Cells for Input

Cells for Auto calcs

Natural Gas Composition (mol%)

Methane
Ethane
Propane
Butane
Nitrogen
Carbondioxide
Total

92%
2%
2%
1%
2%
1%
100%

Pressure
Temperature
Basis
Desired Production Rate

250
1500

psig
F
kgmol/hr Mixed Feed
Tonnes/day

Stream Factor
Operating hours

345
8280

days
hours

Max. Hydrocarbon conc. in Steam reformer outlet gas

Steam to hydrocarbon ratio in Primary Reformer

Natural gas Flow rate

Naphtha

0.50%
3.3

150
100

Naptha composition (mol%)

45.98
53.85
0.17

Carbon
Hydrogen(H2)
Sulphur

Total

Mixed Feed

Naphtha
40%

N.Gas
60%

0.17

100
0.17
C

H
45.98

53.85
1.17116

551.76

107.7

5.44

664.9

6.649

Pre Reformer
Naphtha

100

Temperature
Pressure
Pressure Drop
HC to Steam Ratio

727 C
psig
psig
3

Reaction 1
Reaction 2
Reaction 3
Selectivity

CnHm + n H2O ---> nCO + (2n+m)/2 H2

CO + H2O --> CO2 + H2
CO + 3H2--> CH4 + H2O
0.7 mol CH4 / mol of CO2

100% Excess steam is used to ensure all naph

30% based on CO

Stream 1 (Naphtha)
Components

Carbon
Hydrogen(H2)
Hydrogen gas
Carbon monoxide
Carbon dioxide
Methane
Steam

Mol. Wt
12
2
2
28
44
16
18

Total

Steam Consumed
Steam un reacted
CO produced
Co consumed
CO 2 produced.
Ch4 Produced

60.13
82.06
45.98
18.392
27.588
14.14769
4.244308

Stream 2 (Steam)

Mol%
44.6148
52.2511
3.1341
-

Mole Flow
(kgmol/hr)
45.98
53.85
3.23000
-

Mass Flow
(kg/hr)
551.76
107.7
6.46
-

Mol%
-

Mole Flow
(mol/hr)
-

100

103.06

665.92

100
100

137.94
137.94

0.00

H2 for Hyderotreating (a)

3.4
0.17000

Pre reformer
3

team is used to ensure all naphtha converted

0.4
0.3

am 2 (Steam)
Mass
Flow
(kg/hr)
2482.92
2482.92

Stream 3

Mol%
44.93
11.87
6.08
1.83
35.29
100

Mole Flow
(kgmol/hr)
104.47
27.59
14.15
4.24
82.06
232.51

Mass Flow
(kg/hr)
208.95
772.46
622.50
67.91
1477.019077
3148.84
0.00

kgmol/hr

Primary Reformer
N.Gas
727 C
900 psig
10 psig
3
150

Temperature
Pressure
Pressure Drop
HC to Steam Ratio
N.Gas Flow rate

Naphtha
60%
40.0%

Natural Gas

4
Primary Reformer

Steam

Reaction 1
Reaction 2
Reaction 3
Reaction 4
Reaction 5

Components

Methane
Ethane
Propane
Butane
Nitrogen
Carbon dioxide
Carbon monoxide
Hydrogen
Oxygen
Steam
Argon

Reactions in Primary Reformer

CH4 + H2O = CO + 3H2
C2H6 + 2H2O = 2CO + 5H2
C3H8 + 3H2O = 3CO + 7H2
C4H10 + 4H2O = 4CO + 9H2
CO+H2O = CO2 + H2

Mol. Wt
16
30
44
58
28
44
28
2
32
18
40

Total

382.51

Total Primary Reformer Inlet

14643.76554 kg/hr

CO Production
Reaction 1
Reaction 2
Reaction 3
Reaction 4
Total

kgmol/hr
kgmol/hr
kgmol/hr
kgmol/hr

Del H Rxn
21956795774
20784366000
4487031000
3905772000

62.1084923 kgmol/hr

-2556758194

CO Consume
Reaction 5

75%
100%
100%
100%
40%

Stream 4 (Natural Gas)

Mole Flow
Mass Flow
Mol%
(kgmol/hr)
(kg/hr)
37.18694748
142.24
2275.908923
0.784290382
3
90
0.784290382
3
132
0.392145191
1.5
87
0.784290382
3
84
4.090778193 15.64769231 688.4984615
7.212334354
27.59
772.464
27.31285223
104.47
208.9495385
21.45207141
82.06
1477.019077
100

