You are on page 1of 13

394,50 - Rajeev Gandhi Nagar Kota, Ph. No.

: 93141-87482, 0744-2209671
IVRS No : 0744-2439051, 52, 53, www. motioniitjee.com , info@motioniitjee.com
1
IIT-JEE 2013 PAPER-I WITH SOLUTION [CODE - 3]
PART - I [PHYSICS]
1. A particle of mass m is projected from the ground
with an intial speed u
0
at an angle o with the horizontal.
At the highest point of its trajectory, it makes a
completely inelastic collision with another identical
particle, which was thrown vertically upward from the
ground with the same intial speed u
0
. The angle that
the composite system makes with the horizontal
immediately after the collision is
(A)
4
t
(B)
4
t
+ o (C)
2
t
o (D)
2
t
Ans. A
u
0
final kinetic energy of both the particles is
same because the vertical displacement is also
same.
mgh =
1
2
mv
2
(for both the particles)
The final angle which the composite system
makes with the horizontal is 45.
2. The image of an object, formed by a plano-
convex lens at a distance of 8 m, behind the lens, is
real and is one-third the size of the object. The
wavelength of light inside the lens is
3
2
times the
wavelength in free space. The radius of the curved
surface of the lens is
(A) 1 m (B) 2 m (C) 3 m (D) 6 m
Ans. C
h
O
24m
8m
h/3
from wavelength ratio
= 1.5 (from
1
/
2
)
1
8
+
1
24
= (1.5 1)
1
R
R = 3m Ans.
3. The diameter of a cylinder is measured using a Vernier
callipers with no zero error. It is found that the zero of
the Vernier scale lies between 5.10 cm and 5.15 cm of
the main scale. The Vernier scale has 50 divisions
equivalent to 2.45 cm. The 24
th
division of the Vernier
scale exactly coincides with one of the main scale
divisions. The diameter of the cylinder is
(A) 5.112 cm (B) 5.124 cm
(C) 5.136 cm (D) 5.148 cm
Ans. B
L.C.=
| |
|
\ .
3
2.45
0.05 cm=10 cm.
50
Reading = 5.10 cm + 24 10
3
cm.
= 5.124 cm.
4. The work done on a particle of mass m by a
force,
( ) ( ) (
(

+
+
+
j

y x
y
i

y x
x
K
2 / 3
2 2
2 / 3
2 2
(K being a constant
of appropriate dimensions), when the particle is taken
from the point (a,0) to the point (0,a) along a circular
path of radius a about the origin in the x-y plane is
(A)
a
K 2 t
(B)
a
Kt
(C)
a 2
Kt
(D) 0
Ans. D
x
2
+y
2
=a
2
dw =
a 0
3 3
0 a
x y
dx+ dy
a a
} }
w =
a 0
2 2
3
0 a
1 x y
2 2 a
(
| | | |
( +
| |
(
\ . \ .

w = 0 Ans.
5. One end of a horizontal thick copper wire of
length 2L and radius 2R is welded to an end of another
horizontal thin copper wire of length L and radius R.
When the arrangement is stretched by applying forces
at two ends, the ratio of the elongation in the thin wire
to that in the thick wire is
(A) 0.25 (B) 0.50
(C) 2.00 (D) 4.00
394,50 - Rajeev Gandhi Nagar Kota, Ph. No. : 93141-87482, 0744-2209671
IVRS No : 0744-2439051, 52, 53, www. motioniitjee.com , info@motioniitjee.com
2
Ans. C
F
2R
F
R
F F
y =
( )
2
2 F / 4R t
A

y = 2
1
F
2 R t A

y = 2
2
F
R t A


2
1
A
A

= 2 Ans
6. A ray of light travelling in the direction
( ) j

3 i

2
1
+
is incident on a plane mirror. After reflection, it travels
along the direction
( ) j

3 i

2
1
. The angle of incidence is
(A) 30 (B) 45
(C) 60 (D) 75
Ans. A
3
2
3
2
-
1
2
i
r
1
2
Mirror in xz plane
Since y component is reversed
tanu =
(1/2)
( 3/2)
=
1
3
u=30
7. Two rectangul ar bl ocks, havi ng i dentical
dimensions, can be arranged either in configuration I or
in configuration II as shown in the figure. One of the
blocks has thermal conductivity K and the other 2K.
The temperature difference between the ends along
the x-axis is the same in both the configurations. it
takes 9 s to transport a certain amount of heat from
the hot end to the cold end in the configuration I. The
time to transport the same amout of heat in the
configuration II is
2K
K
Configuration I Configuration II
foU;kl I foU;kl II
2K K
(A) 2.0 s (B) 3.0 s (C) 4.5 s (D) 6.0 s
Ans. A
Equivalent circuit diagram
R R/2
T
1
T
2

R
R/2
T
1
T
2
Q =
1 2
T T
9
3R
2

..... (i) Q =
1 2
T T
t
R
3

..... (ii)
Solving (i) & (ii)
t = 2 sec. Ans.
8. A pulse of light of duration 100 ns is absorbed
completely by a small object initially at rest. Power of the
pulse is 30 mW and the speed of light is 3 10
8
ms
-1
. The
final momentum of the object is
(A) 0.3 10
-17
kg ms
-1
(B) 1.0 10
-17
kg ms
-1
(C) 3.0 10
-17
kg ms
-1
(D) 9.0 10
-17
kg ms
-1
Ans. B
Energy given to particle
= 100 10
9
30 10
3
= 3000 10
12
J
E
P=
C
12
8
300010
=
310
= 1 10
17
kg m s
1
9. In the young's double slit experiment using a
monochromatic light of wavelength , the path difference
(in terms of an integer n) corresponding to any point
having half the peak intensity is
(A)
( )
2
1 n 2

