Syllabus cum Comp.

/XI/201314

[1]
S.C.O. 208 II floor, Sec-36 D Chandigarh, Ph.3012085, Mb.9872079084
S So om me e b ba as si ic c c co on nc ce ep pt ts s o of f c ch he em mi is st tr ry y ( (X XI I) )
Review No. 2 ( Solutions)

Objective Questions
Q1. What is the empirical formula of vanadium oxide if 2.74 g of metal oxide contains 1.53 g of
metal?
(a) V
2
O
3
(b) VO \(c) V
2
O
5
(d) V
2
O
7

Sol. (c) Amount of O = 2.74-1.53 = 1.21
Wt Moles Simplest Whole no. ratio
M = 1.53
03 . 0
51
53 . 1
= 1
03 .
03 .
=
1 2 = 2
O = 1.21
075 .
16
21 . 1
= 5 . 2
03 .
075 .
=
2.5 2 = 5
= V
2
O
5
Q2. A compound having the empirical formula (C
3
H
4
O)
n
has a molar mass of 170 5. The
molecular formula of this compound is
(a) C
3
H
4
O (b) C
6
H
8
O
2
(c) C
6
H
12
O
3
\(d) C
9
H
12
O
3

Sol. (d) n =
mass . Emp
mass Molar

Molar mass = [(12 3) + (4 1) + (16 1)]n = 170 5
= (36 + 4 + 16) n = 170 5
56 n = 170
n = 3 n
56
5 170
=

M.F. = (E.F.)
n
= (C
3
H
4
O)
3

= C
9
H
12
O
3

Q3. What volume of hydrogen at NTP will be liberated when 3.25g of zinc completely dissolve in
dilute HCl? (At. mass of Zn = 65)
\(a) 1.12 litre (b) 11.20 litre (c) 2.24 litre (c) 22.40 litre
Sol. (a) Zn + 2HCl ZnCl
2
+ H
2

1 mole 1 mole
65 g 22.4 L
3.25 g 25 . 3
65
4 . 22

= 1.12 L
Q4. Sucrose reacts with oxygen to yield CO
2
and H
2
O according to the reaction.
C
12
H
22
O
11
+12O
2
12CO
2
+ 11H
2
O.
The number of molecules of CO
2
produced per gm of sucrose is
\(a) 2.11 10
22
(b) 6.02 10
22
(c) 1.76 10
21
(d) 9.29 10
23


Syllabus cum Comp./XI/201314

[2]
S.C.O. 208 II floor, Sec-36 D Chandigarh, Ph.3012085, Mb.9872079084
Sol. (a) C
12
H
22
O
11
12CO
2

1 mole produces 12 moles of CO
2

342 g produces 12 N
A
of CO
2

1 g produces
342
10 023 . 6 12
23

= 2.11 10
22
molecules
Q5. 1.6 g of sulphur was burnt in the air to form SO
2
. The number of molecules of SO
2
introduced
into the air will be
(a) 6.02 10
23
(b) 3.01 10
23
(c) 6.02 10
22
\(d) 3.01 10
22

Sol. (d) S + O SO
2

1 mole of S produces 1 mole of SO
2

32 g of S produces N
A
molecules of SO
2

1.6 g of S produces
32
10 023 . 6
23

1.6 = 3.01 10
22
molecules
Q6. Compute the value of x
x = 9.4 g of phenol (C
6
H
5
OH) + 6.02 10
23
(wrong in review) molecules of phenol -0.2 mole of
phenol
\(a) 0.9 mol (b) 9.2 g (c) 0.1 mol (d) 6.02 10
23
molecules
Sol. (a) x = 9.4 g of phenol + 6.02 10
23
molecules - .2 mole
x =
94
4 . 9
moles + 1 mole - .2 mole
= (.1 + 1 - .2) mole
= .9 mole
Q7. The number of moles of oxygen in one litre of air containing 21% oxygen by volume, in
standard conditions, is
(a) 0.186 mol (b) 0.21 mol \(c) 0.0093 mol (d) 2.10 mol
Sol. (c) 100 L of air has 21 L of O
2

