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PHYSICAL CHEMISTRY

PHYSICAL CHEMISTRY
by:

By: Shailendra Kumar

SHAILENDRA KR.

Meq. Approach

Classes at: SCIENCE TUTORIALS; Opp. Khuda Baksh Library, Ashok Rajpath, Patna
PIN POINT STUDY CIRCLE; House No. 5A/65, Opp. Mahual Kothi, Alpana Market, Patna

Confidence building Problems


1. The radius of Bohrs first orbit in H atom is 0.053 nm. The radius of second orbit in He+ would be: (a) 2. 0.0265 nm (b) 0.0530 nm (c) 0.1060 nm (d) 0.2120 The ionization potential of hydrogen atom is 13.6 eV. The energy required to remove an electron from the n = 2 state of hydrogen atom is: (a) 3. 27.2 eV (b) 13.6 eV (c) 6.8 eV (d) 3.4 eV The energy of the electron in second Bohrs orbit in the hydrogen atom is 3.41 eV. The energy of the electron in second Bohrs orbit of He+ ion would be: (a) 4. -85 eV (b) -13.62 eV (c) -1.70 eV (d) -6.82 eV The ratio of the energy of a photon of 2000 wavelength radiation to that of 4000 radiation is: (a) 5. 1/4 (b) 1/2 (c) 2 (d) 4 The Bohrs energy equation for H atom reveals that the energy level of a shell is given by E = 13.58/n2 eV. The smallest amount that an H atom will absorb if in ground state is: (a) 6. 1.0 eV (b) 3.39 eV (c) 6.79 eV
2+

(d)

10.19 eV

The amount of energy required to remove the electron from a Li ion in its ground state is how many times greater than the amount of energy required to remove the electron from an H atom in its ground state? (a) 9 (b) 2 (c) 3 (d) 5 If the ionisation potential for hydrogen atom is 13.6 eV, then the wavelength of light required for the ionisation of hydrogen atom would be: (a) 1911 nm (b) 912 nm (c) 68 nm (d) 91.2 nm The ratio between kinetic energy and the total energy of the electrons of hydrogen atom according to Bohrs model is: (a) 1 : 1 3R (b) (b) 1:1 9R (c) (c) 1:2 2.25R (d) (d) 2:1 R/3 The radius of second stationary orbit in Bohrs atoms in R. The radius of third orbit will be: (a) If the series limit of wavelength of the Lyman series for the hydrogen atom is 912 , then the series limit of wavelength for the Balmer series of the hydrogen atom is: (a) 912 (b) 912 2 (c) 912 4 (d) 912/2
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Opp. Khuda Baksh Library, Ashok Rajpath, Patna - 4 House no. 5A/65, Opp. Mahual Kothi, Alpana Market, Patna

PHYSICAL CHEMISTRY
11.

By: Shailendra Kumar

The number of milliliter of 1M H2SO4 solution required to neutralize 10 ml of 1 M NaOH solution is (a) 2.5 ml (b) 5.0 ml (c) 10.0 ml (d) 20.0 ml The volume of water which must be added to 40 cc of 0.25 N oxalic acid solution to make its exactly decinormal is (a) 40 cc (b) 30 cc (c) 60 cc (d) 25 cc 0.115 ml of sodium metal was dissolved in 500 ml of the solution in distilled water. The normality of the solution would be (a) 0.010 N (b) 0.0115 N (c) 0.023 N (d) 0.046 N 100 cc of 0.5 N NaOH solution is added to 10 cc of 3 N H2SO4 solution and 20 cc of 1N HCl solution. The solution will be (a) Strongly acidic (b) Alkaline (b) 10 N (c) Neutral (c) 1.7 N (d) Fairly acidic (d) 0.83 N The normality of 10 % acetic acid is (a) 1 N H3PO4 is the tribasic acid and one of its salts is NaH2 PO4. What volume of 1 M NaOH should be added to 12 gm NaH2 PO4 (Mol. wt = 120) to exactly converted it into Na3 PO4? (a) 100 cc (b) 300 cc (b) 4.9 gm
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(c) 200 cc (c) 10 gm

(d) 80 cc (d) 2.45 gm

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For preparation of one liter of H2SO4 solution we need H2SO4 equal to (a) 98 cm The average concentration of Na in Human blood serum is about 3.4 gm/liter. What is molarity of Na+ (a) 0.15 (b) 2.3 (c) 15.0 (d) 1.5 H2O2 solution used for hair bleaching is sold as a solution of approx 5.0 gm H2O2 per 100ml of solution ( Mol-wt of H2O2=34). The molarity of this hair bleaching solution is approximately (a) 3.0 (b) 1.5 (b) 18 M (c) 0.15 (c) 10 M (d) 4.0 (d) 2 M The molarity of 98% H2SO4 by weight (d = 1.8 gm/ml) would be (a) 4 M

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01. 06. 11. 16. c a b c 02. 07. 12. 17. d d c b

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03. 08. 13. 18.

