STOICHIOMETRY

1. (*) 40.0 g NaOH, 106.0 g Na2CO3 and 84.0 g NaHCO3 is dissolved in water and the solution is made 1.0 L. 20 mL of this stock solution is titrated with 1.0 N HCl, hence the titre reading of HCl will be : (A) 40 mL if phenolphthalein is used from the very beginning (B) 60 mL if phenolphthalein is used from the very beginning st (C) 40 mL if methyl orange is used after the 1 end point (D) 80 mL if methyl orange is used from the very beginning 2. 11.4 g of a mixture of butane C4H8 and butane C4H10 was burned in excess oxygen. 35.2 g of CO2 and 16.2 g of H2O were obtained. Calculate the % mass of butane in the original mixture. (A) 50.87% (B) 49.13% (C) 50% (D) None of these 3. A sample of hard water contains 244 ppm of HCO3 ions. What is the minimum mass of CaO required to remove ions completely from 1 kg of such water sample? (A) 56 mg (B) 112 mg (C) 168 mg (D) 244 mg 4. When 0.1 mol of H3BO3 is titrated against NaOH of 1 M using phenolphthalein indicator, what volume of NaOH is used up till the end point ? (A) 300 ml (B) 100 ml (C) 3000 ml (D) 1000 ml 5. A metal oxide has the formula Z2O3. It can be reduced by Hydrogen to give free metal and water. 0.16 g of the metal oxide requires 6 mg of hydrogen for complete reduction. The atomic weight of this metal is : (A) 27.9 (B) 159.6 (C) 79.8 (D) 55.8 6. 10.78 g of H3PO4 in 550 mL solution is 0.4 N. Thus this acid has been converted to : 232(A) HPO4 (B) PO4 (C) HPO3 (D) H2PO4 7. A mixture containing Na2CO3, NaOH and inert matter weighs 0.75 g. When the aqueous solution is titrated with 0.5 N HCl, the color of the phenolphthalein disappears when 21 mL of the acid has been added. Methyl orange is then added and 7 mL more of the acid is required to give a red color to the solution. The % of Na2CO3 is : (A) 49.5 (B) 24.5 (C) 37.1 (D) None of these 28. Oxalic acid (H2C2O4) forms two series of salt HC2O4 and C2O4 . If 0.9 g of Oxalic acid is in 100 mL 2solution, HC2O4 and C2O4 have normality respectively : (A) 0.1 N, 0.001 N (B) 0.1 N, 0.2 N (C) 0.2 N, 0.2 N (D) 0.2 N, 0.1 N 9. In a pathology lab, a sample of urine containing 0.120 g of urea, NH2CONH2 was treated with an excess 0.5 M nitrous acid. The urea reacted according to the equation NH2CONH2 + 2HNO2 CO2 + 2N2 + 3H2O The gases produced were passed through aqueous sodium hydroxide and the final volume measured. What was the volume at room temperature and pressure? (A) 9.6 cc (B) 14.4 cc (C) 48 cc (D) 96 cc 10. Reaction between lead nitrate and chromic sulphate takes place as follows : Pb(NO3)2 + Cr2(SO4)3 PbSO4 + 2Cr(NO3)3 If 75 mL of 0.5 M lead nitrate and 50 mL 0.25 M chromic sulphate are mixed in a reaction mixture, concentration of NO3 in solution is : (A) 0.6 M (B) 0.3 M (C) 0.25 M (D) 1 M 11. (*) Phosphoric acid H3PO4 can be neutralized to : 232(A) HPO4 (B) PO4 (C) H2PO4 (D) HPO3 12. (*) Which of the following statements is/are correct? A mixture containing 64 g H2 and 64 g O2 is ignited so that water is formed. (A) H2 is limiting reagent (B) O2 is limiting reagent (C) The reaction contains 72 g H2O and 56 g unreacted H2 (D) The reaction contains 56 g H2O and 72 g unreacted H2