106.68
6
9
6
155.27

5815.84

based CH4
based C2H6
based C3H8
based C4H10
based on CO

Stream 5 (Steam)
Mol%
100
100

CO2 Produced
Reaction 5

62.1084923 kgmol/hr

H2 Produced
Reaction 1
Reaction 2
Reaction 3
Reaction 4
Reaction 5
Total

320.049692
15
21
13.5
62.1084923
536.13

kgmol/hr
kgmol/hr
kgmol/hr
kgmol/hr
kgmol/hr
kgmol/hr

Steam consumption
Reaction 1
106.683231 kgmol/hr
Reaction 2
6 kgmol/hr
Reaction 3
9 kgmol/hr
Reaction 4
6 kgmol/hr
Reaction 5
62.1084923 kgmol/hr
Total
189.791723 kgmol/hr
48577206580

Fed mole dry base

Energy Balance
Feed moles

Equilibrium Shift Conversion

134.27

48.57720658 GJ

Keq

0.7
Components

417.23

572.50 Conv.
33.43%
CO
H20
CO2
H2
134.27
417.23 15.64769231
474.02
a
b
c
-0.3
-860.07 39214.98505
CO conc eqlib
1747.08 CO conc. Eq -26.9352213
-2911.7997
44.89203553

Methane
Ethane
Propane
Butane
Nitrogen
Carbon dioxide
Carbon monoxide
Hydrogen
Oxygen
Steam
Argon
Total

CP /R
CP J/mol.K
Del H/mol

Del H
Del H /mol
Del H /mol

Secondary Reformer
1000 C
890 psig
10 psig

Exit Temperature
Pressure
Pressure Drop
6
Reformer
7

Secondary
Reformer
Air

205813
3464061
498559
650962
-41166

Stream 5 (Steam)
Mole Flow
Mass Flow
(mol/hr)
(kg/hr)
490.4403077 8827.925538
490.4403077 8827.925538

Reactions in Secondary Reformer

CH4 + H2O = CO + 3H2
CH4 + 2O2 = CO2 + 2H2O
2CO + O2 = 2CO2
CH4 + 2CO + 4O2 +2H2= 3CO2 + 4H2O

Reaction 1
Reaction 2
Reaction 3
Reaction 4

Mol%
3.15
0.00
0.00
0.00
0.27
6.89
8.26
47.52
33.92

Stream 6
Mole Flow
(kgmol/hr)
35.56
0.00
0.00
0.00
3.00
77.76
93.16
536.13
382.71

Mass Flow
(kg/hr)
568.98
0.00
0.00
0.00
84.00
3421.27
2608.56
1072.27
6888.6936

Stream 7 (Air)

100

1128.318154

14643.76554

Total Secondary Reformer Inlet

Nitrogen in
223.39 kgmol/hr
Total air
286.40 kgmol/hr
O2 with Air
60.14 kgmol/hr
Argon with Air
2.86 kgmol/hr
CH4 Consumption
Reaction 4
15.04 kgmol/hr
Reaction 1
17.45 kgmol/hr
CO Production

Mol%
78
21
1
99
22823.23

Reaction 1

17.45 kgmol/hr

CO Consumption
Reaction 4

30.07 kgmol/hr

CO2 Production
Reaction 4

45.11 kgmol/hr

H2 production
Reaction 1
52.34 kgmol/hr
H2 Consumed
Reaction4
30.07 kgmol/hr
Steam Consumption
Reaction 1
17.45 kgmol/hr
Steam Production
Reaction 4

60.14 kgmol/hr

382.51
Inlet Temp
382511.38 Ref Temp

727
25

1000 Tau
298

3.355704698
0.298

A
Mol. Wt
16
30
44
58
28
44
28
2
32
18
40

5.406371412
44.94857192
-31553.8975

Heat of Formation
A
-74520
1.702
-83820
1.131
-104680
1.213
-125790
1.935
0
3.28
-393509
5.457
-110525
3.376
0
3.249
0
3.639
-241818
3.47
A
2.595530049
2.595530049
-1822.06209

B
0.009081
0.019225
0.028785
0.036915
0.000593
0.001045
0.000557
0.000422
0.000506
0.00145
B*(tau-1)/2
0.005221115
3.388503339
-2378.72934

D
-0.000002164
-0.000005561
-0.000008824
-0.000011402
0
0
0
0
0
0

0
0
0
0
4000
-115700
-3100
8300
-22700
12100

-1.22506E-06
-0.566305363
397.5463645

-3384.270511
-0.011356612
2.67528E-05

Inlet condition
remaining steam

-1.207E+10

-12.069725 GJ

-31620.1793
-1.2095E+10 -12.0950786 GJ

Inlet steam

Ammonia Production 6.820790031 TPH

85% based on remaining CH4 after Reaction 4

100% based on O2

Stream 7 (Air)
Mole Flow
Mass Flow
(kgmol/hr)
(kg/hr)
223.39
6254.884462
60.14
1924.58
2.863958087
283.53
8179.46

