Material Safety Data Sheet

255 Norman. Lachine (Montreal), Que H8R 1A3

EMERGENCY NUMBERS: (USA) CHEMTREC : 1(800) 424-9300 (24hrs) (CAN) CANUTEC : 1(613) 996-6666 (24hrs) (USA) Anachemia : 1(518) 297-4444 (CAN) Anachemia : 1(514) 489-5711
Protective Clothing TDG Road/Rail

WHMIS

WHMIS CLASS: B-2 D-1B D-2A D-2B

TDG CLASS: 3 6.1 PIN: UN1230 PG: II

Section I. Product Identification and Uses Product name METHANOL

Chemical formula Synonyms
CH3OH
Methyl alcohol, Methyl hydroxide, Methyl hydrate, Wood alcohol, Carbinol, Monohydroxymethane, AC-5730, AC-5730SC, AC-5730PG, GD-5730, GD-5731, AC-5731, AC-5732, M-10798, M-11807, 56902, 56948, 56912, 56894, 56887, 56898

CI# CAS# Code Formula weight Supersedes

Not available. 67-56-1 AC-5730 32.04

Supplier

Anachemia Canada. 255 Norman. Lachine (Montreal), Que H8R 1A3 For laboratory use only.

Material uses

Section II. Ingredients

Name
1) METHANOL

CAS #
67-56-1

%
98-100

TLV
Exposure limits: ACGIH TWA 200 ppm (260 mg/m3): STEL 250 ppm (325 mg/m3) (skin)

Toxicity values of the hazardous ingredients

METHANOL: ORAL (LD50): Acute: 7300 mg/kg (Mouse). 14200 mg/kg (Rabbit). ORAL (LDLo): Acute: 143 mg/kg (Human). DERMAL (LD50): Acute: 15800 mg/kg (Rabbit). VAPOR (LC50): Acute: 64000 ppm (Rat) (4 hour(s)).

Section III. Physical Data

Physical state and appearance / Odor pH (1% soln/water) Odor threshold Percent volatile Freezing point Boiling point Specific gravity Vapor density Vapor pressure Water/oil dist. coeff. Evaporation rate Solubility
Clear, colorless, mobile liquid with mild alcohol odor. Not available. 2000 ppm, irritation at 1000 ppm, poor warning properties. 100% (V/V) -97.8C 64.5C 0.795 (Water = 1) 1.11 (Air = 1) 96 mm Hg @ 20C Readily soluble in water, separates from oil. 5.9 (n-Butyl acetate = 1). Miscible in water.

METHANOL

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Section IV. Fire and Explosion Data

Flash point Flammable limits
CLOSED CUP: 11C (Tag Closed Cup) LOWER: 5.5% UPPER: 36.5%

Auto-ignition temperature 464C

Fire degradation products Fire extinguishing procedures

Oxides of carbon. Formaldehyde.

Use DRY chemical, carbon dioxide, alcohol-resistant foam or water spray. Water may be ineffective to extinguish fires. Wear adequate personal protection to prevent contact with material or its combustion products. Self contained breathing apparatus with a full facepiece operated in a pressure demand or other positive pressure mode. Cool containing vessels with flooding quantities of water. Disperse vapors with water spray if they have not ignited. May re-ignite after fire is extinguished.

Fire and Explosion Hazards

Flammable liquid. Methanol burns with a clean clear flame which is almost invisible in daylight. Concentrations of greater than 20% methanol in water can be ignited. Vapor may travel considerable distance to source of ignition and flash back, eliminate all sources of ignition. Vapor forms explosive mixture with air. Container explosion may occur under fire conditions or when heated. Contact with oxidizers may cause fire and/or explosion. Sensitive to static discharge. Not expected to be sensitive to mechanical impact. Emits toxic fumes under fire conditions.