+ (B)
( )
4
1 n 2

+
(C) ( ) 2n 1
8

+
(D)
( )
16
1 n 2

+
Ans. B
I=4I
0
cos
2

2
=2I
0
cos
2

2
=
1
2
A|=

2
x

A =
4
or (2n+1)

4
10. Two non-reactive monoatomic ideal gases have their
atomic masses in the ratio 2 : 3. The ratio of their
partial pressures, when enclosed in a vessel kept at a
constant temperature, is 4 : 3. The ratio of their densities
is
(A) 1 : 4 (B) 1 : 2
(C) 6 : 9 (D) 8 : 9
Ans. D
2
rms
1
P= v
3
where v
rms
=


3RT
M
P =
1 3RT
3 M
(

P
M

1
2
4 3
=
3 2
1
2

=
8
9
Ans.
394,50 - Rajeev Gandhi Nagar Kota, Ph. No. : 93141-87482, 0744-2209671
IVRS No : 0744-2439051, 52, 53, www. motioniitjee.com , info@motioniitjee.com
3
11. Two non-conducting solid spheres of radii R and
2R, having uniform volume charge densitites
1
and

2
respectively, touch each other. The net electric field at
a distance 2R from the centre of the smaller sphere,
along the line joining the centres of the spheres, is
zero. The ratio
2
1

can be
(A) -4 (B)
25
32

(C)
25
32
(D) 4
Ans. B,D
E
1
=
( )
3
1
2
4
K R
3
2R
t
R P
2R
E
2
=
2
0
R
3

e
as field is zero at P
R
2R
P
2R
( )
3
1
2 0
2
0
1 4
R
R 4 3
3
2R
t
t e
=
e

1
2

= 4
and
1
/
2
= 32/25
12. A horizontal stretched string, fixed at two ends,
is vibrating in its fifth harmonic according to the equation,
y(x,t) = (0.01 m) sin [(62.8 m
-1
)x] cos
( )
1
[ 628s t]

Assuming t=3.14, the correct statement (s) is (are)


(A) The number of nodes is 5.
(B) The length of the string is 0.25 m.
(C) The maximum displacement of the midpoint of the
string, from its equilibrium position is 0.01 m.
(D) The fundamental frequency is 100 Hz.
Ans. BC
K =
2t

= 10m
P
L =
5
2

= 25 cm A = 0.01 m
13. In the circuit shown in the figure, there are two
parallel plate capacitors each of capacitance C. The
switch S
1
is pressed first fo fully charge the capacitor
C
1
and then released. The switch S
2
is then pressed to
charge the capacitor C
2
. After some time, S
2
is released
and then S
3
is pressed. After some time,
2V
0
V
0
C
2 C
1
S
1
S
2
S
3
(A) the charge on the upper plate C
1
is 2CV
0
.
(B) the charge on the upper plate of C
1
is CV
0
.
(C) the charge on the upper plate of C
2
is 0.
(D) the charge on the upper plate of C
2
is -CV
0
.
Ans. BD
Hint.
V'
+

2CV
0
0
2CV
0
=2CV
V = V
0
Final situation
CV
0
CV
0
CV
0
CV
0
C
1
C
2
14. A particle of mass M and positive charge Q,
moving with a constant velocity
1
1
ms i

4 u

=

, enters a
region of uniform static magnetic field normal to the x-y
plane. The region of the magnetic field extends from x =
0 to x = L for all values of y. After passing through this
region, the particle emerges on the other side after 10
milliseconds with a velocity ( ) j

3 2 u
2
+ =

ms
-1
. The
correct statement (s) is (are)
(A) The direction of the magnetic field is -z direction.
(B) The direction of the magnetic field is +z direction.
(C) The magnitude of the magnetic field
Q 3
M 50t
units.
(D) The magnitude of the magnetic field is
Q 3
M 100t
units.
Ans. AC
tanu =
1
3
, u = 30
Also T = 12 10
3
=
2 M
qB
t

y
x
q,m






L
2 3i 2j +
B = 3
2 M 500 M
q 12 10 3q
t t
=

394,50 - Rajeev Gandhi Nagar Kota, Ph. No. : 93141-87482, 0744-2209671
IVRS No : 0744-2439051, 52, 53, www. motioniitjee.com , info@motioniitjee.com
4
15. A solid sphere of radius R and density is
attached to one end of a mass-less spring of force
constant k. The other end of the spring is connected to
another solid sphere of radius R and density 3 . The
complete arrangement is placed in a liquid of density 2
and is allowed to reach equilibrium. The correct
statement(s) is (are)
(A) the net elongation of the spring is
k 3
g R 4
3
t
(B) the net elongation of the spring is
k 3
g R 8
3
t
(C) the light sphere is partially submerged.
(D) the light sphere is completely submerged.
Ans. AD
Hint :
(A) For upper block
kx +
4
3
tR
3
=
4
3
tR
3
2
x =
4
3

