must have both roots positive
and distinct roots.
D > 0 (1 3a)
2
> 4a(a 1) 1 6a + 9a
2
> 4a
2
4a
5a
2
2a + 1 > 0, true a e R. ......(2)
Also, sum of roots > 0 (1 3a) > 0 3a > 1 a >
3
1
......(3)
and, product of roots > 0 a(a 1) > 0 a < 0 or a > 1 .......(4)
Hence, (2) (3) (4)
a e (1, )
So, the smallest integral value of 'a' equals 2.]
MATHEMATICS
Code-A Page # 6
4. Given, 7 sin 3x 2 (3 sin 3x 4 sin
3
3x) = (1 + tan
2
u) + 4 (1 + cot
2
u)
Put, sin 3x = y, we get
y (8y
2
+ 1) = 9 + (tan u 2 cot u)
2
L.H.S. min occurs minimum value
when y = 1 and minimum value = 9. = 9
maximum occurs when y = 1 and maximum value = 9 when tan
2
u = 2
Hence maximum of L.H.S = minimum value of R.H.S.
sin 3x = 1 = sin
2
t
x =
6
t
(minimum positive root).
or sin 3x = |
.
|

\
| t
2
3
sin x =
2
t
(maximum negative root).
Sum =
3
2
6
3
2 6
t
=
t + t
=
t
+
t
.
Hence,
t
15
( ) ) root negative (maximum root) positive (minimum = |
.
|

\
|
t
15
|
.
|

\
| t
3
2
= 10 Ans.]