SULIT

SULIT 4541/1
4541/1
Kimia
Kertas 1
Mei
2008
1¼ jam
BAHAGIAN SEKOLAH
KEMENTERIAN PELAJARAN MALAYSIA
______________________________________________
PEPERIKSAAN PERTENGAHAN TAHUN 2008
TINGKATAN 5

KIMIA

Kertas 1

Satu jam lima belas minit

JANGAN BUKA KERTAS SOALAN INI HINGGA DIBERITAHU

1. Kertas soalan ini mengandungi 50 soalan.

2. Jawab semua soalan
3. Jawab dengan menghitamkan ruangan yang betul pada kertas jawapan
4. Bagi setiap soalan hitamkan satu ruangan sahaja
5. Sekiranya anda hendak menukar jawapan, padamkan tanda yang telah dibuat.
Kemudian hitamkan jawapan yang baru.
6. Rajah yang mengiringi soalan tidak dilukiskan mengikut skala.
7. Anda dibenarkan menggunakan kalkulator saintifik yang tidak boleh
diprogramkan.

Kertas soalan ini mengandungi 23 halaman bercetak

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INFORMATION FOR CANDIDATES

1 This question paper consists of 50 questions.

2 Answer all questions.
3 Answer each question by blackening the correct space on the answer sheet.
4 Blacken only one space for each question.
5 If you wish to change your answer, erase the blackened mark that you have made. Then
blacken the space for the new answer.
6 The diagrams in the questions provided are not drawn to scale unless stated.
7 You may use a non-programmable scientific calculator.

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1 After making observations, a chemist should try to

A collect data
B make inference
C make hypothesis
D identify problems

2 The diagram shows a model of an atom.

Electron

Shell
Nucleus that contains
proton and neutrons

Who introduced this model?

A Neils Bohr
B J.J Thomson
C James Chadwick
D Ernest Rutherford

3 What is the relative molecular mass of hydrated magnesium sulphate,

MgSO4.7H2O?
[Relative atomic mass: Mg, 24; S,32; O,16; H,1]

A 145
B 246
C 305
D 356

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4 The table shows the properties of element Q.

Element Properties
 Non-flammable
Q  Used as carrier gas in gas-liquid chromatography
 Filled in electric light bulbs

Which of the following elements is Q?

A Sodium
B Helium
C Argon
D Silver

5 The table shows the electron arrangement for elements M, N, P and Q.

Element Electron arrangement

M 2.4
N 2.8.2
P 2.6
Q 2.8.7

Which of the following elements react to form an ionic compound?

A M and P
B P and Q
C M and Q
D P and N

6 The diagram shows the electrolysis of molten lead(II) bromide using carbon
electrodes.

Carbon

Lead(II) bromide

heat

What are the products at the anode and the cathode?

Anode Cathode
A Bromine Lead
B Oxygen Hydrogen
C Bromine Hydrogen
D Oxygen Lead

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7 Which of the following is a weak alkali?

A Lithium hydroxide
B Aqueous ammonia
C Cooper(II) hydroxide
D Potassium hydroxide

8 Which of the following salts is prepared through precipitation process?

A Lead(II) chromate(VI)
B Ammonium chloride
C Potassium carbonate
D Barium chloride

9 The diagram shows the formation of ammonia through Haber process.

Hydrogen Nitrogen

Catalyst X
Temperature Y
Pressure Z

Ammonia

Which of the following represent catalyst X, temperature Y and pressure Z?

Catalyst X Temperature Y, oC Pressure Z / atm

A Vanadium(V) oxide 550 200
B Platinum 450 100
C Iron 200 450
D Iron 450 200

10 Which of the following is the meaning of activation energy?

A The maximum energy that the particles need to produce effective

collision
B The amount of energy used by the particles during a collision
C The amount of kinetic energy of molecules during a collision
D The minimum amount of energy that particles must have in order to
react

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11 Which of the following structural formulae shows an unsaturated hydrocarbon?