3
R
k
t
(D) Cannot provide upward force if partially submerged.
16. A uniform circular disc of mass 50 kg and radius
0.4 m is rotating with an angular velocity of 10 rad s
-1
about its own axis, which is vertical. Two uniform circular
rings, each of mass 6.25 kg and radius 0.2 m, are gently
placed symmetrically on the disc in such a manner that
they are touching each other along the axis of the disc
and are horizontal. Assume that the friction is large
enough such that the rings are at rest relative to the
disc and the system rotates about the original axis. The
new angular velocity (in rad s
-1
) of the system is
Ans. 8
Angular momentum conservation
I
1
e
1
= I
2
e
2
2 2
2 2
1 2
MR MR
2(mr mr )
2 2
(
e = + + e
(

( )
2
50 0.4
2
10 =
( )
( ) ( ) { }
2
2 2
50 0.4
2 6.25 0.2 0.2
2
(
( + +
(

e
2
40 = [4 + 1] e
2
e
2
= 8 rad/s
17. The work functions of Silver and Sodium are 4.6
and 2.3 eV, respectively. The ratio of the slope of the
stopping potential versus frequency plot for Silver to
that of Sodium is
Ans. 1
V
f
V=
hf

e e
Slope is planks constant so 1.
18. A bob of mass m, suspended by a string of length
l
1
, is given a minimum velocity required to complete a
full circle in the vertical plane. At the highest point, it
collides elastically with another bob of mass m
suspended by a string of length l
2
, which is initially at
rest. Both the strings are mass-less and inextensible. If
the second bob, after collision acquired the minimum
speed required to complete a full circle in the vertical
plane, the ratio
2
1
l
l
is
Ans. 5
V
bottom
=
2
5g , At top, V
top
=
1
g
Thus V
top
= V
bottom
1
g =
2
5g

1
2

= 5 Ans.
19. A particle of mass 0.2 kg is moving in one
dimension under a force that delivers a constant power
0.5 W to the particle. If the initial speed (in ms
-1
) of the
particle is zero, the speed (in ms
-1
) after 5 s is
Ans. 5
2 2
m(v u )
2
= pt
20. A freshly prepared sample of a radioisotope of
half-life 1386 s has activity 10
3
distintegrations per
second. Given that ln 2 = 0.693, the fraction of the
initial number of nuclei (expressed in nearest integer
percentage) that will decay in the first 80 s after
preparation of the sample is
Ans. 4
Fraction in % =
t
0
0
N (1 e )
N

=
t
(1 e )

=
.04
(1 e ) ~ 4%
394,50 - Rajeev Gandhi Nagar Kota, Ph. No. : 93141-87482, 0744-2209671
IVRS No : 0744-2439051, 52, 53, www. motioniitjee.com , info@motioniitjee.com
5
PART - II [CHEMISTRY]
SECTION A
Single Correct
21. The standard enthalpies of formation of CO2(g),
H
2
O() and glucose(s) at 25C are 400 kJ/mol,
300 kJ/mol and 1300 kJ/mol, respectively. The
standard enthalpy of combustion per gram of
glucose at 25C is
(A) +2900 kJ (B) 2900 kJ
(C) 16.11 kJ (D) +16.11 kJ
Sol. C
C
6
H
12
O
6
(s) + 6O
2
(g) 6CO
2
(g) + 6H
2
O ()
A
f
H 1300 0 400 300
A
r
H = E(A
f
H)
P
E(A
f
H)
R
= [6(400) + 6(300)] [(1300)]
= [2400 1800] + 1300
= 2900
mole
kJ
|
.
|

\
|
|
.
|

\
|
A
= A
mole
gm
. wt molecular
mole
kJ
H
gm
kJ
H
c
c
=
180
2900
= 16.11 kJ/gm
22. KI in acetone, undergoes SN2 reaction with
each of P,Q,R and S. The rates of the reaction
vary as. H
3
CCl
O
Cl
Cl
H CCl
2
(A) P>Q>R>S (B) S>P>R>Q
(C) P>R>Q>S (D) R>P>S>Q
Sol. B
S > P > R > Q
Transition state of compound S is highly stabi-
lize by Ph C
=
O
group so it has more rate of reaction
towards SN
2
.
order of stability of T.S. S > P > R > Q.
In compund R, T.S is stabilize by p-orbital
attached to carbon having leaving group.
23. The compound that does NOT liberate CO
2
, on
treatment with aqueous solium bicarbonate
solution is
(A) Benzoic acid (B) Benzenesulphonic acid
(C) Salicylic acid (D) Carbolic acid (Phenol)
Sol. D
Benzoic acid, Benzene sulphonic acid & salicylic
acid are more acidic than H
2
CO
3
so reaction
proceed in forward direction and release CO
2
but not phenol.
24. Consider the following complex ion P, Q and R
P = [FeF
6
]
3
, Q = [V(H
2
O)
6
]
2+
and
R = [Fe(H
2
O)
6
]
2+
The correct order of the complex ions, according
to their spin-only magnetic moment value (in B.M.) is
(A) R < Q < P (B) Q < R < P
(C) R < P < Q (D) Q < P < R
Sol. B
In all complex ligands are WFL
(P) [Fe F
6
]
3
Fe
+3
3d
5
4s 4p
sp d
3 2
M.M = 5(5 2) +
=
35
BM
(Q) [V(H
2
O)
6
]
2
V
+2


3d
2
4s 4p
d sp
2 3
M.M = + 3(3 2)
=
15
BM
(R) [Fe(H
2
O)
6
]
2
Fe
+2
3d
6
4s 4p

sp
3
d
2
M.M = 4(4 2) +
=
24
BM
Order of M.M Q < R < P
394,50 - Rajeev Gandhi Nagar Kota, Ph. No. : 93141-87482, 0744-2209671
IVRS No : 0744-2439051, 52, 53, www. motioniitjee.com , info@motioniitjee.com
6
25. In the reaction,
P + Q R + S
the time taken for 75%
reaction of P is twice
the time taken for 50%
reacti on of P. The
concentrati on of Q
varies with reaction
ti me as shown i n
figure. the overall order
of the reaction is

