CODE : BLUE

54618/QB/HYD-VAGDEVI-C / IITJEE / 11-5-2013 / IITJEE

NARAYANA IIT ACADEMY

INDIA OUTGOING SR (Y PROGRAMME) (2012 PAPER -1 MODEL) Time : 3:00 ID.NO : IITJEE MODEL Exam Date : 13-5-2013 Max Marks : 210

INSTRUCTIONS : 1) This booklet is your Question Paper containing 60 questions. Maximum marks: 210. The question paper consists of 3 parts (Physics, Chemistry and Mathematics). Each part consists 2) of three sections. In Section I (Single Correct Answer Type, Total Marks: 30), for each question you will be awarded 3 marks if you darken the bubble corresponding to the correct answer ONLY and zero 3) marks if no bubbles are darkened. In all other cases, minus one (-1) mark will be awarded in this section. In Section II (Multiple Correct Answer(s) Type, Total Marks: 20), for each question you will be awarded 4 marks if you darken ALL the bubble(s) corresponding to the correct answer(s) 4) ONLY. In all other cases zero (0) marks will be awarded. No negative marks will be awarded for incorrect answers in this section. In Section III (Integer Answer Type, Total Marks: 20), for each question you will be awarded 4 marks if you darken the bubble corresponding to the correct answer ONLY. In all other cases 5) zero (0) marks will be awarded. No negative marks will be awarded for incorrect answers in this section.

PHYSICS 1) Uniform rod AB is hinged at end A in the horizontal position as shown in Figure. The other end is connected to a block of mass m through a mass less string as shown. The pulley is smooth and mass less. Masses of block and rod are same and equal to m. Then acceleration of the block just after release from this position is

A)

B)

C)

D) None of these

2) A sewing machine needle is oscillating vertically in a line of length 6cm with a frequency 30 per minute. The displacement of the needle 1/6 s after crossing the mean position is A) 4 cm B) 2 cm C) 3 cm D) 1.5 cm 3) A particle falls from rest under gravity. Its potential energy with respect to the ground (PE) and its kinetic energy (KE) are plotted against time (t). Choose the correct graph A) B) C) D)

4) A Force acts on a particle due to which its position vector varies as

, where t is time in seconds. The work done by this force t=0 to t=2s is: A) 23J B) 32J C) zero D) Cant be obtained 5) A cord is used to lower vertically a block of mass M a distance d at a constant downward acceleration of A) . Then the work done by the cord on the block is B) C)

D) Mgd

6) The coefficient of friction between the block and the horizontal surface is . The block moves towards right under action of horizontal force F (figure (a) ). Sometime later another force P is applied to the block making an angle such that ) with vertical as shown in figure

(b). After application of force P, the acceleration of block shall

decrease information insufficient for drawing inference 7) A body is moved from rest along a straight line by a machine delivering constant power. The ratio of displacement and velocity (s/v) varies with time t as : A) B) C) D)

A) C)

increase remains same

B) D)

8)

Power applied to a particle varies with time as watt, where t is in second. Find the change in its kinetic energy between time t =2 s and t =4s A) 32 J B) 46 J C) 61 J D) 102 J 9) A girl is standing on ground near a horizontally moving conveyor belt. She throws her suitcase horizontaly. Such that the initial velocity of Suitcase relative to stationary girl is along dotted line shown in top view of Conveyor belt.

Which of the following arrows represents direction of friction at initial moment?

A) A

B) B

C) C

D) D

10) An automobile enters a turn where radius is R. The road is banked at an angle and the coefficient of friction between wheels and road is . Then condition in which all speed are possible is A) Any value of and B) C) D) 11) A small block of mass m is placed on a smooth wedge of mass m the combination is placed on a smooth horizontal surface and are given velocities u towards each other as shown in the diagram. The maximum height to which the small block of mass m rises after breaking off the vertical section of the wedge is H, relative to its initial level.

A) B) C) D) Initial momentum of system is zero The final velocity of the small block at its height point is zero The kinetic energy of the system when the smaller block is at its highest point

of wedge is . 12) Two blocks are joined by a string as shown. They are released from rest. The friction coefficient of block and surface is . The correct options are

A) B)

Work done by the friction force is

Loss in potential energy C) Gain in kinetic energy is equal to loss in potential energy D) Work done by the friction is zero 13) A Ladder AB is supported by a smooth vertical wall and rough horizontal floor as shown A boy starts moving A to B slowly. The ladder remains at rest, then pick up the correct statements (S)

A) Magnitude of normal reaction by wall on ladder at point B will increase

B) Magnitude of normal reaction by wall on ladder at point B will decrease C) Magnitude of normal reaction by floor on ladder at point A will remain unchanged D) Magnitude of friction force by floor on ladder at point A will increase 14) In elastic collision of two bodies, which of the following do not change after the collision A) Total kinetic energy B) Total linear momentum C) Total energy D) Total angular momentum 15) You lift a suitcase from the floor and keep it on a table. The work done by you on the suitcase does not depend on A) The path taken by the suitcase B) The time taken by you in doing so C) The weight of the suitcase D) Your weight 16) The end B of chain of mass per unit length and length L is released from rest as shown. The force at the hinge (A) when the end B is at L/4 from the ceiling is =[Neglect the length of the curved portion] . Then the value of x

17) What should be minimum value of F(in newton) so that 2kg slides on ground but 1 kg does not slide on it? [g = 10 m/sec2]

18) Power supplied to a particle of mass 2 kg varies with time as . Here t is in second. If velocity of particle at t=0 is v=0. The velocity of particle at time t = 2s will be in m/s. 19) A ball of mass m falls symmetrically on a set of three hemispheres placed in contact with each other on smooth horizontal ground from a height h. Mass of each hemisphere is and radius of each body is R.