Section V. Toxicological Properties

Routes of entry Effects of Acute Exposure Eye
Inhalation and ingestion. Eye contact. Skin contact. Skin absorption. May be fatal by ingestion, inhalation or skin absorption. Irritant. Onset of symptoms may be delayed 1-30 hours. Target organs: heart, blood, central nervous system, liver, kidneys, spleen, eyes, skin, cardiovascular system, gastrointestinal system, respiratory system, lungs. 6000 ppm (METHANOL) is immediately dangerous to life or health.
May cause eye injury which may persist for several days. Liquid, and vapor in high concentrations, cause severe irritation, tearing and burning sensation. IRRITATION: EYE-RABBIT 40 mg MODERATE. Causes skin irritation, scaling, reddening, drying, and cracking of the skin. Prolonged and repeated contact may lead to defatting dermatitis. Liquid can be absorbed in toxic amounts through intact skin. See ingestion and inhalation. IRRITATION: SKIN-RABBIT 20 mg/24H MODERATE.

Skin

Inhalation

Material is irritating to mucous membranes and upper respiratory tract. High levels may cause stupor, headache, nausea, vomiting, dizziness, weakness, digestive and visual disturbances, unconsciousness, central nervous system depression, blindness and death. Methanol may also cause liver and kidney damage. Repeated inhalation may cause impairment of lung function and permanent lung damage. NOTE: The odor threshold of methanol is several times higher than the TLV-TWA. Poisonous or fatal if swallowed. Usual fatal dose: 100-125 milliliters (METHANOL). Can affect the optic nerve resulting in blindness. Can cause mental sluggishness, nausea, vomiting, dyspnea, abdominal pain, diarrhea, convulsions, central nervous system depression, coma and death.

Ingestion

Section V. Toxicological Properties

Effects of Chronic Overexposure

METHANOL

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Repeated skin contact may cause irritation, dryness, craking, dermatitis, erythema, and scaling. Repeated exposure by inhalation or absorption may cause systemic poisoning, brain disorders, impaired vision, nystagmus and blindness. Inhalation may worsen conditions such as emphysema or bronchitis. May cause heart, kidney, lung, central nervous system, liver, spleen, brain, and eye damage. Methanol is reported to cause birth defects in rats exposed to 20000 ppm. Passes through the placental barrier in animal. In Vitro, limited evidence of mutagenicity (mouse lymphoma forward mutation assay); In Vivo, no information. To the best of our knowledge the chronic toxicity of this substance has not been fully investigated. Medical conditions which may be aggravated: Significant exposure to this chemical may adversely affect people with chronic disease of the central nervous system, skin, gastrointestinal tract and/or eyes, emphysema, bronchitis.

Section VI. First Aid Measures

Eye contact
Immediately flush eyes with copious quantities of water for at least 15 minutes holding lids apart to ensure flushing of the entire surface. Seek immediate medical attention.

Skin contact

Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Call a physician. Wash contaminated clothing before reusing. Discard contaminated leather articles such as shoes and belt.

Inhalation

Remove patient to fresh air. Administer approved oxygen supply if breathing is difficult. Administer artificial respiration or CPR if breathing has ceased. Seek immediate medical attention.

Ingestion

If conscious, wash out mouth with water. Have conscious person drink several glasses of water to dilute. Induce vomiting. Seek immediate medical attention. Never give anything by mouth to an unconscious or convulsing person.

Section VII. Reactivity Data

Stability
Stable. Conditions to avoid: High temperatures, sparks, open flames and all other sources of ignition, contamination.

Hazardous decomp. products Incompatibility

Oxides of carbon. Formaldehyde.

Oxidizing agents, sulfuric acid, zinc diethyl, potassium t-butoxide, phosphorus trioxide, alkylaluminum solutions, acids, reducing agents, acetaldehyde, ethylene oxide, chromic anhydride, bases, metals (example; magnesium, potassium, zinc, etc...), isocyanates, acid anhydrides, acid chlorides, perchloric acid, nitric acid, hydrogen peroxide, sodium hydroxide with chromoform, cyanuric chloride, perchlorates, nitrates. Corrosive to aluminum and lead. Attacks some forms of plastics, rubbers and coatings.

Reaction Products

Not available. Hazardous polymerization will not occur.

