Answer

AITS-CRT(Set-III)-Paper-2-PCM(S)-JEE(Advance)/13
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1

ANSWERS, HINTS & SOLUTIONS
CRT (Set-III)
(Paper2)

PHYSICS CHEMISTRY MATHEMATICS
Q. No. ANSWER ANSWER ANSWER
1.
D C B
2.
B A C
3.
C A C
4.
C D C
5.
C A B
6.
D B B
7.
A B D
8.
A A B
9.
B, C A, B, C, D A, C
10.
A, C A, B, D A, B, C
11.
A, B A, B, C A, C
12.
A, C B, C B, C, D
1.
(A) (p, q, t)
(B) (p, s)
(C) (p, r, t)
(D) (p)
(A) (p, s)
(B) (p, r, s)
(C) (p, q r, s)
(D) (p, q, t)
(A) (s)
(B) (r)
(C) (q)
(D) (r)
2.
(A) (q)
(B) (p)
(C) (s)
(D) (r)
(A) (p, r)
(B) (q)
(C) (p, r)
(D) (q, s)
(A) (p)
(B) (p)
(C) (p)
(D) (q)
1.
3 4 5
2.
2 1 4
3.
1 3 3
4.
2 2 3
5.
3 6 1
6.
4 5 7

A
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N
D
I
A

T
E
S
T

S
E
R
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S

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2
P Ph hy ys si ic cs s PART I

1. The z-component of the force and the x-component of displacement are ineffective here.
( )
y
dW F dy 3xy.dy z 0 = = =

( )
4 2
6x dx y x = =
Integrating between x = 0 and x = 2 gives the result.

2.
2
6.77 10
2

=
v = 1000 2 6.77 10
-2
m/s
also
2
RT MV
v 1.4
M RT
= = =
diatomic

3. mgsin L I = =
( )
2
4mL
mgL
3
=
T 2

=

mgsin

O

4. The speed is due to radial motion as well as due to angular motion.

5. Youngs modulus,
F.
Y
A
l
l
=

F is applied force, A is area of cross-section, l is length and l is change in length.
From graph, change in length for 20 N force is 1 10
4
m

6 4
20 1
Y
A(10 )(1 10 )

= 2 10
11
N m
2

6.
1 1 1
v u f
=
1
u 4 1
1 1
v f x
= =

f
m
f u
=
+

7. Both a and b will be independent of material.
8.
1
M (I area) 2 10 5
4

| |
= = =
|
\ .

1 1
W MB 1 5 4 10 J
2 2

| | | |
= = =
| |
\ . \ .

9. Here
s
m
F mg 1
M
| |
> +
|
\ .


3
For m

k
F mg m.a =
For M

k
mg MA =

2
A 0.4m/ s =

10. Impulse = change in momentum

2 1
2(v v ) =

2(3i j) = +
As impulse is in the normal direction of colliding surface

1
tan
3
=

1
1
tan
3
| |
=
|
\ .

2
6

1
1
90 tan
3
| |
= +
|
\ .
.

11.
KAd d
H K(2 rL)
dr dr

= =

2 2
1 1
r
r
dr 2 KL
d
r H
=

2 1
2
1
2 KL( ) dQ
H 80
dt r
ln
r

= = =
| |
|
\ .

dm
L 80
dt
=

dm 8 80
dt L 80 4200 4200

= = =
Kg/second.

12. Gravitational field inside the cavity is
4
E Gr
3
=

where is mass density and r
is separation between centre of sphere and centre of cavity.

Applying law of Conservation of energy :

2
esc
1 GMm GMm
mV 0
2 R 45R
+ =
Solving
esc
88GM
V
45R
= .

