Professional Documents
Culture Documents
Newsletter
of
NORTH EAST INDIA RESEARCH FORUM
http://tech.groups.yahoo.com/group/northeast_india_research/
http://www.geocities.com/ne_india_research_forum/index.html
CONTENTS
1. THE FORUM 5
2. SCIENCE, R&D News 6
3. RECENT DEVELOPMENTS: Organic Chemistry 7
4. NORTH EAST INDIANS MADE US PROUD 8
5. EVENT AND NEWS FROM NORTH EAST INDIA 9
6. NORTH EAST INDIA RESEARCH FORUM MEMBERS
IN NEWS, AWARDS / FELLOWSHIP RECEIVED BY MEMBERS 11
7. INTERNATIONAL CONFERENCE ATTENDED
BY MEMBERS OF THE FORUM 11
8. VISIT BY MEMBERS 11
9. INSTRUMENT OF THE ISSUE – QCM 12
10. ARTICLES SECTION
a) Ceria Based Mixed Oxides: Emerging Materials for Auto Exhaust Catalyst Formulation
Mr. Pranjal Saikia 14
b) COAL: The most abundant natural fuel
Mr. Binoy Kumar Saikia 16
c) Ionic Liquids: An Invitation to Innovate
Dr. Diganta Sarma 18
d) Crystal Polymorphism
Mr. Bipul Sarma 22
e) Octadecanuclear Manganese Single-Molecule Magnet: Synthesis and Magnetic
Properties of [MnII4MnIII14(O)14(OAc)18(hmp)4(hmpH)2(H2O)2]
Dr. Akhilesh Kumar Gupta 26
f) Rain Drop Size Distribution and Radar Observation of precipitating system
Mr. Mahen Konwar 29
g) Challenges in the Plant Biotechnology
Ms .Nabanita Bhattacharyya 31
11. ABSTRACT OF PhD THESIS/ RESEARCH WORK
a) Ph. D. thesis abstract of Dr. Pompi Hazarika 34
(Biofunctionalized gold nanoparticles: Synthesis, Characterization and Applications)
b) Ph. D. thesis abstract of Dr. Sasanka Deka 41
(Studies on the Magnetic and Electrical properties of Nanosized Transition
Metal Oxides and Ferrites)
12. EVENTS FROM HISTORY OF SCIENCE 43
13. INFORMATION ABOUT MEMBERS 44
14. HIGHER STUDY ABROAD ( Country of this Issue: Italy) 45
15. THROUGH THE LENSE OF FORUM MEMBERS 46
THE FORUM
North East India Research Forum was • Selection of name for Newsletter
created on 13th November 2004. There were total 36 proposals submitted
by members of the forum for the
1. How we are growing. Newsletter. The name proposed by Mr.
At the beginning, it was a march hardly Abhishek Choudhury, N. E. QUEST
with few members and today the forum received the maximum number of votes
comprised of a force of more than 140 and hence it is accepted as the name of
researchers. the Newsletter.
- by Mark Twain
the 'tooling factor'. One way to determine becomes invalid. A film that is "soft"
the tooling factor is to move the sensor head (viscoelastic) will not fully couple to the
between the sample position and the oscillation of the crystal, hence the
measurement position; the ratio between the Sauerbrey relation will underestimate the
deposition rates in the two positions gives mass at the surface. A soft film dampens the
the estimated tooling factor. Another way is crystal's oscillation. The damping or,
to use a laboratory technique such as scratch dissipation (D), of the crystal's
tests or white light interference to measure oscillation reveals the the film's softness
the actual thickness deposited on the sample (viscoelasticity). D is defined as
after the deposition is over; the ratio of this
thickness to what the sensor measured is the
estimated tooling factor.
ARTICLES SECTION
IICT, he worked in various research projects COAL: The most abundant natural fuel
in Tea Research Association, Tocklai, Jorhat
and Materials Science Division, RRL,
Jorhat. He also served IIT, Guwahati as a
TA for a very short period. Recently, he
visited Ruhr University, Bochum, Germany
for three months in connection with a DST-
DAAD collaborative program. He has
already published six papers in highly
reputed international journals and three Mr. Binoy Kumar Saikia
papers in the proceedings of international
conferences. His research interest is Energy is vital to human
synthesis and characterization of novel development. Coal is one of the world’s
nano-sized multicomponent mixed metal most important sources of energy, fueling
oxides for catalytic applications. almost 40 % of electricity worldwide. In
Email: pranjal_iict@rediffmail.com many countries this figure is much higher.
psjorhat@yahoo.co.uk Poland relies on coal for over 94 % of its
electricity; South Africa for 92 %, China for
----------------------0----------------------- 77 % and Australia for 76 %. Coal has
played this important role for countries not
only providing electricity, but also an
-Indian thought is an extraordinary essential fuel for steel and cement
mass of material which for detail and production, and other industries activities.
variety has hardly any equal in any Coal is located worldwide. It can be
other part of the world. There is hardly found on every continent in over 70
any height of spiritual insight or countries, with the biggest reservoir in the
rational philosophy attained in the USA, Russia, China and India. Coal reserves
world that has not its parallel in the in India are plentiful but of low quality.
vast stretch that lies between the early India has 10 % of the world’s coal, at over
Vedic seers and the modern naiyAyikas. 92 % billion tones. At current rates of
production, India has enough coal for the
next 217 years. Most of the Indian coal are
high ash bituminous coal and located in
Jharkhand, Orissa, West Bengal and Assam.