12 The diagram shows the atomic symbol of element X.

X
3

Which of the following is true about the sub-atomic particles of element X?

Proton Number Number of neutron Number of electron

A 7 7 10
B 7 7 7
C 3 4 3
D 3 4 2

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13 What is the number of oxygen atom in 0.1 mole of water?

[Avogadro constant: 6.02 x 1023 mol-1]

A 6.02 x 1022
B 6.02 x 1023
C 60.2 x 1023
D 3.01 x 1023

14 X is an element that has the following properties;

 Soft solid
 Reacts with cold water to form alkaline solution
 Store in paraffin oil

Among elements A, B, C and D in the Periodic Table of elements, which element

represent X?

15 The diagram shows the electron arrangement of a compound formed between

atoms P and Q.
2+ 2-

P Q

Which of the following statements is true about the compound?

A There is strong intermolecular force between particles P and Q

B The compound is formed by sharing the electrons
C The compound conduct electricity in molten state
D It is an covalent compound

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16 The diagram shows the set-up of the apparatus used to electrolyses

0.1 mol dm-3 of copper(II) chloride solution by using carbon electrodes.

Carbon

Copper(II) chloride
solution

What is observed at the anode?

A Colourless gas bubbles released

B Greenish yellow gas evolved
C Brown solution produced
D Brown solid deposited

17 Which of the following equations shows the neutralization process?

I CuO + H2SO4  CuSO4 + H2O

II Zn + 2HCl  ZnCl2 + H2
III NH3 + HNO3  NH4NO3
IV CaCO3 + H2SO4  CaSO4 + H2O + CO2

A I only
B II and IV only
C I and III only
D I, II and IV only

18 Which of the following ions form a white precipitate that does not dissolves in
excess sodium hydroxide solution but no change occur in aqueous ammonia
solution?

A Mg2+
B Pb2+
C Ca2+
D Al3+

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19 The diagram shows the lead crystal glass.

What are the major components used in the making of lead crystal glass?

A Copper(II) oxide and lead(II) oxide

B Aluminium silicate and silicon dioxide
C Silicon dioxide and lead(II) oxide
D Iron(III) oxide and boron oxide

20 Chemical equation shows the reaction between zinc and sulphuric acid.

H2SO4(aq) + Zn(s)  ZnSO4(aq) + H2(g)

Which of the following factors increases the rate of reaction?

A Increases of volume of sulphuric acid

B Use of lower concentration of sulphuric acid
C Addition of small amount of copper(II) sulphate
D Use bigger size of zinc

21 The diagram shows the cooking gas cylinder.

Which of the following gasses is filled in the gas cylinder?

A Methane
B Ethene
C Propene
D Butane

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22 The graph shows the cooling curve of acetamide.

Temperature/ oC

T U

V
Time/ s

Which of the following statements are true about the particles in acetamide from S
to V?

I Heat energy is released by particles

II The kinetic energy of the particles increase
III The particle are closer to one another
IV The movement of the particles becomes slower

A I and III only

B III and IV only
C II, III and IV only
D I, III and IV only

23 The chemical equation shows the burning process of ethene in excess air.

C2H4(g) + 3O2  2CO2(g) + 2H2O(l)

What is the maximum volume of carbon dioxide gas evolved when 0.5 mole of
ethene burns completely?
[1 mole of gas occupied 24 dm3 at room temperature and pressure]

A 12 dm3
B 24 dm3
C 36 dm3
D 48 dm3

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24 The diagram shows the structure of atoms Q and R.

Atom Q Atom R

Which of the following is true about atoms Q and R?

A Q exists as a diatomic molecule

B Q and R have the same chemical properties
C R reacts with Q to form an ionic compound
D Q reacts with water to release hydrogen

25 The electron arrangement of atom J is 2.6 and atom G has 4 valence electrons.
What type of bond and the chemical formula of the compound formed between
atoms J and G?

