Professional Documents
Culture Documents
Newsletter
of
NORTH EAST INDIA RESEARCH FORUM
http://tech.groups.yahoo.com/group/northeast_india_research/
http://www.geocities.com/ne_india_research_forum/index.html
CONTENTS
1. THE FORUM 2
2. SCIENCE, R&D News 3
3. NE INDIANS MADE US PROUD 4
4. EVENT AND NEWS FROM NORTH EAST INDIA 5
5. NORTH EAST INDIA RESEARCH FORUM MEMBERS
IN NEWS, AWARDS / FELLOWSHIP RECEIVED BY MEMBERS 6
6. INTERNATIONAL CONFERENCE ATTENDED
BY MEMBERS OF THE FORUM 6
7. INSTRUMENT OF THE ISSUE –AFM 6
8. ARTICLES SECTION
a) Biofuel Based Rural Energy – The Issues and The Challenges
Dr. Dhanapati Deka 8
b) Glimpses Of Lindau Meeting 2002
Dr. Ashim Jyoti Thakur 12
c) Wastelands: The Hidden Potential
Ms. N. Bhattacharyya 16
d) Smart Materials: The Emerging Technology
Dr. Siddhartha Gogoi 17
e) Lentinula edods (Shiitake) – A mushroom species for human health care
Mr. Mahananda Chutia 20
f) Zeta Potential in Surface Chemistry of Minerals
Dr. Manash Ranjan Das 22
g) X-ray Absorption Spectroscopy: A Synchrotron-based Technique
for Structural Analysis-
Mr. Pankaj Bharali 23
h) Applications of structural adhesives in bonding aircraft structures
Dr. Rashmi Rekha Devi 26
i) Intellectual Property And Its Importance With Special Reference To Patents
Mr. Abhishek Choudhury 29
j) Seaweeds: A renewable reservoir of bio active molecules
Dr. Kamalesh Prasad 31
k) What is Nanoparticles and Why Nanoparticles
Md. Harunar Rashid 37
Prof. R.K.Boruah
fortunate to analyse for the first time the Lunar University of Missouri-Kansas City
sample carried back by Apollo-11 mission in (UMKC). He obtained the M.S. and Ph.D.
the early seventies of the last century. Dr degrees in
Goswami is also endowed with several
prestigious national and international awards,
namely the Indian National Science
Academy's Medal for Young Scientists
(1978), the NASA Public Service Group
Achievement Award (1986) and the Shanti
Swarup Bhatnagar Award for his pioneering
contributions to Planetary Sciences (1994). Prof. Deepankar Medhi
hundreds of kilohertz) and positioned above In this way, different kind of forces between
the surface so that it only taps the surface for a surfaces can be detected and quantified by
very small fraction of its oscillation period. AFM: mechanical contact forces, Van der
This is the recommended mode for imaging Waals forces, capillary forces, chemical
soft samples, which could be damaged in bonding, electrostatic forces, magnetic
contact mode. forces, solvation forces, friction forces, etc.
Non-contact mode is, in practice, Even conductivity in a sample can also be
similar to contact mode, but the applied load mapped using special AFM tip.
of the tip on the sample is so low that, in fact,
they are not in contact. The repulsive
interactions between the tip and the sample
allow the tip to scan the sample without
touching it. Usually this is a difficult mode to
operate in ambient conditions with the AFM.
energy carrier (Reddy, 1994).. Majority of the said that an increase in the family income
kerosene lamps are hurricane type lamps, leads to an increase in quantity of energy
which produce very poor light of about 60-70 consumed, a change in the type of fuel used
lumens (lm) (a 100 W bulb produces ~ 1300 and a change in the end use of the fuel
lm and for reading about 200 lm/m2 or lux is consumed ( Deka, 2000). In most of the
sufficient). Moreover, inefficient lighting rural areas, different energy sources and
services in the home and in public areas are devices are available, which are capable to
directly related to poor safety and personal meet their energy requirement. However,
security. these sources contribute to the well-being of
Insufficient access to modern and people only if these sources are properly
affordable energy services and technologies harness and utilized.
for agricultural activities, forces rural Regional variation on geographical
producers to cultivate more land, spending setting, socio-economic conditions of the
more times with excess manpower. Irrigation people, culture, food habit, abundance of
is mainly through electrical and diesel energy resource in the locality etc are also
pumpsets, while the rural industries and the playing important role in energy
transport sectors rely primarily on animal consumption pattern of a locality. Therefore,
power and to some extent on commercial there is need to identify problems along with
sources of energy like diesel and electricity. the demand and supply of energy in rural
Transport sectors in most of the villages are areas for each region before going for a need
still relying on animal power. Due to their base rural energy planning. Assam is a small
poverty, only small fractions are able to use state with a total population above 26
diesel or petrol driven vehicles. Rural millions. It is the centre of north-eastern
industries affect badly due to erratic supply of India and is a strategic corridor for South
electricity. The lack of energy is equally East Asia. Assam per capita income is
debilitating in the social service sector such as almost two third of the National Average.
