Rhodiasolv

Solvents

Rhodiasolv
Effective and environmentally friendly

Home, Personal Care & Industrial Ingredients

Rhodiasolv
Two powerful solvents suitable for a wide range of

applications.
Easy to formulate with other solvents. Totally biodegradable and non toxic for aquatic organisms. Low VOC potential. Non flammable. Specifications and characteristics
General characteristics
Molecular weight (g/mol) Density at 20 C (g/cm3) Refractive index (nD) at 20 C Distillation range under 1013 hPa (C) Vapour pressure at 20 C (Pa) Dynamic viscosity at 20 C (mPa.s) Solubility at 20 C (%): - water in solvent (% wt.) - solvent in water (% wt.) Evaporation rate at 80 C (g/min) Evaporation rate (butyl acetate=1) Solubility parameter (HANSEN method): - /D (J/cm3)1/2 - /P (J/cm3)1/2 - /H (J/cm3)1/2 Flash point (C) Closed cup Autoignition point (C) Freezing point (C) Electrical conductivity (nS.cm-1) Resistivity at 20 C (M.m)

Rhodiasolv RPDE
158.6 1.09 1.425 200-235 6 2.9 3.44 5.7 0.031 0.086 17.21 6.26 9.16 100 360 -20 5 2

Rhodiasolv DIB
244 0.96 1.428 275-295 <3 4.9

0.1 0.007 15.9 2.4 7.0 144 <-70 -

Specifications
Distribution (weight %) (GPC): - Glutarate - Succinate - Adipate Ester content (%) (GPC) Colour Water content (%) Methanol content (%) (GPC) Acid value (mg KOH/g) (Acidimetry) 59-67 20-28 9-17 99.5 10 (Apha) 0.05 0.2 0.3 59-67 20-28 9-17 99 2 (Gardner) 0.1 0.2 2

safe and environmentally

Rhodiasolv RPDE
Rhodiasolv RPDE is ideal to dissolve polar substrates such as resins,

coatings and inks.

Rhodiasolv RPDE is suitable for a wide range of applications.

Paint formulations
Coil coating Can coating Polyester and epoxy sealing coat Industrial paint

Cleaning and stripping applications

Paint stripping Polyurethane resin clean-up Polyester resin clean-up Graffiti removers

Resins for foundry cores

Solvent for resin core binders

Formulations
Liquid detergents Pesticides and insecticides Textile lubricants Corrosion inhibitors Printing inks

Example of substitution:
For cleaning or stripping,
Rhodiasolv RPDE used alone or formulated can substitute methylene chloride which is classified R40 (possible risks of irreversible effects). For coil coating, Rhodiasolv RPDE can be used to substitute isophorone or glycol ether in order to reduce the impact on the environment of this application. In foundry applications, Rhodiasolv RPDE is an excellent and safe solvent to formulate resin core binders.

A powerful solvent
Nature of resin
Cellulose nitrate Acrylic Polyamide Polyurethane Polyester Aminoplast Phenoplast Alkyd Epoxy Vinyl Vinyltoluene Polychloroprene Polyvinyl alcohol

Solubility in RPDE
Soluble Soluble Insoluble Soluble Soluble Soluble Soluble Soluble Soluble Soluble Insoluble Insoluble Insoluble

friendly solvents
Rhodiasolv DIB
Rhodiasolv DIB is ideal for degreasing applications. Rhodiasolv DIB is stable is waterborne systems. Rhodiasolv DIB is an excellent coalescing agent for paint formulations.

Degreasing of non polar residues

With lower polarity and branched structure, Rhodiasolv DIB provides superior performance for greases and oils removal Hydrolytically stable, Rhodiasolv DIB can be formulated in waterborne degreasers

Coalescing agent for paints

High-performance coalescing aid Low-odor and low VOC properties Excellent tox/ecotox profile High stability in paints

Aqueous systems Rhodiasolv DIB can be emulsified in aqueous cleaners

Example of substitution:
Coalescing agent for paints:
Rhodiasolv DIB provides excellent coalescing properties to paint formulations with a clear benefit in odor and VOC reductions. Rhodiasolv DIB can be used in metal degreasing applications. Its low volatility leads to a safer workplace.

Most oils are soluble in Rhodiasolv DIB

Mineral paraffinic oil Mineral naphtenic oil Rapeseed oil Sunflower oil Methyl oleate Soluble Soluble Soluble Soluble Soluble

Safe solvents
Excellent toxicological

and ecotoxicological properties

Toxicological data
Toxicity studies performed on Rhodiasolv RPDE have shown only a low acute toxicity for both oral and dermal routes, no cutaneous irritation, and only minimal and transient ocular irritation potential, as measured under the test conditions. These data and other published studies on dimethyl esters blends indicate that no classification is required according to the criteria of the directive 67/548/EEC. Summary of the experimental results are available upon request.

Test
Acute oral toxicity Acute dermal toxicity Local cutaneous irritation Local ocular irritation

Method
OECD 401/EC B.1 OECD 402/EC B.2 OECD 403/EC B.3 OECD 404/EC B.4

Results
LD50 > 2000 mg/kg LD50 > 2000 mg/kg Not irritating to skin Not irritating to eyes

Ecotoxicological data
Biodegradability Study BD A17 shows the complete and rapid biodegradability of Rhodiasolv RPDE. In test conditions (AFNOR T90-312, ISO 7827, OECD 301A), at 18 days, the percentage of biodegradability of Rhodiasolv RPDE is 97%. Aquatic ecotoxicity test IC50 Daphnia magna/24h = 180 mg/l or Rhodiasolv RPDE.