Jharkhand has the highest reserve of 35.4
billion tones in India. The bulk of coal
production in the organized sector in Assam
comes from Makum coalfields, Margherita,
Assam. Out of 259.37 million tonnes of
proved coal reserves of Assam, Makum
By Dr. S. Radhakrishnan coalfields alone have 249.65 million tonnes
of proved reserves. The Assam Railways
and Trading Company have first started the
(September 5, 1888 – April 17, 1975), was a
coal mining activities in the Makum
philosopher and statesman.
coalfields. The first colliery started was
Ledo Colliery in 1882. The other collieries
The first Vice President of India (1952-
are Baragolai, Tipong, Jeypore, Tikak and
1962) and the second President of India
Tirap, where mining has been carried out.
(1962-1967). His birthday is celebrated in
This coalfield is the most important in the
India as Teacher's Day in his honour.
Northeastern India from the standpoint of
resources of coal and infrastructure
facilities, which accounts for majority Coal liquefaction, where coal can
production of coal due to well-developed act as a substitute for crude oil. There are
mines. two methods of liquefaction: direct coal
The World Coal Institute in liquefaction-where coal is converted to
conjunction with the International Energy liquid fuel in a single process and indirect
Agency (IEA) hosted an international coal liquefaction-where coal is first gasified
workshop in New Delhi on 16-17 May 2006 and then converted to liquid.
on the theme “Coal for Sustainable Energy”. Coal is used as an energy source in
The aim of the workshop was to open a cement production. Large amount of energy
dialogue between industry and government, are required to produce cement. Klins
and between experts from developed and usually burn coal in the form of powder and
developing countries on the role of coal in consume around 450 g of coal for about 900
clean and climate change. In several key g of cement produced. Coal is likely to
messages released from the workshop, the remain an important input for the global
major one was that coal industry is the main cement industry for many years to come.
driver of social and economic development Other uses of coal include alimuna
and plays key role in conforming the great refineries, paper manufactures, and some
challenges of the 21st century-global chemical and pharmaceutical industries.
poverty, energy security and sustainable Several chemical products can be produced
development. from the by-products of coal. Refined coal
The International Energy Agency tar is used in the manufacture of chemical
(IEA) states that coal will remain the such as creosote oil, naphthalene, phenol
dominant fuel in India’s energy scenario and benzene. Ammonia gas recovered from
through to 2030. The power sector will be coke ovens is used to manufacture ammonia
the main driver of India’s coal consumption- salts, nitric acid and agricultural fertilizers.
currently around 68 % of India’s electricity Thousand of different products have coal or
is generated from coal. India is the sixth coal by products as components: soap,
largest electricity generating country in the aspirins, solvents, dye, plastics and fibers
world. IEA projects that biomass and waste, such as rayon and nylon.
the main fuel in the primary energy mix in Coal is also an essential ingredient
2002 will increasingly be displaced by coal. in the production of specialist products viz.
India has a large number of existing coal- activated carbon, carbon fiber, silicon metal.
fired power generating plants mostly While coal makes an important
constructed by Bharat Heavy Electrical contribution to economic and social
Limited and National Thermal Power development worldwide, its environment
Corporation. In April 2006, India became impacts have been a challenge. Coal mining
the first country to join USA on the raises a number of environmental challenges
government steering committee for the viz. land disturbances, mine subsidence,
Future Gen Project. It is an initiative to build water pollution (acid mine drainage), dust &
and operate the world’s first coal-based noise pollution. Technologies have to be
power plant that removes and stores CO2 developed and deployed to minimize these
while producing electricity. disturbances. Clean Coal Technologies
Thus, the importance of coal in our (CCT) are a range of technologies options,
future years is remarkable. Some of the which improve the environmental
important uses of this natural resource are performance of coal. Some of the
listed below for the readers: technologies are: Rehabilitation of land,
Coal is essential for iron and steel Trapping of Coal Bed Methane (CBM),
production. Some 64 % of steel production Coal cleaning, Electrostatic Precipitation &
worldwide comes from iron made in blast Fabric Filters (ESPF), Flue Gas
furnaces, which use coal. Desulphurization (FGD), Fluidized Bed
Combustion (FBC) to reduce NOx & SOx
emissions, Carbon capture & Storage (CCS) Ionic Liquids: An Invitation to Innovate
etc. In CCS, the CO2 is injected into earth’s
subsurface. These technologies reduce
emissions, reduce waste and increase the
amount of energy gained from tonne of coal.
