Code

ENGINEERING CHEMISTRY
(Elective I)

L T P C 3 1 0 4

(Common to B.E. / B.Tech all Branches)

UNIT - I THERMODYNAMICS

(9)

Thermodynamic processes First law of thermodynamics Limitations - Second law of thermodynamics - Clausius and Kelvin statement Entropy - Mathematical expressions Changes in entropy for isothermal expansion - Reversible and irreversible processes Free energy- Gibbs Helmholtz equation Application and simple problems Vant Hoff isotherm and isochore - Simple problems. UNIT II POLYMERS (9)

Introduction to polymers, Thermoplastic and Thermosetting plastic. Ingredients of the plastic (Compounding of plastic.) Fabrication of plastic by Compression, Injection moulding.Preparation - Properties and Uses of PVC Teflon Polystyrene - Polycarbonate and Thermo Cole Resins - Urea-formaldehyde - Phenol-formaldehyde and Epoxy resins Compounding of Plastics - Injection moulding Compression moulding.Preparation, properties and uses of Phenolformaldehyde, PMMA , Kevlar. Effect of heat on the polymers (Glass transition temperatures) Polymers in medicine and surgery. Conducting polymers, Industrial polymers. UNIT III PHASE RULE AND ALLOYS (9)

Gibbs Phase Rule, Explanation, One Component System (Water) , Reduced Phase Rule, Two Component System (Pb-Ag),& (Zn-Mg), Limitations of Phase Rule. Alloys : Introduction, purpose of making alloys, Ferrous Alloys, plain carbon steel, heat resisting steels, stainless steels (corrosion resistant steels), effect of the alloying element, Ni, Cr, Co, Mg, Mo, W, and V. Non-Ferrous AlloysAlloys of Al i) Duralumin ii) Magnalumin. Alloys of Cu-Brasses i) Commercial brass ii) German Silver. Bronzes i) Gun metal ii) High phosphorus bronze. Alloys of pb i) Woods metal. ii) Tinmans solders. Their composition (Reference 1 by Jain & Jain ), properties & uses. UNIT IV FUELS AND COMBUSTION (10)

Analysis of Coal - Proximate and Ultimate analysis - Coke manufacture - Otto Hoffman method - Characteristics of metallurgical coke - Synthetic petrol - Bergius and Fischer Tropsch method Knocking - Octane number - Cetane number Production, Composition and Uses of producer and Water gas Combustion Gross and Net Calorific value - Theoretical calculation of calorific values Simple problems -Calculation of minimum requirement of air - Simple problems - Flue gas

analysis -Orsats apparatus. Bio-diesel, Method to obtain Biodiesel from vegetable oils (Transesterification), advantages and disadvantages of Biodiesel. Propellants: Definition, Characteristi cs of a good propellant, classification of propellants-examples . UNIT III SURFACE CHEMISTRY AND GREEN CHEMISTRY (8)

Adsorption types classification, adsorption of gases on solids; Freundlich and Langmuir adsorption isotherms; Role of adsorbents in catalysis; Green Chemistry: Introduction, Twelve Principles of Green chemistry, numericals on atom eco nomy, synthesis , adipic acid and indigo. Green solvents (ionic liquid supercritical CO2), and products from natural materials.

LECTURE :45

TUTORIAL : 15 TOTAL : 60

TEXTBOOKS 1. P.C. Jain and Monika Jain, Engineering Chemistry, 13thEdition, Dhanpat Rai Publishing Company (P) Ltd., New Delhi, 2004. 2. B.S.Bahl, G.D. Tuli and Arun Bahl, Essentials of Physical Chemistry, S. Chand and Company Ltd., New Delhi, 2004.

REFERENCE BOOKS 1. J.C. Kuriakose and J. Rajaram, Chemistry in Engineering and Technology, Vol.1 & 2, Tata Mcgraw Hill Publishing Company (P) Ltd., New Delhi, 1996. 2. B.K. Sharma, Engineering Chemistry, Krishna Prakasam Media (P) Ltd., Meerut, 2001. 3. Engineering Chemistry Dara & Dara, S Chand 4. Engineering Chemistry Wiley India (ISBN-9788126519880)