Safe solvents for now and tomorrow

Rhodiasolvs are not classified as dangerous to the environment nor to health, according to the criteria of European directive 67/548/ EEC. Rhodiasolvs are not regulated according to the criteria of the national and international regulations of dangerous goods transport. Rhodiasolvs could be a very good alternative to ensure compliance with council directive 1999/13/CE of March 11, 1999 related to the reduction of volatile organic compounds emissions.

Rhodia Home, Personal Care & Industrial Ingredients

Europe:
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Asia Pacific:
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Latin America:
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North America:
CN 7500 Prospect Plains Road CRANBURY, NJ 08512-7500 Tel.: 1-609-860-4000 Tel.: 1-888-776-7337 Fax: 1-609-860-0463 For Samples and Literature, Please Call: 1-800-678-6647

AUSTRALIA 100 York Street (PO BOX 401) SOUTH MELBOURNE - VIC 3205 Tel.: (61) 3 92 80 10 00 Toll free: 1 800 331 099 Fax: (61) 3 96 46 38 17 BELGIUM 243 Bld Sylvain Dupuis B-1070 BRUSSELS Tel.: (32) 2 529 45 11 Fax: (32) 2 529 45 98 BRAZIL Centro Empresarial Av. M. Coelho Aguiar , 215 -BI,B 4 a Caixa Postal 60561/60562 05804 - 902 SAO PAULO - SP Tel.: (55) 11 37 47 78 86 Fax: (55) 11 37 41 80 99 CANADA 2000 Argentia Road Plaza 3, Suite 400 MISSISSAUGA, ONT. LA5N 1V9 Tel.: (1) 905 821 4450 Fax: (1) 905 821 9339 FRANCE 190, avenue Thiers 69547 LYON Cedex 06 Tel.: (33) 4 37 24 85 90 Fax: (33) 4 37 24 85 96 Or for export sales 40, rue de la Haie-Coq 93306 AUBERVILLIERS Cedex Tel.: (33) 1 53 56 53 72 Fax: (33) 1 53 56 53 45

GERMANY - SWITZERLAND Staedelstrasse 10 D-60596 FRANKFURT Tel.: (49) 69 60 93 00 Fax: (49) 69 60 93 333 ITALY Via Milano 78/80 20021 OSPIATE DI BOLLATE (MI) Tel.: (39) 02 38 33 44 91 Fax: (39) 02 38 33 43 15 JAPAN Roppongi First Bldg 1-9-9 Roppongi - Minato-ku TOKYO 106 Tel.: (81) 3 35 85 85 72 Fax: (81) 3 35 85 47 85 MEXICO Av. Insurgentes Sur No. 1971 Torre III, Piso 6 Col. Guadalupe Inn Delegacion Alvaro Obregon CP 01020, MEXICO D.F. Tel.: (52 55) 53 22 48 00 Fax: (52 55) 53 22 48 94 RFC: RE8-980701-P24 SINGAPORE 27.06/07 The Concourse 300 Beach Road SINGAPORE 199555 Tel.: (65) 39 43 217 Fax: (65) 29 65 503

SOUTH AFRICA Cnr 16th Rd & Pharmaceutical Str. HALFWAY HOUSE 1685 Tel.: (27) 11 805 1932 Fax: (27) 11 805 1956 SOUTH KOREA 18th floor, Kangnam Bldg 1321-1 Seocho-Dong Seocho Ku - SEOUL 137-070 Tel.: (82) 23472 5134 Fax: (82) 23472 5588 SPAIN Diagonal, 640, 2 E-08017 BARCELONA Tel.: (34) 9 34 30 49 00 Fax: (34) 9 34 19 73 54 SWEDEN Finnbodavgen 2 S13105 NACKA Tel.: (46) 823 74 80 Fax: (46) 864 18 863

UNITED KINGDOM Poleacre Lane WOODLEY Stockport Cheshire SK6 1PQ Tel.: (44) 1 61 910 15 00 Fax: (44) 1 61 910 15 54 UNITED STATES CN 7500 Prospect Plains Road CRANBURY, NJ 08512-7500 Phone: 1-609-860-4000 Phone: 1-888-776-7337 Fax: 1-609-860-0463 Tel Customer Service : (1) 800 922 2189

The information contained in this document is given in good faith and based on our current knowledge. It is only an indication and is in no way binding, notably regarding infringement of or prejudice to third parties through the use of our products. RHODIA GUARANTEES THAT THIS PRODUCT COMPLIES WITH SALES SPECIFICATIONS. This information must on no account be used as substitute for necessary prior tests which alone can ensure that this product is suitable for a given use. Users are responsible for ensuring compliance with local legislation and for obtaining the necessary certifications and authorisations. Users are requested to check that they are in possession of the latest version of the present document and Rhodia Home, Personal Care & Industrial Ingredients at their disposal to supply any additional information.

www.rhodia-hpcii.com

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Home, Personal Care & Industrial Ingredients

HPCII Rhodiasolv September 2003

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