4
SECTION B

2. For central maxima, path diff (x) = 0
for any point P on the screen.
( ) ( ) | | x x P S P S x
1 m 2 m
+ =
masses x = thickness of glass slab.
= | | ( )x P S P S
m 1 2 m

= ( ) 0 x
D
y
. d
m m
= |
.
|
\
|

Here,
(

=
|
|
.
|
\
|

=
t 4 20
5 t 4 20
d
Dx
x
d
D
y
m
m

=
(
t 4 20
t 4 15
d
Dx
..(i)
At time, t = 0
y =
20
15
d
Dx
=
20
15
2 . 0
2
1
= cm 5 . 7 cm
2
15
m
40
3
200
15
= = = .
R.I. of medium cannot be less than 1 which become
At time
4
19
t = = 4.755. Here after this time R.I. of medium will not change. So position of central
maxima at time t = 5 s will be same as at time t = 4.75 s.
y =
(

1
4
.
d
Dx
= 4 2 . 0
2
1
= - 0.4 m
|y| =40 cm.
For speed of central maxima, differentiating equation (i), w.r.t time we get
( )
2
dy Dx 20
dt d
20 4t
(
(
=
(

Central maxima will be at the centre of geometrical centre of screen when R.I. of medium is 5.
Hence at this
4
15
t = .
|
.
|
\
|
= |
.
|
=
25
20
d
Dx
dt
dy
4
15
t
=
25
20
x 2 . 0 x
2
1
= s / m
25
2
= 8 cm/s.
Fringe width
=
d
D
=
5
10 x 100
x
10 x 2
1
10
3
=10
-6
m = 1m.

y
D
S
1
S
2
= 20 4t

5
SECTION C

1.
3 2
2
2 2
2 2
x x
y
30 10
dy x x dy
and at x 2; 0
dx 10 5 dx
d y x 1 d y
andat x 2; ve
5 5
dx dx
=
= = =
= = = +

Hence the particle is at its lowest (minimum) position, in
its path at x = 2 m
( )
( )
2
2
2
2
2
at x 2
2
2
d y dx dx
2x 2
dt dt
dt
d y
20m/ s
dt
d y
N mg m N 1 10 20 30N
dt
1
P f.v N V 30 10 3watt
100
=
=
| |
=
|
|
\ .
= = + =
= = = =

N
Mg
2
2
d y
dx

Approximate graph

2. Using conservation of charge principle and induction, do charge distribution on each plate.

3. N = mg
N = m r
2

mg = m. 2 sin
2

g
2sin

N
N
mg
mr
2

0.1 10
2 sin30

= 1 rad / s.

4.
2
m I S =

S BA AD =

BA 2di 2aj =
AD 2bk =

S 2(di aj) 2bk =

x y
z
A B
C D

M 4bI(dj ai ) = +

2 2
| M| 4bI d a = +
= 2 Tesla.

5. Nuclear reaction is

1 3 3 1
1 1 2 0
H H He n Q + + +
Q = 1.2745 MeV
Using conservation of linear momentum

6
We get,
K
2
= 1 .44 MeV.
K
1
= 3 MeV.

6. x = A cos t

dx
v A sin t
dt
= =

dx
v A sin t
dt
= =

2
2
2
d x
a A cos t
dt
= =

2
max
a A =

max
= I
max

max
a
I
R
=

2
2
1 A
MR
2 R
=

2
1
MRA
2
=

max
4N.m =


7
C Ch he em mi is st tr ry y PART II

SECTION A

3.
| |
1
2
3
4
a
2 3
2
3
7
a
3
H HCO
K 10
H CO
H CO
K 10
HCO
+
( (
( (

= =
( (
( (

= =
(
(

( )
| |
1 2 2
2
3
2
3
2 2
2 3 3
3 3
2 3
2 2
a a a
3 3
CO
1 1
f CO
H CO HCO CO HCO
H CO H H
1
1
CO CO K K K

+ +

(
(

= = =
( ( ( (
+ + ( (
( ( ( (

( (
+ +
+ +
( (
( (

10 5
11 7
1
0.01
10 10
1
10 10

= =
+ +

5. This diasaccharide is sucrose which is formed by

O
OH
OH
OH
CH
2
OH
H
H
H
H
OH
O
OH
OH
CH
2
OH
H
H
OH
CH
2
OH O H
6
4
3
1
5
2
6
2
1
5
4
3
&

-D-(+)-Glucopyranose.