education, health care, water supply, water 89% of the population are widely scattered
treatment, communicating roads etc. in rural areas and 41% are living below
The use of commercial fuels such as poverty line. Per capita electricity
kerosene, diesel, electricity etc. are largely consumption at 140 kilowatt hour (kwh) is
confined to urban areas whereas their less than one third of the national average
availability in the rural areas is limited due to and the lowest in India. Therefore improved
remoteness and high transportation cost power supply at a reasonable cost is
involved in them ( Singh et al., 1996). essential to revive the state industry and
Availability of electricity, kerosene, petroleum economic development. Most of the
etc makes life easy for the urban people. villagers in this region are still not aware of
Incomes of the households play important role the renewable energy systems, which are
on purchasing of these energy sources to meet thought to be bringing a change of their
their energy needs. LPG occupies major part energy use pattern. Fuel wood is a
as cooking fuel followed by kerosene. Per predominate fuel satisfying about 80% of
capita energy consumption is much higher the cooking energy need of the rural areas of
than rural people. There have always rural- Assam, which are burnt in inefficient
urban disparities on income distribution, traditional cook stoves.
expenditure pattern, energy availability, To address these problems, several
economic development etc. On an average, efforts have been made by both
one in every 25 households in rural areas had governmental and non-governmental
an income of more than Rs. 72,000 while organizations in the form of national
every fourth household in urban areas reported programmes for rural electrification, and
a similar income (Pradhan, 2000). It can be promoting renewable energy technologies
like biogas, improved cook stoves and solar oriented rural energy programmes in India.
cookers. However, in spite of the existence of We should analyze the most effective rural
these programmes for nearly two decades, energy policy in China for implementation
their impact on the rural energy scenario has in India also.
been limited. There is urgent need of It is increasingly being realized that
reorientation of the existing programmes to if local communities are to contribute
meet the energy need of the rural people. significantly and find sustainable solutions
to their environment and energy related
Rural Energy Policy and Issue concerns, there is need to build capacities at
The present supply-demand scenario the grassroots level in terms of creating
indicates that biomass would continue to be awareness regarding energy and
the mainstay of the rural energy sector in the environment issues, and developing
foreseeable future. The penetration of various technical and managerial expertise to plan
commercial fuels will remain quite low, and at and manage programmes effectively. The
the present rate, it would take a long time for existing target oriented programme on rural
the Renewable energy technologies to make energy of Govt. of India including National
any significant impact on the sector. Project for Biogas Development (NPBD),
Therefore, any policy formulated to deal with National Programme of Improved Chullah
rural energy will have to look for highly (NPIC), Integrated Rural Energy Planning,
innovative options and make judicious Solar water heating programme, solar
investment choices. cooker programme etc are fail to generate
There are several issues to be much response from rural people and it is
considered while formulating such policies found that only about 20% has been
such as technological options, dissemination implemented in our state so far out of the
approach, commercialization of rural energy total potentials. For rapid participation of the
technologies and capacity building at the root rural people on any rural energy programme
level. The principal thrust of any meaningful and for a successful implementation of such
rural energy policy is to shift from the present programme, it can be suggested that a
traditional biomass technologies to efficient decentralized rural energy programme is
biomass technologies, which provide greater necessary with the active involvement of the
energy service with same resource. Most rural local communities. Any such programme
energy programmes so far have been run as may be fruitful if the energy requirement in
centralized, target-oriented programmes a particular locality according to food habit,
exclusive of other programmes. However, socio-economic conditions, social
experience suggests that while determining the acceptability to new technologies etc. is
feasibility or adaptability of a particular considered as priorities.
programme or technology, it would be
important to consider the priorities of the local Conclusion
people, and bring about an integration of We need to evolve a comprehensive
various development programmes. The rural energy policy to meet the challenges.
problem of energy development in rural India Seeing the possibilities of supplement the
has many similarities to that in rural China. future cooking and lighting energy by liquid
Enormous challenges face both countries and gaseous fuels obtained from locally
regarding the design and implementation of available biomass sources, the production of
suitable strategies to accelerate the ethanol, biodiesel and pyrolysis oil may be
development of rural renewable energy. While emphasized. Similarly, supply of biogas
some strategies may exit similar forms in both from extremely efficient biogas digesters
countries, China has the state based rural together with efficient storage system may
energy planning against the centralized target be the basis of clean cooking energy. A
Glimpses Of Lindau Meeting 2002 the same discipline. The meeting in 2002
was the 52nd meeting. Every year, about 20-
30 Nobel Laureates and around 500
students/researchers from the different parts
of the globe assemble at Lindau. It is only in
the year 2000, when the meeting completed
50 years of its existence, around 53 Nobel
Laureates from all the discipline gathered
there. The aim of the meeting is to keep the
Dr. Ashim Jyoti Thakur
spirit of Alfred Nobel alive and to have
informal discussions and exchange of views
14th May, 2002, Wednesday.
among students/researchers and Nobel
Place: RRL Jorhat
Laureates through small group interactions,
round table conferences, invited lectures etc.