Research and development is
focusing on increasingly innovative ways of
generating energy. One important option for
the longer term is the move towards
hydrogen-based energy systems, in which Dr. Diganta Sarma
hydrogen is used to produce electricity from
fuel cells. Fuel cells use electrochemical Introduction
reactions between hydrogen and oxygen Chemistry is dominated by the study
instead of combustion process to produce of species in solution. Although any liquid
electricity. Hydrogen does not occur may be used as a solvent, relatively few are
naturally in usable quantities. Coal is prime in general use. However, as the introduction
candidate to provide hydrogen via coal of cleaner technologies has become a major
gasification. Europe, Japan, USA and New concern throughout both industry and
Zealand are considering coal as an option to academia, the search for alternatives to the
produce hydrogen. most damaging solvents has become a high
Alleviating poverty, priority. Solvents are high on the list of
maintaining secure supplies of energy and damaging chemicals for two simple reasons:
protecting the natural environment are some (i) they are used in huge amounts and (ii)
of the biggest challenges facing our world they are usually volatile liquids that are
today. The production of coal is linked to difficult to contain. Today’s environmental
each of these challenges. concerns demand clean reaction processes
that do not use harmful organic solvents and
Reference: World Coal Institute News minimize chemical waste. In view of
Letters environmental pollution caused by the use of
volatile organic solvents, there is a greater
Short biodata of the author: Mr Binoy K need to replace them by environmentally
Saikia passed M Sc in Inorganic Chemistry benign solvents. In this regard, ionic liquids
from Cotton College (Gauhati University) in have emerged as important substitutes for
2000. He then joined in North East Institute several organic reactions.
of Sciences & Technology, Jorhat-785006,
India on January 2002 as a Project Assistant What are Ionic Liquids ?
and completed his research work on X-ray Ionic liquids are salts composed
diffraction and spectroscopic investigation wholly of ions (organic cation and organic
of Assam coal. Presently he is engaged as a or inorganic anion). The ions are poorly
Technical staff in the Department of coordinated, which results in these solvents
Chemical Sciences, Tezpur University, being liquid below 100°C, or even at room
Tezpur-784028, India from March 2005. His temperature which are known as room
areas of research interest are X-ray temperature ionic liquids. At least one ion
diffraction, FT-IR spectroscopy, coal has a delocalized charge and one component
chemistry, acid mine drainage, water & soil is organic, which prevents the formation of a
pollution. stable crystal lattice. Examples of some
common cations and anions that are used to
------------------------0------------------------------
synthesize ionic liquids are listed in Fig. 1.
The Pollution Prevention Act of
1990 in the United States established a
national policy to prevent or reduce
Synthesis
There are two basic methods for the
The design of processes to preparation of ionic liquids: metathesis of a
maximise the amount of raw material that halide salt with, for instance, a silver, group
ends up in the product. 1 metal or ammonium salt of the desired
The use of safe, environmentally anion and acid-base neutralization reactions.
benign solvents where possible.
via hydrogen bonding between the chloride liquids in the range of the short- to medium-
and the protons of the imidazolium ring. chain alcohols.
(c) Effect of ion sizes- Within a Since measurement of dielectric
series of non-haloaluminate ionic liquids constant requires a non-conducting medium,
containing the same cation, a change in the it is not possible in the case of ionic liquids.
anion clearly affects the viscosity. The Therefore, the polarity scales for ionic
general order of increasing viscosity with liquids have been suggested by using
respect to the anion is: [(CF3SO2)2N]- < various methods such as absorption spectra,
[BF4]- < [CF3CO2]- < [CF3SO3]- < fluorescence spectra, refractive index,
[(C2H5SO2) 2N]- < [C3F7CO2]- < [CH3CO2]- organic reactions as probe etc.
< [CH3SO3]- < [C4F9SO3]-. Obviously, this
trend does not exactly correlate with anion Conclusion
size. This may be due to some other The chemistry of room-temperature
properties such as their ability to form weak ionic liquids is at an incredibly exciting
hydrogen bonds with the cation. The stage in its development. No longer mere
viscosities of ionic liquids are also affected curiosities, ionic liquids are beginning to be
by the identity of the organic cation. For used as solvents for a wide range of
ionic liquids with the same anion, the trend synthetic procedures. The advent of systems
is that larger alkyl substituents on the that are easy to handle will allow those
imidazolium cation give rise to more viscous without specialist knowledge of the field to
fluids. use them for the first time. From the over
3. Conductivity: Since ionic liquids increasing popularity of ionic liquids it
are composed entirely of ions, they are seems that one day will come when ionic
expected to possess very high conductivities. liquids totally replace the conventional
Conductivity of ionic liquids is mostly of the volatile organic solvents, and I hope the day
order of 10-1 Sm-1 at ambient temperatures, is not so far.
less conductive than concentrated aqueous
electrolytes. Short biodata of the author: Dr.