[Q]o
[Q]
Time
(A) 2 (B) 3 (C) 0 (D) 1
Sol. D
Linear variation of
conc. with time suggest
that it is zero order
reaction w.r.t. 'Q'
Q
Time
t
75%
= 2t
50%
I
st
ordes w.r.t. 'P'
Hence rate law expression
r = k[P]
1
[Q]
0
over all order = 1 + 0 = 1
26. Concentrated nitric acid, upon long standing,
turns yellow-brown due to the formation of
(A) NO (B) NO
2
(C) N
2
O (D) N
2
O
4
Sol. B
On long standing nitric acid decomposes as
HNO
3
H
2
O + NO
2
+ O
2
brown
& hence due to dissolved NO
2
it turns brown.
27. The arrangement of X

ioins around A
+
ion in
solid AX is given in the figure (not drawn to
scale). If the radius of X

is 250 pm, the radius of


A
+
is
(A) 104 pm
X

A
+
(B) 125 pm
(C) 183 pm
(D) 57 pm
Sol. A
This is ocathedral viod. with coordination
no. = 6

+
r
r
= 0.414 (In ideal octahedral void)
r
+
= 0.414 250 pm = 103.5 pm
28. Upon treatment with ammoniacal H
2
S, the metal
ion that precipitates as a sulfide is
(A) Fe(III) (B) Al(III) (C) Mg(II) (D) Zn(II)
Sol. D
Upon treatment with ammionical H
2
S
ZnS ppt as NH
4
OH + H
2
S in group reagent for
IV
th
group radicals.
29. Methylene blue, from its aqueous solution, is
adsorbed on activated charcoal at 25C. For this
process the correct statement is
(A) The adsorption requires activation at 25C.
(B) The adsorpti on i s accompani ed by a
decreases in enthalpy
(C) The adsorption increases with increase of
temperature.
(D) The adsorption is irreversible.
Sol. B
Adsorption is always exothermic.
30. Sulfide ores are common ofr the metals
(A) Ag, Cu and Pb (B) Ag, Cu and Sn
(C) Ag, Mg and Pb (D) Al, Cu and Pb
Sol. A
Ag
2
S Argentite/silver glance
Cu
2
S Chalcocite
PbS Galena
31. Benzene and naphthalene form an ideal solution
at room temeprature. For this process the true
statement(s) is (are)
(A) AG is positive (B) AS
system
is positive
(C) AS
surrounding
= 0 (D) AH = 0
Sol. B, C, D
(A) AG < 0 for mixing
(B) AS
sys
> 0 because disorder increases
(C) AS
surr
= 0 No heat is exchanged in case of
ideal Solution
(D) AH
mix
= 0 for ideal solution
32. The pair(s) of coordination complexes/ions
exhibiting the same kind of isomerism is(are)
(A) [Cr(NH
3
)
5
Cl
2
]
+
and [Cr(NH
3
)
4
Cl
2
]Cl
(B) [Co(NH
3
)
4
Cl
2
]
+
and [Pt(NH
3
)
2
(H
2
O)Cl]
+
(C) [CoBr
2
Cl
2
]
2
and [PtBR
2
Cl
2
]
2
(D) [Pt(NH
3
)
3
(NO
3
)]Cl and [Pt(NH
3
)
3
Cl]Br
Sol. B,D
(A) [Cr(NH
3
)
5
Cl]Cl
2
no isomerism
[Cr(NH
3
)
4
Cl
2
]Cl only geometrical isomersism
(B) [Co(NH
3
)
4
]Cl
2
]

only geometrical isomersism


[Pt(NH
3
)
2
(H
2
O)Cl]

only geometrical isomersism


(C) [CoBr
2
Cl
2
]
2
no isomerism because complex
is tetrahedral
[PtBr
2
Cl
2
]
2
only geometrical isomersism
(D) [Pt(NH
3
)
3
(NO
3
)]Cl only ionization isomerism
[Pt(NH
3
)
3
Cl]Br only ionization isomerism
33. The initial rate of hydrolysis of methyl acetate
(1M) by a weak acid (HA, 1M) is 1/100
th
of a
strong acid (HX, 1M) at 25C. The K
a
of HA is
(A) 1 10
4
(B) 1 10
5
(C) 1 10
6
(D) 1 10
3
Sol. A
r
1
= k[Acetate][H
+
]
HA
r
2
= k[Acetate][H
+
]
HX
394,50 - Rajeev Gandhi Nagar Kota, Ph. No. : 93141-87482, 0744-2209671
IVRS No : 0744-2439051, 52, 53, www. motioniitjee.com , info@motioniitjee.com
7
1 HA
2 Hx
r [H ] 1
r 100 [H ]
+
+
= =
(given)
a
cK
1
1M 100
=
a
1
cK
100
=
cK
a
= 10
4

