The Research of Lithium Battery

Characteristic and Charger Design

-1-

The Research of Lithium Battery

Characteristic and Charger Design

93 05 21
-2-

()
/ 92 2

()

()

-3-


( 92.6.17)

()

922

()

()

--------------------------------------------------------------------------

()

E9103020

()

()

93

21

1. ( http: //nr.stic.gov.tw/theses/html/authorize.html )

2. (106-36)
106 1702 (
:02-27377606 02-27377689)
3. 85 4 10 ()
89.11.21
4. 85.4.19 (85) 712

-4-

NI DAQ CARD
LABVIEW MATLAB

,
AC110220V , 250300mA ,
NT50 ,

DAQ CARDLABVIEWMATLAB

-5-

ABSTRACT
In view of the fact that the nowadays uses electronic products, for
example:cell phone, notebook, digiatal camera....And so on the product
all does take the li-ion battery as its energy originates, because the liion battery has the high energy density, the weight light, low internal
resistance, the cycle-index long, self-discharge rate is low and so on the
merit, because of initiates us to interest of the li-ion battery research.
This research is tests the li-ion battery the charge&discharge
characteristic, therefore in view of the battery voltage, the current, the
temperature and internal resistance four kind of parameters, penetrates
NI DAQ CARD to pick up the data, and to LABVIEW monitors each
kind of parameter, obtains the data, finally makes the numerical
analysis using MATLAB, Optimizes in order to .
The battery manages the monitor system mainly is different
monitors units by three the group to become, is battery voltage, the
current monitor units, another for temperature monitoring part. This
system slightly revises promptly may use to any battery controls and
monitors.
Then we each parameter which obtain in the basis, designs a input
voltage to be possible in AC110 220V, the charging current
approximately in during 250300 mA, simple also is cheap ( NT$50)
the li-ion handset battery charger, Is good after the actual test effect.
Key Words:LI-ION BATTERY, NI DAQ CADR,LABVIEW
-vi-

...

NSC-91-2213-E-270-006

-vii-

iii

iv

vi

vii

viii

xii

xiv

1-1
1-1-1
1-2

2
3

1-2-1

1-2-2

1-3

1-4

1-4-1

1-5

1-6

10

-viii-

1-6-1

12

1-6-2

13

1-7

14

1-8

15

1-9

16

1-9-1

17

1-9-2

17

1-10

18

1-10-1 OP1

20

1-10-2 OP2

20

1-10-3 OP3

21

1-11

21

LabView
2-1 LabView

23

2-2 LabView

24

2-3

27

2-3-1

27

2-3-2 / VIs

29

2-3-3 I / O VIs

30

2-3-4

31

2-3-5

32

MATLAB
3-1 MATLAB

36

3-2 MATLAB

36
-ix-

3-3

37

3-3-1

38

3-3-2

38

3-3-3

39

3-3-4

39

3-3-5

40

3-3-6

41

3-3-7 ()

41

3-3-8 ()

42

4-1

44

4-2

44

4-2-1

44

4-2-2

45

4-3

47

4-3-1 47
4-3-2 47
4-4

49

4-4-1

49

4-4-2

49

4-5

52

4-5-1

52

4-5-2

52

-x-

4-6

-xi-

54


1.1 2
1.2 (A)2
1.2 (B) 2
1.3 2
1.4 6
1.5 7
1.6 7
1.7 8
1.8 15
1.9 (a)LA25-NP 16
1.9 (b)LA25-NP 16
1.10 LA25-NP 16
1.11 17
1.12 18
1.13 AD590 19
1.14 AD590 19
2.1 26
2.2 27
2.3 31
2.4 31
2.5 32
2.6 32
-xii-

 2.7 33
2.8 33
2.9 34
2.10 35
2.11 /35
3.1 Matlab 37
3.2 38
3.3 38
3.4 39
3.5 40
3.6 40
3.7 41
3.8 42
3.9 42
4.1 46
4.2 15V2A / 46
4.3 / 48
4.4 12V 50
4.5 50
4.6 15W 50
4.7 53
4.8 54
4.9 55
4.10 () 55
-xiii-