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04. 09. 14. 19. c c c b 05. 10. 15. 20. d c c b

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PHYSICAL CHEMISTRY

PHYSICAL CHEMISTRY
by:

By: Shailendra Kumar

SHAILENDRA KR.

Meq. Approach

Classes at: SCIENCE TUTORIALS; Opp. Khuda Baksh Library, Ashok Rajpath, Patna
PIN POINT STUDY CIRCLE; House No. 5A/65, Opp. Mahual Kothi, Alpana Market, Patna

Confidence building Problems


1. 2. The number of molecules in 4.25 g of ammonia is approximately: (a) 3.5 1023 (b) 1.5 1023 (c) 0.5 1023 One mole of P4 molecules contain: (a) 1 molecules 3. 4. (b) 4 molecules (c)
1 4

(d) 2.5 1023

6.022 1023 atoms (d) 24.088 1023 atoms is :


22

The total number of protons, electrons and neutrons in 12 g of


25 23

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(a) 1.084 10 (b) 6.022 10 (c) 6.02210 (d) 18 The number of atoms in 558.5 g of Fe (at. wt. 55.85) is: (a) twice than in 60 g carbon (b) 6.022 1022 (c) Half in 8 g He (d) 558.5 6.023 1023 The volume of 20 g of H2 at STP is : 12 (c) 2.24 litre (a) 224 litre (b) 22.4 litre (d) 112 litre n 100 6 C gg 1 mole of any gas: 2n (b) always occupies 22.4 litre (a) always occupies 1 litre (c) can occupy any volume at NTP (d) always occupies a fixed volume at NTP The equivalent weight of H3PO4 in the following reaction is: H3PO4 + Ca(OH)2 CaHPO4 + 2H2O (a) 98 (b) 49 (c) 32.66 (d) 40 20 g of an acid furnishes 0.5 moles of H3O+ ions in its aqueous solution. The value of 1 g eq. of the acid will be: (a) 40 g (b) 20 g (c) 10 g (d) 100 g How many moles of magnesium phosphate, Mg3(PO4)2 will contain 0.25 mole of oxygen atoms? (a) 0.02 (b) 3.125 102 (c) 1.25 102 (d) 2.5 102 When 100 g of ethylene polymerizes to polyethylene according to the equation, nCH2 == CH2 ( CH2CH2 )n. The weight of polyethylene produced will be: (a) (b) 100 g (c) (d) 100n g

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A mixture containing 100 g H2 and 100 g O2 is ignited so that water is formed according to the reaction, 2H2 + O2 2H2O; How much water will be formed? (a) 113 g (b) 50 g (c) 25 g (d) 200 g The pair of species having same percentage of carbon is: (a) CH3COOH and C6H12O6 (b) CH3COOH and C2H5OH (c) HCOOCH3 and C12H22O11 (d) C6H22O11 and C12H22O11

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PHYSICAL CHEMISTRY
13.

