Safety Data Sheet

1. Identification
Product identifier Ot er !ean" of identification Reco!!ended u"e Reco!!ended re"triction" Co!%an) na!e Addre""

CIRCLESAFE 778A
Not available. Non-destructive testing. None known. Circle Syste s! "nc. &7% /est *incoln 0ve. +.,. -o. 1228 )inckley! "* 6$52$ 815-286-3271 custo erservice1circlesa2e.co C#e -tel 8$$-255-3%2& Contract' ("S$$$16&%

#anufacturer $ I!%orter $ Su%%&ier $ Di"tri'utor infor!ation

Te&e% one E*!ai& E!er(enc) % one nu!'er

+. Ha,ard-". identification
P )"ica& a,ard" Hea&t a,ard" OSHA defined a,ard" La'e& e&e!ent" 4ases under 3ressure 5e3roductive to.icity Not classi2ied. Co 3ressed gas Category 1-

Si(na& /ord Ha,ard "tate!ent Precautionar) "tate!ent Pre0ention Re"%on"e Stora(e Di"%o"a& Ha,ard-". not ot er/i"e c&a""ified -H1OC.

6anger Contains gas under 3ressure7 ay e.3lode i2 #eated. (ay da age 2ertility or t#e unborn c#ild.

,btain s3ecial instructions be2ore use. 6o not #andle until all sa2ety 3recautions #ave been read and understood. /ear 3rotective gloves83rotective clot#ing8eye 3rotection82ace 3rotection. "2 e.3osed or concerned9 Call a 3oison center8doctor. +rotect 2ro sunlig#t. Store in a well-ventilated 3lace. Store locked u3. 6is3ose o2 contents8container in accordance wit# local8regional8national8international regulations. Not classi2ied.

2. Co!%o"ition$infor!ation on in(redient"
#i3ture" C e!ica& na!e Carbon dio.ide "ron o.ide -oric acid CAS nu!'er 12&-38-% 12227-8%-3 1$$&3-35-3 4 :5 :5 :1

5. Fir"t*aid !ea"ure"
In a&ation S6in contact E)e contact In(e"tion #o"t i!%ortant ")!%to!"$effect"7 acute and de&a)ed
C"5C*<S0=<> 7780 %16$36 @ersion '9 $1

"2 sy 3to s develo3 5inse wit# water. 4et

ove victi

to 2res# air. 4et

edical attention i2 sy 3to s 3ersist.

/as# o22 wit# soa3 and water. 4et

edical attention i2 irritation develo3s and 3ersists.

edical attention i2 irritation develo3s and 3ersists. ay cause res3iratory irritation! di;;iness! nausea! or

"n t#e unlikely event o2 swallowing contact a 3#ysician or 3oison control center. )ig# concentrations9 "n#alation o2 3ro3ellant drowsiness.

S6S ?S 5evision date9 "ssue date9 2%-,ctober-2$13

186

Indication of i!!ediate !edica& attention and "%ecia& treat!ent needed 8enera& infor!ation

Areat sy 3to atically. Sy 3to s

ay be delayed.

<nsure t#at edical 3ersonnel are aware o2 t#e 3rotect t#e selves.

aterialBsC involved! and take 3recautions to

9. Fire*fi( tin( !ea"ure"

Suita'&e e3tin(ui" in( !edia :n"uita'&e e3tin(ui" in( !edia S%ecific a,ard" ari"in( fro! t e c e!ica& S%ecia& %rotecti0e e;ui%!ent and %recaution" for firefi( ter" Fire*fi( tin( e;ui%!ent$in"truction" /ater 2og. =oa . 6ry c#e ical 3owder. Carbon dio.ide BC,2C. 6o not use water Det as an e.tinguis#er! as t#is will s3read t#e 2ire. +ressuri;ed container ay e.3lode w#en e.3osed to #eat or 2la e. 6uring 2ire! gases #a;ardous to #ealt# ay be 2or ed. Sel2-contained breat#ing a33aratus and 2ull 3rotective clot#ing ust be worn in case o2 2ire.

Containers s#ould be cooled wit# water to 3revent va3or 3ressure build u3.

