F321 module 1 Practice 1: Molar mass of CaCO3 = 100.1 g mol1 (1) 2.68/100.1 = 0.0268/0.027 (1) (ii) (iii) 0.

0268 mol 24,000 = 643 cm3 (1) moles HNO3 = 2 0.0268 = 0.0536 /0.054 mol (1) (i.e. answer to (i) 2) volume of HNO3 = 0.0536 1000/2.50 = 21.4 cm3 (1) 2
[5]

1.

(i)

2 1

2.

Molar mass of anhydrous calcium nitrate = 164.1 g mol 1 (1) Ratio Ca(NO3)2 : H2O = 69.50/164.1 : 30.50/18 or 0.4235 : 1.694 or 1 : 4 (1) Formula = Ca(NO3)24H2O (1)
[3]

3.

(i) (ii)

because Ca has changed from 0 to +2 (1) and H has changed from +1 to 0 (1) Calcium reacts with water producing hydrogen/H2/calcium/hydroxide/Ca(OH)2 (1) (i.e. one product) Ca(s) + H2O(l) Ca(OH)2(aq) + H2(g) (1) (i.e. full equation) Equation would subsume both two marks

2
[4]

4.

(a)

(atoms of) same element/same atomic number.. with different numbers of neutrons/different masses 1 3 percentage composition protons
85 87

(b) isotope number of neutrons 48 50 electrons 37 37

Rb Rb

71 to 73 27 to 29 must add up to 100

37 37

mark

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ie 1 mark for each atomic structure; 1 for % compositions.

Ar =

(85 72) + (87 28) / 85.56 100

2nd mark for significant figures 2

= 85.6

71/29: 85.58 = 85.6 73/27: 85.54 = 85.5 carbon-12/12C

(c)

1
[7]

5.

(i) (ii)

Simplest (whole number) ratio of atoms/moles/elements ratio Rb : Ag : I = 7.42/85.5 : 37.48/108 : 55.10/127 or 0.0868 : 0.347 : 0.434 or 1 : 4 : 5 = RbAg4I5

2
[3]

6.

(a) (ii)

(i)

12 50/1000 = 0.600 mol

4 mol HCl 1 mol Cl2 / moles Cl2 = 0.15 mol vol of Cl2 = 0.15 24 = 3.60 dm3 2nd mark is consequential on molar ratio given 2

(b)

Evidence that the oxidation number of Mn has reduced and one of the oxidation numbers correct (ie MnO2: ox no of Mn = +4 or MnCl2: ox no of Mn = +2 The other oxidation number of Mn is correct, ie in MnO2: ox no of Mn = +4 or in MnCl2: ox no of Mn = +2 2
[5]

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7.

(i) (ii)

mass = 0.0500 23.0 = 1.15 g moles H2 = 0.0250 volume H2 = 0.0250 24 = 0.600 dm3 ecf from calculated moles H2 0.0500 mol in 50.0 cm3

1
[4]

(iii)

concentration = 0.0500 20 = 1.00 mol dm3

8.

(i) (ii)

2Na + O2 Na2O2 Na2O2 + 2H2O H2O2 + 2NaOH correct covalent bonds shown electron count (14) for rest of molecule correct

1 1

(iii)

2
[4]

9.

(i) (ii)

loss (of electrons) Ba 0 (+)2 (accept 2+)

1 2
[3]

10.

(i) (ii) (iii)

atoms of the same element with different numbers of neutrons/different masses (1)
79 81

1 2 1
[4]

Br 35 protons, 44 neutrons, 35 electrons (1) Br 35 protons, 46 neutrons, 35 electrons (1)

(1s2)2s22p63s23p63d104s24p5 (1)

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