Professional Documents
Culture Documents
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it is more difficult to drive through fog using high beams than using low beams.
High beams are aimed farther down the road than low beams. Because the fog scatters light, there is less light from the high beams to illuminate the road than from the low beams. Also, because the high beams are aimed more directly into the fog, more of their light is reflected back toward the driver, making it more difficult to see.
Practice Problems
pages 481488
stay dispersed?
The particles do not settle out because they have polar or charged layers surrounding them. These layers repel each other and prevent the particles from settling or separating.
percent by mass of the solute sodium hypochlorite, NaOCl, is 3.62%. How many grams of NaOCl are in the solution?
3.62% 100 mass NaOCI __ 1500.0 g
mass NaOCl 54.3 g Solutions Manual Chemistry: Matter and Change Chapter 14
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in the solution?
1500.0 g 54.3 g 1445.7 g solvent
chloride in a solution is found to be 2.65%. If 50.0 grams of calcium chloride is used, what is the mass of the solution?
2.65% 100 50 g CaCl2
__
mass of solution
1.5 L solution
make an aqueous solution that is 15% methanol by volume, how many milliliters of solution are produced?
18 mL 15% __ 100 x mL solution x 120 mL
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HCl is diluted to make 2 L of solution, how much HCl, in grams was in the solution?
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.
mol HCl 5M 0.5 L 2.5 mol HCl mass of HCl 36.45 g HCl __ 1 mol 2.5 mol
1 mol _ 142.04 g
percent by mass H2SO4 1230 g H2SO4 100 (1580 1230) g solution 43.8% H2SO4 by mass
___
1.0000 Kg H2O
1 mol
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S1
0.55 g _ 0.55 g/L 1.0 L P 110.0 kPa _ 0.55 g/L _ 3.0 g/L
2
S2 S1
P1
20.0 kPa
of pressure. What is the pressure on a 1.0-L sample that contains 1.5 g of gas?
S2 1.5 g 1.5 g/L 1.0 L P2 P1 S 1.5 g/L _ 10.0 atm _ 23 atm
2
450 mg of sodium chloride in 240.0 g of broth. What is the percent by mass of sodium chloride in the broth?
1g 450 mg NaCl _ 0.45 g NaCl 1000 mg percent by mass 0.45 g _ 100 0.19% 240.0 g
S1
0.66 g/L
of pressure is 0.52 g/L. How many grams of the gas would be dissolved per 1 L if the pressure increased 40.0 percent?
P2 P1 (P1)(0.400) ( 7.0 atm) (7.0 atm)(0.400) 9.8 atm S2 S1 P _
2
0.5M _ 2.5 L
P1
1 mol
solutions.
Surface area, temperature, and pressure affect the formation of solutions.
Solubility refers to the maximum amount of solute that can dissolve in a given amount of solvent at a particular temperature and pressure.
Practice Problems
page 497
solvation?
The attractive forces between solute and solvent particles overcome the forces holding the solute particles together, thus, pulling the solute particles apart.
20.0 kPa of pressure, how much will dissolve at 110.0 kPa of pressure?
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Tb 0.512C/m 0.625m 0.320C Tb 100C 0.320C 100.320C Tf 1.86C/m 0.625m 1.16C Tf 0.0C 1.16C 1.16C
tion in Table 14.4 to graph the solubilities of aluminum sulfate, lithium sulfate, and potassium chloride at 0C, 20C, 60C, and 100C. Which substances solubility is most affected by increasing temperature? Solubility v. Temperature
90 80
nonvolatile, nonelectrolyte solute) is experimentally found to have a freezing point depression of 0.080C. What is the freezing point depression constant (Kf)? Which is most likely to be the solventwater, ethanol, or chloroform?
Kf T _ m 0.080C _
f
0.045m 1.8C/m
Aluminum sulfate shows the greatest change in solubility over the temperature range.
Practice Problems
page 503
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Chapter 14 Assessment
pages 508511
Section 14.1
Mastering Concepts 54. Explain what is meant by the statement not all mixtures are solutions.
Solutions are homogeneous mixtures that are uniform in composition with a single phase. Mixtures can also be heterogeneous, where the substances that make them up remain distinct.