<. Accidenta& re&ea"e !ea"ure"

Per"ona& %recaution"7 %rotecti0e e;ui%!ent and e!er(enc) %rocedure" #et od" and !ateria&" for contain!ent and c&eanin( u% Eee3 unnecessary 3ersonnel away. Eee3 u3wind. Eee3 out o2 low areas. /ear a33ro3riate 3ersonal 3rotective eFui3 ent. 6o not touc# da aged containers or s3illed aterial unless wearing a33ro3riate 3rotective clot#ing. <nsure adeFuate ventilation. <li inate all ignition sources Bno s oking! 2lares! s3arks! or 2la es in i ediate areaC. Eee3 co bustibles Bwood! 3a3er! oil! etc.C away 2ro s3illed aterial. Sto3 leak i2 you can do so wit#out risk. (ove t#e cylinder to a sa2e and o3en area i2 t#e leak is irre3arable. 0bsorb in ver iculite! dry sand or eart# and 3lace into containers. =ollowing 3roduct recovery! 2lus# area wit# water. S all S3ills9 /i3e u3 wit# absorbent aterial Be.g. clot#! 2leeceC. Clean sur2ace t#oroug#ly to re ove residual conta ination. =or waste dis3osal! see section 13 o2 t#e (S6S. En0iron!enta& %recaution" +revent 2urt#er leakage or s3illage i2 sa2e to do so.

7. Hand&in( and "tora(e

Precaution" for "afe and&in( +ressuri;ed container9 6o not 3ierce or burn! even a2ter use. 6o not use i2 s3ray button is issing or de2ective. 6o not s3ray on a naked 2la e or any ot#er incandescent aterial. 6o not s oke w#ile using or until s3rayed sur2ace is t#oroug#ly dry. 6o not cut! weld! solder! drill! grind! or e.3ose containers to #eat! 2la e! s3arks! or ot#er sources o2 ignition. 4round and bond containers w#en trans2erring aterial. 0void in#alation o2 aerosols. ?se only in well-ventilated areas. 6o not re-use e 3ty containers. *evel 1 0erosol. Contents under 3ressure. 6o not #andle or store near an o3en 2la e! #eat or ot#er sources o2 ignition. 6o not e.3ose to #eat or store at te 3eratures above 12$G=8&%GC as can ay burst. +rotect 2ro direct sunlig#t. 6o not 3uncture! incinerate or crus#. Store away 2ro inco 3atible aterials Bsee Section 1$ o2 t#e (S6SC.

Condition" for "afe "tora(e7 inc&udin( an) inco!%ati'i&itie"

8. E3%o"ure contro&"$%er"ona& %rotection

Occu%ationa& e3%o"ure &i!it" :S. OSHA Ta'&e =*1 Li!it" for Air Conta!inant" -+> CFR 1>1?.1???. Co!%onent" Carbon dio.ide BC0S 12&-38-%C :S. AC8IH T re" o&d Li!it @a&ue" Co!%onent" -oric acid BC0S 1$$&3-35-3C Carbon dio.ide BC0S 12&-38-%C T)%e SA<* A/0 SA<* A/0 @a&ue 6 g8 3 For! "n#alable 2raction. "n#alable 2raction. T)%e +<* @a&ue 5$$$ 33

2 g8 3 3$$$$ 33 5$$$ 33

:S 1IOSH Poc6et 8uide to C e!ica& Ha,ard"A Reco!!ended e3%o"ure &i!it -REL. Co!%onent" Carbon dio.ide BC0S 12&-38-%C T)%e A/0 @a&ue %$$$ g8 3

5$$$ 33
C"5C*<S0=<> 7780 %16$36 @ersion '9 $1 S6S ?S 5evision date9 "ssue date9 2%-,ctober-2$13

286

:S 1IOSH Poc6et 8uide to C e!ica& Ha,ard"A S ort Ter! E3%o"ure Li!it -STEL. Co!%onent" Carbon dio.ide BC0S 12&-38-%C Bio&o(ica& &i!it 0a&ue" A%%ro%riate en(ineerin( contro&" T)%e SA<* @a&ue 5&$$$ g8 3

3$$$$ 33 No biological e.3osure li its noted 2or t#e ingredientBsC. 4ood general ventilation Bty3ically 1$ air c#anges 3er #ourC s#ould be used. @entilation rates s#ould be atc#ed to conditions. "2 a33licable! use 3rocess enclosures! local e.#aust ventilation! or ot#er engineering controls to aintain airborne levels below reco ended e.3osure li its. "2 e.3osure li its #ave not been establis#ed! aintain airborne levels to an acce3table level.