At 4.50 PM, only 10 minutes before
On the formal request of DFG
the closure of the working day, an urgent fax
(Deutch Forschungsgemeinschaft),
came from the Director’s office. I was
Germany, India started participating in the
winding up my works to have a cup of evening
Lindau meeting since 2001 (physics). On
tea. Seeing the fax, my joys knew no bounds.
behalf of India, Department of Science and
The partial content of the fax is as
Technology (DST), Govt. of India has been
follows:
given the responsibility for selecting
students/researchers to represent India in the
URGENT
meeting. After getting the news of my
Dear
selection, it took me several days to come to
Dr. Thakur,
a normal state, as I was excited and at the
Hearty Congratulations!
same time confused with what to do, how
and what to talk with the Nobel Laureates,
I am pleased to inform you that you have been
how they will respond, at what level they
selected for the DST Award for “Participation
will talk, will I be able to understand their
in the Meeting of Nobel Laureates and
explanation etc.. etc.. thousands of such
Students in Lindau, Germany.” A team of 20
questions were having their Brownian
students/young researchers has been chosen to
motions inside my brain. Frankly speaking,
represent India in this meeting.
at that time, I did not have so much of
……………………………………..
exposure to the national and international
Yours sincerely
science. Therefore, confidence level inside
‘me’ was not up to the mark.
G. Padmanabhan
Because, the intellectuality level
within the Nobel Laureates are far above my
Historically, this Lindau meeting is
normal level of intellectuality (if I have
the only gathering where one can have very
any). However, keeping in mind the great
close interactions with the Nobel Laureates in
remark, “Every human being is endowed
a informal way. Dates back to 1951, when the
with his/her faculty of intelligence, but
first of this meeting was organized at Lindau.
intellectuality is perhaps a bit distinct from
Since then every year the same has been
common intelligence”, my confidence level
organized for a week in the month of June by
moved to a higher (how much?) degree.
the Committee of the meetings of Nobel
That was my maiden abroad visit
Laureates in Lindau. The meeting has been
and air travel as well. Actually, the moment
dedicated to one discipline-chemistry, physics
I stepped into the Lokopriya Gopinath
and physiology & medicine rotation wise.
Bordoloi International Airport, Guwahati,
That is, every third year will be dedicated for
everything was quite new to me, my hours. The earlier night Germany lost the
experiences started piled up. Our World cup final. Otherwise we could have
accommodation at Delhi was arranged in a been a part of Germany’s triumph. Without
guesthouse at Safdarjang Enclave. The two having sufficient sleep, in the morning at 8
days stay at the guesthouse was very am we headed for the venue to attend the
enjoyable, memorable one. I was shocked opening ceremony, an excellent hall called
about the knowledge the other people had ‘Inselle Hall’ near to our Hotel, Gasthof Stift
about North East. They were very much almost 5 min walk.
interested in this part of India and asked me so Our programme started at 8.30 in
many silly questions. To my opinion, we the morning, 1st July. Some of the
cannot blame them, because media have interesting events and moments will be
exposed the North East as a dense jungle full mentioned here. The topic of the round table
of extremists, wild animals, cannibals etc., conference was “What can chemistry and
uncivilized people and customs. North East is the scientific community contribute in
far from the ray of modern civilization. But Alfred Nobel’s spirit to the benefit of
eventually, I was able to convince them. mankind in the 21st century.” The
Anyway, it was nice to meet the people of conference was chaired by Prof. Bengt
other premier institutes of India like IITs, IISc. Norden, other participants were Prof. Paul
etc. Before leaving for Germany, we had Crutzen, Prof. Richard Ernst, Prof. Sir
couple of briefings and warm up activities at Harold Croto, Prof. George Olah and Prof.
Delhi. There were tours to Ranbaxy Ahmed Zewail. It was emphasised by all
pharamaceutical Ltd, Institute of Genomics that chemistry should shake hand with
and Integrative Biology (IGIB) etc. and we biology for further progress. The role of
had the opportunity to look at the applied part chemists at the genomic research was
of chemistry and chemical engineering. The discussed in detail. In the afternoon, the
interactive session was very interesting. Then officials conducted Lindau tour for the
S&T minister Dr. Murli Manohar Joshi; DG, participants. In the dinner, I was amazed to
CSIR, Dr. Mashelkar; Secretary, DBT, Dr. see the Nobel laureates taking part in ball
Manju Sharma; Secretary, S&T Dr. V.S. dancing.
Ramamurthy are some of the eminent persons Prof. Ahmed Zewail (1999 Nobel
who addressed us at the briefings. Dr. Joshi’s Laureate) delivered a beautiful lecture on the
lecture was very inspiring, illuminating and topic “Chemistry and Biology in a new
thought provoking. How a strong and focused light.” All realized his research on
observation coupled with a prepared mind can Femtochemistry and its great potentiality. In
gift a researcher excellent piece of work that his lecture it was the feeling like the
was clear from personal experiences in his marriage of chemistry and biology. He
brief lecture. Dr. Padmanabhan sir was kind described success as - “The path of
enough to listen our views and problems. He discovery is not straight. The path is full of
tried to fulfill all our requests at his best. surprises, full of hard work; it depends on
Our journey started on 30th June, 4-15 being in the right place at the right time.
am. Lindau, a picturesque city on the bank of Discovering something also depends on
Constanz, Germany. After a journey of around passion. If you have the passion and you are
23 hours from New Delhi to Lindau via Paris honest about it, you will do something
and Munich, we were completely exhausted. important.”