,

K
a
=
4
10
c

= 1 10
4
34. The hyperconjugative stabilities of tert-butyl
cation and 2-butene, respectively, are due to
(A) o p (empty) and o t el ectron
delocalisations
(B) o o and o t electron delocalisations
(C) o p (fi l l ed) and o t el ectron
delocalisations
(D) p (fi l l ed) o and o t el ectron
delocalisations
Sol. A
C C H
H
H
CH
3
CH
3
vacant
p-orbital
It is o p(empty) electron delocalisation.
C C
H
H CH
3
H
H
H
C
It is o t electron delocalisation.
35. Among P,Q,R and S, the aromatic compound(s)
is/are
Cl
AlCl
3
P
Q
NaH
O O
(NH ) CO
4 2 3
100-115 C
HCl
R
S
O
(A) P (B) Q (C) R (D) S
Sol. ABCD
Cl
AlCl
3
P
Q
NaH
O O
(NH ) CO
4 2 3
100-115 C
HCl
R
S
+
Aromatic
Aromatic
Non aromatic
aldol condensation
Aromatic
OH
O
CH
3
CH
3
N
36. The total number of lone-pairs of electrons in
melamine is
Sol. 0006
N N
NH
2
H N
2
N
NH
2
Malamine
Lone pairs of electrons in malamine is 6.
37. The total number of carboxylic acid group in the
product P is
Sol. 0002
O
O
O
O
O
H O
3
2CO
2
Hydrolysis followed by
decarboxylation

O
O

O
3
H
2
O
2
oxidative ozonolysis

O
HOC
HOC
O
O
O
38. The atomic masses of He and Ne are 4 and 20
a.m.u. respectively. The value of the de Broglie
wavelength of He gas at 73 C is "M" times
that of the de Broglie wavelength of Ne at 727
C. M is
Sol. 0005
=
mkT 3
h

Ne
He

=
He He
Ne Ne
T . M
T . M
=
) 273 73 ( 4
) 273 727 ( 20
+
+
=
5 5
= 5
394,50 - Rajeev Gandhi Nagar Kota, Ph. No. : 93141-87482, 0744-2209671
IVRS No : 0744-2439051, 52, 53, www. motioniitjee.com , info@motioniitjee.com
8
PART - III [MATHEMATICS]
39. EDTA
4
is ethylenediaminetertraacetate ion. The
total number of NCoO bond angl es i n
[Co(EDTA)]
1
complex ion is
Sol. 0006
Co
O N
N O
O
O
1
6
4
3
2
5
octahedral compelx
total N CO O angle is 6
40. A tetrapeptide has COOH group on alanine. This
produces glycine (Gly), valine (Val), phenyl
alanine (Phe) and alanine (Ala), on complete
hydrolysis. For this tetrapeptite, the number of
possible sequencess (primary structures) with
NH
2
group attached to a chiral center is
Sol. 0004
Phe Gly Val Ala
Phe Val Gly Ala
Val Gly Phe Ala
Val Phe Gly Ala
(Glycile has no chiral centre)
SECTION A
Single Correct
41. The value of cot
|
|
.
|

\
|
|
|
.
|

\
|
+

= =

23
1 n
n
1 k
1
k 2 1 cot
is
(A)
25
23
(B)
23
25
(C)
24
23
(D)
23
24
Sol. B
cot
|
|
.
|

\
|
|
|
.
|

\
|
+

= =

23
1 n
n
1 k
1
k 2 1 cot
= cot
23
1
2
n 1
n 1 n
tan
1 n n)

=
| |
| | +
|
|
|
+ +
\ .
\ .

=
|
|
.
|

\
|
|
|
.
|

\
|
+ +
+

23
1 n
1
) 1 n ( n 1
n ) 1 n (
tan cot
=
|
|
.
|

\
|
+

=

23
1 n
1 1
n tan ) 1 n ( tan cot
= cot (tan
1
24 tan
1
(1))
= cot
|
.
|

\
|
+

1 24 1
1 24
tan
1
=
23
25
42. Let k

2 j

3 PR + =

and

SQ
= k

4 j

3 i


determine diagonals of a parallelogram PQRS and
k

3 j

2 i

PT + + =

be another vector. Then the


volume of the parallelepiped determined by the
vectors

PQ , PT
and

PS
is
(A) 5 (B) 20
(C) 10 (D) 30
Sol. C
Required volume
3 2 1
4 3 1
2 1 3
2
1


=
= 10
43. Let complex numbers o and
o
1
lie on circles
(x x
0
)
2
+ (y y
0
)
2
= r
2
and (x x
0
)
2
+
(y y
0
)
2
= 4r
2
, respectively. If z
0
= x
0
+ iy
0
satisfies the equation 2 |z
0
|
2
= r
2
+ 2, then
|o|=
(A)
2
1
(B)
2
1
(C)
7
1
(D)
3
1
Sol. C
o on |Z Z
0
| = r
|o Z
0
|
2
= r
2
o o o
o
Z
o
Z
0
+ |Z
0
|
2
= r
2
.....(1)
Similarly
o
1
on |Z Z
0
| = 2r

2
0
2
Z
| |

o
o
= 4r
2
4
| | o
o o

2
o
| |
Z
o
o

2
o
| |
Z
o
o
+ |Z
0
|
2
= 4r
2
2
2
| |
| |
o
o

0
(Z ) o
0
Z o + |Z
0
|
2
|o|
2
= 4r
2
|o|
2
...(2)
equation (1) (2)
(|o|
2
1| + |Z
0
|
2
(1 |o|
2
) = r
2
. (1 4 |o|
2
)
(|o|
2
1 (1 |Z
0
|
2
) = r
2
(1 4 |o|
2
)
394,50 - Rajeev Gandhi Nagar Kota, Ph. No. : 93141-87482, 0744-2209671
IVRS No : 0744-2439051, 52, 53, www. motioniitjee.com , info@motioniitjee.com
9
(|o|
2
1)
|
|
.
|

