MATERIAL SAFETY DATA SHEET

PRODUCT IDENTIFICATION Iron Fluoride Metal halide 7789-28-8 Synonyms: Formula: Ferrous Fluoride, Iron Difluoride FeF2

Trade Name: Chemical Family: CAS #:

II % 100

HAZARDOUS INGREDIENTS OSHA/PEL 2.5 mg (F) /m3 ACGIH/TLV 2.5 mg (F) /m3 Other Limits N/E Sec. 302 No Sec. 304 No Sec. 313 No

III

PHYSICAL DATA N/E or N/A 4.09 gm/cc at 25 oC N/A Slightly soluble Melting Point: Vapor Density: Vapor Pressure: Appearance and Odor: 1000 oC N/A N/A White powder, no odor

Boiling Point 760 mm Hg: Specific Gravity: % Volatiles: Solubility in H2O: IV

FIRE AND EXPLOSION HAZARDS DATA Autoignition Temperature: N/A Flammability: Non-flammable

Flash Point (Method used): N/A Flammable Limits: Lower: N/A Upper: N/A

Extinguishing Media: Use suitable extinguishing media for surrounding materials and type of fire. Unusual Fire & Explosion Hazard: Firefighters must wear full face, self-contained breathing apparatus with full protective clothing to prevent contact with skin and eyes. Fumes from fire are hazardous. Isolate runoff to prevent environmental pollution. Special Fire Fighting Procedures: When heated to decomposition or on contact with acid or fumes, iron fluoride may emit highly toxic fumes of fluorine.

HEALTH HAZARD INFORMATION

Routes of Entry: Inhalation, ingestion, skin and eyes. Effects of Overexposure: To the best of our knowledge the chemical, physical and toxicological properties of iron fluoride have not been thoroughly investigated and recorded. Iron compounds have varying toxicity. Some iron compounds are suspected carcinogens. In general, ferrous compounds are more toxic than ferric compounds. Acute exposure to excessive levels of ferrous compounds can cause liver and kidney damage, altered respiratory rates and convulsions. Inorganic fluorides are generally highly irritating and toxic. Chronic fluorine poisoning, or fluorosis, occurs among miners of cryolite, and consists of sclerosis of the bones, caused by fixation of the calcium by fluorine. There may also be some calcification of the ligaments. The teeth are mottled, and there is osteosclerosis and ostemalacia. Large doses can cause very severe nausea, vomiting, diarrhea, aggravate attacks of asthma and severe bone changes, making normal movements painful. Some signs of pulmonary fibrosis are noted. Some enzyme system effects are reported. Irritants to the eyes, skin and mucous membranes. Loss of weight, anorexia, anemia, wasting and cachexia and dental defects are among the common findings in chronic fluorine poisoning. There may be and eosinophilia and impairment of growth in young workers. Symptoms of intoxication include gastric, intestinal, circulatory, respiratory and nervous complaints and rashes.

Acute Effects: Inhalation: SEVERE IRRITANT AND CORROSIVE. May cause severe irritation to the respiratory tract and mucous membrane, acute iron poisoning, asthma attacks, excessive salivation, thirst, sweating, vomiting, colic, diarrhea and lung granulomas. Large amounts of iron may cause iron pneumoconiosis. Ingestion: SEVERE IRRITANT AND CORROSIVE. May cause gastrointestinal irritation, severe nausea, vomiting, diarrhea, dehydration and thirst, muscle weakness, lethargy, cramp-like pains and central nervous system depression. Skin: SEVERE IRRITANT AND CORROSIVE. May cause irritation, rashes and skin granulomas. Eyes: SEVERE IRRITANT AND CORROSIVE. Target Organs: May affect the skeleton, liver, kidneys, central nervous system, respiratory system, eyes and skin. Carcinogenicity: NTP: No IARC: No OSHA: No Chronic Effects: Inhalation: May cause fluorosis, pulmonary fibrosis and severe bone changes. May cause chronic iron poisoning and pathological deposition of iron in the body tissue. Ingestion: May damage the liver and affect the circulatory, enzyme and nervous system. Skin: May cause dermatitis. Eyes: No chronic health effects recorded. Medical Conditions, if any, Aggravated by Exposure: Can cause or aggravate attacks of asthma. EMERGENCY AND FIRST AID PROCEDURES: INHALATION: Remove victim to fresh air; keep warm and quiet; give oxygen if breathing is difficult and seek medical attention immediately. INGESTION: Give 1-2 glasses of milk or water; do not induce vomiting; seek medical attention immediately. SKIN: Remove contaminated clothing; brush material off skin; wash affected area with mild soap and water; seek medical attention immediately. EYES: Flush eyes with lukewarm water, lifting upper and lower eyelid, for at least 15 minutes. Seek medical attention immediately.

VI

REACTIVITY DATA

Stability: Stable Conditions to Avoid: Excessive heating. Incompatibility (Material to Avoid): Alkali metals, strong acids, moisture, oxidizing agents. Hazardous Decomposition Products: Hydrofluoric acid, fumes of fluorine. Hazardous Polymerization: Will not occur.

VII

SPILL OR LEAK PROCEDURES

Steps to Be Taken in Case Material Is Released or Spilled: Wear appropriate respiratory and protective equipment specified in section VIII. Isolate spill area and provide ventilation. Vacuum up spill using a high efficiency particulate absolute (HEPA) air filter and place in a closed container for proper disposal. Take care not to raise dust. Waste Disposal Method: Dispose of in accordance with Local, State and Federal Regulations.

VIII

SPECIAL PROTECTION INFORMATION

Respiratory Protection (Specify Type): NIOSH/MSHA approved dust, mist, vapor cartridge respirator. Ventilation: Handle in an inert gas such as argon, in an enclosed, controlled environment. Mechanical exhaust is not recommended. Eye Protection: Face shield and chemical safety goggles. Protective Gloves: Rubber Other Protective Equipment: Lab coat and apron, flame and chemical resistant coveralls, eyewash capable of sustained flushing, safety drench shower and hygienic facilities for washing.

IX

SPECIAL PRECAUTIONS

Precautions to Be Taken in Handling and Storage: Keep container tightly closed. Store in a cool, dry, well-ventilated area. Wash thoroughly after use. Precautionary Labeling: WARNING TOXIC DO NOT SWALLOW OR INHALE. Avoid contact with skin and eyes. Work/Hygienic/Maintenance Practices: Implement engineering and work practice controls to reduce and maintain concentration of exposure at low levels. Use good housekeeping and sanitation practices. Do not use tobacco or food in work area. Wash thoroughly before eating and smoking. Do not blow dust off clothing or skin with compressed air. HMIS Ratings (0-4): Health: 4 Flammability: 0 Reactivity: 0 HMIS Protective Equipment: J: goggles, gloves, apron, respirator. Some of the chemicals listed herein are research or experimental substances which may be toxic, as defined by various governmental regulations. In accordance with Environmental Protection Agency regulations and the Toxic Substance Control Act (TCSA), these materials should only be handled by, or under the direct supervision of, a technically qualified individual, as defined in 40 CFR 710.2 (aa). The above information is accurate to the best of our knowledge. However, since data, safety standards, and governmental regulations are subject to change, and the conditions of handling and use or misuse are beyond our control, ESPI makes no warranty, either express or implied, with respect to the completeness or continuing accuracy of the information contained herein, and disclaims all liability for reliance thereon. Users should satisfy themselves that they have all current data relevant to their particular use.

Issued by: Date:

S. Dierks July 1998