Neglect any rebounding of hemisphere. If sphere comes to rest after the simultaneous collision with three hemispheres then ration of KE of sphere before collision and KE of any hemisphere after collision is p then find the value of p 20) Consider the shown arrangement of three blocks A, B and C. Mass of the each block is 1 kg. The coefficient of friction between any two blocks is 0.2. There is no friction between the block C and the ground. Find the minimum value F (in N) for which sliding occurs at all the surfaces.

CHEMISTRY 21) Let us consider, three types of disubstituted cyclohexanes

These compounds may exist in vaiours stereoisomeric forms (both geometric and optical). What is the total number of stereoisomers that exist if L1 and L2 are two different groups? A) six B) Eight C) Ten D) twelve 22)

A)

B)

C)

D)

23) trans 1 chloro 2 methyl cyclohexane A) B) product. The predominant product is C) D)

24) Which type of confirmation is shown by I and II ?

A) I is eclipsed, II is staggered C) Both are eclipsed 25) Incorrect statement about this compound is:

B) II is eclipsed, I is staggered D) Both are staggered

A) It shows geometrical isomerism C) It posses plane of symmetry 26) A) C) 27) The bond energy A) 1 28) of a B) 10

B) It posses center of symmetry D) It shows optical isomerism Transition state Carbanion

mechanism proceeds through the formation of Carobonium ion B) Free radical D)

single bond is approximately C) 100 D) 1000

Which of the following statements regarding is not correct? A) The molecule of is planar B) The molecule of contains weak N N bond C) In liquid , NOCl acts as a base D) The dipole moment of is zero 29) Which of the following statement(s) is (are) correct? 1. The pH of solution of HCl is 8 2. The conjugate base of is 3. Autoprotolysis constant of water increases with temperature 4. When a solution of a weak monoprotic acid is titrated against a strong base at half neutralization point, pH = (1/2) pKa. A) 2, 3 B) 1, 2, 3 C) 3, 4 30) A self-contained breathing apparatus uses potassium super oxide, dioxide and water in exhaled air into oxygen, as shown by the equation:

D) 2, 3, 4 to convert the carbon

How many molecules of oxygen gas will be produced from 0.468g of carbon dioxide that is exhaled in a typical breath? A) B) C) D) 31) Compound decolourises Baeyers reagent. It undergoes hydrolysis on reaction with

dil. and produces (Y) and (Z). Both (Y) and (Z) give iodoform test positive. Only (Y) gives Tollens test positive. Choose the correct statement A) B) C) D)

32) Which of the following compounds will give a red precipitate on being heated with Fehlings solution. A) B) C) D) 33) Which of the following compounds are planar A) B) C) D)

34) Correct statements regarding molecules P, Q, R and S is/are:

A) Molecule with plane of symmetry P B) Molecule with centre of symmetry Q C) Molecule with alternating axis of symmetry R D) Molecule with simple axis of symmetry S 35) Which of the following reactions can produce benzoic acid ? A) Hydrolysis B) C) of ben zal chl ori de 36) Let us consider the following compounds :

D)

How many of these compounds will show optical activity? 37) How many carbons are present in the parent chain of

38)

In the above reaction how many alkenes are formed ? 39) What is the total number of phenyl hydrazine molecules required to form osazone by glucose ? 40) What is the co-ordination number of in complex ? MATHEMATICS 41) The angle between the line and the y-axis is A) B) C) D)

42)

Let

be three vectors having magnitude 1,1 and 2 respectively. If and is B) C) D)

then the

acute angle between A) 43)

Let , , be three points then equation of a plane parallel to the plane ABC which is at a distance 3 units is A) B) C) D)

44) A man starts from the point P(-3,4) and reaches point Q (0,1) touching x axis at R such that PR + RQ is minimum. Then the point R is A) B) C) D) 45)

Let that

and is perpendicular to both the vectors and

be three non zero vectors such . If the angle between and is and

are the roots of then the value of is A) 10 B) C) D) 20 46) E and F are the interior points on the sides BC and CD of a parallelogram ABCD. Let . If the line EF meets the diagonal AC in G, then is equal to A) 47) B) C) D) , where

Let A) C)

and B) D)

then

48) In a A) ABC, 2r = r1 and B) A=300. then is C) D)

49) The numbers a,b are chosen from the set {1,2,3,4,---,10} such that probability that a divides b is A) B) C) 50) Let A) 6 51)

with replacement. The D) None

. A point P in the XY-plane varies in such a way that perimeter of is 16. Then the maximum area of B) 12 then B) is C) 18 satisfies C) D) D) 9

If z satisfies A)

52)

The vectors and angle between its diagonals is A) B)

are the adjacent sides of a parallelogram. The C) D)

53)

Let A)

and

be two non-collinear unit vectors If B) C)

and D)

then

is

54) The lines A) 55) and B) C) are coplanar if D)

If is perpendicular to and p is non zero scalar, such that A) Lies in the plane B) C) of and
Through the point a plane is drawn at right angles to

, then
D)

56)

being the

origin, to meet the axes in . If the area of triangle is then equals 57) If the number of 3 digit odd numbers divisible by 3, which can be formed using the digits 3, 4, 5, 6 when repetition of digits within the number is allowed is then the value of is 58) If f(x) is twice differential function such that f(a) =0, f(b) = 2, f(c) =-1, f(d) =2, f(e)=0 where a<b<c<d<e. then find the minimum number of zeros of interval 59) is a unit vector perpendicular to the plane containing the point whose position in the

vectors are and satisfying value of is 60) ABC is a triangle and E & F are mid-points of AC and AB. A line is drawn through C which is parallel to AB. It cuts BE (produced) at P. The value of is

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