1 L of air has
100
21
= .21 L of O
2

Volume moles of O
2
(At S.T.P.)
22.4 L 1
.21 L 21 .
4 . 22
1
= .0093 moles
Q8. A boy drinks 500 mL of 9% glucose solution. The number of glucose molecules he has
consumed are [mol. wt. of glucose = 180]
(a) 0.5 10
23
(b) 1.0 10
23
\(c) 1.5 10
23
(d) 2.0 10
23

Sol. (c)
solution of Volume
solute of weight
V
W
% 9
100 mL glucose solution has 9g glucose

Syllabus cum Comp./XI/201314

[3]
S.C.O. 208 II floor, Sec-36 D Chandigarh, Ph.3012085, Mb.9872079084
500 mL glucose solution has g 500
100
9
= 45 g of glucose.
Moles of glucose = 25 .
4
1
180
45
= =
No. of Molecules = .25 6.023 10
23

= 1.5 10
23

Q9. List I List II
(A) 0.5 mol (p) 92 g CH
3
CH
2
OH
(B) 1.0 mol (q) 66g CO
2

(C) 1.5 mol (r) 54 g H
2
O
(D) 2.0 mol (s) 15 g HCHO
(E) 3.0 mol (t) 44g CH
3
CHO
Sol. Moles =
mass Molar
mass Given

(p)
6 16 12 12
92
+ + +
= 2 (D)
(q)
44
66
= 1.5 (C)
(r)
18
54
= 3 (E)
(s)
30
15
= .5 (A)
(t)
44
44
= 1 (B)
Q10. In the reaction, Al(s) + 6HCl (aq) 2Al
3+
(aq) + 6Cl
-
(aq) + 3H
2
(g)
(a) 33.6 L H
2
(g) is produced regardless of temperature and pressure for every mole Al that
reacts
\(b) 67.2 L H
2
(g) at STP is produced for every mole Al that reacts
\(c) 11.2 L H
2
(g) at STP is produced for every mole HCl (aq) consumed.
\(d) 6 L HCl (aq) is consumed for every 3 L H
2
(g) produced.
Sol. Using mole concept
Q11. When 1 L of CO
2
is heated with graphite, the volume of the gases collected is 1.5 L. Calculate
the number of moles of CO produced at STP.
(a)
2 . 11
1
(b)
4 . 22
28
\(c)
4 . 22
1
(d)
4 . 22
14

Sol. (c) CO
2
(g) + C(s) 2CO(g)
Initial volume 1 L O
Suppose reacted x
Produced 2x CO
2
2CO

Syllabus cum Comp./XI/201314

[4]
S.C.O. 208 II floor, Sec-36 D Chandigarh, Ph.3012085, Mb.9872079084
At end 1 x 2x
Total volume = 1 x + 2x = 1.5 Given in Qn
1 + x = 1.5
x = .5 L
Vol. of CO = 2 .5 = 1L
Moles of CO =
4 . 22
1

Q12. Number of electrons present in 3.6 mg of NH
4
+
are:
\(a) 1.2 10
21
(b) 1.2 10
20
(c) 1.2 10
22
(d) 2 10
-3

Sol. (a)
+
4
NH
n =
g 4 14
g 10 6 . 3
3
+

= .2 10
-3
moles
1 mole of NH
4
+
has = 7 + 4 1 = 10 moles of e
-1
s
.2 10
-3
of NH
4
+
has
3
10
10
2 10