(CaCl2) boils at 101.3C. How many kilograms of calcium chloride were dissolved in 1000 grams of the solvent?
Kb 2.53m 2.53 moles solute particles/1 kg solvent 2.53 mol particles 1000 g 1 mol CaCl 110.98 g __ _
2
T 1.3C _ _ 0.512C/m
b
solvent?
A solute is the substance being dissolved. The solvent is the substance in which the solute dissolves.
1 kg _ 0.0936 kg
3 mol particles
1 mol
from a colloid?
A suspension is a heterogeneous mixture that settles out if left undisturbed. The particles dispersed in a colloid are much smaller than those in a suspension and do not settle out.
Tb ( 0.512C/m)(0.556m) 0.285C Tb 100.000C 0.285C 100.285C Tf ( 1.86C/m)(0.556m) 1.03C Tf 0.00C 1.03C 1.03C
a liquid.
Student answers may include whipped cream or beaten egg whites.
boiling point elevation of an aqueous solution of a nonvolatile, nonelectrolyte to be 1.12C. What is the solutions molality?
1.12C 0.512C/m m m 2.19m
mixture is shown in Figure 14.24 on page 508? What characteristic is most useful in classifying the mixture?
The mixture is a suspension. Left undisturbed, the mixture components settle out.
liquid colloids?
The random particle movements in liquid colloids result from collisions between particles in the mixture.
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tion containing 50.0 g of glucose (C6H12O6) dissolved in 500.0 g of water. Calculate the freezing point depression for the same solution.
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Mastering Problems 67. According to lab procedure, you stir 25.0 g of MgCl2 into 550 mL of water. What is the percent by mass of MgCl2 in the solution?
percent by mass of MgCl2 25.0 g MgCl 100 4.3% 25.0 g MgCl 550 g H2O
Section 14.2
Mastering Concepts 62. What is the difference between percent by mass and percent by volume?
Percent by mass is a comparison between the mass of solute and the total mass of the solution. Percent by volume is a comparison between the volume of the solute and the total volume of the solution.
___
solution of HCl but have only 25 mL HCl. What volume of 5% solution can be made from this volume of HCl?
volume of solution 25 mL HCl _ 100 500 mL 5
molality?
Molarity is solution concentration expressed as the moles of solute per volume of solution. Molality expresses concentration as moles of solute per kilogram of solvent. Molality does not depend upon the temperature of the solution.
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.
NaCl differ?
The 2M solution contains more moles of NaCl per volume of water than the 0.5M solution.
__
275 mL
molarity
0.275 L solution
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V1
__
0.17 L HCl V1
__
0.42 L HCl
__
__
volume of HNO3 45 mL
are frequently prepared. Complete Table 14.7 by calculating the volume of concentrated, or 12M, hydrochloric acid that should be used to make 1.0 L of HCl solution with each molarity listed.
Molarity of HCl desired 0.50 1.0 1.5 2.0 5.0 V1 Volume of 12M HCl stock solution needed (mL) 42 mL 83 mL 130 mL 170 mL 420 mL
a 4.0M solution to make 250 mL of solution. Calculate the molarity of the new solution.
M2 4.0M 55 mL __ 0.88M 250 mL
__
0.042 L HCl V1
__ __
1L
_
74.6 g KCl
0.083 L HCl
1.5 mol/L 1 L 0.13 L HCl V1 12 mol/L 0.13 L HCl 1000 mL _ 130 mL HCl
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into 155 grams of water to create a solution with a molality of 8.20 mol/kg?
155 g H2O 1 kg _ 0.155 kg H O 1000 g
2
solution containing the percentage of sulfuric acid and water shown in Figure 14.25?
mol NaCO3 8.20 mol/kg 0.155 kg 1.27 mol mass of NaCO3 1.27 mol NaCO3 105 g 83.00 g NaCO __
3
mol NaCO3
97.1 g H 2SO 4
2
10H8
500.0 g toluene m
1 kg _ 0.5000 kg
10 8
__
95.21 g
2
1.0 g H O 1 mol H O _ __
2
18.0 g H 2O
2
mass of water 100.0 g 35.5 g 64.5 g 6.45 102 kg moles of water 64.5 g H2O 3.58 mol H2O molality 0.771 mol HCOOH __ 12.0m 6.45 102 kg H2O 1 mol H O __
2
1.387 mol MgCl ____ 0.125 1.387 mol MgCl2 9.72 mol H2O
Section 14.3
Mastering Concepts 86. Describe the process of solvation.