\
|
+

2
2 r
1
2
= r
2
(|4 |o|
2
)
(|o|
2
1)
2
r
2
| |

|
\ .
= r
2
(1 4|o|
2
)
1 |o|
2
= 2 8 |o|
2
7 |o|
2
= 1
|o| =
7
1
Use (Z
0
)
2
=
2
r
2
+ 1
44. For a > b > c > 0, the distance between (1, 1)
and the point of intersection of the lines ax + by
+ c = 0 and bx + ay + c = 0 is less than 2 2 .
Then
(A) a + b c > 0 (B) a b + c < 0
(C) a b + c > 0 (D) a + b c < 0
Sol. A
Point of intersection
c c
,
a b a b
| |
|
+ +
\ .
distance between P (1, 1) < 2 2
2
c
1
a b
| |
+
|
+
\ .
< 2 2
c + a + b < 2(a + b)
a + b c > 0
45. Perpendiculars are drawn from points on the line
3
z
1
1 y
2
2 x
=

+
=
+
to the plane x + y + z = 3. The
feet of perpendiculars lie on the line
(A)
13
2 z
8
1 y
5
x

=
(B)
5
2 z
3
1 y
2
x

=
(C)
7
2 z
3
1 y
4
x

= (D)
5
2 z
7
1 y
2
x
=

=
Sol. D
(2r2,r1), 3r
x+y+z=3
P
Q
Equation of PQ
1
) 2 r 2 ( x
=
y ( r 1)
1

=
1
r 3 z
=
Q ( + (2r 2), r 1, + 3r)
lies on x = x + y + z = 3
3 + 4r + 3 = 0
=
3
6 4 +
Q
|
.
|

\
| + +
3
6 r 5
,
3
3 r 7
,
3
r 2
so equation of image
2
x 3
=
7
3 y 3

=
5
6 z 3
2
x
=
7
1 y

=
5
2 z
46. Four persons independently solve a certain
problem correctly with probabilities
8
1
,
4
1
,
4
3
,
2
1
.
Then the probability that the problem is solved
correctly by at least one of them is
(A)
256
235
(B)
256
21
(C)
256
3
(D)
256
253
Sol. A
P(Problem is solved)=1 1/2 1/4 3/4 7/8
47. The area enclosed by the curves y = sin x + cos x
and y = |cos x sin x| over the interval (

t
2
, 0
is
(A) ) 1 2 ( 4 (B) ) 1 2 ( 2 2
(C) ) 1 2 ( 2 + (D) ) 1 2 ( 2 2 +
Sol. B
1
t/4
t/2 0
2
Area =
/ 4
0
(sinx cosx) (cosx sinx)]dx
t
+
}
= 4
}
t 4 /
0
dx x sin
= ) 1 2 ( 2 2 square unit
394,50 - Rajeev Gandhi Nagar Kota, Ph. No. : 93141-87482, 0744-2209671
IVRS No : 0744-2439051, 52, 53, www. motioniitjee.com , info@motioniitjee.com
10
48. A curve passes through the point
|
.
|

\
| t
6
, 1
. Let
the solpe of the curve at each point (x, y) be
x
y
+ sec
|
.
|

\
|
x
y
, x > 0. Then the equation of the
curve is
(A)
2
1
x log
x
y
sin + = |
.
|

\
|
(B)
2 x log
x
y
ec cos + = |
.
|

\
|
(C)
2 x log
x
y 2
sec + = |
.
|

\
|
(D)
2
1
x log
x
y 2
cos + = |
.
|

\
|
Sol. A
dx
dy
=
x
y
+ sec (
x
y
)
x
y
= v
v + x
dx
dv
= v + sec v
}
dv v cos
=
}
x
dx
sin (y/x) = ln x + c
passes through (1, t/6)
2
1
= c
sin (y/x) = log x + 1/2
49. Let f : (

1 ,
2
1
R (the set of all real numbers) be
a positive, non-constant and differentiable
function such that f'(x) < 2 f (x) and f
|
.
|

\
|
2
1
= 1.
Then the value of
}
1
2 / 1
) x ( f dx lies in the interval
(A) (2 e 1, 2e) (B) (e 1, 2e 1)
(C)
|
.
|

\
|

1 e ,
2
1 e
(D)
|
.
|

\
|
2
1 e
, 0
Sol. D
2
) x ( f
) x ( ' f
<
so
y
dy
< 2dx integrating
i.e. lny < 2x + c
f(x) < e
2x+c
also f(1/2) = 1 < e
1+c
Now }
1
2 / 1
dx ) x ( f
< }
+
1
2 / 1
c x 2
dx e
= e
1+c

|
.
|

\
|
2
1 e
Now, }
1
2 / 1
dx ) x ( f
will be less than minimum value
of e
1+c

|
.
|

\
|
2
1 e
which is
|
.
|

\
|
2
1 e
so }
1
2 / 1
dx ) x ( f
<
|
.
|

\
|
2
1 e
also f(x) > 0
so }
1
2 / 1
dx ) x ( f
> 0 so option D.
50. The number of points in ( , ), for which x
2

