1. Which of the following statement regarding the projections shown above is correct?

Cl

H
Cl
H
Compound A








Compound B
(a) both the projections represent the same configuration (b) both A and B are optically active
(c) only A is optically active (d) only B is optically active
2. Which of the following compound does not have molecular plane as nodal plane for its

electron cloud?
(a)
2 2
CH CH (b)
6 6
C H
(c)
2 2
CH C CH (d)
2 2
CH CH CH CH
3. A Two litre vessel contins 0.48 mole of
2
CO
0.48 mole of
2
H
, 0.96 mole of
2
H O
and 0.96 mole of CO at equilibrium.
Calculate number of moles of
2
H O
must be removed to bring the concentration of CO to 0.6M.
( ) ( ) ( ) ( )
( ) 2 2 g 2 g g g
CO H H O CO + +
(a) 0.14 (b)0.58 (c) 1.008 (d)0.054
4. A buffer solution of 0.080M Na2HPO4 and 0.020 M Na3PO4 is prepared. The electrolytic oxidation of 1 millimole
RNHOH is carried out in 100mL buffer to give

+
+
RNHOH
H
2
O 4e
-
4H
+
RNO
2
+
Calculate the appropriate pH of the solution after oxidation is complete. pKa1, pKa2 and pKa3 of H3PO4 are 2.12, 7.20, 12
respectively (log2=0.3010)
(a) 2.52 (b) 9.64 (c)4.63 (d)7.81
5. 2 moles of A(atomic weight 60) is taken in a two litre vessel which immediately comes into equilibrium with B as follows.
( ) ( )
2
g g
A B
The density of the equilibrium mixture is
(a) 0.06 g/ml (b) 0.0006 g/ml (c) 3.6 g/L (d) data insufficient
One ore more than one correct option questions
6. The anion of borax has
(a) a tetrahedral skeleton of B atom (b) two electron deficient B atom
(c) one OH group attached to each B atom (d) four negative charges
7. Reactions yielding diborane are
(a)
4 2
Na BH I +
(b)
3 4
2
Et O
BF NaBH +
(c)
3 3 6 2
B N H H O + (d)
3 2 2
Mg B H O

+
8. Select the correct statement based on the stereochemistry of the following molecules
(i)
H
3
C
C
H
C C
H
CH
3
(I)
(ii)
H
CH
3
Br
Br
CH
3
H
(iii)
CH
3
H
OH
CH
3
H OH
(d)

C
H
2
N
H
C H
3
C
H
CH
3
NH
2
(a) compound I, II optically active and III, IV optically inactive
(b) All compound possess axis of symmetry
(c) All the four compounds have at least one diastereoismer
(d) compounds I, II optical activity is compensated only externally
9. A solution contains 0.1 M NaCl, 0.01 NaBr and 0.001M NaI. Solid AgNO3 is gradually added to the solution and its
addition doesnt change the volume of solution.
Ksp(AgCl)=10
-10
; Ksp(AgBr) =10
-13
, Ksp(AgI)=10
-17
Choose the correct statement(s).
(a) AgI precipitates first.
(b) The maximum
Ag
+
1
]
which can be maintained in the solution so that AgI is almost completeley precipitated
is 10
-11
M.
(c) When the precipitation of AgCl just starts [I
-
] in the solution is 10
-8
M.
(d) The maximum
Ag
+
1
]
which can be maintained in the solution so that AgI and AgBr are almost completely
precipitated is 10
-9
M.
Comprehension 1
( ) ( ) ( ) S g g
A B C +
In a one litre vessel, excess of A is taken which comes into equilibrium with B and C at 0
0
C. After the equilibrium is
established, the pressure inside the vessel is found to be 1 atm, and density of the equilibrium mixture, excluding the solid,
is found to be 2 gm/L
10. Kp of the equilibrium is
(a) 0.25 atm
2
(b) 1 atm
2
(c) 0.5 atm
2
(d) data insufficient

11. If the molecular weight of B is 20, the molecular weight of C (approx) is
(a) 15 (b) 70 (c) 35 (d) none of these
12. If the volume of the vessel is suddenly doubled, the new pressure is
(a) 1 atm (b) 0.89 atm (c) 0.5 atm (d) data insufficient
Comprehension 2
CH
3
CH
3
C H
3
C H
3
Cl
2
hv
A(C
6
H
13
Cl)
RO /ROH
-
B
Hg(OAc)
2
/CH
3
OH
NaBH
4
C
13. Compound A is
(a)

