Professional Documents
Culture Documents
K=
d)
K=
c)K=[H+][NO2]
b)K=
e)
noneofthese
2. Whichofthefollowingisaconjugateacid/basepair?
a)
d)
HCl/OCl
H3O+/OH
b)
e)
3. Theequilibriumconstantforthereaction:
a)
Ka
b)Kb
+
c)
NH
4/NH
3
H2SO4/SO42
noneofthese
A+H+
c)
HA
d)
iscalled:
e)KwKa
4. ForthestepwisedissociationofaqueousH3PO4,whichofthefollowingisnota
conjugateacidbasepair?
a) HPO42andPO43
b)
c)
d)
H2PO4andHPO42
H3O+andH2O
H3PO4andH2PO4
e)
H
2PO4andPO
43
5. Whatistheequilibriumconstantforthefollowingreaction(KaforHN3=1.9105)?
N3+H3O+
a)
5.31010
HN3+H2O
b)1.9109
c)1.9105 d)5.3
10
4
e)1.9109
6. ThehydrogensulfateorbisulfateionHSO4canactaseitheranacidorabaseinwater
solution.InwhichofthefollowingequationsdoesHSO4actasanacid?
a)
HSO4+H2OH2SO4+OH
b)
HSO4+OHH2SO4+O2
c)
noneofthese
d)
HSO4+H3O+SO3+2H2O
e)
HSO
4+H
2O
SO
42+H
3O+
7. At0C,theionproductconstantofwater,Kw,is1.21015.ThepHofpurewaterat
0Cis:
a)
7.00
b)6.88
c)7.56
d)7.46
e)noneofthese
8. UsingthefollowingKavalues,indicatethecorrectorderofbasestrength.
HNO2 Ka=4.0104
HF
Ka=7.2104
a)
CN
>NO
2>F
>H
2O>Cl
b)
CN>F>NO2>Cl>H2O
c)
noneofthese
d)
e)
HCN Ka=6.21010
Cl>H2O>F>NO2>CN
H2O>CN>NO2>F>Cl
9. Theequilibriumconstants(Ka)forHCNandHFinH2Oat25Care6.21010and
7.2104,respectively.Therelativeorderofbasestrengthsis:
a)
d)
F>H2O>CN
F>CN>H2O
b)
e)
H2O>F>CN
noneofthese
c)
CN
>F
>H
2O
10. GiventhefollowingacidsandKavalues:
HClO4
HOAc
HCN
HF
1107
1.76105
4.931010
3.53104
whichshowstheconjugatebaseslistedbyincreasingstrength?
a)
b)
CN,F,OAc,ClO4
CN,ClO4,F,OAc
d)
e)
,OAc
c)
ClO
4,F
,CN
CN,OAc,F,ClO4
ClO4,OAc,CN,F
11. Theconjugatebaseofaweakacidis
a)
d)
b)
aweakbase
e)
noneofthese
astrongbase
aweakacid
c)
astrongacid
12. Whichofthefollowingistheequilibriumconstantexpressionforthedissociationofthe
weakacidHOCl?
a)
K=
d)
K=
b)
e)
K=[H+][OCl]
c)
K=
noneofthese
13. GiventhattheKaforHOClis3.5x108,calculatetheKvalueforthereactionofHOCl
withOH.
a)
3.5x10
6
b)
3.5x108
c)
3.5x1022
d) 2.9x107
e)
2.9x1021
1415.Thefollowingthreeequationsrepresentequilibriathatliefartotheright.
HNO3(aq)+CN(aq)
HCN(aq)+NO3(aq)
HCN(aq)+OH(aq)
H2O(l)+CN(aq)
H2O(l)+CH3O(aq)
CH3OH(aq)+OH(aq)
14. Identifythestrongestacid.
a)
HCN
b)HNO3
c)H2O
d)OH
e)CH3OH
d)H2O
e)NO3
15. Identifythestrongestbase.
a)
CH
3O b)CH3OH
c)CN
16. Calculatethe[H+]inasolutionthathasapHof11.70.
a) 2.3M
d)
2.0
10
12M
b)
e)
11.7M
noneofthese
c)
5.0103M
17. Calculatethe[H+]inasolutionthathasapHof2.30.
a)
d)
2.3M
2.0 1012M
b)
e)
11.7M
c)
5.0
10
3M
noneofthese
18. ThepHofasolutionat25Cinwhich[OH]=3.4105Mis:
a)
4.5
b)10.5
c)9.5
d)6.3
19. ConsiderthereactionHNO2(aq)+H2O(l)
theconjugatebase?
a)
d)
HNO2(aq)
NO(aq)*
b)
e)noneofthese
H3O+(aq)+NO2(aq).Whichspeciesis
H2O(l)*
c)
e)
Twoofthese
H3O+(aq)
20. InwhichofthefollowingreactionsdoestheH2PO4ionactasanacid?
a)
b)
c)
H3PO4+H2OH3O++H2PO4
H2PO4+OHH3PO4+O2
Twoofthese
+
d)
H
2PO4+H
2O
H
3O+HPO
42
e)
Theioncannotactasanacid.