The explanation for this observation Diganta Sarma was born (September,
was based on the reduction of available 1978) and brought up in a small village
charge carriers due to ion pairing and/or ion Naharani of Golaghat District, Assam.
aggregation and to the reduced ion mobility
After completing his M.Sc. degree
due to the large ion size. Parameters such as
viscosity and density of liquid, ion size and
(2000) from the Department of
degree of dissociation affect the Chemistry, Gauhati University, he went
conductivity. So it is rather difficult to to Tezpur University to work in a MNES
estimate the contribution of each parameter sponsored project for one year, then he
to the conductivity of an ionic liquid. moved over to RRL Jorhat to work in a
However, proportionality between the DBT sponsored project in the Natural
conductivity and inverse of the viscosity has Product Chemistry Division where he
been observed for several liquids in a wide worked for almost eight months. He then
temperature range. came to National Chemical Laboratory,
4. Polarity: Different combinations Pune to pursue his Ph.D. degree. During
of anions and cations produce solvents with
this period he attended one international
different polarities. No ionic liquids have
shown themselves to be “super-polar”;
symposium (7th Tetrahedron
regardless of the method used to assess their Symposium, Challenges in Organic
polarities, ionic liquids come within the Chemistry, Organizer: Elsevier) at
range of molecular solvents. Most general Kyoto Research Park, Kyoto, Japan
measures of overall polarity place ionic during 25-26th May, 2006. After
submitting his Ph.D. thesis to Pune
1897 Ostwald famous ‘Rule of clear and elusive in literature till today.
Steps’ on relative stability McCrone defined polymorph as “a solid
of polymorph. crystalline phase of a given compound
1906-19 Summarization of organic resulting from the possibility of at least two
crystal polymorphism in crystalline arrangements of the molecules of
Groth’s five volume that compound in the solid state”. Burger
collection. tried to simplify it as “if these (solids
1926 Tamman’s work on composed of only one component) can exist
thermodynamic stability and in different crystal lattices, then we speak of
relationship of different polymorphism”. In modern language crystal
polymorphic modification described as ‘supermolecule par excellence’
1937 Bloom and Buerger pointed by Dunitz. In his view polymorphic
out about the fundamental modification are ‘superisomer’ and
property change and its polymorphism is a kind of
importance for polymorph. ‘superisomerism’1. Scheme 1 describes the
1956-69 McCrone work on understanding of polymorphism
pharmaceutical importance
for drug polymorphism.
1973 Corradini coined the term
conformational
polymorphism.
Polymorphism arises due to
torsional degree of freedom
of molecular conformers.
1989 Bavin pointed that
metastable polymorph can
used for tabletting and
stable one for suspensions.
1998 Unexpected formation of
stable and less soluble
polymorph of Ritonavir
Scheme 1
(Norvir) in Abbott
laboratory highlights the
Polymorphism in organic solids is
significance of polymorph
of fundamental importance as its ability to
screening for drug before
alter physical and chemical properties in
marketting.
different structures, such as melting point,
2002 ‘Polymorphism in
density, compressibility, solubility,
molecular crystal’ by
hardness, dipole moment and bioavailability.
Bernstein provides valuable
Polymorphism has received particular
update on polymorphism
attention in the recent literature because of
and emerged as a growing
its importance in drug substances and
subject.
pharmaceutical formulations. Molecular
recognition, crystal nucleation,
“Allotrope” first introduced by
crystallization, and the phase relationship
Berzelius which describes the existence of
between solid can be inferred from study of
different crystal structures for same element.
polymorphism. These studies represent
Allotrope and polymorph are closely related.
special opportunities to analyze structure–
Polymorphism is used in general to refer the
property relationships because the
structural diversity of compound whereas
conformation, hydrogen bonding and lattice
allotropy is the structural diversity of
energy of the same molecule in different
element. Definition of polymorphism is not
--------------------0-------------------
References:
1. J. Bernstein, Polymorphism in Molecular
Crystals, Clarendon, Oxford, 2002.
2. B. Sarma, S. Roy, A. Nangia, Chem.
Commun,. 2006, 4918.
3. Cambridge Structural Database (CSD),
version 5.27, ConQuest 1.9, January 2007
update, www.ccdc.cam.ac.uk.
Mark Twain
Born: November 30th , 1835
Short Biodata of the author: Bipul Sarma Died: April 21st, 1910
(born in Nalbari district, Assam) received
his bachelor degree in chemistry from B.
Barooah College, Guwahati and did master
degree from Cotton College (Gauhati
University) in 2003. After qualifying CSIR- -Don't go around saying the world
JRF, he joined in a DST sponsored project owes you a living. The world owes you
under the supervision of Prof. J. B. Baruah nothing. It was here first.
in IIT-Guwahati. Then he moved to School
of Chemistry, University of Hyderabad and -Education: that which reveals to the
joined as a Ph. D. research Scholar under the wise, and conceals from the stupid, the
supervision of Prof. Ashwini Nangia in July, vast limits of their knowledge.
2004. Presently he is working in the area of
organic more precisely crystal engineering -Always acknowledge a fault. This will
and polymorphism in organic molecules throw those in authority off their guard
including drug and synthesis. and give you an opportunity to commit
more.
--------------------0-------------------
--------------------0-------------------
χMT = 59.5 emuK/mol is expected for an all calculations. The final R(F) and wR(F2)
aggregate of noninteracting four S = 5/2 and were 0.0586 and 0.1348, respectively.
fourteen S = 2 . Below ~50K, χMT drops
faster down to 2.0 K (7.6 emuK/mol) References:
indicating the existence of antiferromagnetic 1. A. Caneschi, D. Gatteschi, C.
intermolecular interactions and/or zero-field Sangregorio, R. Sessoli, L. Sorace, A.
splitting effects. Magnetization data were Cornia, M. A. Novak, C. Paulsen, W.
collected in the ranges 40-50 kG and 2.0- Werndorfer J. Magn. Magn. Mater. 1999,
10.0 K and the reduce magnetization M/NµB 200, 182.
is plotted as a function of H/T in Figure 3. 2. T. Lis Acta Crystallogr. 1980, B36, 2042.