A solute introduced into a solvent is surrounded by solvent particles. Due to the attraction between solute and solvent particles, solute particles are pulled apart and surrounded by solvent particles. Once separated, solute particles disperse into solution.
18.02 g H2O
0.771 mol mole fraction ___ 0.177 0.771 mol 3.58 mol
solvation?
increase the temperature of the solvent, increase the surface area of the solute, agitation
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unsaturated solutions.
A saturated solution contains the maximum amount of solute under a given set of conditions. An unsaturated solution contains less than the maximum amount.
__
P 2 185 kPa
Mastering Problems 89. At a pressure of 1.5 atm, the solubility of a gas is 0.54 g/L. Calculate the solubility when the pressure is doubled.
0.54 g/L 3.0 atm S2 1.5 atm S 2 1.08 g/L
__
__
9.5 g/L. How many grams of gas will dissolve in 1L if the pressure is reduced by 3.5 atm?
S2 9.5 g/L 1.0 atm 4.5 atm
__
__
S 2 2.1 g/L
S 2 4.5 g/L
inside a bottle of soft drink is 4.0 atm at 25C. The solubility of CO2 is 0.12 mol/L. When the bottle is opened, the partial pressure drops to 3.0 104 atm. What is the solubility of CO2 in the open drink? Express your answer in grams per liter.
(0.12 mol/L)(3.0 104 atm) 4.0 atm 9.0 106 mol/L CO2 S 9.0 106 mol CO 2 1L 4.0 104 g/L CO2
___
2
40
60
80
100
120
Section 14.4
Mastering Concepts 95. Define the term colligative property.
A physical property of a solution that is affected by the number of solute particles but not their nature.
Temperature (C) The solubility of KBr is 95 g/100 g H 2O. The solubility of KNO 3 is nearly twice as high at the same temperature, at nearly 170 g/100 g H 2O.
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into 1.00 liter of water. Use Table 14.6 to find the freezing point of the solution.
mol MgCl 2 179 g MgCl __ 1.88 mol MgCl
2
95.3 g/mol
kg H 2O 1.00 L H 2O 1000 g
2
1gH O 1000 mL _ _
2
T b K bm
T b represents the difference between the boiling points of a solution and the pure solvent; K b is the molal boiling point elevation constant; m represents the solution molality.
1 kg _ 1.00 kg H O
2
1L
1 mL H 2O
boiling by adding 12.5 grams of NaCl to a pot holding 0.750 liters of water. At what temperature should the solution in the pot boil? Use Table 14.5 for the necessary constant.
mol NaCl 12.5 g NaCl __ 0.214 mol NaCl 58.44 g/mol 1gH O 1000 mL _ _
2
Mastering Problems 99. Calculate the freezing point of a solution of 12.1 grams of naphthalene (C 10H 8) dissolved into 0.175 kg of benzene (C 6H 6). Refer to Table 14.6 for the necessary constant.
mol C 10H 8 12.1 g C10H8 0.0945 mol C 10H 8 m 0.0945 mol C H __ 0.540m
10 8
1 kg _ 0.750 kg H O
1L
1 mL H 2O
1 mol C H __
10 8
128.08 g C 10H 8
solution molality
particle molality 0.285m 2 0.570m Tb 0.512C/ m 0.570 m 0.292C Tb 100.00C 0.292C 100.29C
0.175 kg C 6H 6
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changes from 78.5C to 85.2C when an amount of naphthalene (C 10H 8) is added to 1.00 kg of ethanol. How much naphthalene, in grams, is required to cause this change? Refer to Table 14.5 for needed data.
T b 85.2C 78.5C 6.70C solution molality moles of solute 6.70C _ 5.49m 1.22C/m
10 8
are colloids composed of pigment particles dispersed in oil. Based on what you know about colloids, recommend an appropriate location for storing cans of leftover household paint. Justify your recommendation.