1.1 4
1.2 8
1.3 () 11

xiv


1-1 :

NotebookPDAMobile phonePDA

260~270 kWh/m

-1-

100
90
80
70
60
(%) 50
40
30
20
10
0

1995 1996 1997 1998 1999 2000 2001 2002 2003

1.1

1-1-1 :

(A)
(B)
1.2 (A)(B)

1.3

-2-

:
1. electrode

2. electrolyte

3. film

4. shell

1-2 :

3 6.94 86
0.534

()
1%
-3-

3.6V
2.5V 7.2V 5V

z :
.
z :
.
z
z
z
z
z
z : Li-ion

1.

Li-ion
(V)

3.7

(Wh/L)

350

(Wh/kg)

120

(W/kg)

300

(cycles)

1000

-4-

1-2-1 :

1-2-2 :

IC

-5-

IC MOSFET
IC
MOSFET IC

1.4
MOSFET ONOFF
V+ e
IC b MOSFET

-6-

IC

1.5

V+()
e IC a
MOSFET

IC

1.6

1-3 :

500 500 80
-7-

 4.14.2V 3.2V

0.5C1C 90%

1-4 :

()

Reserve

()

1.7

1-4-1 :
1.2

(Ni-Cd)

1.2V

-8-

100-200Wh/L
45-65Wh/Kg

(Ni-MH)

1.2V

3.6V
(Li-ion)

3.6V
(Li-polymer)

Notebook
PDA
Notebook

200-350Wh/L
50-80Wh/Kg
200-350Wh/L
90-150Wh/kg
200-350Wh/L
90-150Wh/kg

1-5 :

1. (Primary battery):

2. (Rechargeable battery):

3. (Nominal Capacity): mAH AH-

4. (Nominal Voltage):

.
5. :

6. (Open circuit voltage OCV):

7. (Over discharge):
-9-


8. (Over charge):

9. (Constant current CC):

10. (Constant current CV):

11. (Energy density):

1-6 :

1995
1.3

NB/PC ( )Cellular
Phone ( )Camcorder ( )MD Player (
)PDAPHS NB/PC ( )
50%Cellular Phone ( )
31%

- 10 -

 1.3

2001

2002

2003

(%)

NB/PC

145286 166400 194480 51.1

PDA

2409

6854

13996

3.7

Cellular 106950 111540 118140 31.0

PHS

3840

3360

3000

0.8

Camcorder 19884

22275

24570

6.5

MD Player 17236

19958

23990

6.3

Others

2194

2243

2507

0.7

Total

297799 332630 380683 100.0

AGR

20.0%

11.7%

14.4%

NB/PC
18650 ( 18 mm 65 mm )

1996 Sony Energy Tech.

7.3%Matsushita 20%Moli Energy 33%
- 11 -

Sanyo 50%A&T Battery 75% Japan Storage

100%

10 mm

Sanyo
2003
2 1

1-6-1

- 12 -

 LiPF6LiClO4
LiSO4LiBF4

1-6-2

1.

- 13 -


600~800
CoNiFeAl
Li2O H2ONa2CO3 Li2CO3
Li2CO3 LiCoO2
2.:

30min ~ 120min
80%

1-7

- 14 -


LA25 NP( Sensor)AD590( Sensor)

1.8

1-8

()

- 15 -

1-9

LA25-NP (1.9)
1A
0.5 1A0.5
5mA

1.9 (a)LA25-NP

(b)LA25-NP

1.10 LA25-NP

M
( M )
100025 1A 25mA
100
40
40 100 M I = V M
I 1/40
- 16 -

1-9-1

1879
Lorentz Force

(sensor)

1-9-2

1.11

Ic
1.11BFL

- 17 -

VH

1.12

1.12

B B= I*(u/l) ( )
I

1-10

AD590 IC 1A/k

100M

AD590
- 18 -

-55~150 C 4~30V

IC
AN6701S AD590

1.14 AD590

1.15

AD590

OP1(OP741)
- 19 -

OP2(OP741) 2.73V
OP3(OP741)