By: Shailendra Kumar

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Polyethylene can be produced from calcium carbide according to the following sequence of reaction; CaC2 + H2O CaO + HC CH nHC CH + nH2 ( CH2CH2 )n The mass of polyethylene which can be produced from 20.0 kg of CaC2 is: (a) 6.75 kg (b) 7.75 kg (c) 8.75 kg (d) 9.75 kg The normality of 4% (wt./vol.) NaOH is: (a) 0.1 (b) 1.0 (c) 0.05 (d) 0.01 10 mL of concentrated H2SO4 (18 M) is diluted to one litre. The approximate stregth of the dilute acid is: (a) 18 M (b) 180 M (c) 0.18 M (d) 1.8 M 34 g of hydrogen peroxide is present in 1120 mL of solution. This solution is called: (a) 10 vol solution (b) 20 vol solution (c) 30 vol solution (d) 32 vol solution The volume occupied by one molecule of water (density 1 g cm3) is: (a) 18 cm3 (b) 22400 cm3 (c) 6.023 1023 cm3 (d) 3.0 1023 cm3 50 mL of an aqueous solution of glucose contains 6.02 1022 molecules. The concentration of solution is: (a) 0.1 M (b) 1.0 M (c) 0.2 M (d) 2.0 M The percent of N in 66% pure (NH4)2SO4 sample is: (a) 32 (b) 28 (c) 14 (d) none of these The number of moles of water present in 90 g of a water is: (a) 2 (b) 3 (c) 4 (d) 5 Weight of a single molecule of water is: (a) 3.0 1023 g (b) 6.02 1023 g (c) 6.02 1023 g (d) None of these How many atoms are contained in a mole of Ca(OH)2 ? (a) 30 6.02 1023 atom / mol (b) 5 6.02 1023 atom / mol 23 (c) 3 6.02 10 atom / mol (d) None of the above The solution A and B are 0.1 and 0.2 molar in a substance. If 100 mL of A are mixed with 25 mL of B and there is no change in volume, then the final molarity of the solution is: (a) 0.15 M (b) 0.18 M (c) 0.12 M (d) 0.30 M How many atoms are present in a mole of CH3COOC2H5 ? (a) 14 6.02 1023 atom/mol (b) 10 6.02 1023 atom/mol 23 (c) 7 6.02 10 atom/mol (d) None of the above The reaction, 2C + O2 2CO2 is carried out by taking 24 g carbon and 96 g O2. Which one is limiting reagent? (a) C (b) O2 (d) CO2 (d) None of these The weight of 350 mL of a diatomic gas at 0C and 2 atm pressure in 1 g. The weight of one atom is: (a) 16/N (b) 32/N (c) 16N (d) 32N (N is the av. no.) In a compound C, H, N atoms are present in 9 : 1 : 3.5 by weight. Molecular weight of compound is 108, its molecular formula is: (a) C2H6N2 (b) C3H4N (d) C6H8N2 (d) C9H12N3 In a gaseous reaction of the type aA + bB cC + dD, which is wrong. (a) a litre of A combines with b litre of B to give C and D (b) a mole of A combines with b mole of B to give C and D (c) a g of A combines with b g of B to give C and D (d) a molecules of A combines with b molecules of B to give C and D For the reaction, A + 2B C, 5 moles of A and 8 moles of B will produce (a) 5 moles of C (b) 4 moles of C (c) 8 moles of C (d) 13 moles of C

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01. 06. 11. 16. 21. 26. b d a a a a 02. 07. 12. 17. 22. 27. d b a d b c

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03. 08. 13. 18. 23. 28.

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a a c d c c

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04. 09. 14. 19. 24. 29. a b b c a b 05. 10. 15. 20. 25. a b c d a

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PHYSICAL CHEMISTRY

PHYSICAL CHEMISTRY
by:

By: Shailendra Kumar

SHAILENDRA KR.

Meq. Approach

Classes at: SCIENCE TUTORIALS; Opp. Khuda Baksh Library, Ashok Rajpath, Patna
PIN POINT STUDY CIRCLE; House No. 5A/65, Opp. Mahual Kothi, Alpana Market, Patna

Confidence building Problems


1. 2. Hydrogen ion concentration in mol/L in a solution of pH = 5.4 will be: (a) 3.98 108 (b) 3.88 106 (c) 3.68 108 (d) 3.98 106 5 If the dissociation constant of an acid HA is 1 10 , the pH of a 0.1 M solution of the acid HA will be approximately : (a) 3 (b) 5 (c) 1 (d) 6 The pH of a solution is 5.0. To this solution sufficient acid is added to decrease the pH to 2.0. The increase in hydrogen ion concentration is : (a) 1000 times (b) 5/2 times (c) 100 times (d) 5 times When the pH of a solution is 2. The hydrogen ion concentration is: (b) 1 102 M (c) 1 107 M (d) 1 1012 M (a) 1 1014 M 1 The pH of the solution obtained by mixing 10 mL of 10 N HCl and 10 mL of 101 N NaOH is: (a) 8 (b) 2 (c) 7 (d) None of these Which addition would not change the pH of 10 mL of dilute hydrochloric acid ? (a) 20 mL of the same dilute hydrochloric acid (b) 5 mL of pure water (c) 20 mL of pure water (d) 10 mL of concentrated hydrochloric acid At 90C, pure water has [H3O+] = 106 mol/litre. The value of Kw at 90C is: (a) 106 (b) 1012 (c) 1014 (d) 108 0.4 g of NaOH present in one litre solution shows the pH: (a) 12 (b) 2 (c) 6 (d) 10 pH of a 108 M solution of HCl in water is: (a) 8 (b) 8 (c) Between 7 and 8 (d) Between 6 and 7 When 1.0 mL of dil. HCl acid is added to 100 mL of a buffer solution of pH 4.0, the pH of the solution: (a) Becomes 7 (b) Does not change (c) Becomes 2 (d) Becomes 10 The gastric juice in our stomach contains enough hydrochloric acid to make the hydrogen ion concentration about 0.01 mol/litre. The pH of the gastric juice is: (a) 0.01 (b) 1 (c) 2 (d) 14 A certain buffer solution contains equal concentration of X and HX. The Kb for X is 1010. The pH of the buffer is: (a) 4 (b) 7 (c) 10 (d) 14 106 M HCl is diluted to 100 times. Its pH is: (a) 6.0 (b) 8.0 (c) 6.95 (d) 9.5 An aqueous solution contains a substance which yields 4 103 mol litre1 ion of H3O+. If log 2 = 0.3010, the pH of the solution is: (a) 1.5 (b) 2.398 (c) 3.0 (d) 3.4 The pH of 1% ionised 0.1 M, solution of a weak monoprotic acid is: (a) 1 (b) 2 (c) 3 (d) 11 A monoprotic acid in 1.00 M solution is 0.01% ionized. The dissociation constant of this acid is: (a) 1 104 (b) 1 106 (c) 1 108 (d) 105