When a colloid is exposed to heat, suspended particles can settle out. Paint should be stored in a cool location where it cannot freeze, and away from direct sunlight and objects like water heaters or furnaces that generate heat.
5.49 mol C H __
__
128 g C 10H 8 1 mol C 10H 8
boiling point of 1.00 kg of water: 50.0 grams of strontium chloride (SrCl 2) or 150.0 grams of carbon tetrachloride (CCl 4)? Justify your answer.
50.0 grams SrCl 2 has the greatest effect. mol SrCl 2 50.0 g mol SrCl __ 0.315 mol SrCl
2
mixture is used to cool milk and cream to make homemade ice cream. How many grams of rock salt must be added to water to lower the freezing point by 10.0C?
T f K fm 10.0C 5.38m ions of Na and Cl m 1.86C/ m Kf 2.69 mol NaCl moles of solute molality 1 kg solvent kilograms of solvent 1 kg H2O 1 mol NaCl 157 g NaCl per 1 kg H 2O 58.44 g NaCl 2.69 mol NaCl __ __
solution molality
T b SrCl 2 solution 100.0C 0.484C 100.484C mol CCl 4 150.0 g mol CCl __ 0.974 mol CCl
4
154 g mol
solution molality
Mixed Review 104. Apply your knowledge of polarity and solubility to predict whether solvation is possible in each situation shown in Table 14.9. Explain your answers.
MgCl2(s) in H2O(l): Yes. NH3(l) in C6H6(l): No. H2(g) in H2O(l): No. I2(l) in Br2(l): Yes. Predictions are based on the general rule like dissolves like. A polar solvent like water will dissolve a polar solute like magnesium chloride, and a nonpolar solvent like liquid bromine will dissolve a nonpolar solute like liquid iodine. Ammonia is a polar molecule, while benzene is nonpolar. Water is a polar molecule while diatomic hydrogen is nonpolar.
particle molality 0.974m 1 0.974m T b 0.512C/m 0.974m 0.310C T b CCl 4 solution 100.0C 0.310C 100.31C
temperature data to determine the general trend followed by the gases (NH3, CO2, O2) in the chart. Compare this trend to the trend followed by most of the solids in the chart. Identify the solids listed that do not follow the general trend followed by most of the solids in the chart.
For the gases, solubility decreases as temperature increases. For most solids, solubility increases as temperature increases. Ca(OH)2 and Li2SO4 do not follow the general trend for solids. Solutions Manual
288
_ _ __ __
T f
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shown in Figure 14.27. Calculate the mole fraction of each gas present in the sample.
Argon 1.00% Oxygen 21.0%
tion described in the previous problem? The density of the Ca(NO 3) 2 solution is 1.08 kg/L.
mass of solution 3.00 L 3.24 kg solution mass of solute 246 g 1 kg _ 0.246 kg 1000 g 1.08 kg solution 1 L solution
__
Nitrogen 78.0%
78.0 g N 2
28.0 g N2 1 mol O 2
1L
_ 0.656 mol O
32.0 g O 2 39.9 g Ar
molality, m 0.501m
_____
2.79 mol N2 XO2
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.
2.79 mol N 2 0.656 mol O 2 0.0251 mol Ar 0.804 0.656 mol O _____
2
Think Critically 112. Develop a plan for making 1000 mL of a 5% by volume solution of hydrochloric acid in water. Your plan should describe the amounts of solute and solvent necessary, as well as the steps involved in making the solution.
% by volume 5% volume solute __ 100 volume solution
_____
0.0251 mol N 2
vol solute 50 mL 50 mL HCl needed. Subtract the volume of HCl from the total solution volume to determine a volume of 950 mL H2O needed. Dissolve 50 mL HCl in somewhat less than 950 mL H2O. Add water until the volume of the solution is 1000 mL.
of potassium chloride at 25C and then heated it to 50C, would you describe the solution as unsaturated, saturated, or supersaturated? Explain.
unsaturated; the solubility of KCl in water increases with temperature. A solution at 50C holds more solute than one at 25C.