Mol%
0.22
15.98
8.67
5.68
39.42
0.00
30.03

Stream 8
Mole Flow
(kgmol/hr)
3.08
226.39
122.86
80.54
558.40
0.00
425.40

Mass Flow
(kg/hr)
49.26
6338.88
5406.00
2255.06
1116.80
0.00
7657.23

100

1416.67

22823.23

kg/hr
0.00

Energy Balance
Feed moles
1128318.15

Mol%
37.19%
0.78%
0.78%
0.39%
0.78%
4.09%
7.21%
27.31%
0.00%
21.45%
0.00%
100.00%
Steam

Stream 4
Mole Flow
(mol/hr)
142244.31
3000.00
3000.00
1500.00
3000.00
15647.69
27588.00
104474.77
0.00
0.00
300454.77
300454.77

kj/kg
110.5683

Components
47.34%
1.00%
1.00%
0.50%
1.00%
5.21%
9.18%
34.77%
0.00%
0.00%
0.00%
100.00%
0.00%
100.00%

Mol. Wt

Methane
Ethane
Propane
Butane
Nitrogen
Carbon dioxide
Carbon monoxide
Hydrogen
Oxygen
Steam
Argon

16
30
44
58
28
44
28
2
32
18
40

Total

CP /R
CP J/mol.K
Del H/mol

2.678469167
22.26879266
21712.07284

3893.2373
-3782.669
10304.94 kg
-3.898E+10 -38.9801945

-51.04991956

Del H

24498125945

Del H /mol
Del H /mol

21803.417
24601191213

Inlet Temp
Ref Temp

25
1000

298 Tau
1273

0.234092694
4.271812081

Stream 4

A
Heat of Formation
A
-74520
-83820
-104680
-125790
0
-393509
-110525
0
0
-241818

B
1.702
1.131
1.213
1.935
3.28
5.457
3.376
3.249
3.639
3.47

C
0.009081
-2.164E-06
0.019225
-5.561E-06
0.028785
-8.824E-06
0.036915 -1.1402E-05
0.000593
0
0.001045
0
0.000557
0
0.000422
0
0.000506
0
0.00145
0

Mol%

D
0
0
0
0
4000
-115700
-3100
8300
-22700
12100

2.260970291 0.000606304 -6.8203E-08 -4274.76197

2.260970291 0.476251997 -0.04748459 -0.01126853
2204.446034 464.345697 -46.2974754 -2.8962E-05

3.15%
0.00%
0.00%
0.00%
0.27%
6.89%
8.26%
47.52%
0.00%
0.00%
0.00%
66.08%

24.49812595 GJ

Inlet condition
remaining steam

24.60119121 GJ
Inlet steam

53.2251454 GJ

kj/kg
110.5683
110.5683
3893.2373
4624.7286
4514.1603
6888.69 kg
31096667168 31.09666717 31.09666717
Consumption /ton NH3

7.803369574

Stream 4
Mole Flow
(kgmol/hr)

mol%

12055.57
0.00
0.00
0.00
1017.03
26360.14
31583.12
181754.55
0.00
0.00
0.00
252770.41

4.77%
0.00%
0.00%
0.00%
0.40%
10.43%
12.49%
71.90%
0.00%
0.00%
0.00%
100.00%

High Temperature Shift Converter

400 C
880 psig
10 psig

Temperature
Pressure
Pressure Drop

752

SR outlet stream
HTS

9
Reactions in HTS
CO+H2O = CO2 + H2

Reaction 1

Components

Mol. Wt

Methane
Nitrogen
Carbon dioxide
Carbon monoxide
Hydrogen
Steam

Mol%
0.22
15.98
8.67
5.68
39.42
30.03
100

16
28
44
28
2
18

Total
CO Consume
Reaction 1
CO2 Produced
Reaction 1
H2 Produced
Reaction 1
Steam Consume
Reaction 1

80% based on CO

Stream 9 (SR outlet)

Mole Flow
Mass Flow
(kgmol/hr)
(kg/hr)
3.08
49.26
226.39
6338.88
122.86
5406.00
80.54
2255.06
558.40
1116.80
425.40
7657.23
1416.7
22823.2

Stream 10 (HTS out

Mol%
0.22
15.98
13.22
1.14
43.96
25.48
100

64.43 kgmol/hr
64.43 kgmol/hr
64.43 kgmol/hr
64.43 kgmol/hr

Energy Balance

deg F
T0
T
A
CO
H2O
CO2

deg c
deg K
315.5555556 588.5555556 tau
25
298
B
3.376
271.895211
0.000557 0.044859488
3.47 1476.144306
-0.00145 -0.616832635
5.457 670.4662531
0.001045 0.128392383
600
77