Only the driving force was our spirit, Self organization is an important
otherwise we did not have any stamina that phenomenon in supramolecular chemistry.
could fuel us and kept us going. We reached Prof. Jean-Marie Lehn put forwarded his
Germany on the wee hours of 1st July 2002. findings in self-organisation of functional
For lack of time, hardly we could sleep for 4 supramolecular systems.
Evergreen, 1991 Nobel Laureate Prof. fossil fuel, tropical and sub tropical region is
Richard Ernst discussed the application of badly affected.
Fourier Transformation (FT) methods in Prof. George Olah, pointed out the
spectroscopy, especially the revolutionary challenges to come in the future with
changes in 2-D NMR spectroscopy. Although extensive data in his lecture, “Hydrocarbons
FT is an integral part of Mathematics, but and Global Warming: Facts, Challenges and
nevertheless it also occupies an important possible solutions.” It is well known and
position in other disciplines. We were very well recognized that among the
much delighted to know his other interests.
Can you believe? He has vast knowledge and
collection of Tibetan arts. He criticized the
foreign policy of Bush administration
vehementally in cartoon he prepared himself.
An interesting presentation was from
Prof. Paul Boyer. Our general perception is
that the oxygen we breathe is our friend.
Because with breathing it goes to the cells and
helps in the synthesis of energy molecule,
namely ATP. ATP breaks down to provide the
energy required for the different functions of
our body. But can it be our foe? The free
radical character of oxygen makes it so
reactive that we cannot ignore the dark side of
it. At this stage it becomes dangerous. environmental problems, Global warming is
The subject matter of Prof. Paul one of the extremes. The main reason for
Crutzen (1995) of Mainz was atmospheric this is the emission of carbon dioxide due to
chemistry and climate. The ozone layer in the the excessive use of coal, oil, natural gas etc.
stratosphere acts as a blanket and cut the UV His research is how to synthesise methanol
radiation so that it cannot reach the earth, from carbon dioxide and water and from
thereby saving the lives on earth. On the other methanol ultimately hydrocarbon in a
hand, reacting with water molecule it forms sustainable manner. In this way we can
hydroxyl radical. This hydroxyl radical reduce the amount of carbon dioxide in the
destroys the unwanted gases coming out from atmosphere and at the same time fuel
the industries. Hence, the hydroxyl radical is scarcity will also be reduced.
called the ‘detergent’ of atmosphere. Due to The most popular Nobel Laureate
geographical reasons, the amount of hydroxyl was Prof. Harold Croto of Sussex University
radicals is larger in the tropical region. (1998) with a smile always. When he
Therefore a large amount of the emitted gas is proceeded to the stage with models of
removed from this area. On the other hand, Fullerene and carbon nano tube in hand, it
since the amount of rain fall and the water looked so attractive that everybody was
vapour content is highest in this region, happy. Croto described this nanotube as
tropical region plays an important role in order “elongated cousins of Buckminister
to keep our environment clean. In this regard, fullerene.” His suggestion to us was, “You
we find the relevance of studying atmospheric need to learn is doubt. Don’t believe
chemistry. On the basis of these arguments, anything you’re told without good reason
one can think that the tropical region is the and argument.”
cleanest part of the atmosphere. But the reality Olah is very much true in the saying
reveals something different. With the increase that Science is international-there is no
in the burning of anthropogenic mass and American or German Science. A scientist
shouldnot worry about the nationalities rather To wind up, “Lindau in general and
concentrates on solutions. We should find out this meeting is like a magnet.” Like other
the best science and solutions. participants, it attracts me a lot and I hope I
After genome sequence, now it is turn will have opportunity again to visit Lindau
for structural genomics. The aim is to find out at least once more during my life time, so
the 3-D structures of all proteins. Prof. Johann that it doesn’t remain as ‘once in lifetime’
Deisenhofer illustrated these developments in achievement. With that hope, I sign out here.
simple and lucid way. He was more confident
that the research in structural genomics would Short Biodata of the Author:
help in understanding the protein folding and Ashim Jyoti Thakur, hails from a small hilly
unfolding. town, Diphu in the Karbi Anglong District
of Assam. Presently, a lecturer (since 29th
July 2004) in the Department of Chemical
Sciences, Tezpur University, Napaam,
Tezpur, Assam. He graduated from Cotton
College (1995), Guwahati and completed his
Masters from Gauhati University in 1998
(1997 batch).
This practice will reduce the pressure on the Smart Materials: The Emerging
agricultural lands available. Technology
With the help of proper management
techniques, the wastelands can provide
adequate support to the majority of our
population, which still lives on a bare
subsistence level. These lands are capable of
producing enough fodder, forage, fuel or at
least some vegetation cover to prevent further
soil degradation. Recently, experimental
practices are going on in various parts to
utilize the wastelands successfully to grow
market oriented medicinal and aromatic Dr. Siddhartha Gogoi
plants, bio-diesel plants etc. Possibilities are
bright for the considerable improvement of What is Smart material? The
fertility status of wastelands due to material can be treated as a smart when it
accumulation of biomass, crop stubbles, leaf exhibit interesting intrinsic characteristics
litter, rhizospheric microbes etc. from the which can be exploited within systems, or
cultivated lands. structures that, in turn, can exhibit ‘smart’
References: behavior. For example, a photo-chromic
1. Bhatt BP et al (2005), Restoration of material that changes its colour when
degraded land through Agro-forestry exposed to light is smart but a simple metal
inventions; Agroforestry in Northeast that changes its physical state when heating
India, Opportunities and Challenges. Pp to its melting point is not smart.