The split of isofield lines shows that the 3. R. Sessoli, D. Gatteschi, A. Canneschi,
zero-field splitting exists in the complex 1. M. A. Novak Nature 1993, 365, 141.
4. G. Aromi, S. M. J. Aubin, M. A. Bolcar,
G. Christou, H. J. Eppley, K. Folting, D.
N. Hendrickson, J. C. Huffman, R. C.
Squire, H.-L. Tsai, S. Wang, M. W.
Wemple Polyhdron, 1998, 17, 3005.
5. S. M. J. Aubin, S. Spagna, H. J. Eppley,
R. E. Sager, G. Christou, D. N.
Hendrickson Chem. Commun. 1998,
803.
6. H. Oshio, N. Hoshino, Y. Ito J. Am.
Chem. Soc. 2000, 122, 12602.
7. Bara, A.-L., P. Debrunner, D. Gatteschi,
Also carried out were ac susceptibility Ch. E. Schulz, R. Sessoli Europhys. Lett.
measurements for the powder sample 1 in a 1996, 35, 133.
5.0 G ac field oscillating at 250 – 1000 Hz 8. S. L. Castro, Z. M. Sun, C. M. Grant, J. C.
in the temperature range of 2.0 – 10 K. Bollinger, D. N. Hendrickson, G.
Preliminary results indicate that the out-of- Christou J. Am Chem. Soc. 1998, 120,
2365.
phase(χM” ) signals showed a frequency
9. M. A. Bolcar, S. M. J. Aubin, K. Folting,
dependence. As the frequency of the ac field
D. N. Hendrickson, G. Christou Chem.
is changed from 1000 to 250 Hz, the χM”
Commun. 1997, 1485.
peak shifted from 2.58 to 2.37 K. This ac
10. C. Boskovic, E. K. Brechin, W. E.
behavior establishes the complex 1 as a new
Streib, K. Folting, D. N. Hendrickson, G.
class of single-molecule magnet.
Christou Chem. Commun. 2001, 467.
11. R. C. Squire, S. M. J. Aubin, K. Folting,
Acknowledgements: This work was
W. E. Streib, D. N. Hendrickson, G.
supported by the NRL program of the
Christou; Angew. Chem. Int. Ed. Engl.
Ministry of Science and Technology, Korea.
1995, 34, 887.
Crystal data:
C78H108Cl12Mn18N6O58 (including six Short Bio-data of the author: Dr. Akhilesh
dichloromethanes), M = 3472.02, triclinic, Kumar Gupta is Senior Research Scientist at
space group P1, a = 14.411(1), b = Dept. of Chemistry, National Tsing Hua
University, Hsinchu, Taiwan, Republic of
15.177(1), c = 15.729(1) Å, α = 70.328(2), β
China continuing research on Photovoltaics
= 78.407(2), γ = 81.046(2) °, V = 3159.0(5)
as well as OLEDs material. He has
Å3, Z = 1, T = -100 °C., µ(MoKα) = 2.071 completed his PhD from North-Eastern Hill
mm-1. 17933 reflections measured, 13817 University, Shillong in the year 2000 and in
unique (Rint = 0.0282) which were used in the same year joined as post doctoral fellow
at IIT, Kanpur in the group of Prof.
T.K.Chandrashekar (from June, 2000 to Rain Drop Size Distribution and Radar
July, 2001) and did research on Observation of precipitating system
photodynamic theraupeutic agent based on
expanded porphyrins at. He left for South
Korea in August 2001 and did post Dcotoral
studies at Department of Chemistry, Kongju
National University, Kongju, Chungnam
under supervision of Prof. Kim Jinkwon in
the field of single molecule magnets based
on 1 st series Transition Metals (From 2001-
2003), followed by joining the group of Mr. Mahen Konwar,
Prof. Won Kyung Seok at Department of
Chemistry, Dongguk University, Seoul, Almost in everybody’s life
South Korea (from 2003 –2005) to pursue individual enjoys rain either in their
further research on Samsung Korea project childhood days or later part of their life. One
based on ruthenium solar cell dye. After good shower can turn a leafless deserted tree
completing successfully he moved to into a beautiful green tree; full of life!! Rain
Department of Organic Chemistry and can bring out smile to the face of farmers
Centre for Molecular Devices, Royal who used to longing for rain to come or it
Institute of Technology, Stockholm, Sweden can create beautiful poem in the mind of a
to do further research on solar cell based on poet!! Now a day’s one single heavy shower
both ruthenium and organic dye (from 2005- can even bring havoc to the city life that
2006). reflects the unplanned lifestyle that we are
(Email: akhileshkumargupta@yahoo.com ) heading for. Such is the importance of rain
in day to day life. Understanding of the rain
drop size distribution (RDSD) is very
important in the soil erosion, radio
---------------------0---------------------- communication, forecasting and in studying
the microphysics of rain phenomenon.