80.54
425.40
122.86

H2
N2
CH4

558.40
226.39
3.08

H1

3.249
3.28
1.702

1814.244528
0.000422
0.23564518
742.5550369
0.000593 0.134248517
5.240108316
0.009081 0.027958533
4980.545444
-0.045728533
H2
H3
H4
Cp/R
4980.545444 -40.03450175 -5.289439427 -5.521270877 4929.700232

deg F
T0
T

deg c
77
730.5602

deg K
25
388.089

298 tau
661.089

CO
H2O
CO2
H2
N2
CH4

B
54.37904219
0.000557 0.008971898
1252.571704
-0.00145 -0.523408925
1022.061553
0.001045 0.195721884
2023.578068
0.000422 0.262834701
742.5550369
0.000593 0.134248517
5.240108316
0.009081 0.027958533
5100.385513
0.106326609
H2
H3
H4
Cp/R
5100.385513 22.98408452 -0.326193928 -281.7116191 4841.331784
16.11
360.97
187.29
622.83
226.39
3.08

H1

H rxn

-2706.066081

Del H total

-0.004353061

3.376
3.47
5.457
3.249
3.28
1.702

Heat Coservation for steam generation

Fed mole dry base
Energy Balance
Feed moles
Components

Methane
Ethane
Propane
Butane
Nitrogen
Carbon dioxide
Carbon monoxide
Hydrogen
Oxygen
Steam

#REF!
Inlet Temp
1416671.45 Out let temp

388.089
661.089 Tau
200.5555556 473.5555556
A

Mol. Wt
16
30
44
58
28
44
28
2
32
18

Heat of Formation
A
-74520
-83820
-104680
-125790
0
-393509
-110525
0
0
-241818

B
1.702
1.131
1.213
1.935
3.28
5.457
3.376
3.249
3.639
3.47

C
0.009081
-2.164E-06
0.019225
-5.561E-06
0.028785
-8.824E-06
0.036915 -1.1402E-05
0.000593
0
0.001045
0
0.000557
0
0.000422
0
0.000506
0
0.00145
0

Argon

40

Total

3.600259972 0.002823536 -4.7029E-09

3.600259972 1.601854648 -0.00152744
-675.169153 -300.40132 0.286446762

CP /R
CP J/mol.K
Del H/mol
Del H

5.175160265
43.02628244
-8068.866948
-11430933435 -11.4309334 GJ

Del H /mol
Del H /mol

-8108.511269
-11487096411 -11.4870964 GJ

Del H total stream

Hrxn

-205813

Del H rxn total -287511.849

GJ
-11.4873839 -11487383.9

Low Temperature Shift converter

200 C
870 psig
10 psig

Exit Temperature
Pressure
Pressure Drop

10

11
LTS

Reactions in LTS
Reaction 1
CO+H2O = CO2 + H2

Stream 10 (HTS outlet)

Mole Flow
Mass Flow
(kgmol/hr)
(kg/hr)
3.08
49.26
226.39
6338.88
187.29
8240.92
16.11
451.01
622.83
1245.66
360.97
6497.49
1416.67
22823.23
CO Consume
Reaction 1
CO2 Produced
Reaction 1
H2 Produced
Reaction 1
Steam Consume
Reaction 1

80% based on CO

Stream 11(LTS outlet)

Mole Flow
Mass Flow
Mol%
(kgmol/hr)
(kg/hr)
0.22
3.08
49.26
15.98
226.39
6338.88
14.13
200.18
8807.91
0.23
3.22
90.20
44.87
635.72
1271.43
24.57
348.09
6265.541586
100
1416.67
22823.23

12.89 kgmol/hr
12.89 kgmol/hr
12.89 kgmol/hr
12.89 kgmol/hr

1.975018643
C

D
0
0
0

0
0
0

-3100 -249666.811
12100 5147361.991
-115700 -14215309.78

CO
H2O
CO2

0
0
-0.000002164

0
0
-6.66251E-06
-6.66251E-06
CP
del H
40.98552773 -11908.57278 kj

8300
4000
0

4634727.48
905554.9231
0
-3777332.2

H2
N2
CH4

-3100 -49933.3622
12100 4367757.239
-115700 -21669877.53
8300 5169497.682
4000 905554.9231
0
0
-11277001.05

CO
H2O
CO2
H2
N2
CH4

0.450771379
C

D
0
0
0
0
0
-6.66251E-06
-6.66251E-06
CP
del H
40.25083246 14614.63451 kj
0
0
0
0
0
-0.000002164