Type of bond Chemical formula

A Ion JG2
B Ion GJ2
C Covalent GJ2
D Covalent JG2

26 The diagram shows the set-up of apparatus for the electrolysis of silver nitrate
solution.

Silver Silver

Silver nitrate solution

What is formed at the cathode?

A Silver atoms
B Oxygen gas
C Hydrogen gas
D Silver ions

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27 The distilled water is added to 20 cm3 of 1.0 mol dm-3 sodium hydroxide solution
to produce 250 cm3 of sodium hydroxide solution.
What is the concentration of the sodium hydroxide solution produced?

A 0.02 mol dm-3

B 0.04 mol dm-3
C 0.06 mol dm-3
D 0.08 mol dm-3

28 Ammonium sulphate is used as a chemical fertilizer. This fertilizer can be

prepared in the laboratory through the reaction between

A aqueous of ammonia solution and dilute sulphuric acid

B aqueous of ammonia solution and sulphur dioxide
C ammonia gas and sulphur and oxygen
D ammonia gas and sulphur trioxide

29 The diagram shows the arrangement of atoms in steel.

Iron atom

X atom

What is X?

A Tin
B Zinc
C Carbon
D Copper

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30 The graph shows the maximum volume of carbon dioxide gas evolved when
calcium carbonate react with hydrochloric acid.

Volume of CO2 gas/ cm3

35

Time/ s
120

What is the rate of reaction at 120 s?

A 0.00 cm3 s-1

B 0.15 cm3 s-1
C 0.29 cm3 s-1
D 0.35 cm3 s-1

31
Steam/Catalyst
Compound X Compound Y

Process A Acidified potassium

dichromate (VI)

CH3COOH

What could be the organic compounds X and Y, Catalyst and Process A in the
diagram?

Compound X Compound Catalyst Process A

Y
A Ethene Ethanol Phosphoric acid Oxidation
B Ethane Ethene Nickel Hydrogenation
C Ethane Ethene Nickel Oxidation
D Ethene Ethanol Phosphoric acid Hydrogenation

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32 The table shows the melting point and boiling point for substances P, Q, R
and S.

Substance Melting point/ oC Boiling point/ oC

P 79 108
Q -180 -120
R -95 69
S -160 -90

Which of the substances exists as a liquid at room temperature?

A Q
B R
C S
D P

33 The equation shows the reaction of the extraction of iron from iron(III) oxide.

2Fe2O3  4Fe + 3O2

What is the mass of iron which can be extracted from 10.0 g of iron(III) oxide?
[Relative atomic mass: Fe,56; O,16]

A 3.5 g
B 4.5 g
C 6.0 g
D 7.0 g

34 The table shows the proton number for element M and N. Element N is more
electronegative than element M because

Element Proton number

M 8
N 9

A atomic size of N is smaller

B atom N releases electrons easier
C atom N has less valence electron
D atom N has larger number of neutron

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35 The diagram shows the information of elements X and Y

7 16
X Y
3 8

Which of the following is the diagram of electron arrangement for the compound
formed when element X reacts with element Y?

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36 The diagram shows the voltaic cell.

Copper Magnesium

Copper(II) chloride Magnesium nitrate

solution solution

Which of the following half-equations represent the reaction at the negative

terminal and positive terminal?

Negative Terminal Positive terminal

A Mg  Mg2+ + 2e Cu2+ + 2e  Cu
B Mg2+ + 2e  Mg Cu  Cu2+ + 2e
C Cu2+ + 2e  Cu Mg  Mg2+ + 2e
D Cu  Cu2+ + 2e Mg2+ + 2e  Mg

37 Which of the following solutions has the highest concentration of hydrogen ion?

A 50 cm3 of 1.0 mol dm-3 H2SO4 solution

B 50 cm3 of 2.0 mol dm-3 H2SO4 solution
C 100 cm3 of 1.0 mol dm-3 H2SO4 solution
D 150 cm3 of 1.0 mol dm-3 H2SO4 solution

38 The reaction between lead(II) nitrate and potassium iodide solution is represented
by the equation below

Pb(NO3)2 (aq) + 2KI (aq)  PbI2 (s) + 2KNO3 (aq)

10.0 cm3 of 1.0 mol dm-3 potassium iodide solution is mixed with 20.0 cm3 of 1.0
mol dm-3 lead(II) nitrate solution.
What is the maximum mass of lead(II) iodide produced in this reaction?
[Relative atomic mass: I ,127 and Pb, 207]
A 3.34 g
B 4.61 g
C 6.68 g
D 9.22 g

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39 The diagram shows a structural formula of a polymer.