Everybody experiences that
-Do not keep company with a fool for as generally at the very initial stage of a rain
we can see he is a two-legged beast. event, very large rain drops are observed
Like an unseen thorn he pierces the then heavy rain that contain all types of rain
heart with his sharp words. drops (convective) followed by steady type
of rain (stratiform). The convective rain lasts
for lesser amount of time than that of
stratiform type of rain. The transition period
when convective type of rain is transformed
into stratiform type of rain is named as
“transition rain”. For better and complete
understanding of rain phenomenon RDSD is
the most widely term which is defined as the
number of drops per unit volume per unit
By Chanakya (Indian politician, strategist drop diameter. It is formulated as
and writer, 350 BC-275 BC)
N D0
N Di =
AWt ∆t
---------------------0---------------------- N
where Di is the number of drops
per unit volume, of diameter D and terminal
velocity
Wt , and N D0 is the number of
threats of abiotic and biotic stress and cloths is also expected to emerge from
expanding the horizons by producing transgenic crops (Tyagi, 2000)..
specialty foods, biochemicals,
pharmaceuticals etc. Indian plant Are they safe?
biotechnology also has come of age Although, there are lots of foods
accomplishing research projects of national products, agricultural plants or organisms
and international importance (e.g. rice that have been modified by genetic
genome sequencing project). These manipulation e.g. genetically modified
biotechnological tools and its outcome have organisms (GMO) and foods. But, are they
immense potential and the same is evident 100% safe for human or for the
from the fact that currently over 130 million environment? It is a debatable question. It is
acres are planted under transgenic crops all already demonstrated that GM plants and the
over the world. The global market value of some other engineered organisms as
biotech crops was about 3.8 billion US presently being developed pose several
dollars in 1998 (Gupta, 2002). environmental risks. Most criticisms of
The potential to improve plant and genetic engineering focus on food safety and
animal productivity and their proper use in environmental impacts.
agriculture relies largely on newly Some of the key questions are:
developed DNA biotechnology and • What impact will GMOs have on the
molecular markers. These techniques enable health of those who eat them? Will some
the selection of successful genotypes, better individuals develop allergic reactions?
isolation and cloning of favourable traits and • "Bt corn," a common GMO, includes a
the creation of transgenic organisms of gene from Bacillus thuringienis which
importance to agriculture. In India, produces a pesticide that kills the
concerted efforts of several laboratories and European corn borer.
generous support of the Department of • StarLink is a variety of Bt corn that
Biotechnology and Indian Council of includes a protein (Cry9C) that does not
Agricultural Research along with the inputs break down as easily in the body, which
from the Rockefeller Foundation are increases the risk of allergic reactions in
beginning to pay dividends and pave way some people.
for future progress towards sustainable • GM wheat could cross with native
agriculture. grasses (gene flow) to alter the makeup
The "green revolution" for example, of the ecosystem and potentially create
increased wheat production 10-fold in India "super weeds" a possibility that has
and several other countries in South East raised concerns in the "Wheat Belt" of
Asia. Other than better production, biotech the United States and elsewhere.
crops have also developed that may
• There is a worry over the potential
influence not only on the modern agriculture
impact of some GMOs on nontarget
but also the community health. A new type
organisms.
of rice called "golden rice" is fortified
• It will soon be possible to engineer
through biotechnology with beta-carotene by
bacteria and viruses to produce deadly
engineered pathway for provitamin A
pathogens.
biosynthesis and iron-rich rice (Wu, 2005).
Such rice is expected to provide for vitamin
It is the time to rethink in this direction.
A and iron deficiency in millions of under-
Plant biotechnology and its outcome are
nourished children and women throughout
encouraging at present which might be
the world. Similarly, plants are being used to
environmentally safe also. Therefore, in the
produce vaccines and therapeutic agents like
current R&D programmes researchers
insulin, antibodies and drug biomolecules.
should focus on the better product
Production of plastics and novel Fibre for
development rather than just the publication
which in turn will make Plant Biotechnology Short Biodata of the Author: Ms. Nabanita
more relevant and responsive to the Bhattacharyya is working as a lecturer
society’s needs. Department of Botany, Nowgong College,
Assam. Her research area is Plant
Reference Physiology and Biochemistry. The title of
1. Tyagi A K, Plant Biotechnology for her Ph.D thesis is ‘Investigation on
Agriculture and Human Health. India physiological performances on Houttuynia
Chem 2000 October 6-8, 2000 cordata Thunb (Masandari)- with reference
2. Gupta PK, Molecular markers and QTL to its phytoremediation potential
analysis in crop plants Curr. Sci., 2002, in uncultivable land’
83, 113–114.
3. G Wu et al., Stepwise engineering to Email: msnbhattacharyya@yahoo.co.uk
produce high yields of very long-chain
polyunsaturated fatty acids in plants, ------------------------o-----------------------
Nat. Biotechnol. 2005, 12, 1013–1017.
4. http://www.struggle.ws/rbr/rbr5/biot
ech.html
This was how the Rocket Cone was transported to the Launch Pad at Thumba in the
beginning
The person on the left... He is our very own... Dr. A. P. J. Abdul Kalam...The
present President of India
(b)
bp M 1 2 3 4 5 M bp
500 500
200 200
100 100
The functionality of the linker was absorbance at 526 nm was observed (green
confirmed using a solid phase hybridization spectrum).
assay. The linker was then employed in the
DNA-directed assembly of AuNPs in (a)
solution, and the process was monitored
using atomic force microscopy (AFM).