H rxn
Del H total

1.396011497
0.716326479

D
0
0
0
0
4000
-115700
-3100
8300
-22700
12100

Outlet temp
Ref
Stream 10 (HTS outlet)
Mole Flow
Mol%
(mol/hr)
0.22%
0.27
0.22%
0.00%
0.00
0.00%
0.00%
0.00
0.00%
0.00%
0.00
0.00%
15.98%
19.63
15.98%
13.22%
16.24
13.22%
1.14%
1.40
1.14%
43.96%
54.02
43.96%
0.00%
0.00
0.00%
25.48%
31.31
25.48%

-7960.20916
-0.02542691
1.52315E-05

J/mol
-0.00028751

0.00%
100.00%
Steam

0.00
122.86

0.00%

deg F
T0
T

deg c
deg K
200.5555556 473.5555556 tau
1.589112603
25
298
B
C
3.376 54.37904219
0.000557 0.008971898
0
3.47 1252.571704
-0.00145 -0.523408925
0
5.457 1022.061553
0.001045 0.195721884
0
393
77

A
16.11
360.97
187.29

0
0
0

622.83
226.39
3.08

3.249
3.28
1.702

2023.578068
0.000422 0.262834701
0
0
742.5550369
0.000593 0.134248517
0
0
5.240108316
0.009081 0.027958533 -0.000002164 -6.66251E-06
5100.385513
0.106326609
-6.66251E-06
H1
H2
H3
H4
Cp/R
CP
del H
5100.385513 65.18292446 -2.547138433 -31.64441542 5131.376884 42.66226741 -7489.598056

deg F
T0
T

deg c
77
430.5416

deg K
25
221.412

298 tau
494.412

0.60273618

B
C
10.87580844
0.000557
0.00179438
0
0
1207.857184
-0.00145 -0.504724183
0
0
1092.380613
0.001045 0.209187785
0
0
2065.444776
0.000422 0.268272606
0
0
742.5550369
0.000593 0.134248517
0
0
5.240108316
0.009081 0.027958533 -0.000002164 -6.66251E-06
5124.353527
0.136737637
-6.66251E-06
H1
H2
H3
H4
Cp/R
CP
del H
5124.353527 32.65399935 -0.387738329 -238.7079539 4917.911834 40.88751899 8030.799379
3.22
348.09
200.18
635.72
226.39
3.08

-541.2132161
-0.011893219

3.376
3.47
5.457
3.249
3.28
1.702

D
-3100 -49933.3622
12100 4367757.239
-115700 -21669877.53

8300
4000
0

5169497.682
905554.9231
0
-11277001.05

kj

D
-3100 -9986.672441
12100 4211836.288
-115700 -23160791.08
8300 5276451.722
4000 905554.9231
0
0
-12776934.82
kj

Cooler Separator
120 C
860 psig
10 psig

Temperature
Pressure
Pressure Drop
Assumptions:
Water Condensed
CO2 Solubility in Water

Components

LTS outlet stream

11

100%
0%

Mol. Wt

Methane
Nitrogen
Carbon dioxide
Carbon monoxide
Hydrogen
Steam

16
28
44
28
2
18

Total

Mol%
0.22
15.98
14.13
0.23
44.87
24.57
100

Stream 11 (LTS outlet)

Mole Flow
(kgmol/hr)
Mass Flow (kg/hr)
3.08
49.26
226.39
6338.88
200.18
8807.91
3.22
90.20
635.72
1271.43
348.09
6265.54
1416.7
22823.2

CO2 Removal
120 C
850 psig
10 psig

Temperature
Pressure
Pressure Drop

Stream from
Cooler Separator
Lean Solvent

Assumptions:
Solvent Used
Rich Solvent Loading
Lean Solvent Loading
Solution Strength
Components

Methane
Nitrogen
Carbon dioxide
Carbon monoxide
Hydrogen
MDEA
Water
Total
Total Mass in

13
14

MDEA
0 mol of Acid gas /mol of pure solvent
0 mol of Acid gas /mol of pure solvent
50% by weight
Stream 13 (Feed Gas)
Mole Flow
Mol. Wt
Mol%
(kgmol/hr)
Mass Flow (kg/hr)
16
0.29
3.08
49.26
28
21.19
226.39
6338.88
44
18.73
200.18
8807.91
28
0.30
3.22
90.20
2
59.49
635.72
1271.43
119.7
0.00
0.00
0.00
18
0.00
0.00
0.00
100.00
1068.6
16557.7
157705.54 kg/hr

Total Mass out

Fed mole dry base

Energy Balance
Feed moles

157705.54 kg/hr

600

315.5555556

315.5555556
25

588.5555556
298

#REF!
Inlet Temp
1416671.45 Ref Temp
A

Components

Methane
Ethane
Propane
Butane
Nitrogen
Carbon dioxide
Carbon monoxide
Hydrogen
Oxygen
Steam
Argon