21. Indecidingwhichoftwoacidsisthestronger,onemustknow:
a) theconcentrationofeachacidsolution
b)
theequilibriumconstantofeachacid
c) bothaandcmustbeknown
d)
e)
thepHofeachacidsolution
alloftheabove
22. Whichofthefollowingisnottrueforasolutionat25Cthathasahydroxide
concentrationof2.5106M?
a)
b)
c)
Kw=11014
d)
Thesolutionisacidic.
Thesolutionisbasic.
e)
The[H+]is4109M.
TheKwisindependentofwhatthesolutioncontains.
23. CalculatethepHof0.250MHNO3(aq).
a)
0.600
b)2.50
c)12.0
d)1.20
e)13.4
24. SolidcalciumhydroxideisdissolvedinwateruntilthepHofthesolutionis10.94.The
hydroxideionconcentration[OH]ofthesolutionis:
a)
d)
1.11011M
1.01014M
b)
e)
3.06M
c)
8.7
10
4M
noneofthese
25. Aswaterisheated,itspHdecreases.Thismeansthat
a)
d)
b)[H+]>[OH]
e)noneofthese
thewaterisnolongerneutral
aandbarecorrect
c)[OH]>[H+]
26. Whichofthefollowingindicatesthemostbasicsolution?
+
a)
[H
]=1
10
10M
d) pH=4.2
b)pOH=6.7
c)[OH]=7105M
e)Atleasttwoofthesolutionsareequallybasic.
27. CalculatethepOHofa5.0MsolutionofHCl.
a)
0.70
b)0.70
c)14.70
d)13.30
e)noneofthese
28. Fornitrousacid,HNO2,Ka=4.0104.CalculatethepHof0.25MHNO2.
a)
2.00
b)2.30
c)2.70
d)3.70
e)noneofthese
29. Aceticacid(HC2H3O2)isaweakacid(Ka=1.8105).CalculatethepHofa17.6M
HC2H3O2solution.
a)
4.31
c)1.75
b)6.40
d)0.97
e)7.40
30. DeterminethemolarityofasolutionoftheweakacidHClO2(Ka=1.10102)ifithasa
pHof1.25.
a)
0.287M
b)1.23M
c)0.819M
d)3.17M
e)1.52M
3132. Thefollowingquestionsrefertoasolutionthatcontains1.00Mhydrofluoricacid,HF
(Ka=7.2104),and3.00Mhydrocyanicacid,HCN(Ka=6.21010).
31. WhatisthepHofthismixtureofweakacids?
a)
0.00
b)1.57
c)3.14
d)4.37
e)9.21
32. Determinethe[CN]atequilibrium.
a)
d)
4.31105M
6.21010M
b)
e)
4.28107M
noneofthese
c)
6.9
10
8M
33. Calculatethe[H+]ina0.010MsolutionofHCN,Ka=6.21010.
a)
d)
1.0 107M
6.2 1010M
b)
2.5
10
6M
e)
noneofthese
c)
3.6 103M
34. Inasolutionpreparedbydissolving0.100moleofpropionicacidinenoughwaterto
make1.00Lofsolution,thepHisobservedtobe1.35.TheKaforpropionicacid
(HC3H5O2)is:
a)
d)
2.0 102
5.0 1012
b)
3.6
10
2
e)
noneofthese
c)
4.5 102
35. Asolutionof2.5Mweakacidis0.52%ionized.WhatistheKavalueofthisacid?
a)
6.8x10
5
d) 1.3x102
b)
e)
1.1x105
noneofthese
c)
0.11
36. ThepHofa0.100Msolutionofanaqueousweakacid(HA)is3.20.TheKafortheweak
acidis:
a)
d)
6.3104
3.2
b)
e)
c)
4.0
10
6
7.2105
noneofthese
37. Saccharinisamonoproticacid.IfthepHofa1.50102Msolutionofthisacidis5.53,
whatistheKaofsaccharin?
a)
d)
2.0104
8.41012
b)
e)
c)
5.8
10
10
2.9106
noneofthese
38. Amonoproticweakacidwhendissolvedinwateris0.92%dissociatedandproducesa
solutionwithapHof3.42.CalculatetheKaoftheacid.
a)
d)
1.4x107
b)
2.8x103
Needtoknowtheinitialconcentrationoftheacid.
c)
3.5x10
6
e)
Noneofthese.