6. For SHE, E
0
=0 at every temperature.

7. No of molecules of K
2
S in 10 L water = 30.11410
22

No. of moles of K
2
S = 2 mol
Molality = 210
1
m
T
f
= iK
f
m = 1.116
o
C
T
f
= 272.034 K

8. MO
2
+ 4H
+
+ PO
4
3
+ e
MPO
4
+ 2H
2
O
M + PO
4
3
MPO
4
+ 3e

The net cell reaction will be
3MO
2
+ 12H
+
+4PO
4
3
+ M 4MPO
4
+ 6H
2
O

11. T constant
PV = nRT (where R and T constant)

n
P
V
=

I
n
P
V
=

8

II
n
P
2V
=

III
n
P
V
=

IV
2n
P
2V
=

II IV 1 II
P P P P < = =
Average K.E. depends only on absolute T.
(Av. KE)
I
= (Av. KE)
II
=(Av. KE)
III
=(Av. KE)
IV

Mass
Density
Volume
=

d
II
< d
I
< d
IV
= d
III

12.
2
2
Z
E 13.6
n
=
For Li
Z = 3
Energy of 1s for Li
1
9
E 13.6
1
=
Energy of 2s for Li
2
9
E 13.6
4
=

1 2
E E <
So statement (A) is correct.
Shape of all the d-orbital are not same.
So statement (B) is wrong.
Energy of 3d > energy of 4s
So (C) is wrong statement.
SECTION B

1. (A)
O
O
O

Gives positive test with 2, 4-dinitrophenyl hydrazine and
form highly stable hydrate.
(B)
CH C
OH
O

Gives positive test with 2, 4-dinitrophenyl hydrazine
(>C=O group test) and Fehling solution (
C OH

group test). It forms highly stable hydrate also.

(C)
O
C
H CI
3
Gives positive test with 2, 4-dinitrophenylhydrazine,
Tollens reagent and Fehlings solution (due to C
O
H
group). It forms stable hydrate also.

(D)
H
O

Gives positive test with 2,4-dinitrophenylhydrazine and
Tollens reagent (due to CHO group). It gives Perkins
reaction (being an aromatic aldehyde)


9
2. Use relations:
( )
1
pH pKw pKa logC
2
= + +

Salt
pOH pKb log
Base
(
= +
(

( )
1
pH pKw pKa pKb
2
= +
pH pOH 14 + =

SECTION C

1. CH
3
OH(g)
CO(g) + 2H
2
(g)
Initially 0.2 mole 0 0
At eq. (0.2x) x 2x

2
H
mix
mix
mix
mix
r
M
2 2
r 2
M 16
32(0.2 X) X(28) 2X(2)
M
0.2 X X 2X
X 0.1
= =
=
+ +
=
+ +
=

K
c
=
= =
2
x(2x) 0.1 0.04
0.04
0.2 x 0.1

100 K
c
= 4

2. It is a pyrosilicate.
Pyrosilicate ion is
6
2 7
Si O

Si
O
O O
O
Si
O
O
O

In this two units of
6
2 7
Si O
joined along a corner containing oxygen atom.

3.
2 O
O
O
CH
3
H
CH
3
H
O
COOH
C H
3
O H
and
O
O
O
CH
3
H
H
CH
3
O
cis trans
Cis form is optically active. It gives two stereoisomers dcis, lcis. Trans form is optically
inactive because it contains center of symmetry.

4.
CH
2
=C=CH
2
2
H /H O
3 3
O
||
CH C CH
+


10
5.
CO
CO
CO
Fe Fe
CO CO
CO
CO
CO
CO

6. Hg
2
Cl
2
Hg + HgCl
2
H = ?
2Hg + Cl
2
Hg
2
Cl
2
Hf
1
= 125 KJ / mole
Hg + Cl
2
HgCl
2
Hf
2
= 640 KJ / mole
H = Hf
2
Hf
1
= 640 + 125 = 515 KJ/ mol
103 x = 515
x = 5

11
M Ma at th he em ma at ti ic cs s PART III

SECTION A

1. ( )
( )
( )
e e
e
1
I
1 1
II
f x
I f x lnxdx lnx.f x dx
x
= =

I = I I
1

I
1
= ( )
e
1
1
f x dx
x

=
1 1
e 2

1 1 3 1
I 1
e 2 2 e
= + =

2. ( ) ( )( )( )
4x 2a p x a p x y z a b c
det B 4t 2b q 4 2 1 y b q 8 a b c 8 p q r
4z 2c r z c r p q r x y z
= = = =
= 8 2 = 16.