Mol. Wt
16
30
44
58
28
44
28
2
32
18
40

Heat of Formation
A
-74520
-83820
-104680
-125790
0
-393509
-110525
0
0
-241818

Total

CP /R
CP J/mol.K
Del H/mol
Del H

126876.0559
1054847.529
-306491809.8
-4.34198E+14 -434198.196 GJ

Del H /mol
Del H /mol

-306491934
-4.34198E+14 -434198.372 GJ

Del H total stream

B
1.702
1.131
1.213
1.935
3.28
5.457
3.376
3.249
3.639
3.47

0.009081
0.019225
0.028785
0.036915
0.000593
0.001045
0.000557
0.000422
0.000506
0.00145

3.617178513
3.617178513
-1050.991312

286.2144178
126872.4911
-36863507.14

Hrxn
Del H rxn total

-434198.4461

-4.34198E+11

13

Cooler
Condenser
12

Mol%
0.29
21.19
18.73
0.30
59.49
0.00
100

Stream 12
Mole Flow
(kgmol/hr)
3.08
226.39
200.18
3.22
635.72
0.00
1068.59

Mass Flow
(kg/hr)
49.26
6338.88
8807.91
90.20
1271.43
0.00
16557.69

Stream 13 (Condensed Water)

Mole Flow
Mass Flow
Mol%
(kgmol/hr)
(kg/hr)
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
100.00
348.09
6265.541586
100
348.09
6265.54

22823.23

15

Treated Gas

CO2 Removal

Stripper
16

Rich Solvent

MDEA M.wt
119.7
H20
18
CO2
44
Stream 14 (Lean Solvent)
Mole Flow
Mass Flow
Mol%
(kgmol/hr)
(kg/hr)
0.00
0.00
0.00
0.00
0.00
0.00
0.13
5.89
258.94
0.00
0.00
0.00
0.00
0.00
0.00
13.05
588.51
70444.45
86.81
3913.58
70444.45
4507.97
141147.85

Mol%
0.35
26.07
0.01
0.37
73.20
0.00
0.00
100

Stream 15 (Treated Gas)

Mole Flow
Mass Flow
(kgmol/hr)
(kg/hr)
3.08
49.26
226.39
6338.88
0.09
3.82
3.22
90.20
635.72
1271.43
0.00
0.00
0.00
0
868.49
7753.60

0.00
Tau

Outlet temp
Ref

1.975018643
0.506324335

Stream 12 (CO2 Removal outlet)

C

-2.164E-06
-5.561E-06
-8.824E-06
-1.1402E-05
0
0
0
0
0
0

0
0
0
0
4000
-115700
-3100
8300
-22700
12100

-4.7029E-09 -9018.98237
-0.00095719 -0.05142257
0.278116843 8.51882E-05

Mol%
0.22%
0.00%
0.00%
0.00%
15.98%
14.13%
0.23%
44.87%
0.00%
24.57%
0.00%
100.00%
Steam

Mole Flow (mol/hr)

342.74
0.00
0.00
0.00
25201.86
22284.24
358.62
70768.78
0.00
38749.30
0.00
157705.54

0.22%
0.00%
0.00%
0.00%
15.98%
14.13%
0.23%
44.87%
0.00%
24.57%
0.00%

157705.54
0
0
0

-205813 J/mol
-73809067.3 -0.07380907

CP /R
CP J/mol.K
Del H/mol
Del H

Lean
1
0.01
6.65
7.66

Stream 16 (Rich Solvent)

Mole Flow
Mass Flow
Mol%
(kgmol/hr)
(kg/hr)
0.00
0.00
0.00
0.00
0.00
0.00
4.38
205.98
9063.03
0.00
0.00
0.00
0.00
0.00
0.00
12.50
588.51
70444.45
83.13
3913.58
70444.45
100.00
4708.07
149951.94

50% Rich
13.05483029
0.130548303
86.81462141
100

1
0.35
6.65
8

50% L/R
12.5
0.9575
4.375 Co2 stripped
83.125
200.09
100

0.0425

Methanator
400 C
840 psig
10 psig

Temperature
Pressure
Pressure Drop

From CO2 Removal Unit

Methanator

12

Reaction 1

Components

Methane
Nitrogen
Carbon monoxide
Hydrogen
Steam

Reactions in Methanator
CO+3H2 = CH4 +H2O

Mol. Wt
16
28
28
2
18

Total
CO Consume
Reaction 1
H2 Consume
Reaction 1
CH4 Produced
Reaction 1
Steam Produced
Reaction 1

100% based on CO

Stream 12 (CO2 Removal outlet)