H H

C C

H Cl n

Which of the following is the monomer of the polymer?

A
Cl

Cl
B

Cl
C

Cl Cl
D

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40 The graph shows the volume of carbon dioxide gas released against time for the
reaction between 25 cm3 of hydrochloric acid with excess marble.

CaCO3 + 2HCl  CaCl2 + CO2 + H2O

Volume of CO2/ cm3

180

Time/s

What is the concentration of acid used?

[Molar volume: 24 dm3 mol-1 at room temperature]

A 0.3 mol dm-3

B 0.4 mol dm-3
C 0.5 mol dm-3
D 0.6 mol dm-3

41
 3.0 g of carbon reacts with 0.5 g of
hydrogen gas to form compound X.
 Relative molecular mass of
compound X is 42.

What is the molecular formula of compound X?

[Relative atomic mass: C,12; H,1]

A CH2
B C2H4
C C2H6
D C3H6

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42 Magnesium ribbon reacts with element Q from group 17 in Periodic Table.

Which of the following chemical equations is correct?

A Mg + Q → MgQ
B Mg + Q2 → MgQ2
C 2Mg + Q2 → 2MgQ
D Mg + 2Q → MgQ2

43 Which of the following pairs show the correct uses of the isotopes?

Isotope Uses
I Cobalt-60 To destroy bacteria in food
II Carbon-14 To estimate the age of artifacts
III Iodine-131 To detect the location of tumour
IV Sodium-24 To detect leaks in underground petroleum
piping

A I and II only
B II and IV only
C I,II and III only
D I, II, III and IV

44 Sulphur dioxide gas, SO2 causes environmental pollution.

Which of the following environmental pollutions is affected by sulphur dioxide,
SO2?

I pH of the soil increases

II Lakes and rivers become acidic
III Salts are leached out of the top soil
IV Buildings and metal structures will corrode

A I and II only
B I and III only
C II, III and IV only
D I, II, III and IV

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45 Which of the following diagrams is used to electroplate an iron spoon with silver?

Iron spoon Silver strip

Silver chloride

Iron spoon Silver strip

Silver nitrate

Iron spoon Silver strip

Silver chloride

Iron spoon Silver strip

Silver nitrate

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46 What is the volume of 0.2 mol dm-3sulphuric acid solution required to completely
neutralize 50 cm3 of 0.2 mol dm-3 potassium hydroxide solution?

A 25 cm3
B 30 cm3
C 45 cm3
D 50 cm3

47 The diagram shows the structural formula of compound X.

Compound X

Which of the following is an isomer of X?

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48 Which pair of the organic compounds below can be distinguished by using

acidified potassium manganate(VII)?

A C2H6 and C3H8

B C2H5OH and C3H6

C CH3CH2COOH and CH3CHCHOH

D CH3CH2CH2CH3 and CH2CHCH2CH2CH3

49 Which of the following reactions represent the precipitation reactions?

I Pb(NO3)2 + Na2SO4 → PbSO4 + 2NaNO3

II Ba(NO3)2 + 2KCl → BaCl2 + 2KNO3
III Pb(NO3)2 + 2KCl → PbCl2 + 2KNO3
IV Ca(NO3)2 + Na2SO4 → CaSO4 + 2NaNO3

A I and III only

B I, II and III only
C I, III and IV only
D 1, II, III and IV

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50 The diagram shows the graph of volume of oxygen gas against time. Curve I is
obtained from the decomposition of 20 cm3 of 0.2 mol dm-3 hydrogen peroxide
solution.