AFM studies confirmed the formation of NP
assemblies with interparticle spacing
corresponding to the DNA linker used.
Ph. D. thesis abstract of Dr. Sasanka Deka nanocrystalline oxides. All the experimental
methods and characterization techniques
used are briefly discussed in the specific
sections.
Synthesis procedures and the
structural and magnetic properties of the
transition metal (Co, Ni, Mn and Fe) doped
nanocrystalline ZnO are discussed in the
Dr. Sasanka Deka third chapter. The nanocrystalline
materials having particle sizes in the range
Title of Thesis: Studies on the Magnetic and of 10-40 nm are synthesized by an
Electrical properties of Nanosized Transition autocombustion method. Optical and XPS
Metal Oxides and Ferrites studies showed that the Zn ions have been
replaced by divalent transition metal ions in
Nanosized magnetic materials have the tetrahedral site of the wurtzite structure
received great attention and importance of ZnO. Room temperature ferromagnetism
during the last decade. Nanomagnetic is observed after doping Co, Ni and Fe in
material is one of the hottest subjects of ZnO. However, the magnetic properties
present day research activities. The physical change drastically when the synthesize
properties of nanosized magnetic materials procedure is modified slightly. Mn doped
differ considerably from that of their bulk ZnO samples are found to be always
counterparts and the magnetic characteristics paramagnetic down to 12 K. The origin of
of many materials can be tuned by reducing the observed ferromagnetism is found to be
their size. The objectives of this research from metallic nanoclusters or secondary
work are the synthesis and studies on the ferromagnetic phases depending on the
structural and magnetic properties of some synthesis conditions and metal ions used.
selected transition metal oxides and ferrites The detailed studies on the
in nanocrystalline form. synthesis, characterization, and magnetic
The present research work has been properties of nanocrystalline NiZn ferrite,
carried out on transition metal doped zinc Ni0.5Zn0.5Fe2O4, are discussed in the fourth
oxide based diluted magnetic chapter. Narrow particle size distribution
semiconductors (DMSs), some ferrites and with high rate of reproducibility is achieved
magneto-polymer nanocomposite systems. by using a simple autocombustion method
The respective nanocrystalline oxides are for the synthesis. The TC of the
synthesized by a simple solution combustion nanocrystalline ferrite is increased to large
method and characterized using various values due to the unusual cation distribution
techniques. The results from the studies on in the nanosized ferrite. The nanosized
different materials are presented in this ferrite sintered using Bi2O3 and Ag as
thesis, consisting of six chapters. additives showed good microstructure, high
The first chapter is a brief density at low sintering temperatures, very
introduction to magnetism, and a review of high magnetic permeability and dielectric
the structural and magnetic properties of the constant values at room temperature.
different magnetic oxides such as ZnO based The fifth chapter deals with
diluted magnetic semiconductor materials, synthesis and studies on the structural and
ZnFe2O4, Ni0.5Zn0.5Fe2O4, γ-Fe2O3, magnetic properties of nanocrystalline
polymer/metal/ferrite nanocomposites and ZnFe2O4 and γ-Fe2O3. Single phase of
the Co/CoO/Co3O4 nanocomposites, studied superparamagnetic ZnFe2O4 obtained when
in the present research work. smaller amounts of glycine is used as the
The second chapter describes the fuel in the autocombustion reaction.
method employed for the synthesis of the However, Fe3O4 is found to be formed as a
secondary phase, when larger amounts of
glycine are used. Zn-doped γ-Fe2O3 is Liberto Manna. At present Dr. Deka is
synthesized by the same autocombustion working on size and shape control of II-VI
method. Zn-doping is found to stabilize the and III-V semiconductor materials using
maghemite phase and increases the colloidal synthesis method.
transformation temperature to the hematite
phase.
The sixth chapter deals with the
synthesis, characterization and preliminary ---------------------0----------------------
studies on some magnetic nanocomposites.
Ni/NiFe2O4 and Co/CoFe2O4
nanocomposites are synthesized under in -Truth is generally the best vindication
situ conditions by an autocombustion against slander
method. The composites are then blended
with PVDF polymer matrix. Moderate -Always bear in mind that your own
values of initial permeability and dielectric resolution to succeed is more important
constant are obtained for the than any one thing.
polymer/metal/ferrite nanocomposites,
comparable to that reported in the literature.
Co/CoO/Co3O4 nanocomposite is
synthesized using the same autocombustion
method. This nanocomposite could be
transformed to Co/CoO nanocomposite by
proper reduction at elevated temperatures.