427-436. Science and technology have made
2. IFPRI, (1999) “How large a threat is soil amazing developments in the design of
degradation?” 2020 News Letter. electronics and machinery using standard
3. Vancatesan J (2006), Wastelands: is it time materials, which do not have particularly
to rethink? Current Science, 91(11): 1454- special properties (i.e. steel, aluminum,
1455 gold). Science and technology in the next
4. WRI (2005) World Resources 2000-2001; century will rely heavily on the development
People and Ecosystem- the Fraying Web of new materials. "Smart" or "intelligent"
of Life. materials will play an important role in this
development. Imagine the range of
Short Biodata of the Author: possibilities, which exist for special
Ms. Nabanita Bhattacharyya is working as a materials that have properties scientists can
lecturer Department of Botany, Nowgong manipulate. Some such materials have the
College, Assam. Her research area is Plant ability to change shape or size simply by
Physiology and Biochemistry. The title of her adding a little bit of heat, or to change from
Ph.D thesis is ‘Investigation on physiological a liquid to a solid almost instantly when near
performances on Houttuynia cordata Thunb a magnet; these materials are called smart
(Masandari)- with reference to its materials. These are materials that have one
phytoremediation potential in uncultivable or more properties that can be significantly
land’ altered in a controlled fashion by external
stimuli, such as stress, temperature,
Email: msnbhattacharyya@yahoo.co.uk moisture, pH, electric or magnetic fields.
Research on smart materials is
------------------------o----------------------- concentrated in the United States and Japan
and shows a distinct difference between
agent, liver function, controls high blood medicine as well as special food in China
pressure and heart ailments and helps in and Japan. However, South Asian countries
building resistance. The most significant also started Shiitake cultivation in large
shiitake product on the market today is LEM scale. The eco climatic condition of NE
(trade name), an extract produced from region is congenial for large-scale
mycelia that shows high oral activity. propagation of quite a number of medicinal
Lentinan, an approved drug in Japan is the mushroom species, which can be harnessed
highly purified polysaccharide fraction of to take care of human health. A concerted
extracted mushrooms. It is generally effort from government, NGOs, educational
administered by injection and has been used as institutions and corporate sector is essential
an agent to prolong survival of patients in for assured market of Shiitake for country
conventional cancer therapy as well as in wide growers as well as its popularization of
AIDS research. Lentinan is currently in Phase this high value medicinal mushroom.
II clinical trials in the U.S.
Short Biodata of the Author
Mr. Mahananda Chutia is working as a
project assistant at Regional Research
Laboratory, Jorhat, Assam in the Plant
Science Division in a project related
mushroom and medicinal & aromatic plants
(DBT Project). He did his M.Sc. (2003) in
Botany with specialization in Microbiology.
He has also qualified NE SLET. He has
published several research article in national
North- Eastern region of India and international journals. His research
comprising hills and plains with varied eco- interests include Microbial diversity and
climatic pockets offers tremendous scope for Molecular Biology, Cell Biology and
large scale cultivation of medicinal Immunology.
mushrooms. Shiitakes grow naturally on Asian Email: mahanaba@yahoo.co.uk
oaks and beeches. For cultivation purposes, --------------------o--------------------------
they will also grow on other hard woods
including oak, sweetgum, poplar, cottonwood,
eucalyptus, alder, ironwood, beech, birch, Once you start a working on something,
willow, and many other non-aromatic don't be afraid of failure and don't
broadleaf trees. In India, the tribal population abandon it. People who work sincerely
of Manipur, Nagaland, and Mizoram grow this are the happiest.
medicinal mushroom species. At present,
Manipur is the only state in NE India, where
active cultivation of Shiitake has been initiated
in an organized way. However, Horticulture
Department, Govt. of Meghalaya has also
started working with Shiitake in order to
introduce this important species of mushroom.
A small Shiitake farming unit can earn at least
75 to 80 thousand rupees annually which can Chanakya(Indian politician, strategist and
provide very good incentive to the rural poor. writer, 350 BC-275 BC)
Shiitake cultivation and marketing is
indeed a global industry. For thousand of
years, Shiitake has been revered as traditional
energy occur. Because of the high probability coordinating shells. In the EXAFS region,
of such transition, a sudden raise of absorption the photoelectrons have high kinetic energy
is observed. In NEXAFS, the ejected (E-E0 is large), and single scattering by the
photoelectrons have low kinetic energy (E-E0 nearest neighboring atoms normally
is small) and experience strong multiple dominates.
scattering by the first and even higher
Figure 2: Schematic diagram of XAS experimental set up. The sample holder
(Koningsberger cell, golden colour) is also shown.