x sin x cos x = 0, is
(A) 6 (B) 4 (C) 2 (D) 0
Sol. C
f() ; f() =
f(0) = 1
f'(x) = x (2 cos x)
SECTION B
Multiple Correct
51. A rectangular sheet of fixed perimeter with sides
having their lengths in the ratio 8 : 15 is
converted into an open rectangular box by folding
after removing squares of equal area from all
four corners. If the total area of removed squares
is 100, the resulting box has maximum volume.
Then the lengths of the sides of the rectangular
sheet are
(A) 24 (B) 32 (C) 45 (D) 60
Sol. A,C
(8x 2y) (15x 2y). y
(120x
2
46xy + 4y
2
).y
4y
3
46xy
2
+ 120x
2
y
differentiate with respective y
12y
2
92xy + 120x
2
= 0
at y = 5
12.25 92x.5 + 120x
2
= 0
6x
2
23x + 15 = 0
x = 5/6, x = 3
maximum will be at x = 3
Ans. is 24 & 45
394,50 - Rajeev Gandhi Nagar Kota, Ph. No. : 93141-87482, 0744-2209671
IVRS No : 0744-2439051, 52, 53, www. motioniitjee.com , info@motioniitjee.com
11
52. Let S
n
=
=
+

n 4
1 k
2
) 1 k ( k
) 1 (
k
2
. Then S
n
can take
value(s)
(A) 1056 (B) 1088
(C) 1120 (D) 1332
Sol. A,D
S
n
= (1)
2
+ (1)
3
2
2
+ (1)
6
(3)
2
+ ......
S
n
= (1
2
2
2
+ 3
2
+ 4
2
) + (5
2
6
2
+ 7
2
+ 8
2
) +.....
....... + (4n 3)
2
(4n 2)
2
+ (4n 1)
2
+ (4n)
2
]
S
n
= E4n
2
+ E(4n 1)
2
E(4n 3)
2
E(4n 2)
2
S
n
= 32 En E12
S
n
= 16 n
2
+ 4n
S
n
= 4n (4n + 1)
53. A line l passing through the origin is perpendicular
to the lines
l
1
: (3 + t)
i
+ ( 1 + 2t) j

+ (4 + 2t)k

, < t <
l
2
: (3 + 2s)
i
+ (3 + 2s) j

+ (2 + s)k

, < s <
Then, the coordinate(s) of the point(s) on l
2
at
a distance of 17 from the point of intersection
of l and l
1
is (are)
(A)
|
.
|

\
|
3
5
,
3
7
,
3
7
(B) ( 1, 1, 0)
(C) (1, 1, 1) (D)
|
.
|

\
|
9
8
,
9
7
,
9
7
Sol. B,D
1 2 2
2 2 1
k

= 2
i
+ 3 j

2
k

so equation of l is
2
x
=
3
y

,
2
z
to find point of intersection
2
t 3 +
=
3
t 2 1 +
9 + 3t = 2 + 4t
7t = 7 t = 1
So A(2, 3, 2)
A.T.Q.
(2s + 1)
2
+ (2s + 6)
2
+ s
2
= 17, 9s
2
+ 28s + 20 = 0
9s
2
+ 18s + 10s + 20 = 0
(9s + 10) (s + 2) = 0
s =
9
10
, 2
so required points are
(1, 1, 0) &
|
.
|

\
|
9
8
,
9
7
,
9
7
so ans. B and D
54. Let f(x) = x sin tx, x > 0. Then for all natural
numbers n, f' (x) vanishes at
(A) a unique point in the interval
|
.
|

\
|
+
2
1
n , n
(B) a unique point in the interval
|
.
|

\
|
+ + 1 n ,
2
1
n
(C) a unique point in the interval (n, n + 1)
(D) two points in the interval (n, n + 1)
Sol. B
f(x) = x sin tx x > 0
then for all x x e n f'(x)
f''(x) = x cos t x n + sin tx 1 = 0
= tan tx =
x
t
period of tan tx = 1
so graph of tan tx
0 1/2 1
3/2 2
y=
y=tan x t
x t
55. For 3 3 matrices M and N, which of the following
statement(s) is (are) NOT correct ?
(A) N
T
M N is symmetric or skew symmetric,
according as M is symmetric or skew symmetric
(B) M N N M is skew symmetric for all symmetric
matrices M and N
(C) M N is symmetric for all symmetric matrices
M and N
(D) (adj M) (adj N) = adj (M N) for all invertible
matrices M and N
Sol. C,D
from the standard result
394,50 - Rajeev Gandhi Nagar Kota, Ph. No. : 93141-87482, 0744-2209671
IVRS No : 0744-2439051, 52, 53, www. motioniitjee.com , info@motioniitjee.com
12
SECTION C
Integer Answer Type
56. A vertical line passing through the point (h, 0)
intersects the ellipse
3
y
4
x
2 2
+ = 1 at the points P
and Q. Let the tangents to the ellipse at P and
Q meet at the point R. If A(h) = area of the
triangle PQR, A
1
=
1 h 2 / 1
max
s s
A(h) and A
2
=
1 h 2 / 1
min
s s
A(h), then
5
8
A
1
8A
2
=
Sol. 9
4
x
2
+
3
y
2
= 1 P is
|
|
|
.
|