Indi0idua& %rotection !ea"ure"7 "uc a" %er"ona& %rotecti0e e;ui%!ent E)e$face %rotection /ear sa2ety glasses wit# side s#ields Bor gogglesC. S6in %rotection Hand %rotection Ot er Re"%irator) %rotection T er!a& a,ard" 8enera& )(iene con"ideration" /ear 3rotective gloves. /ear suitable 3rotective clot#ing. "2 3er issible levels are e.ceeded use N",S) air-su33lied res3irator. ec#anical 2ilter 8 organic va3or cartridge or an

/ear a33ro3riate t#er al 3rotective clot#ing! w#en necessary. /#en using do not s oke. 0lways observe good 3ersonal #ygiene easures! suc# as was#ing a2ter #andling t#e aterial and be2ore eating! drinking! and8or s oking. 5outinely was# work clot#ing and 3rotective eFui3 ent to re ove conta inants.

>. P )"ica& and c e!ica& %ro%ertie"

A%%earance P )"ica& "tate For! Co&or Odor Odor t re" o&d %H #e&tin( %oint$free,in( %oint Initia& 'oi&in( %oint and 'oi&in( ran(e F&a" %oint E0a%oration rate F&a!!a'i&it) -"o&id7 (a". 0erosol s3ray can - +ressuri;ed *iFuid. *iFuid. 0erosol. 6ark green. Slig#t. 6etergent like. Not available. 8-% Not available. Not available. Not available. Not available. Not available.

:%%er$&o/er f&a!!a'i&it) or e3%&o"i0e &i!it" Not available. F&a!!a'i&it) &i!it * &o/er -4. F&a!!a'i&it) &i!it * u%%er -4. E3%&o"i0e &i!it * &o/er -4. E3%&o"i0e &i!it * u%%er -4. @a%or %re""ure @a%or den"it) Re&ati0e den"it) So&u'i&it)-ie". Partition coefficient -n*octano&$/ater. Auto*i(nition te!%erature Deco!%o"ition te!%erature @i"co"it) Not available. Not available. Not available. Not available. Not available. 1 B68 G= B2$ GCCC Soluble in water. Not available. Not available. Not available. Not available.

1?. Sta'i&it) and reacti0it)

Reacti0it)
C"5C*<S0=<> 7780 %16$36 @ersion '9 $1

A#e 3roduct is stable and non-reactive under nor al conditions o2 use! storage and trans3ort.
S6S ?S 5evision date9 "ssue date9 2%-,ctober-2$13

386

C e!ica& "ta'i&it) Po""i'i&it) of a,ardou" reaction" Condition" to a0oid Inco!%ati'&e !ateria&" Ha,ardou" deco!%o"ition %roduct"

Stable under nor al te 3erature conditions. No dangerous reaction known under conditions o2 nor al use. )eat! 2la es and s3arks. Contact wit# inco 3atible Strong o.idi;ing agents. No #a;ardous deco 3osition 3roducts are known. aterials.

11. To3ico&o(ica& infor!ation

Infor!ation on &i6e&) route" of e3%o"ure <.3ected to be a low ingestion #a;ard. In(e"tion In a&ation S6in contact E)e contact S)!%to!" re&ated to t e % )"ica&7 c e!ica& and to3ico&o(ica& c aracteri"tic" Acute to3icit) S6in corro"ion$irritation Seriou" e)e da!a(e$e)e irritation Re"%irator) "en"iti,ation S6in "en"iti,ation 8er! ce&& !uta(enicit) Carcino(enicit) Re%roducti0e to3icit) S%ecific tar(et or(an to3icit) * "in(&e e3%o"ure S%ecific tar(et or(an to3icit) * re%eated e3%o"ure A"%iration a,ard C ronic effect" (ay cause irritation to t#e res3iratory syste . (ay cause skin irritation. (ay cause eye irritation. )ig# concentrations9 "n#alation o2 3ro3ellant or drowsiness. ay cause res3iratory irritation! di;;iness! nausea!

Infor!ation on to3ico&o(ica& effect" <.3ected to be a low #a;ard 2or usual industrial or co +rolonged skin contact 6irect contact wit# eyes ay cause te 3orary irritation. ay cause te 3orary irritation. ercial #andling by trained 3ersonnel.

