EXCEL INDUSTRIES LIMITED

CODEX 661 MATERIAL SAFETY DATA SHEET SECTION 1 : CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product identifier Chemical Name Molecular formula Chemical class Trade name Synonyms Name of manufacturer : : : : : : :

1-Hydroxyethylidene 1,1 diphosphonic Acid C2P2O7H8 Organic liquid CODEX 661 HEDP, Etidronic Acid, ADPA, Ethane-1-hydroxy-1,1-diphosphonate

CORPORATE HEAD OFFICE : Excel Industries Limited 184-87, S.V. Road Jogeshwari (West) Mumbai - 400 102 Maharashtra, INDIA Emergency Tel. : +91 22 6646 4200, 2678 8258 Fax : +91 22 2678 3508 Product use

MANUFACTURED AT : Excel Industries Limited D-9, MIDC Lote Parshuram Tal - Khed District - Ratnagiri 415722 Maharashtra, INDIA Emergency Tel. : +91 2356 272062, 272019 Fax : +91 2356 272336

: Used in cooling water treatment, textiles, sugar processing, dyes, soaps & detergents, oilfields, peroxide bleaching

SECTION 2 : COMPOSITION / INFORMATION ON INGREDIENTS Ingredient name 1-Hydroxy Ethylidene1,1 Diphosphonic Acid Water CAS No. 2809-21-4 7732-18-5 % 58-62 % active acid 38-42 % EC / EINECS No. 220-552-8 231-791-2 Symbol Xi, C ----R / S Phrases R41 -----

Note: See Section 16 for full text of R & S phrases mentioned above. SECTION 3 : HAZARDS IDENTIFICATION Potential hazards Potential health effects Relevant route of exposure Skin contact Eye Contact Inhalation Ingestion : : : : : : : Irritant, Corrosive Irritant, Corrosive Irritant effect on skin Causes severe irritation to eyes, pain.. Risk of serious damage to eyes. Inhalation hazard is unlikely. May cause slight irritation, coughing. Not thought to produce harmful effects. May cause slight irritation, discomfort.

Date of MSDS preparation : 27th October 2006

Rev.: 01

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CODEX 661 MATERIAL SAFETY DATA SHEET R-phrases S-phrases NFPA Code Environmental effects Hazard symbols : : : : : R41 ----Suggested rating H=3; F=1; R=1 ----Xi, C

SECTION 4 : FIRST AID MEASURES Eyes Skin Inhalation Ingestion : : Immediately flush eyes with plenty of water for atleast 15 minutes. Eyelids should be held apart during the flushing. Seek medical attention immediately. Remove contaminated clothing. Wash affected area with large amounts of water & soap. Seek medical attention immediately. If the clothing is contaminated, it should be laundered. In case of exposure remove exposed person to fresh air. If breathing has ceased, give artificial respiration immediately. Seek medical attention.. First rinse mouth. Give large amount of water to drink. Do not induce vomiting. Never give anything by mouth to an unconscious person. If a person vomits place him in recovery position. Aspiration may cause pulmonary edema and pneumonitis. Seek medical attention immediately. Pre-existing disorders of liver, kidney.

: :

Medical conditions likely to be aggravated by exposure Note to Physician

Treat symptomatically

SECTION 5 : FIREFIGHTING MEASURES HAZCHEM code Hazardous combustion products Conditions under which flammability could occur Extinguishing media Unsuitable fire extinguishing media Sensitivity to explosion Fire fighting procedure Special protective equipment for the fighters : : : : : : : : ----Corrosive vapours, Carbon dioxide, Phosphorus oxides Heat Water, Dry chemical powder, Dry sand , Alcohol resistant foam, CO2 None No Do not enter the area without proper protection. Do not allow the fire fighting water to enter water bodies. Do not breathe fumes. Wear self-contained breathing apparatus and full protective clothing. Equipment should be thoroughly decontaminated after use.

Date of MSDS preparation : 27th October 2006

Rev.: 01

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EXCEL INDUSTRIES LIMITED

CODEX 661 MATERIAL SAFETY DATA SHEET SECTION 6 : ACCIDENTAL RELEASE MEASURES Personal precautions : Try to stop the leak without taking undue risk. Do not inhale. Avoid contact with material. Use respiratory & personal protection recommended in Section 8. : Prevent mixing with water bodies, sewers. : Construct temporary dykes of sand, earth, dirt to prevent spreading of material. Absorb on sand, suitable absorbents or inert material.. Carefully collect material in containers for disposal. Use respiratory equipment & personal protective clothing. Don't use water for clean up. Dispose as per instructions mentioned in Section 13. : After clean up operations, decontaminate & launder all protective clothing and equipment before storing & reusing

Environmental precautions Procedures for dealing with release or spill (Major/Minor)

Additional instructions

SECTION 7 : HANDLING AND STORAGE HANDLING : Safe handling practices and equipment : Good industrial practice in housekeeping and personal hygiene should be followed. Avoid contact with eyes, skin and clothing. Ensure good ventilation at workplace. Instruction for fire & explosion protection: No smoking. STORAGE : Appropriate storage practices/ requirements: Store in cool, dry, well-ventilated area away from water, heat and ignition sources. Keep containers closed. Isolate from incompatible material & conditions. Protect against physical damage. Check regularly for leaks. Material of construction of containers: HDPE carbuoys, HMHDPE drums

SECTION 8 : EXPOSURE CONTROL / PERSONAL PROTECTION Occupational exposure limit values / Biological limit values: No data available Applicable control measures, including engineering controls: Good industrial practice in housekeeping should be followed. Ensure adequate ventilation of workplace & storage areas. Provide eyewash facility & safety shower. Industrial Hygiene Controls: Good personal hygiene practices should be followed. Avoid contact with eyes, skin and clothing. Wash hands before breaks and after work. Do not eat, drink, smoke in the workplace. Use personal protective equipment. Personal protective equipment for each exposure route (type & MOC): - Eyes : Safety goggles, Face shield. - Skin : PVC / Rubber gloves. - Clothing : Chemical resistant apron - Foot : Safety shoes / Gumboots - Respiratory protection : If risk of overexposure exists wear respirator with appropriate filter.