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PHYSICAL CHEMISTRY
17.

By: Shailendra Kumar

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50 mL of 2 N acetic acid mixed with 10 mL of 1N sodium acetate solution will have an approximate pH of (Ka = 105): (a) 4 (b) 5 (c) 6 (d) 7 A monoprotic acid in 1.00 M solution is 0.001% ionized. The dissociation constant of this acid is: (a) 1.0 103 (b) 1.0 103 (c) 1.0 108 (d) 1.0 1010 0.2 molar solution of formic acid is 3.2% ionized. Its ionization constant is: (a) 9.6 103 (b) 2.1 104 (c) 1.25 106 (d) 4.8 105 The pH of a 1 108 M aqueous solution of HCl is slightly less than 7 because: (a) The ionization of HCl is incomplete (b) The ionization of water is negligible (c) The ionization of water at such a low concentration of HCl is significant (d) The ionization of both HCl and water are negligible One litre of water contains 107 mole H+ ions. Degree of ionization of water is: (a) 1.8 107 % (b) 1.8 109 % (c) 3.6 107% (d) 3.6 109 % pKa values of four acids are given below at 25C. The strongest acid is: (a) 2.0 (b) 2.5 (c) 3.0 (d) 4.0 The pH of a simple sodium acetate and acetic acid buffer is given by, pH = pKa + log Ka of acetic acid = 1.8 105. If [Salt] = [Acid] = 0.1 M, the pH of the solution would be about: (a) 7 (b) 4.7 (c) 5.3 (d) 1.4 The pH of a 0.02 M ammonia solution which is 5% ionized will be: (a) 2 (b) 5 (c) 7 (d) 11 Which solution will have pH closer to 1.0 ? (a) 100 mL of (M/10) HCl + 100 mL of (M/10) NaOH (b) 55 mL of (M/10) HCl + 45 mL of (M/10) NaOH [Salt] (c) 10 mL of (M/10) HCl + 90 mL of (M/10) NaOH (d) 75 mL of (M/5) HCl + 25 mL of (M/5) NaOH [Acid] The number of mole of hydroxide [OH] ion in 0.3 litre of 0.005 M solution of Ba(OH)2 is: (a) 0.0075 (b) 0.0015 (c) 0.0030 (d) 0.0050 A 0.01 M ammonia solution is 5% ionized. The concentration of [OH] ion is: (a) 0.005 M (b) 0.0001 M (c) 0.0005 M (d) 0.05 M 0.04 g of pure NaOH is dissolved in 10 litre of distilled water. The pH of the solution is: (a) 9 (b) 10 (c) 11 (d) 12 A certain weak acid has a dissociation constant 1.0 104. The equilibrium constant for its reaction with a strong base is: (a) 1.0 104 (b) 1.0 1010 (c) 1 1010 (d) 1.0 1014 5 If Ka for a weak acid is 10 . pKb value of its conjugate base is: (a) 5 (b) 6 (c) 7 (d) 9 A buffer mixture of acetic acid and potassium acetate has pH = 5.24. The ratio of [CH3COO] / [CH3COOH] in this buffer is, (pKa = 4.74): (a) 3 : 1 (b) 1 : 3 (c) 1 : 1 (d) 1 : 2

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01. 06. 11. 16. 21. 26. 31. d a c c a c a 02. 07. 12. 17. 22. 27. a b a a a c

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03. 08. 13. 18. 23. 28.

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a a c d b b

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04. 09. 14. 19. 24. 29. b d b b d c 05. 10. 15. 20. 25. 30. c b c c d d

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PHYSICAL CHEMISTRY

PHYSICAL CHEMISTRY
by:

By: Shailendra Kumar

SHAILENDRA KR.

