F321 module 1 Practice 4: Molar mass CaO = 56.

1 (g mol1)

1.

(i)

(anywhere) calc: 0.0267379

1.50 moles CaO = 56.1 = = 0.0267/0.027

Allow 56 which gives 0.0268 (ii) moles HNO3 = 2 0.0267 = 0.0534 or 0.0535 /0.053 mol (i.e. answer to (i) x 2)

0.0534 (or 5) 1000 2.50 volume of HNO3 = = 21.4 cm3

calc from value above = 21.3903743 If 0.053 mol, answer is 21 cm3 but accept 21.2 cm3 If 0.054 mol, answer is 22 cm3 but accept 21.6 cm3

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2.

(i)

dative covalent, bonded pair comes from same atom/ electron pair is donated from one atom/ both electrons are from the same atom

(ii)

Ca(NO3)2

CaO + 2NO2 + O2 1
[2]

or double equation with 2/2/4/1

3.

(i) (ii) (iii)

203.3 g mol1 Accept 203 white precipitate / goes white Ag+(aq) + Cl(aq) AgCl(s) equation state symbols AgCl dissolves in NH3(aq)

1 1

(iv)

AgBr dissolves in conc NH3(aq)/ partially soluble in NH3(aq) AgI insoluble in NH3(aq) 3
[7]

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4.

(i) (ii)

a proton donor MgO + 2HCl MgCl2 + H2O

1 1
[2]

5. isotope
12 13

protons 6 6 6 7

neutrons 6 6

electrons

C C

[2]

6.

(i) (ii)

mass spectrometry mass of an isotope compared with carbon-12 1/12th of mass of carbon-12/on a scale where carbon-12 is 12 mass of 1 mole of the isotope/mass of 1 mole of carbon-12 is equivalent to the first mark mass of the isotope that contains the same number of atoms as are in 1 mole of carbon-12 1 mark (mark lost because of mass units)

(iii)

12 95/100 + 13 5/100 OR 12.05 = 12.1 (mark for significant figures) (12.1 scores both marks)

2
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7.

(i)

moles CO2 = 1000 /44 mol = 22.7 mol volume CO2 in 2000 = 22.7 24 = 545 dm3 reduction = 545 60/100 = 327 dm3
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(ii)

8.

(a)

Ca(s) + ..2

HCl(aq) .CaCl2(aq) + .H2(g).

(g) not required for H2 (b) In Ca, oxidation state = 0 and In CaCl2, oxidation state = +2 2

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Oxidation number increases from Ca to CaC l2

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9.

(i) (ii)

moles HCl = 2.0 50/1000 = 0.10 moles Ca = moles HCl = 0.050 mass Ca = 40.1 0.050 = 2.00 g / 2.005 g (accept 40 0.050 = 2.0 g) (mass Ca of 4.0 g would score 1 mark as ecf as molar ratio has not been identified)

(iii)

Ca has reacted with water Ca + 2H2O Ca(OH)2 + H2 state symbols not required 1st mark for H2 2nd mark is for the rest of the balanced equation
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10.

(a)

(i) (ii)

atoms of same element/same atomic number.. with different numbers of neutrons/different masses isotope
46 47

1 2

protons 22 22

neutrons 24 25

electrons 22 22

Ti Ti

(b)

Ar =

(46 8.9) + (47 9.8) + (48 81.3) / 47.724 100

2
[5]

= 47.7

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