moles of e
-1
s
= 2 6.023 10
23
10
-3

= 2 6.023 10
20

= 12.046 10
20

= 1.2 10
21

Q13. Caffeine has a molecular weight of 194. If it contains 28.9% by mass of nitrogen, number of
atoms of nitrogen in one molecule of caffeine is:
\(a) 4 (b) 6 (c) 2 (d) 3
Sol. (a) 100 g of caffeine has 28.9 g of N
194 g of caffeine has 198
100
9 . 28
= 57.22 g of N
194 g = 1 molecule of caffeine = 57.22 g of N
1 atom of N = 14 g
57.22 g =
14
22 . 57
~ 4 (No. of atoms of N)
Q14. Four grams of hydrocarbon (C
x
H
y
) on complete combustion gave 12 gram of CO
2
. What is the
empirical formula of the hydrocarbon? [EAMCET (Medical) 2005]
(a) CH
3
(b) C
4
H
9
(c) CH (d) C
3
H
8
Sol. (d)
Q15. The ratio of oxygen atoms to hydrogen atoms in (NH
4
)
2
SO
4
is:
(a) 1 : 1 (b) 2 : 1 \(c) 1 : 2 (d) 4 : 1
Sol. (c)
2
1
8
4
H
O
= =
Q16. A certain compound has the molecular formula X
4
O
6
. If 10.0 g of the compound contains
5.62g of X, the atomic mass of X is
(a) 62.0 amu (b) 48.0 amu (c) 32.0 amu \(d) 30.8 amu

Syllabus cum Comp./XI/201314

[5]
S.C.O. 208 II floor, Sec-36 D Chandigarh, Ph.3012085, Mb.9872079084
Sol.
Q17. An ore contains 1.34% of the mineral argentite, Ag
2
S, by mass. How many gram of this ore
would have to be processed in order to obtain 1.00 g of pure solid silver, Ag?
(a) 74.6 g \(b) 85.7 g (c) 107.9 g (c) 134.0g
Sol. (b) Ag
2
S 2Ag
(2 108 + 32) g 2 108 g
? 1g
248 g 216 g 216g of Ag is in 248g of Ag
2
S
? 1 g 1g of Ag is in
216
248
= 1.148 g of Ag
2
S
For 1g of Ag, Ag
2
S reqd. in 1.148 g
1.34 g pure Ag
2
S is in 100 g of ore
1.148 g pure Ag
2
S is in
34 . 1
100
1.148 = 85.7g of ore
Q18. One mole of magnesium nitride on the reaction with an excess of water gives [UP SEE 08]
(a) one mole of NH
3
\(b) two moles of NH
3
(c) one mole of HNO
3
(d) two moles of HNO
3

Sol. Mg
3
N
2
+ 6H
2
O 2NH
3
+ 3Mg (OH)
2

Q19. The compound AB contains elements A and B in the ratio of 1 : 35.5 by mass. The mass of B
that will be required to react with 2g of A is
(a) 7.1 g (b) 3.55 g \(c) 71 g (d) 35.5 g
Q20. X g of calcium carbonate was completely burnt in air. The weight of solid residue formed is
28g. What is the value of X in grams? [EAMCET (Engg.) 2005]
(a) 44 (b) 200 (c) 150 \(d) 50
Sol. (d) CaCO
3

A
CaO + CO
2

1 mole 1 mole
100 g 56 g
28
56
100
28 g
= 50 g
Q21. The volume of air needed for complete combustion of 1 kg carbon at STP is:
(a) 9333.33 litre (b) 933.33 litre (c) 93.33 litre (d) 1866.67 litre
Sol. Note: Above given options are not correct.
C + O
2
= CO
2

1 mole 1 mole
12 g 22.4 L
1000 g 1000
12
4 . 22
= 1866 L O
2

100 L air has 21 L O
2

1866 L O
2
is in
21
100
1866 air


Syllabus cum Comp./XI/201314

[6]
S.C.O. 208 II floor, Sec-36 D Chandigarh, Ph.3012085, Mb.9872079084
Ans. 8888.92 of air.
Q22. In the commercial manufacture of nitric acid, how many moles of NO
2
produce 7.33 mol HNO
3

in the reaction?
3NO
2
(g) + H
2
O(l) 2HNO
3
(aq) + NO(g)
(a) 15.562 mol \(b) 10.995 mol (c) 13.056 mol (d) 18.556 mol
Sol. 3NO
2
2HNO
3