AD590 AD590 Sensor

1.15

1-10-1 OP1

1.15 AD590 1K 1
A 0 273.2K
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9K 2K

25 0
273.2A + 25A = 298.2A 10K
2.982 V298.2A* 10K = 2.982V

1-10-2 OP2

1.15 0 OP1 2.732 V

- 20 -

 1 0.01V OP2 20K

20K 0 2.732 V
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OP3 10 0.1
LabVIEW 10
OP3 DAQ DAQ
( DAQ 6024E 10V10V)
DAQ OP3

1-11

:
a

- 21 -

RE
VE
VZ
I

- 22 -

 LabView
2-1 LabView

LabVIEW(Laboratory Virtual Instrument Engineering Workbench)

National Instrument 1986
GLabVIEW
(Virtual Instrument)
DAQ(Data Acquisition)
(Image Acquisition)
LabVIEW C BASIC
LabVIEW
LabVIEW

LabVIEW
LabVIEW
CC++
LabVIEW

LabVIEW (Breakpoint)
(Single-Step)

(Auto Debugging)
LabVIEW
- 23 -


LabVIEW

Front Control Panel

2-2 LabView

LabVIEW

Front Panel( 2.1)

Block Diagram
( 2.2)Icon/Connector

Controls
Indicators

VI
- 24 -

LabVIEW
VI
Sub VISubroutine

Terminal Sub VI
Temperature VI

LabVIEW
VI

VI
VI
InputOutput

Sub VI

LabVIEW
- 25 -

(Block Diagram)LabVIEW

VIs

LabVIEW

2.1

- 26 -

 2.2

2-3 :
2-3-1 :

: X Y

: X Y
true
false

: X Y 1
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- 27 -

: X 1 false 0
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1000
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2-3-2 / VIs

1. Write Characters To File

character string
*txt new fie path
append to file
True

2.Read Characters From File

- 29 -

2-3-3 I / 0 VIs

1.Write to Digital Port

Write to Digital Port 8bits

Device DAQ Pettern
Port Width

2.AI Acquire Wavefroms VIS

AI Acquire Wavefroms
Channels DAQ-BOX
Device DAQ Sample Rate
Number Waveform
data

- 30 -

2-3-4

( 2.3)

2.3

2.4
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2.5

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(2)
(3)

2.6
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BOX Digital

2.7

for loop
STOP
SUB VI

2.8

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2.8
SUB VI
2.8 channels
file path() waveform() SUB VI

2.9

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( 2.9) 2.10 2.10

(1)
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2.10(2) DAQ-BOX

(2)
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2.11 /
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MATLAB
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laboratory

for...next
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Jack Little C
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4.2

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250
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400

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350
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3.3
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400

500

600

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3-3-3

4.2

4.1

3.9

3.8

3.7

3.6

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100
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200

250

3.4

3.4

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3-3-4
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32

31

T( )

30

29

28

27

26

100

200

300
t (unit 1 minute)

400

500

600

3.5

(
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3-3-5

4.2

3.8

3.6

3.4

3.2

2.8

2.6

2.4

20

40

60

80
100
t (unit 1 minute)

3.6
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120

140

160

180

 3.6 ()()

0.6V 3.4V

3-3-6 ()

3.7

42Vcutoff
(
3.7)

3-3-7 ()
- 41 -

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3.8
0.5 m

3-3-8 ()
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1
2
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3.5

Voltage (V)

2.5

1.5

0.5

20

40

60

80
100
time / 1 min

120

3.9
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140

160

180

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4-1

TOPSwitch TOPSwitch

4-2

4-2-1

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3 LM2937LM2991

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- 54 -

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- 55 -


1. National Instruments,Labview Basics Course Manual,
1999.
2. National Instruments,DAQ 6023E/6024E/6025E User
Manual,1999.
3. ,LabVIEW,
,2002.
4. ,LabVIEW,
,1998.
5.,,, LabVIEW ,
,2001.
6.,, 126 ,86 6
.
7.,, 117
,85 9 .
8.,
, 126 ,86 6 .
9.,,,
66 ,81 6 .
10., 131 ,86 11
.
11.,,,, MATLAB 6.X ,

