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SOLUTIONS
&
THEIR PROPERTIES
SOLUTIONS
Learning objectives:
Discuss different kinds of solutions
Types of Homogeneous Mixtures
Solutions
• most important class of homogeneous mixtures
• contain particles with diameters in range 0.1-2 nm
• transparent, do not separate on standing (salt water, sugar water)
Colloids
• contain particles with diameters in the range 2-500nm
• murky, do not separate on standing (milk, fog,)
Suspensions
• having larger particles than colloids
• Not truly homogeneous
• Particles separate on standing (blood, paint)
Solutes and Solvents
• A solution consists of a solute and a solvent:
solute the substance which is being dissolved.
solvent the substance (usually a liquid) that
dissolves the solute (usually, the solvent is the most
abundant component in the mixture).
• Aqueous solution are solutions in which the solvent is
water.
Solvent-solvent interactions:
Energy is required (+ ΔH) to overcome intermolecular forces
between solvent molecules because the molecules must be
separated and pushed apart to make room for solute particles
Solute-solute interactions:
Energy is required (+ ΔH) to overcome intermolecular forces holding
solute particles together in a crystal.
Solvent-solute:
Energy is released (- ΔH) when solvent molecules cluster around
solute particles and solvate them
Energy Changes and the Solution
Process
The solute-solvent
interactions are less than
the sum of the solute-solute
and solvent-solvent
interactions.
Enthalpy of solution
UNITS OF CONCENTRATION
Learning objectives:
Interconvert units of concentration
Perform calculations using solution density,
molarity,mole fraction, weight percent, parts per
million, parts per billion, and molality.
Units of Concentration
• Concentration: The amount of solute present in a given
amount of solution.
• Molarity (M):
Moles of solute
Molarity
Liters of SOLUTION
Moles of A
XA
Total number of moles
Units of Concentration
• Mass percent: The ratio of the mass of a solute to the
mass of a solution, multiplied by 100%.
mass of solute
% by massof solute = 100%
mass of solution
mass of solution =mass of solute +mass of solvent
Units of Concentration
• Parts per Million (ppm): Mass of solute
x 10 6
Total mass of solution
• One ppm gives 1 gram of solute per 1,000,000 g or one
mg per kg of solution.
• Molality (m):
Moles of solute
Molality =
Kilograms of SOLVENT
Units of Concentration
FACTORS AFFECTING
SOLUBILITY
Learning objectives:
Define saturated, unsaturated and supersaturated
solutions
Describe crystallization process
Discuss the effect of temperature and pressure on
solubility
State Henry’s Law and its examples
Saturated and Unsaturated Solutions
• Saturated: Contains the maximum amount of solute that
will dissolve in a given solvent.
Sgas = k . Pgas