Section VIII. Preventive Measures

METHANOL

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Protective Clothing in Wear self-contained breathing apparatus, rubber boots and heavy rubber gloves. Full suit. case of spill and leak

Spill and leak

Evacuate and ventilate the area. Eliminate all sources of ignition. DO NOT touch damaged container or spilled material. Stop leak if without risk. Dyke the area with sand or a natural barrier. Use water spray to reduce vapors. Absorb on sand or vermiculite and place in a closed container for disposal. Use non-sparking tools. Transport outdoors. Wash spill site after material pick up is complete. DO NOT empty into drains. Runoff to sewer may create fire or explosion hazard.

Waste disposal

Burn in a chemical incinerator equipped with an after burner and scrubber. According to all applicable regulations. Harmful to aquatic life at high concentrations. Can be dangerous if allowed to enter drinking water intakes. Do not contaminate domestic or irrigation water supplies, lakes, streams, ponds, or rivers.

Storage and Handling

Store in a cool place away from heated areas, sparks, and flame. Store in a well ventilated area. Store away from incompatible materials. Do not add any other material to the container. Do not wash down the drain. Do not breathe gas/fumes/vapor/spray. In case of insufficient ventilation, wear suitable respiratory equipment. Keep container tightly closed and dry. Do not use pressure to dispense. Keep at temperature not exceeding 25C. Product is highly hygroscopic. Manipulate under an adequate fume hood. Take precautionary measures against electrostatic discharges. Ground the container while dispensing. Ground all equipment containing material. Use only explosion proof equipment. Use non-sparking tools. Watch for accumulation in low confined areas. Empty containers may contain a hazardous residue. Handle and open container with care. Take off immediately all contaminated clothing. This product must be manipulated by qualified personnel. Do not get in eyes, on skin, or on clothing. Wash well after use. In accordance with good storage and handling practices. Do not allow smoking and food consumption while handling. In case of accident or if you feel unwell, seek medical advice immediately (show the label when possible.). Never use welding or cutting torch on or near drum (even empty) because product (even just residue) can ignite explosively.

Section IX. Protective Measures

Protective clothing
Face shield and splash goggles. Impervious butyl rubber or neoprene gloves, apron, coveralls, and/or other resistant protective clothing. Sufficient to protect skin. Prior to use, user should confirm impermeability. A OSHA/MSHA jointly approved respirator is advised in the absence of proper environmental controls. If more than TLV, do not breathe vapor. Wear self-contained breathing apparatus. Do not wear contact lenses. Make eye bath and emergency shower available. Ensure that eyewash station and safety shower is proximal to the work-station location.

Engineering controls

Use only in a chemical fume hood to keep airborne levels below recommended exposure limits. Use explosion-proof ventilation equipment. Do not use in unventilated spaces. Vapors are heavier than air and may travel along the ground or pool in low areas. Because vapor is heavy, ventilation must be provided at floor level as well as at higher levels.

Section X. Other Information

Special Precautions or Flammable liquid! Highly toxic! Irritant! Readily absorbed through skin. Do not breathe vapor. comments Avoid all contact with the product. Avoid prolonged or repeated exposure. Use only in a chemical fume hood. May develop pressure. Open carefully. Keep away from heat, sparks and flame. Take precautionary measures against static discharges. Bond and ground transfer containers and equipment to avoid static accumulation. Use non-sparking tools. Handle and open container with care. Container should be opened only by a technically qualified person. RTECS no. PC1400000 (Methanol). Synergistic materials: Alcohols may interact synergistically with chlorinated solvents (example: carbon tetrachloride, chloroform, bromotrichloromethane), dithiocarbamates (example: disulfiram), dimethylnitrosamine and thioacetamide. ANTAGONISM: Ethanol. NOTE TO PHYSICIAN: When plasma methanol concentrations are higher than 20 milligrames per deciliter, when ingested doses are greater than 30 milliliters, and when there is evidence of acidosis or visual abnormalities, a 10% solution of ethanol in 5% aqueous dextrose, administered intravenously, is a safe, effective antidote (Western Journal of Medicine, March 1985, p 337).

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NFPA

Prepared by MSDS Department/Dpartement de F.S..

Validated 10-May-2007

Telephone# (514) 489-5711

While the company believes the data set forth herein are accurate as of the date hereof, the company makes no warranty with respect thereto and expressly disclaims all liability for reliance thereon. Such data are offered solely for your consideration, investigation and verification.