Date of MSDS preparation : 27th October 2006

Rev.: 01

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EXCEL INDUSTRIES LIMITED

CODEX 661 MATERIAL SAFETY DATA SHEET SECTION 9 : PHYSICAL AND CHEMICAL PROPERTIES Physical state Appearance Odour Vapor pressure & reference temperature Boiling point Melting point Specific gravity pH Solubility in water Flash point (with method) Upper explosive limit in air Lower explosive limit in air Auto ignition temperature : : : : : : : : : : : : : Liquid Colourless to pale yellow clear liquid Slight caramel odour 17 mm Hg at 20C @ 105C -25C 1.43 0.02 @ 25C < 2 (1% solution) Miscible in water Not applicable Not applicable Not applicable Not applicable

SECTION 10 : STABILITY AND REACTIVITY Chemical stability Conditions to avoid Incompatibility with other materials Hazardous decomposition products Hazardous polymerization Effect of weather (Humidity/ oxygen/ CO2) : : : : Generally stable under normal conditions of handling and storage. Heat Corrodes base metals. Reacts with oxidising substances, alkalies Gives off hydrogen by reaction with metals. Oxides of carbon, Oxides of phosphorus None None

SECTION 11 : TOXICOLOGICAL INFORMATION Toxicology data: Skin Ingestion Inhalation Irritancy Sensitization Carcinogenicity Reproductive toxicity Teratogenicity Mutagenicity Name of toxicologically synergistic products : Dermal LD50 (Rabbit) - 10000 mg/kg Dermal LD50 (Rat) - 7000 mg/kg : Oral LD50 (Rat) - > 2000 mg/kg : No data available : Irritation of skin, eyes, respiratory system : No data available : No data available : None : None : None : No data available

Date of MSDS preparation : 27th October 2006

Rev.: 01

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EXCEL INDUSTRIES LIMITED

CODEX 661 MATERIAL SAFETY DATA SHEET SECTION 12 : ECOLOGICAL INFORMATION Ecotoxicity: 1. Aquatic toxicity : EC50 / Daphnia / 48H : > 500 mg/l 2. Toxicity to algae : EC50 / Algae / 96H : 3.0 mg/l 3. Toxicity to fish : LC50 / Rainbow trout / 96H : 368 mg/l LC50 / Shrimp / 96H : 1770 mg/l : : : :

LC50 / Daphnia / 96H : > 400 mg/l

LC50 / Bluegill sunfish / 96H : 868 mg/l LC50 / Sheepshead minnow / 96H : 2180 mg/l No data available Not readily biodegradable T : 373 days No data available No data available

Mobility Persistence and degradability in soil/ water Bioaccumulation potential Other adverse effects (ODP, GWP, etc).

SECTION 13 : DISPOSAL CONSIDERATION Waste disposal information of product & contaminated packaging: Spill and waste disposal procedures approved by state and local authorities must be observed. Labels should not be removed from containers until they have been cleaned and decontaminated. Decontaminate the container taking suitable precaution considering hazard before reuse or recycle and dispose off as per local rules. Do not use empty containers for storing food. SECTION 14 : TRANSPORT INFORMATION Regulatory information IMDG UN No. 3265 Proper shipping name Corrosive liquid, Acidic, Organic, N.O.S.(Hydroxy ethylidene diphosphonic acid) Corrosive liquid, Acidic, Organic, N.O.S.(Hydroxy ethylidene diphosphonic acid) Corrosive liquid, Acidic, Organic, N.O.S.(Hydroxy ethylidene diphosphonic acid) Corrosive liquid, Acidic, Organic, N.O.S.(Hydroxy ethylidene diphosphonic acid) UN Class & Subs. Haz class 8 Packaging group III Label Additional information

ADR/ RID

3265

III

US-DOT

3265

III

ICAO/ IATA

3265

III

SECTION 15 : REGULATORY INFORMATION National laws/ Regional laws: Europe - EC / EINECS No. - 220-552-8 - Hazard Symbol - Xi

Date of MSDS preparation : 27th October 2006

Rev.: 01

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CODEX 661 MATERIAL SAFETY DATA SHEET SECTION 16 : OTHER INFORMATION Full text of R & S phrases given below: R41 - Risk of serious damage to eyes

DISCLAIMER: Information contained in this Material Safety Data Sheet is believed to be reliable but no representation, guarantee or warranties of any kind are made as to the accuracy, suitability for a particular application or results to be obtained from them. It is up to the user to ensure that the information contained in the Material Safety Data Sheet is relevant to the product manufactured/ handled or sold by him as the case may be. Excel Industries Limited makes no warranties, expressed or implied, in respect of the adequacy of this document for any particular purpose.

Date of MSDS preparation : 27th October 2006

Rev.: 01

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