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Name_______________________________________________________________ Sec_______

SN____

I. Write P if the compound is polar, NP if non-polar and A if amphiphatic. _____1. A few I2 crystals dissolved in oil. _____2. As compound A is added to the red oil and blue water, the volume of the blue water increases. _____3. The dichloromethane (DCM) is miscible in oil. _____4. A few drops of DCM is added to the mixture in a separatory funnel. The DCM combined with the upper layer. Give the polarity of the upper layer in a mixture. _____5. The detergent is used to washed off grease and oil in clothes with water. What is the polarity of the detergent? II. Complete the table below. Compounds CO2 Lewis Structure Molecular Geometry Polarity

CCl4

HBr

III. Write the correct answers on the blank provided. __________________1. It maintains electrical neutrality in the half-cells through the migration of ions. __________________2. It is the direction of flow of electrons in an electrochemical cell. __________________3. The species that is responsible for the pink color with phenolphthalein. __________________4. It refers to the point in titration where there is a sudden change in the physical property of solution such as the color of the indicator. __________________5. The color of phenolphthalein in acidic solution. __________________6. This is a substance that quantitatively reacts with the analyte in titration. __________________7. The endpoint of phenolphthalein indicator. __________________8. The oxidation number of I in KIO4. __________________9. A certain part of the universe that is under study. __________________10. The amount of heat energy required to raise the temperature of one gram of the substance by 1 C. __________________11. A process that releases heat to the surroundings. __________________12. Specific heat of water in J/g C. __________________13. A thermodynamic quantity used to describe heat flow at constant pressure. __________________14. Common name of Lead chromate. __________________15. It is used to measure the heat changes at adiabatic condition.
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III. Modified True or False. Write T if the statement is true. Otherwise, provide the correct word/phrases of the underlined word/s. __________________1. A CuSO4 solution will produce a dim light in the conductivity test. __________________2. Whitewash is the common name of CaO. __________________3. A salt produced from CH3COOH and NaOH has a pH below 7. __________________4. Cathode is a negative electrode at which reduction takes place. __________________5. A 3.5 M H2SO4 means that 3.5 moles of H2SO4 is present in 1000g of solution. __________________6. The electrode with higher standard reduction potential is a good oxidizing agent. __________________7. A spontaneous redox reaction has G < 1. __________________8. Electrolytic cell transforms chemical energy to electrical energy. __________________9. A blue-black color is observed when I2 reacts with the starch solution. __________________10. The conversion of I to I2 is an example of reduction reaction.
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IV. Problem Solving. Show the complete solution and box your final answer. 1. In the titration between H2SO4 and KOH, the ff. data were obtained: Volume of acid Final vol. reading (KOH) Initial vol reading (KOH) Concn (KOH) 10.00 mL 20.50 mL 0.00 mL 0.2753 M

a. Show the balanced chemical equation between the acid and base.

b. What is the concentration (in M) of the acid?

2. Fifty mL of two unknown substances were mixed in an improvised calorimeter. The heat capacity of the calorimeter is 68. 5J/g C. The calorimeter contains exactly 300.0 g water and the temperature increases by 2.23 C. a. Compute the heat of reaction.
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b. Is the reaction exothermic or endothermic? Explain.

3. Consider this redox reaction: Mg (s) + 2 Ag Mg E Ag /Ag = 0.80 V and E Mg /Mg = -2.37 V
0 + 0 2+

2+

+ Ag (s)

a. Based on the reduction potential provided for each electrode, which is the cathode?

b. Show the half-reaction for two electrodes.

c.

Give the balanced redox equation.

d. What is the cell voltage of this redox reaction?

e. Which is the reducing agent?

f.

Which will be reduced in the reaction?

g. Is the redox reaction spontaneous? Explain.

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