13. What volume of 0.40 M Ba(OH)2 must be added to 50.0 mL of 0.30 M NaOH to get a solution in which the molarity of the OH ions is 0.50 M ? (A) 33 mL (B) 66 mL (C) 133 mL (D) 100 mL 14. Calculate the number of O-atoms required to combine with 7g N2 to form N2O3 if 80% of N2 is converted into product : (N2 + 1.5O2 N2O3) 23 23 23 23 (A) 6.02 * 10 (B) 18 * 10 (C) 3.6 * 10 (D) 3.24 * 10 15. 10 ml of 1 M BaCl2 solution and 5 ml of 0.5 M K2SO4 are mixed together to precipitate out BaSO4. The amount of BaSO4 precipitated will be : (A) 0.0025 moles (B) 0.025 moles (C) 0.00025 moles (D) 0.0050 moles 16. One litre of N/2 HCl solution was heated in a beaker. When volume was reduced to 600 mL, 9.125 gm of HCl was lost out. The new normality of solution is : (A) 0.2 (B) 0.4 (C) 0.8 (D) 0.04 17. A solution contained sodium hydroxide and sodium carbonate. Using phenolphthalein as an, indicator, 25 mL of the solution required 18.0 mL of 0.1 N HCI for neutralization. Methyl orange was then added when a further 16.0 mL of the acid was required. The NaOH percentage in the mixture is approximately: (A) 5% (B) 13% (C) 61% (D) 95% 18. 50 mL of a solution, containing 1.0 g each of NaHCO3, Na2CO3 and NaOH was titrated with 1 N HCI. What volume of HCl will be used up if methyl orange is added after the first end point with phenolphthalein? (A) 34.4 mL (B) 47.12 mL (C) 15.11 mL (D) 21.30 mL 19. An excess of NaOH was added to 100 mL of a ferric chloride solution. This caused the precipitation of 2.14 g of Fe(OH)3. Calculate the normality of the ferric chloride solution : (A) 0.2 N (B) 0.3 N (C) 0.6 N (D) 1.8 N 20. One litre of a sample of hard water contains 5.55 mg of CaCl2 and 4.75 mg of MgCl2. Find the total 6 hardness in terms of ppm (parts of CaCO3 per 10 parts of water by weight). (A) 5 ppm (B) 20 ppm (C) 10 ppm (D) None of these 21. 100 ml of 0.06 M Ca(NO3)2 is added to 50 ml of 0.06 M Na2C2O4. After the reaction is complete : (A) 0.003 moles of calcium oxalate will get precipitated (B) 0.003 M of excess of Ca2+ will remain in excess
(C) Sodium oxalate is limiting reagent (D) Calcium nitrate is in excess

22. KClO4 can be prepared by means of following series of reactions:

(A) (B) (C) (D)

The amount of Cl2 is needed to prepare 277 gms of KClO4 by above series of reactions is 568 gm The volume of KOH in litres used by Cl2 if KOH is 1.5 molar is 1.067 L The amount of Cl2 is needed to prepare 200 gms of KClO4 by above series of reactions 284 gm The volume of KOH in litres used by Cl2 if KOH is 1.5 molar is 10.67 L

23. When Borax ) is neutralized by an acid. The equivalent weight of Borax is : (Atomic mass of Boron = 11) (A) 382 (B) 191 (C) 101 (D) 202 24. Two liquids 'A' (Molecular mass = 20) and 'B' (Molecular mass = 40) are partially miscible. When 1 mol of A and 3 mol of B are shaken together and allowed to settle, two layer 'M' and 'N' are formed as shown in diagram. Layer 'M' contains 0.2 mole fraction of 'A' and layer 'N ' contain 0.6 mole fraction of A. Calculate the ratio of total moles of layer M to total moles of layer N. (A) 5 (B) 7 (C) 9 (D) 15

1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. 16. 17. 18. 19. 20. 21. 22. 23. 24.

ACD A B B D A A B D A ABC BC A C A B A D C C ACD AD B B