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-1
K x 10 (s )
10
20
30
40
50
60
2,46
10,8
47,5
163
576
1850
5480
273
283
293
303
313
323
333
2,46
10,8
47,5
163
576
1850
5480
3,66
3,53
3,41
3,30
3,19
3,10
3,00
LnK
-10,613
-9,133
-7,652
-6,419
-5,157
-3,989
-2,904
0.00320
0.00360
0.00400
-4.00000
lnk
y = -11683x + 32,17
-8.00000
Ln k
Linear (Ln k)
-12.00000
1/T
a = -11683
b = 32.17
-Ea /R = -11683
lnK0= 32.17
R =8.312x10-3 J/molK
509
24.1
514
24.2
ln k ln ko
Linealizando tenemos:
y=a + mx
Entonces:
Ea
RT
522
38.1
541
90.2
546
140
555
172
766
782
787
795
814
819
828
1.31
1.28
1.27
1.26
1.23
1.22
1.21
y=a + mx
Luego:
-9.385
-8.331
-8.327
-7.873
-7.011
-6.571
-6.365
r = k P PH 2
77.0 C,
k P = 2.7 10-5
40.2 C ,
k P = 0.284 10-5
LnK = LnK 0 -
Ea
RT
LnK 2 = LnK 0 -
Ea
RT2
LnK1 = LnK 0 -
Ea
RT1
Siendo:
T1 = 77 C (350K )
K P1 = 2.7 10-5
T2 = 40.2 C (313.2K )
K P2 = 0.284 10-5
Luego:
Ln (
E 1
K2
1
)= - a( - )
K1
R T2 T1
Ln (
E
0.284 105
1
1
)= - a(
)
5
2.7 10
R 313.2 350
Ea = 55773.34775 J / mol
LnK1 = LnK 0 -
Ea
RT1
LnK 0 = LnK1 +
Ea
RT1
55773.34775
8.314 350
K 0 = 5693.519306 mol / cc (s atm) 1
LnK 0 = Ln (2.7 10-5 ) -
b) Recordemos que:
r = K P PH 2 ...... (1)
K P = K0Pe
r = K C H 2 .....(2)
K C = K 0C e
Pero:
H2 =
LnK C
E
=- C
(1/ T )
R
PH 2
RT
K P PH2 = KC
PH2
RT
KC = K P RT ......(3)
Aplicando logaritmo a (3) y derivando respecto a la inversa de T:
LnKC
LnK P
( LnT )
=
+
(1/ T )
(1/ T )
(1/ T )
E
E
- C = - P -T
R
R
EC - EP = RT .....(4)
Reemplazando valores en la ecuacin a T1 = 77 C (350K )
Ep
RT
Ec
RT
EC - EP = 8.314 350
EC - EP = 2909.9 J / mol
EC - EP =2.9099 KJ / mol
4. Calclese la energa de activacin y el factor de frecuencia a partir de los siguientes datos,
obtenidos para la formacin del ter metil-etilico en solucin con alcohol etlico.
0
12
18
24
30
273.15
5.6
279.15
11.8
285.15
24.5
291.15
48.8
297.15
100
303.15
208
Solucin:
K 105
5.6
11.8
24.5
48.8
100
208
T
0
6
12
18
24
30
1/T
3.663 103
3.584 103
3.509 103
3.436 103
3.367 103
3.300 103
y=a + mx
m=-9913,419
a=26,489003
Luego:
LnT
-9.7902
-9.0448
-8.3143
-7.6252
-6.9078
-6.1754
k aT b e E / RT
273,32
298,06
323,13
1,052
14,36
129,6
K x 10 (s-1)
Solucin:
De la ecuacin:
Sacndole logaritmo neperiano tenemos:
Donde:
T(K)
273.32
298.06
323.13
-11.462
-8.8485
-6.6485
3.659x10-3
3.355x10-3
3.095x10-3
5.6106
5.6973
5.7781
*10-53
20.96220685