39. Howmanymolesofbenzoicacid,amonoproticacidwithKa=6.4105,mustbe
dissolvedin500.mLofH2OtoproduceasolutionwithpH=2.50?
a)
d)
1.6101
0.50
b)
e)
c)
7.8
10
2
2.0102
noneofthese
40. CalculatethepHofa0.10MsolutionofHOCl,Ka=3.5108.
a)
4.23
b)8.46
c)3.73
d)1.00
e)3.23
41. CalculatethepOHofa0.80Msolutionofaceticacid(Ka=1.8105).
a)
9.25
b)2.42
c)4.74
d)11.58
e)7.87
42. ThepKaofHOClis7.5.CalculatethepHofa0.5MsolutionofHOCl.
a)
7.5
b)6.5
c)3.9
d)10.1
e)0.3
43. When2.0102molofnicotinicacid(amonoproticacid)isdissolvedin350mLof
water,thepHis3.05.CalculatetheKaofnicotinicacid.
a)
d)
1.6102
7.9107
b)
1.4
10
5
e)
noneofthese
c)
3.9105
44. Aswaterisheated,itspHdecreases.Thismeansthat
a) thewaterisnolongerneutral.
b) theKwvalueisdecreasing.
c) thewaterhasalower(OH]thancoolerwater.
d)
thedissociationofwaterisanendothermicprocess.
e) noneofthese.
45. Whatconcentrationofaceticacid(Ka=1.80105)hasthesamepHasthatof5.00103
MHCl?
a)
d)
3.60103M
5.00M
b)
e)
46. ConsiderthereactionHOCl+F
5.00103M
noneofthese
c)
1.39M
HF+OCl
GiventhatKaforHOClis3.5108andtheKaforHFis7.2104(bothat25C),which
ofthefollowingistrueconcerningKfortheabovereactionat25C?
a) Kisgreaterthan1.
b)
K
islessthan1.
c) Kisequalto1.
d)
e)
Cannotbedeterminedwiththeaboveinformation.
Noneofthese(ad)
47. CalculatethepHofa0.10MsolutionofCa(OH)2.
a)
13.30
b)13.00
c)0.20
d)0.10
e)noneofthese
d)12.3
e)noneofthese
48. CalculatethepHofa0.02MsolutionofKOH.
a)
1.7
b)2.0
c)12.0
49. A0.400gsampleofNaOH(s)isaddedtoenoughwatertomake250.0mLofsolution.
ThepHofthissolutionis:
a)
12.000
b)1.398
c)2.000
d)12.602
e)noneofthese
50. The[OH]ina0.50Mpyridine(C5H5N;Kb=1.7109)solutionis
a)
d)
0.50M
3.31010M
b)
2.9
10
5M
e)
noneofthese
c)
1.8109M
5152. Thefollowingquestionsrefertoa0.70Msolutionofhypochlorousacid,HClO.
51. TheKafortheacidis3.5108.Determinethepercentdissociation.
a)
1.3%
b)0.84%
c)0.41%
d)0.022%
e)0.15%
52. Ifthemolaritywasdecreasedto0.3M,whichofthefollowingstatementswouldbe
true?
a) Thepercentdissociationwouldnotchange.
b) Thepercentdissociationwouldincrease.*
c) Thepercentdissociationwoulddecrease.
d) Theequilibriumconstantwouldstaythesame.*
e)
Twoofthese.
53. Thepainkillermorphineisaweakbasewhenaddedtowater.Thereactionproduces
onemoleofhydroxideionsforeveryonemoleofmorphinethatdissolves.TheKbis1.6
106.WhatisthepHofa5.00103Msolutionofmorphine?
a)
8.23
b)9.95
c)11.3
d)10.2
e)noneofthese
54. CalculatethepHofa0.10Msolutionofpyridine(C5H5N;Kb=1.7109):
a)
8.15
c)9.12
b)5.88
d)11.24
e)noneofthese
55. WhichofthefollowingaqueoussolutionswillhavethehighestpH?
ForNH3,Kb=1.8105;forC2H3O2,Kb=5.61010.
a)
2.0MNaOH
d) 2.0MHCl
b)
e)
2.0MNH3
allthesame
c)
2.0MHC2H3O2
56. CalculatethepHofthefollowingaqueoussolution:0.78MHOCl(pKa=7.46)
a)
10.22
b)3.78
c)7.57
d)6.43
e)noneofthese
57. Thedihydrogenphosphateion,H2PO4,hasbothaconjugateacidandaconjugatebase.
Theseare,respectively:
a)
H3PO4,PO43
b)
H
3PO4,HPO42
d)
HPO42,PO43
e)
HPO42,H3PO4
c)
H2PO4,HPO42
58. HOAc
H2CO3
Ka=1.8105
Ka1=4.3107
Ka2=5.61011
Whichofthefollowing0.01MsolutionshasthehighestpH?
a)
d)
HOAc
H2CO3
b)
e)
c)
Na
2CO3
NaOAc
NaHCO3
59. Whichofthefollowingspeciesispresentinthegreatestconcentrationina0.100M
H2SO4solutioninH2O?
a)
H
3O+
d)
HSO4
b)
H2SO4
e)
SO42
c)
Allspeciesareinequilibriumandthereforehavethesameconcentration.