Meq. Approach

Classes at: SCIENCE TUTORIALS; Opp. Khuda Baksh Library, Ashok Rajpath, Patna
PIN POINT STUDY CIRCLE; House No. 5A/65, Opp. Mahual Kothi, Alpana Market, Patna

Confidence building Problems


01. 02. Assume that the nucleus of the F atom is a sphere of radius 5 10-13 cm. Calculate the density of matter in F nucleus. [ Ans.: 6.02 1013 g mL1] A metal M of atomic weight 54.94 has a density of 7.42 g/cm3. Calculate the volume occupied and the radius of the atom of this metal assuming it to be sphere. [ Ans.: radius = 1.432 108 cm, volume = 1.23 1023cm3] 03. 04. 1.60 g of a metal were dissolved in HNO3 to prepare its nitrate. The nitrate was strongly heated to give 2 g oxide. Calculate equivalent weight of metal. [ Ans.: 32 ] Find the milli equivalent of : (a) Ca(OH)2 in 74 g (b) NaOH in 20 g (c) H2SO4 in 2.45 g

[ Ans.: (a) 2000 (b) 500 (c) 50 ] 05. 06. 07. Find the weight of NaOH in its 50 milli equivalents. Find the weight of H2SO4 in 1200 mL of a solution of 0.2 N strenght. [Ans.: 2 g ] [Ans.: 11.76 g]

Calculate the amount of calcium oxide required when it reacts with 852 g of P4O10 .[ IIT 2005] [ Ans.: 1008 g ]

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What weight of Na2CO3 of 95% purity would be required to neutralize 45.6 mL of 0.235 N acid . [Ans.: 0.5978 g ] How many millilitre of 0.5 M H2SO4 are needed to dissolve 0.5 g of copper II carbonate? [ IIT 1999] [Ans.: V = 8.097 mL ]

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What is the strength in g per litre of a solution of H2SO4 , 12 mL of which neutralized 15 mL of N/10 NaOH solution? [Ans.: 6.125 g/litre] The formula weight of an acid is 82.0. 100 cm3 of a solution of this acid containing 39.0 g of the acid per litre were completely neutralized by 95.0 cm3 of aqueous NaOH containing 40.0 g of NaOH per litre. What is the basicity of the acid? [ROORKEE 2000] [Ans.: Acid is dibasic]

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PHYSICAL CHEMISTRY
12. 13.

By: Shailendra Kumar

Calculate the normality of the resulting solution made by adding 2 drops (0.1 mL) of 0.1 N H2SO4 in 1 litre of distilled water. [ Ans.: N = 105] What volume at NTP of ammonia gas will be required to be passed into 30 mL of N H2SO4 solution to bring down the acid normality to 0.2 N ? [UPSEAT 1991] [Ans.: 537.6 mL]

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Two litre of NH3 at 30C and 0.20 atmosphere is neutralized by 134 mL of a solution of H2SO4 . Calculate normality of H2SO4 . [Ans.: N = 0.12 ] Calculate normality of mixture obtained by mixing: (a) 100 mL of 0.1 N HCl + 50 mL of 0.25 N NaOH (b) 100 mL of 0.2 M H2SO4 + 200 mL of 0.2 M HCl (c) 100 mL of 0.2 M H2SO4 + 100 mL of 0.2 M NaOH (d) 1 g equivalent of NaOH + 100 mL of 0.1 N HCl [Ans.: (a) 0.0167, (b) 0.267, (c) 0.1, (d) 9.9 ]

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Calculate the amount of KOH required to neutralize 15 Meq. of the following: (a) HCl (b) KHSO4 (c) N2O5 (d) CO2.

[ Ans.: (a) 0.84 g (b) 0.84 g (c) 0.84 g (d) 0.84 g] 17. What volume of water is required to make 0.20 N solution from 1600 mL of 0.2050 N solution? [Ans.: 40 mL ] 18. What volume of a solution of hydrochloric acid containing 73 g of acid per litre would suffice for the exact neutralization of sodium hydroxide obtained by allowing 0.46 g of metallic sodium to act upon water? [UPSEAT 1997] [ Ans.: V = 10 mL ] Find out equivalent weight of H3PO4 in the reaction Ca(OH)2 + H3PO4 CaHPO4 + 2H2O 20. 8KI + 5H2SO4 4K2SO4 + 4I2 + H2S + 4H2O [ Ans.: 49 ]

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What volume of 0.20 M H2SO4 is required to produce 34.0 g of H2S by the reaction? [ Ans.: V = 25 L ]

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