Mole Flow
Mass Flow
Mol%
(mol/hr)
(kg/hr)
0.35
3.08
49.26
26.07
226.39
6338.88
0.37
3.22
90.20
73.21
635.72
1271.43
0.00
0.00
0.00
100
868.4
7749.8

3.22 kgmol/hr
9.66 kgmol/hr
3.22 kgmol/hr
3.22 kgmol/hr

600 315.5555556
Fed mole dry base
Energy Balance
Feed moles
Components

#REF!
Inlet Temp
868406.11 Ref Temp
Mol. Wt

315.5555556 588.5555556 Tau

25
298
A

Stream 14 (Methanator outl

Mol%
0.73
26.26
0.00
72.63
0.37
100

Components

Methane
Ethane
Propane
Butane
Nitrogen
Carbon dioxide
Carbon monoxide
Hydrogen
Oxygen
Steam
Argon

Mol. Wt
16
30
44
58
28
44
28
2
32
18
40

Heat of Formation
A
-74520
-83820
-104680
-125790
0
-393509
-110525
0
0
-241818

Total

B
1.702
1.131
1.213
1.935
3.28
5.457
3.376
3.249
3.639
3.47

C
0.009081
-2.164E-06
0.019225
-5.561E-06
0.028785
-8.824E-06
0.036915 -1.1402E-05
0.000593
0
0.001045
0
0.000557
0
0.000422
0
0.000506
0
0.00145
0

3.25206802 0.000497779 -7.6721E-09

3.25206802 0.220654222 -0.00156151
-944.90643
-64.11231 0.453704998

CP /R
CP J/mol.K
Del H/mol
Del H

3.51168365
29.1961379
-8483.1001
-7.367E+09 -7.36677591 GJ

Del H /mol
Del H /mol

-8385.2103
-7.282E+09

Hrxn

-205813

Del H rxn total -663028069

-7.2817678 GJ

Del H total stream

-0.000010 -10.2729774

14

Methanator

Cooler and
Separator

16

Knock out water

15

Stream 14 (Methanator outlet)

Mole Flow
Mass Flow
(mol/hr)
(kg/hr)
6.30
100.80
226.39
6338.88
0.00
0.00
626.05
1252.11
3.22
57.99
861.96
7749.78

1.975018643
0.506324335

Mol%
0.73
26.36
0.00
72.90
0.00
100

Stream 16
Mole Flow
(mol/hr)
6.30
226.39
0.00
626.05
0.00
858.74

Mass Flow
(kg/hr)
100.80
6338.88
0.00
1252.11
0
7691.79

861963.09
Outlet temp
Ref
Stream 12 (CO2 Removal outlet)

Stream 15 (Knock out Water)

Mole Flow
Mol%
(mol/hr)
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
100.00
3.22
100
3.22

339.15
612.15
298 Tau
Stream 14 (Methanator outlet)

D
0
0
0
0
4000
-115700
-3100
8300
-22700
12100
7107.296827
0.040522919
-6.7131E-05

Mol%
0.35%
0.00%
0.00%
0.00%
26.07%
0.00%
0.37%
73.21%
0.00%
0.00%
0.00%
100.00%
Steam

Mole Flow
(mol/hr)
3078.79
0.00
0.00
0.00
226388.73
0.00
3221.51
635717.07
0.00
0.00
0.00
868406.11
868406.11

0.35%
0.00%
0.00%
0.00%
26.07%
0.00%
0.37%
73.21%
0.00%
0.00%
0.00%

Mol%
0.73%
0.00%
0.00%
0.00%
26.26%
0.00%
0.00%
72.63%
0.00%
0.37%
0.00%
100.00%
Steam

Mole Flow
(mol/hr)
6300.30
0.00
0.00
0.00
226388.73
0.00
0.00
626052.55
0.00
3221.51
0.00
861963.09

861963.09
3.246660499 0.000534045 -1.5817E-08
3.246660499 0.118309356 -0.0008071
2095.151977 322.1669046 -9.27408305

J/mol
-0.66302807

CP /R
CP J/mol.K
Del H/mol
Del H

3.528957488
29.33975255
9217.083264
7944785599 7.944785599

Knock out Water)

Mass Flow
(kg/hr)
0.00
0.00
0.00
0.00
57.99
57.99

0.486808789
2.054194631
Methanator outlet)

Heat Recovery via Boiler Feed water

0F
105
73 40.55555556
861963.09
Ti
T out

339.15
612.15
313 Tau

Stream 15 & 16

0.511312587
1.955750799

0.73%
0.00%
0.00%
0.00%
26.07%
0.00%
0.00%
72.09%
0.00%
0.37%
0.00%

7124.169703
0.164794729
0.000138154

GJ

Mol%
0.73%
0.00%
0.00%
0.00%
26.26%
0.00%
0.00%
72.63%
0.00%
0.37%
0.00%
100.00%
Steam