Figure 3: Actual XAS experimental set up showing different Ionization Chambers (ICs).
film adhesives over the redux system are the flow and glow line thickness during
twofold: (1) these are supplied at exactly the cure. AF163-2 is a film adhesive supported
desired weight and (2) the formulation is with nylon scrim to control flow and glue
precisely controlled. line thickness which was developed by 3M
The next major improvement in Co.
aircraft adhesives occurred in the late 1950s Scrims act as carriers for the
with the introduction of adhesives based on otherwise fragile raw adhesive polymers
epoxy resins. They dominate the field of enabling the film to be handled. The scrim
structural adhesives Once cured they are also serves as a glue line control device and
characterized by high chemical and controls the adhesive flow during the curing
corrosion resistance as well as good phase. Scrims may be of cotton fabric,
mechanical and thermal properties. Since polyester, nylon or of glass.
these adhesives crosslink via an addition 2. Metal/Metal honeycomb bonds-hot cure
reaction, no volatiles are released during hot Only epoxy systems are used for
cure. This made low pressure bonding these applications. Hexcel Redux 308 is an
possible and the use of no perforated unsupported epoxy film adhesive with no
honeycomb feasible in sandwich structure. flow modifiers and is bonded at 1800C at a
There are two basic needs of an pressure of 345 kPa.
adhesive bonding in aircraft structures. The AF3109-24 is another unsupported epoxy
first is that the adhesive will stay stuck for film adhesive with no flow modifiers and
the life of the structure, in all service and was developed by 3M Co.
storage environments, while the second is 3. Structural metal to metal- cold cure
that the adhesive will not fail even when the Two epoxy systems most used in
surrounding structure has been broken. aircraft structural bonding are Hysol-Dexter
The adhesive materials used for EA9330.1 and SW9323B/A-150. The two
these purposes fall into three distinct groups. adhesives contain a small amount of glass
These are beads to control the thickness of the glue
1. Metal/metal- hot cure line.
The hot cure adhesive materials Figure 1 gives some of the
used by the aircraft industry are mainly indication of the degree to which bonding is
based on either phenolic or epoxy resin utilized in a modern aircraft. Aircraft
systems. applications to date have included the
Redux film 775 is one of the most bonding of reinforcing doublers and
important of the metal-to metal adhesives stiffeners to both fuselage and wing panels;
used for major structural build applications. the former being employed to reinforce
In the UK, Redux Film 775 was first used in holes for mechanical fasteners and
1962 by DeHavilland on the 125 Business window/door openings. In addition epoxy
Jet. Cytec FM47 is a film adhesive film adhesives are frequently employed for
supported by glass fibre scrim and the production of honeycomb sandwich
toughened with polyvinyl butyral. 3M Co. structures where aluminium or Nomex
developed an unsupported film adhesive honeycomb is bonded to aluminium or
toughened with nitrile rubber (AF31). composite skins. Such structures have been
Hexcel Redux 308A (NA) is an employed to produce aircraft structures such
unsupported film adhesive with spun rock as rudders, flaps, elevators, ailrons, doors,
wool added to control flow during curing floor panels as well as engine structures
and aluminium powder to increase such as nacelles and thurst reservers since
toughness. This adhesive film is also used in they provide attractive combinations of
bonding the metal-to-metal flanges of metal- strength, stiffness and weight in addition to
to-metal honeycomb structures. Cytec offering excellent fatigue and sound
FM73 is a film adhesive supported by insulating characteristics. Cold cure epoxy
polyester knit fabric scrim which controls adhesives are employed in the repair of
aircraft components which have suffered which could not have been achieved with
damage due to accidents (ground impacts for conventional riveted structures. Cessna made
example), lightning strike and bird impact. an even more extensive application of
Some aircraft manufacturers have bonding to the fuselage of the Citation II jet
made extensive use of adhesive bonding. De aircraft, and used the same technology to
Havilland and Fokker were the pioneers in make wings on other aircraft with far fewer
adhesive bonding in primary aircraft fuel leaks than on conventional riveted wing
structures. Extensive use of adhesive bonding boxes. The secondary structures, control
was seen in bonding aluminium airframe of surfaces and fixed panels, on the Boeing 747
the SAAB 340 aircraft. The aircraft has a made extensive use of metal bonding, mainly
superior structural efficiency and durability, with honeycomb.
Figure1 Diagram of an aircraft showing the sections of the aircraft that are adhesively bonded.
Short Biodata of the Author structures, carbo - graphite materials for high
performance applications and development of
Dr. Rashmi Rekha Devi, has been serving as wood-polymer composites.
Scientist ‘B’ in Defence Materials & Stores
Research & Development Establishment -------------------------o----------------------------
(DMSRDE), DRDO, Kanpur since 2005. She
did her M. Sc. in Polymer Science from the -The world is his who does his job with
Department of Chemical Sciences, Tezpur compassion
University, Assam in 2000. She was awarded
Ph. D. degree by the same university in the by Saint Tiruvalluvar (Tamil poet)
year 2006. Her Ph.D. works are on Wood-
polymer composites. Her areas of interests are
Development of UV-curable adhesives,
structural adhesives for joining aircraft
Intellectual Property And Its and Technology I would like to highlight the
Importance With Special Reference form of IP which is more useful for us and it
To Patents is nothing but PATENTS.
Now, what is a Patent?