3. Replace x
1
x
and solve to get
( )
x 1
f x
2
+
=
( )
10099 1 10100
f 10099 5050
2 2
+
= = =

4. cubic is x
3
6x
2
+ 11x 30 = 0
(x 5) (x
2
x + 6) = 0
Hence a = 5 ; bc = 6
bc 6
a 5
=

5. r = 7
sin30 =
R r 1
R r 2
=
+

2R 2r = R + r
R = 3r = 21.

6.
2
0 0 1
1 1 c
A 0 c / b 1 0
2 2 ab
c / a 0 1
= =
If A is independent of a, b and c then c
2
= ab a, c, b are G.P.

7.
( )
( )
1 1
n
1
n
n 1
tan t
1
C dt
n sin t
+
=


12
( )
1 1
1
n
1 1
2 n 1
n
1
a a
n
n 1
tan t
dt
sin t
tan t
L limn C limn dt 0 ; L
1
sin t
n

+
= = =

applying Leibnitz rule.

8. 2f(x) and
x
f
2
| |
|
\ .
have the same domain as f(x) and f(2x), f(x + 2),
f
f
2
| |
|
\ .
have the range a f(x).
m = 2, n = 3
Verify by considering f(x) = sin
1
x ; d : |x| 1 ; R ,
2 2
(
(

10. (A)
| |
x 0
x x
f(x) lim ;
x
+
=
| |
2x
if x 0
x
f(x)
0
if x 0
x
>
<

x 0
lim f(x) 0
=
(B)
1/ x
1/ x
x 0
xe
lim
1 e
+
;
1/ x
x 0
x
lim f(x) 0
1 e
+
= =
+
;
( )
x 0
0 h
lim f(x) 0
1
= =
(C)
( )
1/ 5
x 3
lim x 3
Sgn (x 3) = 0 where sgn is the signum function (bvious)

(D)
1
x 0
tan x
lim
x
does not exist as RHL = 1; LHL = 1

11. Area (T) =
2 3
c.c c
2 2
=
Area (R) =
e
3
2
0
c
x dx
2

=
3 3 3
c c c
2 3 6
=

3
3
c 0 c 0
area (T) c 6
lim lim 3
area (R) 2
c
+ +

= =

12.
x 3
y 0
x 1
+
= >
+
x < 3 or x > 1
As x 3, y 0; x , y 1 range (0, 1) (1, )

SECTION B

1. We have ( )
( )
i2 i2
n 1
n
n n
z 1 z 1 z e ..... z e

| | | |
| | =
| |
\ . \ .

( )
( )
i2
n 1
n 1
n
1 z ..... z z 1 .... z e

| |
| + + + =
|
\ .
(1)
Put z = 1 and take modulus ( )
n 1
2
n 2 sin sin ..... sin n 1
n n n

=
(A) if n = 21

20
2 9 10 20
21 2 sin sub .....sin sin .....sin
21 21 21 21 21

=

13
21 =
2
20
10
sin ......sin 2
21 21
| |

|
\ .

10
10 21
sin ..... sin
21 21
2

=
(B) If n = 22

2
21
2 10
22 2 sin sin .... sin
22 22 22
| |
=
|
\ .