60. ThepHofa0.150Msolutionofaweakbaseis10.98.CalculatethepHofa0.0400M
solutionofthebase.
a)
10.50
b)10.69
c)11.20
d)11.50
e)noneofthese
3,NH4Cl,KCl,NaC2H3O2,KOH
e) noneofthese
62. IfyouknowKbforammonia,NH3,youcancalculatetheequilibriumconstant,Ka,for
thefollowingreaction:
NH4+
NH3+H+
bytheequation:
a)
Ka=KwKb
b)K
a=K
w/Kb
c)Ka=1/Kb
d)Ka=Kb/Kw
63. WhichofthefollowingwouldgivethehighestpHwhendissolvedinwatertoforma
0.10Msolution?
a) astrongacid
b)
thepotassiumsaltofaweakacid
c) theammoniumsaltofastrongacid
d)
e)
aweakacid
thepotassiumsaltofastrongacid
64. Thehydrogenhalides(HF,HCl,HBr,andHI)areallpolarmolecules.Thestrengthof
theacideachformsinwaterisbasedonwhichofthefollowing?
a)
b)
c)
6569.
thepolarityofthemolecule
thestrengthofthebond
noneofthese
d)
thesizeofthemolecule
e)
twoofthese
Usethefollowingchoicestodescribeanaqueoussolutionmadefromeachofthe
followingsubstances.
a) acidic
b)
neutral
c)
basic
d) cannottell
e)
Noneofthese(ad)
65. solidsodiumnitrate(NaNO3)
b)neutral
66. solidsilverchloride(AgCl)
b)neutral
67. solidsodiumcarbonate(Na2CO3)
c)basic
68. solidammoniumacetate(NH4C2H3O2)
ForNH4+,Ka=5.61010;forC2H3O2,Kb=5.61010.
b)neutral
69. solidammoniumperchlorate(NH4ClO4)
ForNH4+,Ka=5.61010;forClO4,Kb1021.
a)acidic
70. ThepHofa1.0MaqueoussolutionofNaClis:
a)
7.0
b)
greaterthan7.0
d) notenoughinformationisgiven
e)
c)
lessthan7.0
noneofthese(ad)
71. ThepHofa1.0Msodiumacetatesolutionis:
a)
d)
7.0
b)
greaterthan7.0
notenoughinformationisgiven
e)
c)
lessthan7.0
noneofthese(ad)
72. Whichofthefollowingsolutionscontainsthestrongestacid?
a) 5.00MHCN(Ka=6.2x1010)
b) 3.50MH2C6H6O6(Ka1=7.9x105,Ka2=1.6x1012).
c) 2.50MHC2H3O2(Ka=1.8x105)
d) 4.00MHOCl(Ka=3.5x108)
4
e)
1.00
M
HF(Ka=7.2x10
73. Theautoionizationofwater,asrepresentedbythebelowequation,isknowntobeendothermic.
Whichofthefollowingcorrectlystateswhatoccursasthetemperatureofwaterisraised?
H2O(l)+H2O(l)
H3O+(aq)+OH(aq)
a) ThepHofthewaterdoesnotchange,andthewaterremainsneutral.
b) ThepHofthewaterdecreases,andthewaterbecomesmoreacidic.
c)
ThepHofthewaterdecreases,andthewaterremainsneutral.
d) ThepHofthewaterincreases,andthewaterbecomesmoreacidic.
e) ThepHofthewaterincreasesandthewaterremainsneutral.
74. Whichofthefollowingcorrectlylabelsthesalts?
HF(Ka=7.2x104)
NH3(Kb=1.8x105)
HCN(Ka=6.2x1010)
a) NaCN=acidic,NH4F=basic,KCN=neutral
b) NaCN=acidic,NH4F=neutral,KCN=basic
c) NaCN=basic,NH4F=basic,KCN=neutral
d) NaCN=basic,NH4F=neutral,KCN=basic
e)
NaCN=basic,NH
4F=acidic,KCN=basic
75. Whichofthefollowingstatements(ac)aretrue?
a) ThepHofastrongacidisalwayslowerthanthepHofaweakacid.
b) ThepHofasolutioncanneverbenegative.
c) Foraconjugateacidbasepair,Ka=1/Kb.
d) Atleasttwoofthestatementsacaretrue.
e)
Allofthestatementsacarefalse.