__ __
0.500 mol Ca(NO 3) 2 1L 164.09 g Ca(NO3)2 1 mol Ca(NO 3) 2 Chemistry: Matter and Change Chapter 14
246 g Ca(NO3)2
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diagram in Figure 14.21. Compare the dotted lines surrounding Tf and Tb and describe the differences you observe. How might these lines be positioned differently for solutions of electrolytes and nonelectrolytes? Why?
Phase Diagram Pure solvent 1 atm Solution
at various pressures is shown in Figure 14.28. Extrapolate the data to 15 atm. Use Henrys law to verify the solubility determined by your extrapolation.
Solubility v. Gas Pressure
70 60 50 40 30 20 10 0 2.0 4.0 6.0 8.0 10.0
LIQUID P Normal boiling point of water GAS Tf Normal freezing point of water Boiling point of solution Tb
S S _ _
1 2
P1
P2
S2
Increasing Temperature
___
As pressure increases with water depth during a dive, gas concentration in the blood increases. If blood (solvent) volume is low, the gas (solute) concentration will be higher than normal levels at specific depths. A well-hydrated diver has a greater amount of solvent in which gases can be dissolved.
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The freezing point of the solution is below the normal freezing point of water, while the boiling point of the solution is above the normal boiling point of water. Tf and Tb would be larger for electrolytes than nonelectrolytes. Electrolytes dissociate in water, resulting in a larger number of particles in solution.
is lost from the body than is taken in. Scuba divers are advised to hydrate their bodies before diving. Use your knowledge of the relationship between pressure and gas solubility to explain the importance of hydration prior to a dive.
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collected in an experiment. Plot a graph of the molarity of KI versus temperature. What is the solubility of KI at 55C?
Solubility vs. Temperature 13 12
Solubility (M)
has the highest concentration? Rank the solutions from the greatest to the smallest boiling point depression. Explain your answer. a. 0.10 mol NaBr in 100.0 mL solution b. 2.1 mol KOH in 1.00 L solution c. 1.2 mol KMnO4 in 3.00 L solution
The molarities are 1.0M NaBr, 2.1M KOH, and 0.40M KMnO4. Because the KOH solution contributes the greatest concentration of particles to solution, it has the greatest boiling point elevation; KMnO4 has the lowest concentration of particles and the smallest boiling point depression. Boiling point elevation depends only upon concentration. 0.10 mol NaBr __ 1.0M NaBr 0.1000 L 1.00 L
2.1 mol KOH __ 2.1M KOH 1.2 mol KMnO __ 0.40M KMnO
4
Molarity equals 8.67M, 9.76M, 10.6M, 11.6M, and 12.4M at 20C, 40C, 60C, 80C, and 100C, respectively. The solubility of KI at 55C is about 10.4M.
3.00 L
Challenge
Measurements of Solubility of a Gas
Measurement 1 2 3 4 5 Solubility 0.225 0.45 0.9 1.8 3.6
sample of a solid solute and three aqueous solutions containing that solute. How would you determine which solution is saturated, unsaturated, and supersaturated?
Add a pinch of solute to each container. If the solution is supersaturated, crystallization will occur; saturated, no solute will dissolve; unsaturated, solute will dissolve.
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of dissolved KBr in 2.3 liters of water. What volume of this solution, in mL, would you use to make 1.5 liters of a 0.1M KBr? What is the boiling point of this new solution?
Step1: Calculate molarity of original solution 135.2 g KBr M 1 mol KBr _ 1.14 mol KBr 119 g KBr
b. NO2
polar
c. H2S
polar
Step 2: Dilute the solution Calculate required volume 0.10M 1.5 L __ 0.496M 1000 mL 300 mL 0.30 L _ V1 1L Step 3: Calculate boiling point of new solution Tb Kbm m 0.10 mol KBr __ __ 1LH O 1000 mL H O 1000 g H O O 1 mL H _ __ 0.10m 1 L H2O
2 2 2 2
d. NCl3
polar
b. Pb(CH3COO)2
lead(II) acetate
1 g H2O
c. (NH4)2CO3
ammonium carbonate
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.