11 10
10 22 11
sin ..... sin
22 22
2 2

= =
(C) Again put z = 1 is ..(1) and take modulus
( )
n 1
2
1 cos cos ..... cos n 1 2
n n n

= .
n = 21

20
2 20
1 cos cos .... cos 2
21 21 21

=

10
10 1
cos ...... cos
21 21
2

=
(D)
10
2 10 11
sin , sin ..... sin
22 22 22
2

=

10
10 9 11
cos cos .... cos
22 22 22
2

=
( ) sin cos 90 =

2. (A) 1
st
, 4
th
, 7
th
terms are a, a+3d, a+6d
ax+by+c=0
ax+(a+3d)y+(a+6d)=0
a(x+y+1)+3d(y+2)=0 passes through (1, 2)
(B) a, b, c are three consecutive terms of A.P.
a = A+(m1)d, b = A+md, c = A+(m+1)d.
(A+(m1)d)x+A+md)y+A+(m+1)d = 0
( )
x
A x y 1 d m my m x 1 0
(
+ + + + + + =

x + y + 1 = 0, x + 1 = 0
x = 1, y = 2
(C) a = A + (r1)d,
( )
2
b A r 1 d = + ,
( )
2
c A 2r r 1 d = +
( ) ( ) ( ) ( )
2 2
A r 1 d x A r 1 d y A 2r r 1 d 0
(
+ + + + + =

( ) ( ) ( ) ( ) A x y 1 d r 1 x r 1 y 2r 1 0 ( + + + + + + + =

X + y + 1 = 0, x + y + 1 + r(y + 2) = 0
Y = 2, x = 1
(D) a = A + (r1)d,
( )
2
b A r 1 d = + ,
( )
2
c A 3r 2r 1 d = +
( ) ( ) ( ) ( )
2 2
A r 1 d x A r 1 d y A 3r 2r 1 d 0
(
+ + + + + =

( ) ( ) ( ) ( ) A x y 1 d r 1 x r 1 y 3r 1 0 ( + + + + + + + =

x + y + 1 = 0, x + y + 1 + r(y + 3) = 0
y = 3, x = 2

SECTION C

14

1. Let A (z
1
), B(z
2
) and P(z) forms a triangle ABC then
1
2
tan / 2 3
tan / 2 2
implies PB PA =
AB
5
. This
implies locus of P is branch of hyperbola of eccentricity = 5

2.
1 3 5 7
2 4 6
S S S S
tan7x 0 0
1 S S S
+
= =
+

3 5 7
7tanx 35tan x 21tan x tan x 0 + =

3 2 2 3
tan , tan , tan ,0, tan , tan ,tan
7 7 7 7 7 7

are the roots of equation

3 5 7
7x 35x 21x x 0 + =

2 2 2
2 3
tan ,tan , tan
7 7 7

are the roots of equation
2 3
7 35x 21x x 0 + =

2 2 2
2 3
cot ,cot ,cot
7 7 7

are roots of equation
3 2
7x 35x 21x 1 0 + =

2 2 2
2 3
cot cot cot 5
7 7 7

+ + =

3. (A) 2x + 2yy = 0
x
y'
y
=

( )
y' 2 1 A = =
(B) cos y.y + cos x = sin x.cos y.y + sin y cos x
when x = y = p
y 1 = 0 + 0
(C) 2e
xy
(xy + y) + e
x
e
y
y + e
y
e
x
e
x
e
y
y = e.e
xy
(xy + y)
at x = 1, y = 1
2e(y + 1) + e
2
y + e
2
e ey = e
2
(y + 1)
ey + e = 0 y = 1
Hence |A + B + C| = 3

4. Focus is
11
,0
6
| |
|
\ .
Distance of focus from line =
5
2
a b 3 =

5. Put
n n
a tan =

6. ( )
K 2
f x 0 has K
= distinct roots, ( )
K 1
f x 0 has K
= + 1 distinct roots, ( )
K
f x 0 = has K distinct
roots K 1 8 K 7 + = =

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AITS-CRT(Set-III)-Paper-2-PCM(S)-JEE(Advance)/13

is separation between centre of sphere and centre of cavity.

joined along a corner containing oxygen atom.

Sgn (x 3) = 0 where sgn is the signum function (bvious)

does not exist as RHL = 1; LHL = 1

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