Not a res3iratory sensiti;er. A#is 3roduct is not e.3ected to cause skin sensiti;ation. No data available to indicate 3roduct or any co 3onents 3resent at greater t#an $.1H are utagenic or genoto.ic. A#is 3roduct is not considered to be a carcinogen by "05C! 0C4")! NA+! or ,S)0. (ay da age 2ertility or t#e unborn c#ild. Not classi2ied. Not classi2ied. Not classi2ied. +rolonged in#alation ay be #ar 2ul.

1+. Eco&o(ica& infor!ation

Ecoto3icit) Per"i"tence and de(rada'i&it) Bioaccu!u&ati0e %otentia& #o'i&it) in "oi& Ot er ad0er"e effect" Not e.3ected to be #ar 2ul to aFuatic organis s. No data is available on t#e degradability o2 t#is 3roduct. No data available 2or t#is 3roduct. Not available. No ot#er adverse environ ental e22ects Be.g. o;one de3letion! 3#otoc#e ical o;one creation 3otential! endocrine disru3tion! global war ing 3otentialC are e.3ected 2ro t#is co 3onent.

12. Di"%o"a& con"ideration"

Di"%o"a& in"truction" Collect and reclai or dis3ose in sealed containers at licensed waste dis3osal site. Contents under 3ressure. 6o not 3uncture! incinerate or crus#. 6is3ose in accordance wit# all a33licable regulations. A#e waste code s#ould be assigned in discussion between t#e user! t#e 3roducer and t#e waste dis3osal co 3any. 6is3ose o2 in accordance wit# local regulations. < 3ty containers or liners ay retain so e 3roduct residues. A#is aterial and its container ust be dis3osed o2 in a sa2e anner Bsee9 6is3osal instructionsC. < 3ty containers s#ould be taken to an a33roved waste #andling site 2or recycling or dis3osal. 6o not re-use e 3ty containers.

Ha,ardou" /a"te code Ca"te fro! re"idue" $ unu"ed %roduct" Conta!inated %ac6a(in(

15. Tran"%ort infor!ation

DOT :1 nu!'er :1 %ro%er " i%%in( na!e Tran"%ort a,ard c&a""-e".
C"5C*<S0=<> 7780 %16$36 @ersion '9 $1

?N1%5$ 0<5,S,*S 2.2

S6S ?S "ssue date9 2%-,ctober-2$13

5evision date9 -

&86

Su'"idiar) c&a""-e". Pac6in( (rou% S%ecia& %recaution" for u"er IATA :1 nu!'er :1 %ro%er " i%%in( na!e Tran"%ort a,ard c&a""-e". Su'"idiar) c&a""-e". Pac6a(in( (rou% En0iron!enta& a,ard" La'e&" re;uired ER8 Code S%ecia& %recaution" for u"er I#D8 :1 nu!'er :1 %ro%er " i%%in( na!e Tran"%ort a,ard c&a""-e". Su'"idiar) c&a""-e". Pac6a(in( (rou% En0iron!enta& a,ard" #arine %o&&utant La'e&" re;uired E!S S%ecia& %recaution" for u"er Tran"%ort in 'u&6 accordin( to Anne3 II of #ARPOL 72$78 and t e IBC Code

Not available. 5ead sa2ety instructions! S6S and e ergency 3rocedures be2ore #andling. ?N1%5$ 0<5,S,*S 2.2 Not available. No 2.2 1$* 5ead sa2ety instructions! S6S and e ergency 3rocedures be2ore #andling. ?N1%5$ 0<5,S,*S 2.2 Not available. No 2.2 =-6!S-? 5ead sa2ety instructions! S6S and e ergency 3rocedures be2ore #andling. A#is substance8 i.ture is not intended to be trans3orted in bulk.