\
|
|
|
.
|

\
|

4
h
1 3 , h
2
Q is
|
|
|
.
|

\
|
|
|
.
|

\
|

4
h
1 3 , h
2
T at P is
4
x
2
+
2
h
y 3 1
4
3
| |

|
\ . = 1 so R is =
h
4
so area of APQR =
2
1
. 2
|
|
.
|

\
|

4
h
1 . 3
2

|
.
|

\
|
h
h
4
=
2
3

h
) h 4 (
2 / 3 2

Now
dn
dA
< 0 so ft
n
is decreasing
so A
2
min A(h) = A(1) = 9/2

2
1
s h s 1
A
1
= min A(h) = A
1
2
| |
|
\ .
=
8
5 . 45

2
1
s h s 1 so
5
8
A, 8A
2
= 9
57. The coefficients of three consecutive terms of
(1 + x)
n + 5
are in the ratio 5 : 10 : 14. Then n =
Sol. 6
(1 + x)
n + 5
three consecutive terms
n + 5
C
r
:
n + 5
C
r + 1
:
n + 5
C
r + 2
= 5 : 10 : 14
) 1 r 5 n )( r 5 n (
! ) 5 n (
+ +
+
:
) 1 r 5 n )( 1 r (
) 5 n (
+ +
+
:

) 2 r )( 1 r (
) 5 n (
+ +
+
= 5 : 10 : 14
) 1 r 5 n )( r 5 n (
1
+ +
:
) 1 r 5 n )( 1 r (
1
+ +
:

) 2 r )( 1 r (
1
+ +
= 5 : 10 : 14
take two at a time
(i)
) 1 r 5 n )( r 5 n (
1
+ +
=
) 1 r 5 n )( 1 r (
1
+
= 5/10
r 5 n
1 r
+
+
=
10
5

2
1
r 5 n
1 r
=
+
+
3r = n + 3 ...(1)
(ii)
) 1 r 5 n )( 1 n (
1
+ +
=
) 2 r )( 1 r (
1
+ +
= 10 : 14
14
10
2 r
1
1 r 5 n
1
=
+
+
24 r = 10n +12
12r = 5n + 16 ...(2)
solve one (1) & (2)
12
6 n 5 +
=
3
3 n +
n = 6
58. Consi der the set of ei ght vectors
V = {
k

c j

a i

a + +
: a, b, c e { 1, 1}}. Three
non-coplanar vectors can be chosen from V in
2
p
ways. Then p is
Sol. 5
P = 5
pair of coplanar vector
1 1 1 1, 1, 1
1 1 1 1, 1, 1
1 1 1 1, 1, 1
1 1 1 1 : 1, 1
for one pair 6 possibilities
for four pair 2p possibilities
So No. n-coplaner vector
8
C
3
24 = 32
2
p
= 32
P = 5
59. Of the three independent events E
1
, E
2
and E
3
the probability that only E
1
occurs is o, only E
2
occurs is | and only E
3
occurs is . Let the prob-
ability p that none of events E
1
, E
2
or E
3
occurs
satisfy the equations (o 2|) p = o| and
(| 3)p = 2|. All the given probabilities are as-
sumed to lie in the interval (0, 1).
Then
3
1
E of occurrence of obability Pr
E of occurrence of obability Pr
=
394,50 - Rajeev Gandhi Nagar Kota, Ph. No. : 93141-87482, 0744-2209671
IVRS No : 0744-2439051, 52, 53, www. motioniitjee.com , info@motioniitjee.com
13
Sol. 6
E
1
& E
2
& E
3
independent
P(E
1
E
2
' E
3
') = o = E
1
E
2
' E
3
'
P(E
1
' E
2
E
3
') = | = E
1
' E
2
E
3
'
P(E
1
' E
2
' E
3
) = r = E
1
' E
2
' E
3
P(E
1
' E
2
' E
3
') = p = E
1
' E
2
' E
3
'
(o 2|) p = o| (| 3r) p = 2|r
(E
1
E
2
' E
3
' 2E
1
' E
2
E
3
') E
1
' E
2
' E
3
' = E
1
E
2
' E
3
' E
1
' E
2
E
3
'
E
1
E
2
' E
3
' 2E
1
' E
2
E
3
' = E
1
E
2
E
3
'
E
1
E
2
' 2E
1
' E
2
= E
1
E
2
2
2
E '
E

1
1
2E '
E
= 1
(E
1
' E
2
E
3
' 3E
1
' E
2
' E
3
) E
1
' E
2
' E
3
' = 2E
1
' E
2
E
3
'
E
1
' E
2
' E
3
E
1
' E
2
E
3
' 3E
1
' E
2
' E
3
= 2 E
2
E
1
' E
3
E
2
E
3
' 3E
2
' E
3
= 2E
2
E
3
3
3
E
' E

2
2
E
' E 3
= 2
3
3
E
' E
3
|
|
.
|

\
|
+
1
1
E
' E 2
1
= 2
b
b 1
3
|
.
|

\
|
+
a
) a 1 ( 2
1
= 2
b
b 1
3
a
) a 1 ( 6
= 2
b
1
1 3 6
|
.
|

\
|
1
a
1
= 2
b
1
1 3
a
6
+ 6 = 2
b
1

a
6
= 0
b
1
=
a
6

b
a
= 6
60. A pack contains n cards numbered from 1 to n.
Two consecutive numbered cards are removed
from the pack and the sum of the numbers on the
remaining cards is 1224. If the smaller of the
numbers on the removed cards is k, then k 20 =
Sol. 5
2
) 1 n ( n
k k 1 = 1224
2
) 1 n ( n +
2k 1 = 1224
2
) 1 n ( n +
2k = 1225
n(n + 1) 4k = 2450
n =
2
) 2450 k 4 ( 4 1 1 + +
=
2
k 16 9801 1 +
Now 9801+16k should be perfect square
99
2
+ 16k = a
2
so 16k = a
2
99
2
16k = (a 99) (a + 99)
at k = 25 a = 101
k 20 = 5

You might also like