Volume of oxygen /cm3

2V II

V I

Time/s

Which of the following solutions will produce curve II?

A 40 cm3 0.1 mol dm-3 hydrogen peroxide solution

B 20 cm3 0.4 mol dm-3 hydrogen peroxide solution
C 30 cm3 0.2 mol dm-3 hydrogen peroxide solution
D 40 cm3 0.4 mol dm-3 hydrogen peroxide solution

END OF QUESTION PAPER

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4541
Chemistry
Marking Scheme
Mei
2008

BAHAGIAN SEKOLAH
KEMENTERIAN PELAJARAN MALAYSIA
______________________________________________
PEPERIKSAAN PERTENGAHAN TAHUN 2008

FORM 5 CHEMISTRY

MARKING SCHEME FOR PAPER 1, 2 AND PAPER 3

Peraturan pemarkahan ini mengandungi halaman bercetak.

1
PAPER 1

1 B 21 D 41 D
2 C 22 D 42 B
3 B 23 B 43 D
4 C 24 A 44 C
5 D 25 C 45 B
6 A 26 A 46 A
7 B 27 D 47 B
8 A 28 A 48 D
9 D 29 C 49 C
10 D 30 A 50 B
11 D 31 A
12 C 32 B
13 A 33 D
14 A 34 A
15 C 35 C
16 B 36 A
17 C 37 D
18 C 38 B
19 C 39 B
20 C 40 D

2
 PAPER 2-SECTION A

No. Rubric Mark

1 a G 1
Has stable /octet electron arrangement//8 valence electron 1

b (i) 2A + 2H2O  2AOH + H2 1

(ii) Use a small pieces//use a forcep// use a google 1

c G,E,D, A,J,L 1

d Has same valence electron// valence electron is 1 1

e (i) DE2 r: E2D 1

(ii) [can draw the diagram of electron arrangement correctly]
- Correct structure of atoms
- Correct ratio of atoms=1:2 2
(iii) Has (neutral ) molecule 1
TOTAL 10
2 a T1 1
b(i) PQ: solid + liquid 1
(ii) RS: liquid 1
c Heat energy absorbed 1
is used to overcome the forces of attraction between particles 1
// Heat is absorbed to overcome the intermolecular forces
r: ion/atom
(1+1)
d The particles / molecules move faster 1
e (i) Iodine/I2//napthalene/C10H8 1
(ii) Copper/ Cu 1
(iii) Ion 1
Diffusion 1
TOTAL 10

3
3 a (i) 3H2 + N2  2NH3 1
(ii) ( Extract from ) air 1
b (i) Neutralization 1
(ii) H2SO4+ 2NH3  (NH4)2SO4 1
//H2SO4+ 2NH4OH  (NH4)2SO4 + H2O
(iii) Fertilizer 1
c (i) Tin 1
(ii)

Copper atom
Copper atom Tin atom

(1+1)
d  In pure copper the layer of atom are easily slide over each
other when external force is applied on them. 1
 The different size of foreign atoms in allloy are prevent the
layers of atom from slide each other when external force is 1
applied.
TOTAL 10
4 a 1 Diagram of set up of apparatus complete and functional 1
2 Label
(Anode) – impure copper and (cathode )– pure copper 1
3 ( Electrolyte) – copper (II) sulphate / copper (II) chloride // copper
(II) nitrate solution 1
a: chemical formula

b(i) 1 become thinner // decrease in mass 1

2 become thicker // increase in mass 1

(ii) 1 ( Remain )unchanged 1

2 Number of Cu2+ ions produced at anode same as number of
copper atoms produced at cathode // the rate of formation of Cu2+