3 moles 2 moles

2
3
moles 1 mole
7.33 mole of HNO
3
is produced from

2
3
7.33 = 10.995 moles of NO
2

(Objective Question More than one correct answer)
Q1. Which one of the following statements is/are correct?
\(a) One mole of CH
4
and 17g NH
3
at NTP occupies same volume
(b) One gram mole of silver equals 108/6.023 10
23
g
\(c) One gram mole of CO
2
is 6.023 10
23
times heavier than one molecule of CO
2

\(d) One mole Ag weighs more than that of two moles of Ca
Sol. (a) right Both are 1 mole = 22.4 L
(b) x 1 gm mole = 1 mole = 108g
(c) right
(d) right 1 mole Ag = 108g
2 mole of Ca = 2 40 g
(Subjective Question )
Q23. Glucose, or blood sugar, has the molecular formula C
6
H
12
O
6
. What is the empirical formula,
and what is the percent composition of glucose?
(Comprehension
Passage-1:- The term mole first used by Ostwald in 1896 refers for the ratio of mass of a substance
in g and its molecular weight. 1 mole of a gaseous compound occupies 22.4 litre at NTP and
contains 6.023 10
23
molecules of gas.
Q1. Weight of 1 atom of hydrogen is:
(a) 1.66 10
-24
amu (b) 3.32 10
-24
g \ (c) 1.66 10
-24
g (d) 3.32 10
-24
amu
Sol. 6.023 10
23
atom = 1 g
1 atom =
23
10 023 . 6
1

g = 1.66 10
-24
g
Q2. Avogadros number of Rupees can be spend in years.if 10 lacs rupees per second are
spend:

Syllabus cum Comp./XI/201314

[7]
S.C.O. 208 II floor, Sec-36 D Chandigarh, Ph.3012085, Mb.9872079084
\(a) 1.91 10
10
year (b) 2.91 10
10
year (c) 3.91 10
10
year (d) 4.91 10
10
year
Sol. (a) 10
6
rupees in .317 10
-7
yr [1 yr = 365 24 60 60 sec] 1 sec = .317 10
7
yr
6.023 10
23
in =
6
7
10
10 317 .

6.023 10
23
= 1.91 10
10
yr
Q3. The amount of sulphur required to produce 100 mole of H
2
SO
4
is:
(a) 3.2 10
3
g (b) 32.65 g (c) 32 g (d) 3.2 g
Sol. S + O
2
SO
2
(1)
SO
2
+ 1/2O
2
SO
3
(2)
SO
3
+ H
2
O H
2
SO
4
(3)
S + 3/2O
2
+ H
2
O H
2
SO
4
(a)
1 mole 1 mole
100 mole 100 mole
100 32 = 3200 g
Q5. A substance contains 3.4% sulphur. If it contains two molecules of sulphur per molecule the
minimum molecular weight of substance will be:
(a) 941 (b) 1882 (c) 470.5 (d) 1411.5
Sol. (b) 100 g of sample has 3.4 g of S, 1 molecule has 2S atoms i.e. 64g of S
3.4 g of S in 100 g sample
64 g of S in g 35 . 1882 64
4 . 3
100
=

4 . 3
100
64 = 1882.35 g
64 g of S ( 1 molecule has 2 S i.e 64 g)
6. The volume of air needed to burn 12 g carbon completely at STP is:
\(a) 22.4 litre (b) 112 litre (c) 44.8 litre (d) 50 litre
Sol. (a) C + O
2
CO
2

1 mole 1 mole
12 g 22.4 L
Q7. The maximum number of atoms present are in:
\(a) 4 g He (b) 4 g O
2
(c) 4 g O
3
(d) 4g H
2
O
2

Sol. (a) 4 g of He N
A

(b) 32 g of O
2
2 N
A
atoms
4 g of O
2

4
N
32
4 N 2
A A
=

atoms
(c) 3 16 g of O
3
3 N
A
atoms
4 g of O
3

4
N
16 3
4 N 3
A A
=

atoms
(d) 34 g of H
2
O
2
has 4 N
A
of atoms ; 4 g of H
2
O
2
has
34
16
34
4 N 4
A
=

N
A