Sediment of life
Meersburg, Germany
Freedom
Stockholm, Sweden
UPCOMING CONFERENCE
POLY-2007: Second Circular: Call for Papers
International Seminar on Frontiers in Polymer Science and Technology : POLY-2007
Date: 1-3 November, 2007
Venue: Administrative Staff College, Khanapara, Guwahati, Assam, India
Organizer: Prof. Sukumar Maiti Polymer Award Foundation, Kolkata, India
Collaborators: Tezpur University, Assam, India; Jadavpur University, Kolkata, India
Themes:
1. Novel polymer synthesis and characterization.
2. Polymer blends and polymer nanocomposites.
3. Bio-medical applications of polymers.
4. Polymers in electronics.
5. New catalysts for olefin polymerization.
6. Recycling of polymers and biodegradable polymers.
7. Pollution by polymers and polymer waste management.
Call for papers: Full papers may be sent in MS word document within 4-5 pages of A4 size paper together
with a print copy. The papers will be published in a special issue of Journal of Polymer Materials.
Prizes:
1. Foundation award 2007 for the best researcher in polymer science and technology in India. Selection
is in process. Contact: Prof. B. C. Ray, Jadavpur University ( bcrjuchem@yahoo.co.in).
2. S. N. Ghosh Memorial Award will be given to the young scientist (Under 32 years) for the best paper
presentation in the conference.
3. Conference prizes will be given to the young scientist (Under 32 years) for the best paper presentation
in the different themes of the conference.
Registration fee:
1. Delegates from Industry: Rs.2000/- , from Academic Institutions / R & D organizations: Rs.1000/-,
Students and research Scholars: Rs.250/-
from Foreign country : US$300
Payment (Demand Draft) should be made in favour of “Prof. Sukumar Maiti Polymer Award Foundation”
payable at Kolkata.
Cultural Program: Cultural program and local tour will be organized by the organizer
Travel Assistance: Few students and retired scientists/ teachers will be given travel assistance for which
separate request may be sent to the convenor on or before 11 September, 2007.
Last date for receiving abstract of the paper: 11 July, 2007; full paper: 11 August, 2007;
Registration fee: 11 September, 2007; Late registration fee : 10% extra
Patron: Dr. T. Ramasami, Secretary, DST, New Delhi.
Advisors: Prof M. K. Choudhuri, Vice-chancellor, Tezpur University, Prof. D. Konwer,Dean, Tezpur
University, Prof. S. K. Sanyal, Vice-chancellor, Jadavpur University, Dr. S. Sivaram, Director, NCL, Pune
Convenor: Prof. S. K. Dolui, Tezpur University
Chairman: Prof. B. C. Ray, Jadavpur University
To apply please read the full texts of the announcements for Postdoc and PhD.
Applications must be received no later than October 1st, 2007 at 12.00 (GMT+1.00)
------------------------------------------------0-----------------------------------------------
http://www.mrseiler.org/cartoons.html
(by Nick D Kim)
Karolinska Institutet
is looking for a
Please note that according to the rules for scholarship stipends at Karolinska Institutet a
scholarship for the pursuit of postdoc studies may be awarded to a foreign citizen who
has obtained a doctorate or the equivalent outside Sweden. The head of department
decides whether the education and scientific qualifications in question can be regarded
as equivalent to at least those of a Swedish doctorate. The basis of the assessment made
by the head of department must be clearly set out in the scholarship decision.
A scholarship for the pursuit of postdoc studies may be awarded for up to two years in
the five years following the public defence (or equivalent) of a doctoral thesis.
Area of Successful candidates will participate in all steps involved in structure determination of
responsibilities/duties: target proteins and target RNA/protein complexes.
Qualifications: Suitable candidates have a PhD in a relevant area, preferably in RNA Biochemistry,
Structural Biology or related subjects. General requirement to be eligible for this
position is a doctoral degree from a University outside Sweden.
Requirements:
Two letters of recommendation
Capabilities of team working in a larger group
A good background in cell biology and basic biochemistry
Skills for directing work and instructing fellows at a technical level
An established record of publications in related fields
Contact:
Manuel Portero-Otin
c/Montserrat Roig,2
Lleida, Spain 25008
Phone: 34 973702408
We offer:
• A 4 year position at PhD student level in an Emmy Noether excellence Team
(salary: BATO IIa/2).
• A stimulating work environment in one of the most exciting scientific cities in
Germany.
Our location is the Institute of Pathology, and we are part of the Faculty of
Medicine and the University Clinic `Carl Gustav Carus' at the University of
Technology Dresden (TUDresden). Our new research group is also strongly linked
to the Max Planck Institute of Molecular Cell Biology and Genetics in Dresden.
Requirements:
Profile:
- Student with a master in biology, biomedical science, biotechnology or
equivalent.
- Background in immunology and molecular biology is recommended.
- You are willing to work with mice (experience is an advantage)
- You are practical, social and communicative.
- You have an excellent knowledge of English, both written and spoken.
- Knowledge of German is an advantage but not necessary.
Contact:
Ben Wielockx
Schubertstrasse 15
Dresden, Germany 01307
Phone: +49/3514583038
Moderators:
1. Arindam Adhikari, Ph.D. 2. Jadab Sharma, Ph.D.
Institute of Surface Chemistry, Royal Email: js_in1@yahoo.co.in
Institute of Technology, Stockholm, Sweden
Email: arindam_tsk@yahoo.com
http://tech.groups.yahoo.com/group/northeast_india_research/
http://www.geocities.com/ne_india_research_forum/