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A BCC iron metal foil is 25 m thick. Assume that all of the unit cells are arranged so that ao is perpendicular to the foil surface. For a 1 cm x 1 cm piece of foil, calculate: (a) the thickness of the foil in number of unit cells (b) total number of unit cells in the piece of foil DATA: rFe = 0.124 nm A steel bar is placed in a furnace and carbon is allowed to diffuse into the material. What is the temperature (C) required to obtain 0.50% C at a distance of 0.5 mm beneath the surface of a 0.20% C steel in 5 hours when 0.71% C is present at the surface at all time? DATA: For the diffusion coefficient, Do = 0.23 cm2/sec and Q = 134 kJ/mole R = gas constant = 8.314 J/moleK The fraction of vacant lattice sites in aluminum at 650C is 10-3. What is the energy required to create vacancies in aluminum? Determine the Miller indices for the planes in the unit cell shown below.

2.

3. 4.

(answer)

A close packed plane in the fcc structure is the: (a) (110) (b) (001) (c) (111) (d) none of the above The major types of atomic bonds are: (a) metallic, covalent, ionic (b) van der Waals, covalent, metallic (c) hydrogen, ionic, metallic (d) none of the above From the energy as a function of atomic separation diagram, the equilibrium separation distance between two atoms is: (a) when E = 0 (b) when E is the minimum value (c) when E is the maximum value (d) none of the above T/F Non-steady state diffusion occurs when one end of a semi-infinite rod is held at a constant surface composition. A x-ray diffraction pattern taken from an unknown solid with a cubic crystal structure can be used to determine: (a) the composition of the solid (b) the density of the solid (c) the lattice parameter, a (d) all of the above

NA = 6.02 ! 10 23 atoms / mole R = 8.314 J / mole K k = 8.62 ! 10 "5 eV / atom K K = 273 +C E = # Fdr EN = " APF = A B + = Eatt . + Erep r rn VS VC

C1 != C2 != C1 != C2 != C1 = C2 =

nm

1

nm + nm nm

1 2

" 100 " 100 " 100 " 100 " 100 " 100

Aave =

100 C1 C2 + A1 A2 C1 !A1 + C2 ! A2

nm + nm C1A2

Aave =

a = 2R 2 a = 4R / 3

$NA N= A nA $= VC NA

number of atoms length number of atoms PD = area n% = 2d hkl sin& hkl LD = d hkl = a

2 2 2

$ ' & C ) 1 ) x103 C1 !! = & & C1 C2 ) + & ) % #1 #2 ( $ ' & C ) 2 ) x103 C2 !! = & & C1 C2 ) + & ) % #1 #2 (

#ave =

#ave =

C1 + C2 = 100 nm =

1

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