3

155

( , 116023) ( , 113004)

CDM 2,
, T PD ,
CDM 2, ,

CDM
,

CDM 30% ,

N H 4NO 3 , 540,

(CDM + )
CDM 2CDM g

M ob il 1967
[ 1 ] , [ 2 ]

540 , 1m o lg
L

100% 83. 3% 66. 7% 50. 0%

1617% A 0A 1A 2A 3

CDM 2 ( CDM
ZSM 25 ZSM 211 )

A 4CDM 2

1. 3

[ 3, 4 ]

CDM 2

, 100%

11311

N 2

, 5001h,

1. 1

11312

(
99. 5% ) ;
, : H 2 14. 0%
O 2 0. 8% CH 4 33. 0% CO 1. 5% CO 2 3. 0%
C 2H 4 20. 8% C 2H 6 16. 0% C 3H 6 0. 8% C 3H 8
0. 2% H 2O 810- 6 , H 2 S 3m g g
L , N 2
1. 2
CDM 2,
35, n ( SiO 2 ) g
m ( ZSM 211) g
m ( ZSM 25 ) 65g
n (A l2O 3 ) 60,

2mm , 10g;
350 420; 0. 6 0. 7M Pa;
1;
n ( ) g
n ( ) = 5g
(W H SV ) 018h - 1
11313

102
( ) ,
, 70
: 1996211204

156

80, 30m lg
m in

, 25, 30m lg
m in
C 2R 1B

199827

, CDM g(CDM + ) ,

2 , CDM g(CDM + ) ,
(C E )
CDM ,

2. 1 CDM -
21111

CDM 2
,
1, 1

2
1, CDM
( ) ,
, CDM g(CDM + )
1617% , 1
1

2 CDM 2 CDM

1 CDM 2

w (CDM g

21112 A 0 A 2 N H 3 2T PD

g
%

(CDM + ) )

A0

100. 0

81. 89 0. 36 16. 32 0. 42

1. 00

A1

83. 3

83. 22 0. 10 15. 62 0. 38

0. 65

A2

66. 7

83. 94 0. 05 14. 42 0. 27

1. 31

A4

16. 7

87. 46 0. 00 10. 82 0. 21

1. 51

g
%

EB

2EB

PB

: 0. 8h - 1 , n (B ) g
1,
n ( E ) = 5g
0165M Pa, 390E , B , T , EB
, PB , 2EB

1 CDM 2 CDM

[ 5, 6 ] , B

A 0 ( CDM g( CDM + ) = 100% ) A 2

(CDM g
(CDM + ) = 66. 7% ) ,
T PD 33

, A 2 A 0 ,

3A 0 A 2 N H 3 2T PD

157

A 2 A 0

2. 2

, ,
55 , ,

, CDM g(CDM + )
CDM g(CDM + ) 100%

4
(CDM + ) = 50. 0% )
A 3 (CDM g

8313% , S T 0111% 0;

,
0
,

5005502h
T PD 4,
,

5
CDM 2 CDM

4A 3 N H 3 2T PD

2. 3

2 CDM 2

(C E ) (S T )

CDM 2
5002h, 1

2 CDM 2

g
%

(CDM + ) )
w (CDM g

g
%

g
%

350

370

390

410

350

370

390

410

A0

100. 0

98. 3

96. 6

97. 8

97. 3

0. 96

1. 03

1. 94

7. 62

A1

83. 3

95. 9

98. 0

98. 3

97. 8

0. 00

0. 00

0. 59

4. 80

A3

50. 0

77. 2

88. 5

92. 9

94. 0

0. 00

0. 00

0. 16

3. 04

A4

16. 7

48. 9

63. 6

74. 7

82. 9

0. 00

0. 00

0. 00

0. 00

: 1

2 , CDM 2
, , C E S T
w (CDM g(CDM + ) ) 83. 3% ,

C E , , C E

; CDM 2
, , w (CDM g(CDM

158

+ ) ) , C ES T

199827

,
,
,

3
( 1 ) CDM 2,

CDM ( 50. 0% < w (CDM g

(CDM + ) < 100. 0% ) , ,

( 2) CDM 2
,
( 3) CDM 2

1U S 3 308 069, 1967

2T reacy M M J , N ew sam J M. N a tu re (L ondon ) , 1988; 332:
249
3 M arten s J A , T iden M , J acob s P A et al. Z eolite, 1984; 4: 98
4P rezz2Parien te J E, Sartre J A. A pp l C a ta l, 1991; 69: 125
5Becker K A. J C a ta l, 1973; 28: 403
6A nderson J R ,M o le T , Ch ristov V. J C a ta l, 1980; 61: 477

Study on Polym olecular S ieves for Benzene A lkyla t ion

w ith D ilute Ethylene O ff Ga s
X ie S ujuan , X u H ongy i , W ang Q ing x ia and X u L ongy a
(D alian In stitu te of Chem ical Physics, Ch inese A cadem y of Science, D alian 116023)

Z hang S hu rong and L i Y uy ing

(R efinery N o. 2, Fu shun Petrochem ical Com p any, Fu shun 113004)

Abstract
Ca ta ly t ic p rop ert ies of d ifferen t com pound CDM 2 zeo lite ca ta ly st s ( CDM a re the co 2
cry sta llized zeo lites of ZSM 25 and ZSM 211) , w ith o r w ithou t t rea tm en t of steam , u sed fo r benzene
a lky la t ion w ith d ilu te ethy lene in the FCC off ga s have been invest iga ted by a con t inuou s flow
fixed bed reacto r. T he resu lt s show tha t p rop erly com pounded CDM 2 can reduce the by 2p roduct
to luene w h ile keep ing p rop er reactan t conversion and thu s im p roving the ca ta ly t ic p rop ert ies. In
add it ion, the acid ic d ist ribu t ion of som e CDM 2 ca ta ly st s ha s been cha racterized by m ean s of
T PD.
Keywords: zeo lite, a lky la t ion, ethy lbenzene
( 226)
L H - 3023
,
L H 23023

,
, ,

( )