We usually fence our plot where we
planned to stay. The reason for doing that is
to protect it from acquisition by another
party. Patent is nothing but fencing around
our invention. So that we can legally
prohibit the other party from using my
invention for his profit. In a formal way we
Abhishek Choudhury can say that patent is monopoly granted to
the applicant by the judiciary. Patents are
“Intellectual Property”(IP) is issued for a period of twenty years and are
nothing but a type of property. Now what is country specific also. There exist three
the difference between the property we essential criteria which determines the
thought of and the property named as IP. For patentability of an invention. These are
this we have to define first the two types of 1. Novelty
property. One is of tangible form and the 2. Non-obviousness and
other is of intangible form. By tangible 3. Utility
property we mean Land, Jewallaries, After 18 months from the date of
Buildings etc. which we can touch, see and filing of a patent, the patent document is
then feel. But, IP is not a property of such published by the patent office of the
type. This is the one which we, the human respective countries. Legally the most
beings create through our intellectual important part of a patent document is the
understanding. It may be a poem or a story ‘CLAIMS’. The whole invention is legally
or a piece of art or an invention. The protected by claims from any sort of
tangible properties we care a lot. Because exploitation.
we spend money to buy or to acquire those Another part of the patent document
and where there is investment we always try which is very important from researchers
to maintain that. Our aim is to save our point of view is ‘DESCRIPTION’. In this
property for the sake of ourselves and for part we have background of the invention
our coming generations. and the whole experimentation which is
Similarly IP is also a valued done. In this part the inventors have to
property. We use our most valuable time to describe the exact condition of
create it. Directly and indirectly we spend experimentation that can be repeated by
money also for its creation. The ultimate anybody anywhere, which is known as best
work is a outcome of our own effort. This is mode.
not less then that what we invest for Grant of a patent does not guarantee
acquiring tangible properties. Why not to any monitory benefit until and unless we
aware of our IP then? commercialize our invention. We have two
In a formal term IP is a product of ways for commercial utilization of our
the intellect that has commercial value, invention. One is to license our invention to
including copyrighted property such as a second party for production and sell. The
literary or artistic works, and ideational second one is to manufacture, produce and
property, such as patents, appellations of sell by ownself. Developed countries like
origin, business methods, and industrial US, UK, JAPAN etc. are very strong in
processes. protecting their IP.
As we are in a profession, which is University of Texas, North Carolina
related with Research in the area of Science University, Massachusetts Institute of
Technology and many more are having
-----------------------------o-------------------------------
The Archimedes screw. This was a machine with a revolving screw shaped blade,
and was used to drain ships and transfer water from a low-lying body of water into
irrigation canals. Versions of the Archimedes screw are still in use today in developing
countries.
CHAPTER I
OsO4 - Catalyzed Amination of Silyl Enol
Ethers : Enantioselective Synthesis of α-
Amino Ketones
OsO4, Chloramine-T O
OTMS
t-BuOH : H2O (1 : 1) NHTs
R2 R1
R1 (DHQD)2-CLB or PYR
R2
R1, R2 = alkyl, aryl 1
Scheme-1
CHAPTER II Section A :
Synthesis of Optically Active Amino Acids Enantioselective Synthesis of α-Hydroxy β-
Using Asymmetric Aminohydroxylation Amino Acids
In recent years syn-β-amino-α-
hydroxy acids (2) have received
The OsO4 catalyzed asymmetric
considerable attention as crucial component
aminohydroxylation (AA) of olefins has
of peptidomimetic protease inhibitors. For
become the most powerful method for the
instance (2S,3R)-β-amino-α- hydroxy unit
preparation of a wide variety of
has been found in amastatin and a marine
enantiomerically pure aminoalcohols. Direct
natural product microginin which inhibits
and one pot introduction of both amino and
angiotensin-converting enzyme. Several
hydroxyl functionalities make this process
multistep syntheses are known for the
more practical. In this chapter this synthetic
synthesis of this moiety. Here a very short
methodology is applied to synthesize amino
route is described for the synthesis of two
acids. This chapter is further divided into
such compounds (Scheme 2).
two sections.
Scheme - 2
Section B : important class of non-proteinogenic
A Short and Efficient Synthesis of aminoacids. Aryl glycines are present in
Enantiomerically Pure Naphthyl Glycine many biologically active compounds such as
1–Naphthyl glycine (3) is a cephalosporins or nocardicins. Moreover
representative example of aryl glycines, an they have potential interest as
Scheme - 3
Scheme 4
Section B : various stages of clinical trials. In the past
Asymmetric Synthesis of the Antiarrhythmia few years considerable progress was made
agent R-(+)–Sotalol in the preparation of R-(+)–Sotalol by chiral
Reentrant ventricular arrhythmia is a major chromatographic separation, chiral
factor for most cases of sudden cardiac homogeneous hydrogenation etc. This
death. Class III antiarrhythmia compounds section describes the enantioselective
such as R-(+)–Sotalol effectively control synthesis of R-(+)–Sotalol using asymmetric
such arrhythmia and these drugs are in dihydroxylation process (Scheme 5).