1 kg H2O
particle molality 0.10m 2 0.20m Tb 0.512C/m 0.20m 0.10C Tb 100.0C 0.10C 100.1C
Cumulative Review 121. The radius of an argon atom is 94 pm. Assuming the atom is spherical, what is the volume of an argon atom in nm3? V 4/3r3. (Chapter 3)
1 nm 94 pm _ 0.094 nm 1000 pm V ( 4/3)(3.14)(0.094 nm)3 3.5 103 nm3
of bismuth oxide with carbon at high temperatures. 2Bi2O3 3C 0 4Bi 3CO2 How many moles of Bi2O3 reacted to produce 12.6 mol of CO2? (Chapter 11)
12.6 mol CO2 2 mol Bi O __ 8.40 mol Bi O
2 3
3 mol CO2
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Additional Assessment
Writing in Chemistry
126. Homogenized Milk The first homogenized
milk was sold in the United States around 1919. Today, almost all milk sold in this country is homogenized, in the form of a colloidal emulsion. Research the homogenization process. Write a brief article describing the process. The article may include a flowchart or diagram of the process, as well as a discussion of the reputed benefits and/or drawbacks associated with drinking homogenized milk.
Student answers will vary. Students should note that raw milk contains fat dispersed throughout. If left to stand, the fat separates out, leaving a cream layer and a skim milk layer. The process of homogenization breaks the fat globules into smaller sizes and reduces their tendency to form a cream layer.
Relate the trend to the relationship between gas solubility and temperature.
In general, dissolved oxygen in surface ocean waters increases as latitude increases towards both north and south. Surface water temperatures are greatest near the equator. Surface water temperature decreases toward the poles. As temperature decreases, gas solubility generally increases.
0.9000
Document-Based Questions
0.6000
Percent
0.5000 0.4000 0.3189 0.3000 0.2575 0.2000 0.1000 0.0000 0.4779 0.1030 0.0515 1 2 0.1596 3 4
Solution number
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0.1545
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(0.004779) 0.2628 g
6. What is the empirical formula for this
10.4 g O 11.7 g H
1.008 g H
is dissolved in 1 L of water, which solute will have the greatest effect on the vapor pressure of its respective solution? a. KBr b. C6H12O6 c. MgCl2 d. CaSO4
c MgCl2 will produce the most number of particles in solution: 1 mol Mg2, 2 mol Cl
Calculate the simplest ratio of moles. 6.486 mol C 0.65 mol O __ 9.98; __ 1.00; 0.65 0.65 11.607 mol H __ 17.86 0.65 The empirical formula is C10H18O.
ionic compound formed by the calcium ion (Ca2) and the acetate ion (C2H3O2)? a. CaC2H3O2 b. CaC4H6O3 c. (Ca)2C2H3O2 d. Ca(C2H3O2)2
d
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Fe will be produced? a. 6 b. 3 c. 12 d. 9
c
H2, what will be true? a. There will be no reactants left. b. 2 moles of hydrogen gas will be left over c. 30 moles of water will be produced d. 7 moles of Fe will be produced
b Fe3O4(s) 4 H2(g) 3 Fe(s) 4 H2O(l) 7 mol Fe3O4 4 mol H __ 28 mol H
2
Use the information below to answer Questions 14 and 15. The electron configuration for silicon is 1s2 2s2 2p6 3s2 3p2.
14. Explain how this configuration demonstrates
1 mol Fe3O4
used
how Hunds rule and the Pauli exclusion principle are used in constructing the orbital diagram.
Hunds rule mandates that the last two electrons will be placed in separate p-orbitals. The Pauli exclusion principal determines that shared electrons in any given orbital must have opposite spins, as shown by up and down arrows.
100 90 80 70 60 50 40 30 20 10 0
1s 2s 2p 3s 3p
KCl
NaCl
KClO3 Ce2(SO4)3
0 10 20 30 40 50 60 70 80 90 100
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boiling point elevation freezing point depression vapor pressure increase osmotic pressure heat of solution
Mg-Cl: 3.16 1.31 1.85 Al-N: 3.04 1.61 1.43 H-Cl: 3.16 2.20 0.96 Mg-Cl has the greatest polarity.
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.
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