C H
3
C H
3
CH
3
Cl
(b)

C H
3
C H
3
CH
3
CH
3
Cl

(c)

Cl
C H
3
CH
3
CH
3
C H
3

(d)

C H
3
C H
3
CH
3
Cl

14. The product obtained when B is subjected to hydroboration-oxidation is
(a)

C H
3
C H
3
CH
3
CH
3
O H
(b)

C H
3
C H
3
CH
3
OH
(c)

C H
3
C H
3
CH
3
OH
CH
3
(d)

C H
3
C H
3
CH
3
OH
15. Which of the following statements is/are correct about C?
(a) It is isomeric with the product obtained in the previous question.
(b) It exhibits metamerism
(c) It exhibits functional isomerism
(d) It exhibits stereo isomerism
MATCH THE FOLLOWING
M1.
COLUMN I
COLUMN II
pH and nature of any of the solutions in column I
A
X solution
Y solution
Z solution
1 2
2
p a a
K K
pH
p
+

K solution
L solution
Q
Buffer solution is formed
20 ml of 0.1 M
3
CH COONa +
5 ml of 0.2 M HCl
M solution
( )
( )
log
p a
salt
pH K
acid
+
3 1 2
, , ,
K K K
K
a a a
a
one of p p p p
_

,
D 0.1 moles of borax + 1L of water Psolution
3 1 2
, , ,
H
K K K
K
a a a
Ka a
p p one of p p p p
_

,
Amphoteric species is generated.
M2:
COLUMN I COLUMN II
A
CH
3
CH
3
H
2
/Ni
excess
Diastereomers will be generated
CH
3
CH
3
H
2
/Ni
excess
Q
Enantiomers will be generated
C H
3
H H
CH
3 D
2
/Ni
excess
Meso compound will be formed
D
C H
2
CH
3
NBS
CCl
4
Two hydrogens(any isotope) will be added across
the double bond
Radical rearrangement will occur.
NUMERICALS
N1.

CH
3
NBS/CCl
4
How many compounds will be generated in the above reaction?( Consider only specific action of NBS/CCl4?
N2.

S(-) 2 chlorobutane
Cl
2
/hv
monochlorination
A(No. of compounds)
fractional
distillation
B(No. of fractions)
Out of all fractions separated, how many are optically active fractions?
N3. For a equilibrium reaction Kp is given as 0.25 atm
-1
at 300K. Calculate Kc(M
-1
). R = 008L atm mole
-1
K
-1
.
N4.
reductive
ozonolysis
X methyl glyoxal acetaldehyde formaldehyde + +
. How many structure are possible for X?
reductive
ozonolysis
X methyl glyoxal acetaldehyde formaldehyde + +
methyl glyoxal =
O
H
O
C H
3
N5. How many of the following solutions will act as buffer solutions?
10 ml of 0.1 M KCN + 5ml of 0.1 M HCl
10 ml of 0.1 M H3PO4 + 25ml of 0.1 M NaOH
10 ml of 0.1 M H3PO4 + 10ml of 0.1 M NaOH
10 ml of 0.1 M NH4CN
10 ml of 0.1 M Na2B4O7.10H2O
10 ml of 0.1 M CH3COOH + 5ml of 0.1 M HCl
10 ml of 0.1 M NaOH + 10ml of 0.1 M HCl
10 ml of 0.1 M CH3COONH4 + 10ml of H2O
10 ml of 0.1 M H3PO4 + 30ml of 0.1 M NaOH
N6. 1:1.5:2 mole ratios of propene, propane and 1-bromo propane were mixed. This mixture was subjected to alcoholic KOH
and the mixture completely reacted with the reagent. This mixture is then subjected to catalytic hydrogenation. 2 moles of
H2 is required for the complete hydrogenation. Find the number of moles of propane in the flask after completion of the
process.
N7. How many of the following molecules cannot exist : C14H28Cl4; C12H16N2O3; C36H71Cl3; C18H24O2Cl5; C10H20N4O2Cl5;
C5H14O2; C8H22N4; C7H12N3Cl5; C6H4O2
N8. For the reaction:
AB(g) A(g) + B(g)
AB is 33% dissociated at a total pressure of p. the p/Kp will be equal to _____