Sample Paper for Cumulative Examination Class- XI Subject Chemistry Time Allowed : 3 Hrs. M.M.

70
General Instructions:
All questions are Compulsory. 1) Question nos. 1 to 8 are very short answer questions and carry 1 mark each. 2) Question nos. 9 to 18 are short answer questions and carry 2 marks each. 3) Question nos. 19 to 27 are also short answer questions and carry 3 marks each. 4) Question nos. 28 to 30 are long answer questions and carry 5 marks each. 5) Use Log tables if necessary, use of calculators is not allowed. Q1 Q2 Q3 Given that density of water is 1 gmL -1. What is its density in Kgm-3? Define Law of multiple proportions. How many electrons will be present in the sub-shells having ms value of -1/2 for n=4? Q4 Q5 Q6 Why standard heat of formation of diamond is not zero though it is an element? Write conjugate acids for the following Bronsted bases: HCOO- , NH3 For the following equilibrium Kc =6.3 X 10 -14 at 1000 k NO(g)+O3(g) NO2(g) +O2 (g)

What is Kc for the reverse reaction? Q7 Q8 What is the oxidation number of S in H2S2O7? In the reaction H2S(g) + Cl2(g) Which species is reduced? Q9 Q10 Q11 Calculate the molecular mass of CO2 , H2O Out of 3d and 4s orbital , which is filled first and why? What is the total number of sigma and Pi bonds in the following molecules? 2HCl (g) + S(s)

a) C2H2 b) C2H4 Q12 What is the basic difference between the terms electron gain enthalpy and electronegativity ? Q13 State first law of thermodynamics. Give its mathematical expression.

Q14

Using the equation of state pv =nRT , show that at a given temperature density of a gas is proportional to gas pressure p ?

Q15

Give four conditions to have better yield of ammonia in Habers process 3H2(g) + N2 (g) 2NH3 ; H = -92.3KJ

Q16 Yellow light emitted from a sodium lamp has a wavelength ( ) of 580nm. Calculate the frequency ( v) and wavenumber (v) of the yellow light. OR Calculate the wavelength, frequency of a light wave whose period is 2.0 x 10-10s. Q17 Balance the following equation by half equation method. MnO-4 + H + I Q18 Q19
+

Mn 2+ + H2O + I2

Write the names of isotopes of hydrogen. What is the mass ratio of these isotopes? You are told by your chemistry teacher to dissolve 4g of sodium hydroxide in 250 ml of solution . Find out

a) Strength of solution b) Molarity of Solution Q20 Calculate the uncertainity in the momentum of an electron if it is confined to a linear region of Length 1x10 -10 metre. Q21 How would you explain the fact that the first ionization enthalpy of sodium is lower than that of magnesium but its second ionization enthalpy is higher than that of magnesium? Q22 i. ii. Q23 Discuss the shape of the following molecules using VSEPR model BeCl2 BCl3 (a) What will be the conjugate bases for the following Bronsted acids: HF , H2SO4 (b) What are buffer solutions? Give one example of natural buffer. Q24 (a) What is meant by 10V H2O2 solution? (b) What are Non- stoichiometric hydrides? Give one example. (c) What causes the temporary and permanent hardness of water. OR (a) What do you understand by the terms

(i) (ii)

syn gas water gas shift reaction

(b) How does H2O2 behave as a bleaching agent? Q25 (a) In terms of Charles law explain why -273oC is the lowest possible temperature. (b) Critical temperature for Carbon Dioxide and methane are 31.1oC and - 81.9oC respectively.Which of these has stronger intermolecular forces and why? Q26 Depict the galvanic cell in which the reaction Zn (s) + 2 Ag+ (aq) Further show: (i) (ii) (iii) Q27 Which of the electrode is negatively charged. The carriers of the current in the cell , and Individual reaction at each electrode. Zn
2+

(aq) + 2Ag(s) takes place,

A neon dioxygen mixture contains 70.6 g dioxygen and 167.5g neon. If pressure of the mixture of gases in the cylinder is 25 bar. What is the partial pressure of dioxygen and neon in the mixture?

Q28 (a) State Boyles Law and Charles law through graphs only. (b) Give relations between volume and number of moles of a gas. (c) What is the S.I. value of universal gas constant R. (d) What do you understand by STP now a days. OR (a) What is absolute zero? (b) Define compressibility factor Z. (c) What type of intermolecular forces exist in the following: i. ii. iii. Alcohol and water NaCl in water CH4

Q29 (a) Give the shape of molecules ammonia, water , PCl5 , CH4, BeCl2 , BCl3 (b) Describe the shape of ethene on the basis of hybridization. OR (a) Which of the following molecules are polar and which are non- polar and why?

BF3, NH3 , H2O (b) Which of the following does not exist and why? (Explain on the basis of molecular orbital theory) He2 and H2 Q30 (a) Define the following:i. ii.
rH
o

= Enthalpy of reaction

Hesss Law

(b) Calculate the Enthalpy of formation of CH3OH(I) from the following data (i) CH3 OH( l) + 3/2 O2 (g) C(s) + O2 (g) H2(g) + O2 (g) (a) Give relationship between (i) (ii) (iii)
rH and rG and
o o o

CO2 (g) + 2H2O( l) CO2 (g) H2O (l) OR H = -393 KJ H = - 286KJ

H =1726KJ

fH fS

rH and Bond Enthalpy

(b) Define (i) (ii) Spontaneous reaction Second law of Thermodynamics