S Gd&t Ngh an

K thi chn i tuyn d thi hsg quc gia lp 12

Nm hc 2006 - 2007
chnh thc

Mn thi: ha hc
Bn Thi gian 180 pht (khng k thi gian giao )
Ngy thi: 06/11/2006
chnh
( thi ny c 2 trang)
Cu I.
1, Tnh s oxi ha ring l ca cc nguyn t trong:
K2S2O3 ; K3[Cu(CN)4]; K3[Cr(OH)6]; Na2Cr2O11 .
2, Mt hp cht ha hc c tn l Beryl thnh phn gm c 31,3
%Si; 53,6% O , cn li l ca 2 nguyn t X, Y. Xc nh cng
thc ca Beryl di dng cng thc oxit kp v dng silicat kp.
Bit cu hnh electron nguyn t ca X, Y c electron cui
cng ng vi 4 s lng t sau:
X:

n=3

Y:

n=2

l=1
l=0

s= +

m=-1
m=0

s=

1
2

1
2

Cu II.
1, X, Y l 2 cht kh v c khng mu. Nung nng hai kh ny
trong bnh kn nhit cao v p sut cao, sau lm
lnh c cht rn A. Ha tan hon ton A vo nc c dung
dch B. Cho B tan trong dung dch kim hoc dung dch
axit li gii phng ra hai kh X, Y. Cho bit X, Y l cc kh g?
Cng thc v tn gi A, B? Cho bit trng thi lai ha ca
nguyn t trung tm trong X, Y. Vit cc phng trnh phn
ng.
2, Xc nh cc cht ng vi cc ch ci A, B, C, D, X, Y, Z, T, U
v hon thnh cc phng trnh phn ng theo s sau:
+B(kh)

A(kh) ---
(1)
+X(kh)

(4)

Y(kh) +Z(kh)
---

Lm

---
lnh
C(kh)
(2)

(3) +Mg ,
0
+U(kh) t /este

D(kh)

T(kh) ----- A (kh)

(6)

(5)

Bit cc cht kh c thnh phn nguyn t N, O, S, H v

chng l nhng hp cht v c.
Cu III.
1, Gii thch ti sao bc kim loi khng tc dng c vi dung
dch HCl m tc dng c vi dung dch HI gii phng
+
H2 . Bit E0 Ag Ag = +0,8V; Tch s tan ca AgCl v AgI ln l-

t l TAgCl = 10-9,75 v TAgI = 10-16 ; nng ca HCl , HI u

bng 1M.
2, 8200C hng s cn bng ca hai phn ng:
- CaO(r) + CO2 (kh)
CaCO3(r)
l k1 = 0,2
-
v C(r) + CO2 (kh)
2CO(kh)
l k2 =2,0
-

Ngi ta cho 1mol CaCO3 v 1 mol C vo bnh chn khng

22,4 lt, c gi 8200C . Hy tnh thnh phn ca h trng
thi cn bng? nhit 8200C s phn hy ca CaCO3 s
hon ton khi th tch bnh bng bao nhiu?
Cu IV
1, Ha tan a gam kim loi M bng mt lng va 200gam
dung dch HCl thu c dung dch mui c nng 11,96%
v 4,48 lt H2 (ktc)
a, Tnh a v xc nh M
b, M to ra c hp cht M' trong M c mc oxi ha +4.
M' c kh nng oxiha Br- , Cl- thnh cc n cht . M'
ch oxi ha Br- trong dung dch cha Cl- v Br- c cng
nng 1M th nn dng mi trng l H2SO4 c hay
long ? Gii thch ?
Cho bit: M+4 + 2e
M2+ E0 = +1,23V
Br2
+ 2e
2BrE0 = +1,07V
Cl2
+ 2e
2ClE0 = +1,36V
2, a. C mt pin trong xy ra phn ng:
Pb(r) + CuBr2 (dd 0,01M) PbBr2(r) + Cu(r)
Hy biu din pin theo h thng k hiu quy c v vit phng trnh xy ra mi in cc.
b. 250C sc in ng ca pin bng 0,442V th tch s
2+
tan ca PbBr2 (r) bng bao nhiu. Cho E 0 Pb Pb = -0,126V ;
2+

E0 Cu Cu = 0,34V
Cu V.
1, Cho cc phng
trnh phn ng vi h s ca 1 cht cho trc
t0 cao
nh sau:
a, 3MnO2 (A)0 + O2
t
b, MnO2 + 2NH3
(B) + N2 + H2O
t0
c, (D) + Na2CO
nng chy 2NaFeO2
+CO2
Pt 3
d, (E) + 7H2
NH3 + H2O
e,
(G)
+ H 2O
+ (H)

2Na2[Pb(OH)4]
+
Na2[Pb(OH)6]
Xc nh cng thc phn t ca A, B, C, D, E, G, H v cn
bng cc phng trnh phn ng.
2

2, Ha tan 11 gam Ba(NO3)2 vo 100gam H2O , nhit si ca

dung dch tng 0,4660C ; KS(H2O) = 0,51.
a, V sao kt qu thc t li cao hn tnh theo l thuyt.
b, Tnh in li ca Ba(NO3)2 trong dung dch .
Cho bit:
Be =9; Al =27; Si = 28 ; O = 16; Ag = 108; Cl =
35,5; I = 127;
C= 12; Ca = 40 ; Mn = 55; H = 1; Ba =
137 ; N =14; Br = 80;
Cu = 64; Pb = 207; Fe = 56, Zn = 65;
___________Ht___________
Th sinh khng c s dng bng Tun hon cc nguyn t ho
hc
H

tn:.......................................................................................

bo

danh: ....................................................