Mole Flow
(mol/hr)
6300.30
0.00
0.00
0.00
226388.73
0.00
0.00
626052.55
0.00
3221.51
3.22
861966.31

0.73%
0.00%
0.00%
0.00%
26.07%
0.00%
0.00%
72.09%
0.00%
0.37%
0.00%

861966.31
3.246660499 0.000534045 -1.5817E-08
3.246660499 0.126312504 -0.00091568
1899.500449 282.6675146 -7.83794501
CP /R
CP J/mol.K
Del H/mol
Del H

3.514276803
29.21769734
-8740.47416
-7533966141 -7.53396614 GJ

7124.17
0.142219484
0.000113536

Ammonia Conversion Loop

400 C
840 psig
10 psig

Temperature
Pressure
Pressure Drop

21
From Methanator

Ammonia
Converter

16

Reaction 1

Reactions in Ammonia Converter

N2+3H2 = 2NH3

25% based onN2

Iteration No. 1
Components

Methane
Nitrogen
Hydrogen
Ammonia

Mol. Wt
16
28
2
17

Total

Stream 16 (Methanator Outlet)

Mole Flow
Mass Flow
Mol%
(kgmol/hr)
(kg/hr)
0.73%
6.30
100.80
26.36%
226.39
6338.88
72.90%
626.05
1252.11
0.00%
0.00
0.00
1
858.7
7691.8

H2 Consume
Reaction 1
N2 Consume
Reaction 1

NH3 Produced
Reaction 1

Stream 17 (Converter outle

Mol%
11.20%
18.06%
54.19%
16.54%
100.00%

Calculations for Purge stream 20 Rate

674.33 kgmol/hr
674.33
224.78 kgmol/hr
224.78

449.55 kgmol/hr

Feed Stream Flow

Feed Stream Inert
Required Inert Conc.

Purge Stream 20 flow

Recycle Stream 21 Flow

858.7
0.01
10%

7.97
3323.63

449.55

R /F

3.870351356

Note: This indicates that at the start-up, until the system get stabilized, recycle is required after that all the stream s

Scale up Factor Calculations

NH3 production based on 100 kgmol/hr ofNaphthas Feed
Scale up Factor
All the stream flow should be multiplied by this factor to get the desired production rate.

ammonia price
dollar
Total Input

20

Recycle Stream

Ammonia
Converter

17

Cooler and
Ammonia
Separator

18

Liquid Ammonia

19
Sep. Efficiency65%

Stream 17 (Converter outlet)

Mole Flow
Mass Flow
(kgmol/hr)
(kg/hr)
418.24
6691.80
674.33
18881.22
2022.99
4045.98
617.27
10493.52
3732.82
40112.51

kgmol/hr
mol%
mol%

Methane
Nitrogen
Hydrogen
NH3

kgmol/hr
kgmol/hr

N2 :H2

Stream 18 (Mixed feed)

Mole Flow
Mass Flow
Mol%
(kgmol/hr)
(kg/hr)
10.00%
418.24
6691.80
21.50%
899.11
25174.96
64.49%
2697.32
5394.63
4.01%
167.71
2851.124902
100.00%
4182.37
40112.51

Stream 19 (Liquid Ammonia)

Mole Flow
Mol%
(kgmol/hr)
0.00%
0.00
0.00%
0.00
0.00%
0.00
100.00%
401.22
100.00%
401.22

Purge Stream 20
Mole Flow
Mass Flow
Mol%
(kgmol/hr)
(kg/hr)
12.55%
1.00
16.00
20.24%
1.61
45.14
60.72%
4.84
135.43
6.48%
0.52
1.03

Recycle Stream 21
Mole Flow
Mol%
(kgmol/hr)
12.55%
417.24
20.24%
672.72
60.72%
2018.15
6.48%
215.53
3323.63
100.00%
3323.63

100.00%

quired after that all the stream should be purged.

6820.79 kg/hr
163.7 Tonnes/day
9.2
e desired production rate.

Purge Stream

6.820790031 TPH

7.97

197.61

Required
2290.790353

15231.46505

0.44780919

15.23146505

Nh3/ton naphtha

Put Basis
2265.2595

365.5551613
0.44780919
2.233093965

179.1236761
-2053.970289 -4586.708657

2233.093965

(Liquid Ammonia)
Mass Flow
(kg/hr)
0.00
0.00
0.00
6820.79
6820.79

46933.31

le Stream 21
Mass Flow
(kg/hr)
6675.80
18836.07
56508.22
431.05
82648.76
82451.15