12.,, 138
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,87 6 .
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Mission ,Proceedings of the 32nd Intersociety Energy

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34. , , ,
29 ,pp.97-102,1993.
35.Power Integrations ,2000.
36., ,
- 59 -

,2000(12).
37., ,,2000(2)

- 60 -

COMPUTER
LABVIEW

MATLAB

MATLAB
Plot

NO

DD
Digital

Data

test

Digital Output

Digital

Take in

Error

Save

DATA

- 61 -

 DAQ Card-6024E /

68
34
67
33
66
32
65
31
64
30
63
29
62
28
61
27
60
26
59
25
58
24
57
23

ACH0
ACH8
AIGND
ACH1
ACH9
AIGND
ACH2
ACH10
AIGND
ACH3
ACH11
AIGND
AISENSE
ACH4
ACH12
AIGND
ACH5
ACH13
AIGND
ACH6
ACH14
AIGND
ACH7
ACH15

12
46
13
47
14
48
15
49
16
50
17
51
18
52
19
53
20
54
21
55
22
56

DGND
SCANCLK
DGND
DIO3
+5V
DIO7
DGND
DIO2
DIO6
DGND
DIO1
DIO5
DGND
DIO0
DIO4
DGND
RESERVED
AOGND
DAC1OUT
AOGND
DAC0OUT
AIGND

- 62 -

1
FREQ_OUT
35
DGND
2
GPCTR0_OU
T
36
DGND
3
PFI9/GPCTR
0
_GATE
37
PFI8/GPCTR
0
_SOURCE
4
DGND
38
PFI7/STARTS
CAN
5
PFI6/WFTRI
G
39
DGND
6
PFI5/UPDAT
E
40
GPCTR1_OU
T
7
DGND
41
PFI4/GPCTR
1
_GATE
8
+5V
42
PFI3/GPCCT
R1
_SOURCE
9
DGND
43
PFI2/CONVE
RT
10
PFI1/TRIG2
44
DGND
11
PFI0/TRIG1
45
EXTSTROBE

DAQ BOX SCB-68 Board

AIGND
ACH<0~15>

AISENSE
DAC0OUT
DAC1OUT
AOGND
DGND

DIO<0~7>
+5V
SCANCLK
EXTSTROBE
PFI0/TRIG1

PFI1/TRIG2

(AIGND
AOGNDDGND)
ACH0~ACH15 16
ACH<i,i+8> (i=0~7)

0 0

1 1

AIGNDDGND

+5V AIGNDAOGND

DIO6 DIO7
01
+5V

PFI0/Trigger1
(PFIs)PFI

PFI2/Trigger2
PFIs
- 63 -


TRIG2
PFI2/CONVERT PFIs

/
PFI3/GPCTR1 PFI3/Counter1 Source PFIs
_SOURCE

1
PFI4/GPCTR1 PFI4/Counter1 Gate PFIs
_GATE

GPCTR_GATE
1
GPCTR1_OUT Counter1 Output 1

PFI5/UPDATE PFIs

6024E
6025E


PFI6/WFTRIG PFI6/Waveform Trigger PFIs

PFI7/STARTSCAN PFI7/Start of Scan PFIs

PFI8/GPCTR PFI8/Counter0 Source PFIs

_SOURCE

0
PFI9/GPCTR PFI9/Counter0 Gate PFIs
_GATE

- 64 -

GPCTR0_OUT
FREQ_OUT

0
Counter0 Output 0

Frequency Output

Measurement & Automation Explorer

Measurement & Automation Explorer
MAX MAX National Instruments (NI)
NI DAQ, GPIB, IMAQ, IVI,
Motion, VISA, and VXI

NI

- 65 -

 DAQ BOX

DAQ BOX DAQ

My System Devices and Interfaces

DAQ, GPIB,
IMAQ, IVI, Motion, VISA, and VXI Devices and
Interfaces PCI-6024E
Test Panel DAQ BOX

Analog InputAnalog Output

Counter I/ODigital I/O
Analog Input 0~15

- 66 -

 Channel
DAQ
Average Reading

- 67 -