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PROCESS SIDE
0.4362
30
H2O
Ar
CO2
O2
75.31
0.0048
0.469
0
100
18
40
44
32
17.82
30.8
924.7
5321.7 95790.7
0.3
13.6
33.1
1458.2
0.0
0.0
7066.4 125931.3
13.86
9125.8 126508.6
*There is some problem with the outlet analysis you have provided, sum was not 100%.
*You will notice a difference in inlet and outlet mass flow rate due to assumption mentioned in section 1.1.1 against ethane and also due
to incorrect analysis. In this magnitude these are not going to impact our calculations for efficiency especially for the case you are
referring to.
T2
H n.H
f 77
n CpdT
T1
Component
N2
H2
CH4
C2H6
H2O
Ar
CO2
CO
O2
Enthalpy
979784.33
441325.79
-30927630
-507409.73
-514008790
2080.9579
-5291304.8
0
46184738
-5.03E+08 BTU/hr
900
n.H
f 77
( A BT
CT
DT 3 ) dT
77
n.H
f 77
BT
n AT
2
CT
DT
900
)
77
T2
H n.H
Enthalpy
1728892.5
36913062
-5984297.7
0
-341254567
3685.0109
-88668033
-16726344
0
-4.14E+08 BTU/hr
f 77
T1
1465
n.H
f 77
( A BT
CT
DT 3 ) dT
77
n.H
f 77
BT
n AT
2
2.
n CpdT
CT
DT
8.91E+07
1465
)
77
BTU/hr
FUEL SIDE
1.775
30
H2O
Ar
CO2
O2
0.000
0.005
2.019
0.000
100
18
40
44
32
17.80
21.4
642.3
0.0
0.0 Neglected water coming in with natural gas
0.1
2.3
24.3
1071.4
0.0
0.0
1206 21469.94
Mass
(Lb/hr)
296312.3
0.0 Calculations in section 2.1.2 and 2.1.3 are
0.0 interlinked
0.0
0.0
0.0
0.0
90018.9 Total O2 Moles calculated
386331.3
Mass
CH 4 2 O 2 CO 2 2 H 2 O
(Lb/hr)
7
299091.4
C 2 H 6 O 2 2 CO 2 3 H 2 O
0.0
2
0.0
0.0
39349.6
2.3
49636.3 Total CO2 & O2 moles calculated
19721.6 O2 (D.B)
4.6 %
407801.2 CO2 (D.B)
8.42 %
Assuming flue gas analysis provided is dry basis
Enthalpy
141354911
0
0
0
-190201665
766.04359
-166606558
-21103624
204715968
-3.18E+07 BTU/hr
T2
H n. H
n CpdT
f 77
T1
1750
n. H
f 77
( A BT
CT
DT 3 ) dT
77
n. H
f 77
BT
n AT
2
CT
DT
1750
)
77
Enthalpy
15952.015
0
-33966367
-773311.19
0
9.3037269
-4120545
0
199398.34
-3.86E+07 BTU/hr
T2
H n.H
f 77
n CpdT
T1
100
n.H
f 77
( A BT
CT
DT 3 ) dT
77
n.H
f 77
BT
n AT
2
CT
DT
100
)
77
Enthalpy
1330721.6
0
0
0
0
0
0
-133519864
1731824.5
-1.30E+08 BTU/hr
T2
H n.H
f 77
n CpdT
T1
95
n.H
f 77
n ( A BT CT
DT 3 ) dT
77
n.H
f 77
BT
n AT
2
CT
DT
95
)
77
EFFICIENCY CALCULATIONS
Efficiency
64.94 %
process
fuel
The efficiency number is low, I dont know if there is a problem with any flow meter or temperature meter or
analysis etc.
You cannot introduce heat of reaction into your calculation while working with heat of formations
as the heat of reaction is automatically covered in heat of formation.
This is not intended to calculate exactly the efficiency of your reformer but to explain as an example so that you
can identify your fault.
Once you have understood these calculations use HYSYS instead as its physical property data bank
is much better than of what you were using (David.M. Himmelblau)
ERRORS AND OMISSIONS ARE EXPECTED AS THIS HAS NOT BEEN CROSS CHECKED AT ALL
Component
N2
H2
CH4
C2H6
H2O (g)
Ar
CO2
CO
O2
Heat of formation
@ 77 Deg.F
BTU/Lbmol
0
0
-32226.104
-36457.6102
-104130.2756
0
-169445.406
-47589.912
0
A
6.931
6.89276
8.20009
11.79943
7.99694
6.931
8.63029
6.91905
6.9549
B
0.000525561
1.82835E-05
0.01068091
0.0332688
0.00164432
0.000525561
0.01011687
0.00098229
0.00276762
C
1.3678E-06
7.85832E-07
8.74979E-07
-1.39002E-05
1.81736E-06
1.3678E-06
-6.89993E-06
8.47972E-07
-1.45001E-06
D
-6.86169E-10
-2.07882E-10
-2.629E-09
1.73992E-09
-8.58727E-10
-6.86169E-10
1.7839E-09
-5.3058E-10
3.13329E-10