42 4

2013 4

Vol.42 No.4
Apr.2013

Technology & Development of Chemical Industry

1, 2 1 1 1 1 3
(1. 4300812. 430081
3. 414000)
BTX

BTX
O 622.1

BTX

1671-9905(2013)04-0014-04

1.1

C4

C4 C4

C4

BTX


















10%
1500 t

[1]

BTX

+

+

64%

BTX

2011 (20114219110002) (B1205)

(1967-)

E-mail:hbchengzz
@163.com430081
2013-02-04

15



400~520




1.2

1. 2. 3.
4. 5. 6.

HZSM-5
HZSM-5 Zn
Ca

1 Cyclar

1.3.2 GTA

LAC
DLP ZSM-5
[2]

GTA

50% C3 3%

HZSM-5





/kgm-3 /m2g-1 /mLg-1 /nm

Ca-ZSM-5

670

200

0.5

-ZSM-5

650

200

0.5

LAC ZSM-5

690

300

0.22

4.88

20d

DLP ZSM-5

680

330

0.25

4.9

30d

LAC 4

60% 480~520 0.1~0.4MPa

20d
2

 

LAC DLP

Ca Zn-ZSM-5



12

CaZn
ZSM-5
2000h
1.3

BP UOP Cyclar
Nano-forming
GTA
1.3.1 Cyclar
LPG
Ga ZSM-5
BTX 5500.7MPa
3
65%







GTA

1.3.3 Nano-forming
Nano-forming
DLP ZSM-5

60%
4

500~600
0.3~0.5MPa
30d
3

16

42

27%



10%1- (15%)2- (23%) (25%)

2

BTX 20 t

GTA




1.
3

2.

Nano-forming
2

/MPa

Cyclar

Ga-ZSM-5

520~550

0.5~0.7

GTA

LAC ZSM-5

460~540

0.1~0.4

Nano-forming

DLP ZSM-5

500~600

0.3~0.5

N-

4
4

5
N-
Udex Sulfolane

/ ta-1

10

10

30

60

20

N-

2.1 Udex

IFP Arosolvan N-
[3]

20 50

Formex N- 3

100
100

/ / /

lg


295 -5.6

233

0.9

287

28

200

1.1

189

18

237

N- 206

-24

21

230

N-

244

1/

0.4

0.3
0.2
1.3325
20
0.69
0.55
0.55

6%~8%
BTX

Udex[4]

10%~20%
Udex 4

0.54



3 N-




N-

N- N-






N-

Udex

17

2.2 Sulfolane













sulfolane[5]

SED
COS
SED 5

Formex











[1] .
[J]. 201142(1)45-48.

BTX


[2] . ZSM-5
[J]. 200816(6)23-26.
[3] . [J]. 2009

SED

2.3 Formex

38(5)467-471.
[4] . [J].

[6]

Snamprogetti
N- NFM
230

Formex 6

200523(3)228-230.
[5] Yu DarongZhang Zhigang. Commercial practiceon
technology for high-temperature cracking of C4 fraction to
increase pro-pyleneyield[J].China Petroleum Processing &
Petrochemical Technology2003(3)29-32.
[6] Schwab PBreitscheidel BSchulzR. Metathesis Catalyst
and its preparation and use[P].US 61301812001.

Aromatics Preparation by Light Oil and Mixed C4

CHENG Zheng-zai1,2, WANG Yang1, YAO Na1, DAI Zhi-chao1, CHEN Pan1, NEI Wei3
(1.Institute of Chemical Engineering and TechnologyWuhan University of Science and TechnologyWuhan 430081China2.Key
Laboratory of Coal Transition and Novel Carbon Materials of Hubei ProvinceWuhan 430081China; 3. China National Chemical
Engineering Forth Construction Co. Ltd.Yueyang 414000China)
Abstract: Aromatization reactionaromatics extraction process and BTX distillation process were introduced. Combined to the natural production requirementa economical and practical technology of aromatic hydrocarbon preparing by mixed C4 was chosen.
Key words: aromatization of C4; aromatic extraction; BTX; extractive distillation

()

CHENG Zheng-zai WANG Yang YAO Na DAI Zhichao CHEN Pan NEI Wei
,CHENG Zheng-zai(430081;
430081) ,,,,WANG Yang,YAO Na,DAI Zhi-chao,CHEN Pan(
,,430081) ,NEI Wei(, ,414000)

Technology & Development of Chemical Industry

2013(4)

http://d.g.wanfangdata.com.cn/Periodical_gxhg201304006.aspx