19. Re(u&ator) infor!ation

:S federa& re(u&ation" TSCA Section 1+-'. E3%ort 1otification -5? CFR 7?77 Su'%t. D. Not regulated. :S. OSHA S%ecifica&&) Re(u&ated Su'"tance" -+> CFR 1>1?.1??1*1?9?. Not listed. CERCLA Ha,ardou" Su'"tance Li"t -5? CFR 2?+.5. Not listed. Su%erfund A!end!ent" and Reaut ori,ation Act of 1>8< -SARA. Ha,ard cate(orie" " ediate )a;ard - No 6elayed )a;ard - Ies =ire )a;ard - No +ressure )a;ard - Ies 5eactivity )a;ard - No SARA 2?+ E3tre!e&) a,ardou" "u'"tance SARA 211$21+ Ha,ardou" c e!ica& SARA 212 -TRI re%ortin(. C e!ica& na!e =or alde#yde Ot er federa& re(u&ation" C&ean Air Act -CAA. Section 11+ Ha,ardou" Air Po&&utant" -HAP". Li"t Not regulated. C&ean Air Act -CAA. Section 11+-r. Accidenta& Re&ea"e Pre0ention -5? CFR <8.12?. Not regulated. Safe Drin6in( Cater Act -SDCA. Food and Dru( Ad!ini"tration -FDA. :S "tate re(u&ation" :S. #a""ac u"ett" RTD * Su'"tance Li"t Carbon dio.ide BC0S 12&-38-%C
C"5C*<S0=<> 7780 %16$36 @ersion '9 $1 S6S ?S 5evision date9 "ssue date9 2%-,ctober-2$13

No Ies

CAS nu!'er 5$-$$-$

4 ') /t. : $.1

Not regulated. Not regulated.

586

:S. 1e/ Eer"e) Cor6er and Co!!unit) Ri( t*to*Dno/ Act Not regulated. :S. Penn")&0ania RTD * Ha,ardou" Su'"tance" Carbon dio.ide BC0S 12&-38-%C :S. R ode I"&and RTD Not regulated. :S. Ca&ifornia Pro%o"ition <9 A#is 3roduct contains trace a ounts o2 a c#e ical known to t#e State o2 Cali2ornia to cause cancer! birt# de2ects or ot#er re3roductive #ar . :S * Ca&ifornia Pro%o"ition <9 * Carcino(en" F Re%roducti0e To3icit) -CRT.A Li"ted "u'"tance =or alde#yde BC0S 5$-$$-$C Internationa& In0entorie" Countr)-". or re(ion 0ustralia Canada Canada C#ina <uro3e <uro3e Ja3an Eorea New Kealand +#ili33ines ?nited States N +uerto 5ico In0entor) na!e 0ustralian "nventory o2 C#e ical Substances B0"CSC 6o estic Substances *ist B6S*C Non-6o estic Substances *ist BN6S*C "nventory o2 <.isting C#e ical Substances in C#ina B"<CSCC <uro3ean "nventory o2 <.isting Co Substances B<"N<CSC ercial C#e ical On in0entor) -)e"$no.G Ies Ies No Ies Ies No No Ies Ies No Ies

<uro3ean *ist o2 Noti2ied C#e ical Substances B<*"NCSC "nventory o2 <.isting and New C#e ical Substances B<NCSC <.isting C#e icals *ist B<C*C New Kealand "nventory +#ili33ine "nventory o2 C#e icals and C#e ical Substances B+"CCSC Ao.ic Substances Control 0ct BASC0C "nventory

L0 MIesM indicates t#is 3roduct co 3lies wit# t#e inventory reFuire ents ad inistered by t#e governing countryBsC. 0 MNoM indicates t#at one or ore co 3onents o2 t#e 3roduct are not listed or e.e 3t 2ro listing on t#e inventory ad inistered by t#e governing countryBsC.

1<. Ot er infor!ation7 inc&udin( date of %re%aration or &a"t re0i"ion

I""ue date Re0i"ion date @er"ion H 1FPA Ratin(" 2%-,ctober-2$13 $1

? 1
Li"t of a''re0iation" Reference" Di"c&ai!er

A/09 Ai e weig#ted average. SA<*9 S#ort ter e.3osure li it. )S6-> - )a;ardous Substances 6ata -ank A#e in2or ation in t#is B(CS6S was obtained 2ro sources w#ic# we believe are reliable but cannot guarantee. 0dditionally! your use o2 t#is in2or ation is beyond our control and ay be beyond our knowledge. A#ere2ore! t#e in2or ation is 3rovided wit#out any re3resentation or warranty e.3ress or i 3lied.

C"5C*<S0=<> 7780 %16$36 @ersion '9 $1

S6S ?S 5evision date9 "ssue date9 2%-,ctober-2$13

686