Scheme 5
CHAPTER IV
Transfer Hydrogenation of carbonyl
compounds using transition metal catalysts
The reduction of multiple bonds Section A: Transfer
with the aid of hydrogen donor in the Hydrogenation of Carbonyl Compounds
presence of a catalyst is known as Using Homogeneous Macrocyclic Nickel
transfer hydrogenation. In comparison complex
with catalytic reduction using molecular Compounds of most of the elements
hydrogen, transfer reduction using H- from the second transition series in the
donors such as ammonium formate, periodic table are suitable for catalytic
isopropanol, etc. has real and potential reduction. Both salts and complexes of Pd,
Pt, Ru, Ir, Rh, Fe, Ni, and Co have been
advantages since it avoids the risks and
used as catalysts for the transfer of hydrogen
constraints associated with high pressure from molecular hydrogen or hydrogen
reactors. In this chapter several donors to organic substrates. Most of the
homogeneous, heterogeneous and chiral complexes reported contain the triphenyl
catalysts have been synthesized and phosphine moiety. This section describes the
screened for transfer hydrogenation of synthesis of Ni complex (I) and its
carbonyl compounds. This chapter is remarkable catalytic activity for the
divided into three sections. chemoselective reduction of carbonyl
compounds (Scheme 6).
Scheme 6
Scheme 7
Section C asymmetric transfer hydrogenation. But Ni
Use of Chiral Nickel Complexes for based catalyst is not studied so far for
Asymmetric Transfer Hydrogenation of asymmetric transfer hydrogenation. This
Ketones section contains a study on various Ni based
The interest over the development of chiral complex for asymmetric transfer
new chiral catalyst is increasingly growing hydrogenation of carbonyl compounds
in recent years and many Rh and Ru based (Scheme 8).
catalysts have been developed for
Scheme 8
CHAPTER V catalyst, these materials exhibit appreciable
acid activity with shape selective features. In
Organic Transformations Using addition, these materials can act as support
Heterogeneous Catalysis for a variety of catalytically active metals.
Zeolites and clays are Use of these catalysts for various organic
aluminosilicates finding numerous transformations are investigated in this
applications in many areas of catalysis chapter which is further divided into three
generating intense interest in industrial and sections.
academic laboratories. Reusability and
recyclability make these catalysts more
useful particularly in the industrial scale. As
Scheme- 9
Scheme 10
Section C : has been studied. The study has resulted in
Cu-Exchanged Montmorillonite K10 clay the development of a convenient
Mediated Insertion Reaction of Methyl methodology for the synthesis of β-acid
Diazoacetate into Acids and Thiols esters and β-thio esters respectively (Scheme
The reaction of methyl diazoacetate 11).
with a variety of aromatic and aliphatic
acids and thiols catalyzed by Cu–Mont K10
Scheme 11
Chapter I
Highly Regioseletive Ring Opening of
Epoxides with NaN3: A Short Synthesis of
(-)-Cytoxazone
OH OH
COOMe COOMe COOMe
OH OTs
MeO MeO MeO
1 2 3
O
HN N3
O O COOMe
COOMe
MeO OH OH
MeO MeO
Cytoxazone 6
5 4
Scheme 1
Ref: Boruwa, J.; Borah, J. C.; Kalita, B.; Barua, N. C. Tetrahedron Lett. 2004, 45, 7355-7358.
7 8
Kinetic Resolution
9 10
N N
O O
O O
11 12
Scheme 2
Ref: Boruwa, J.; Kalita, B.; Barua, N.C.; Borah, J.C.; Mazumder, S.; Thakur, D.; Gogoi, D.K.;
Bora, T.C.
Bioorg. Med. Chem. Lett, 2004, 14, 3571-3574.
Chapter III
Selectively Protected 1, 2-diol from Epoxides Nitrite ester has been projected as new
in Aqueous Media: A Short Asymmetric protecting group for alcohol by synthesizing
Synthesis of Chloramphenicol a series of selectively protected 1,2-diol from
epoxides in aqueous media. The utility of achieving a short synthesis of widely used
this reaction has been demonstrated by antibiotic Chloramphenicol.
O ONO ONO
O COOMe COOMe
OMe
OH N3
13 14 15
OH OH
OH
OH HN O
O2N
NH2
16 17 Cl Cl
Scheme 3
Ref: Boruwa, J.; Borah, J.C.; Gogoi, S.; Barua, N.C. Tetrahedron Lett. 2005, 46, 1743-1746
OR
OH OHC O2N
EtO
O O O O
O OH
18 19 20
OTBS OTBS
OHC
O O OH O O
21 22
OTBS OAc OAc
O O O O OAc
O O
23 24
Scheme 4
Ref: Boruwa, J; Barua, N. C. Tetrahedron 2006, 62, 1193-1198 (Rated among the top 25 articles
published in Tetrahedron in 2006).
and M. Sc from the same university in 2000.
Short Biodata of the Author In 2001 he joined Regional Research
Joshodeep Boruwa was born in 1976 in Laboratory, Jorhat (CSIR) and received his
Dibrugarh, Assam. He obtained his B. Sc Ph. D degree in 2006 working on total
degree from Dibrugarh University in 1997 synthesis of natural products under the
By Mahen Konwar
Aula Magna Auditorium, Stockholm
By Mahen Konwar
Physics: John C Mather
6. Pankaj Bharali,
Indian Institute of Chemical Technology, Hyderabad, India.
Email: pankaj_rrlj@yahoo.co.in
7. Arindam Adhikari, Ph.D. (Volunteer editor of this Issue )
Logo designed by:
Manab Sharma, Ph.D.
Dept of Chemistry, Technion-Israel Institute of Technology, Israel.
Email: mansharma123@yahoo.com