4
 ions at the anode is the same as the rate of discharge of Cu2+ at
cathode. 1

(Anode ):Cu  Cu2+ + 2e 1

c (i)
2+
(ii) (Cathode ): Cu + 2e  Cu 1

d Electroplating of metals/ Extraction of reactive metals 1

TOTAL 10
5 a 2H2O2  O2 + 2H2O 1

b Number of mole of H2O2 = 20 x 2/1000= 0.04 1

2 mol of H2O2 produce 1 mol of O2 //
Number of mole of O2 = 0.04/2 = 0.02 1
Volume, O2 = 0.2 x 24dm3 = 4.8 dm3
1

c (i) 1
Rate of reaction in experiment II is higher than experiment I
(ii)  The concentration/number of molecule per unit volumeof 1
hydrogen peroxide in II is higher
1
 The frequency of collision between H2O2 molecule is higher
1
 The frequency of effective collision is higher

d Volume of gas/cm3

II

Time(s)
1
Label Y axes and X axes 1
Correct curve and label I and II

TOTAL 10

5
6 a A compound that contain element of carbon and derive from living 1
organisms.

b (i) C2H4 1
(ii) ethene 1
(iii) double bond between carbon atoms 1
(a: C=C )
c (i) Acidified potassium manganat (VII) // Acidified potassium 1
dicromate (VI)
(ii) Oxidation 1
(iii) Purple to colourless // orange to green 1

d (i) C2H4 + H2O  C2H5OH 1

(ii) Alcohol 1
(iii) Temperature 300 oC // Pressure 60 atmosphere // concentrated
phosphoric acid 1
TOTAL 10

6
 SECTION B

No. Rubric Mark

7 a (i) Compound that form when non metal atom gain/receive/accept

electron that release/lose/donate by metal atom to achieve stable
/octet/duplet electron arrangemen 1

(ii)
Compound that form between non metal atom by sharing their
valence electron to achieve stable/octet /duplet electron
1
arrangement

b Between P and Q
 Atom X has 1 valence electron
1
 +
Atom X loses/donates/transfers 1 electrons to form X ion //
X X+ + e- and attain stable octet electron arrangement 1
 Atom Y has 7 valence electrons
1
 Atom gains/receives/accept 1 electron to formY- ion// 1
Y + e-Y-
 attain the stable /octet electron arrangement 1
 The two oppositely-charged ions// the X+ and Y- ion are
bonded together by a strong electrostatic force 1
 To form a ionic compound with the formula XY// diagramn 1

Max 7

7
(ii)
Between Y and Z
 Atom Z has 4 valence electrons and atom Y has 1 valence 1
electrons
 One atom Z contributes 4 electrons and (each) atom Y
1
contributes one electron for sharing .
 Atom Z shared 4 pairs of electron with 4 atoms Y 1
1
 to attain a octet /stable electron arrangement respectively 1
 diagram

Z Y
Y

(iii)
 Magnesium oxide is an ionic compounds 1

 Strong electrostatic force of attraction exists between

Mg2+ and O2 -// 1

the oppositely-charged magnesium ions and oxide ions in

Magnesium oxide are held together by strong ionic bonds
 A lot of heat energy // high of energy is required to break the
strong forces 1

 Tetrachloromethane is a covalent compound 1

 Weak intermolecular forces //held together by weak (Van der
1
Waals) force of attractions between molecule
 little heat energy //low energy is needed to overcome the
1
weak forces

8
 TOTAL 20
8 a Empirical formula- Formula shows simplest ratio of atoms of each
1
element in the compound
Molecular formula- Formula shows actual number of atoms of
1
each element in the compound

b
Molecular Formula = ( Empirical formula )n
= ( CH2 )n

Relative Molecular Mass ( CH2 )n = 70

1
12n + 2n= 70
14n=70
n=5
1
1
Molecular Formula C5H10
c(i)
1. Metal Z is cleaned using sand paper
1
2. A crucible and its lid are weighed and the mass is recoded 1
3. Metal Z is palced in the crucible. The crucible,lid and its
content is weighed and the mass is recorded. 1
4. The crucible with its content is heated strongly without
lid. 1
5. When metal Z start burn, the crucible is covered by its
lid 1
6. the covered is raise a little at intervals
1
7. When there is no more reaction, the lid is removed and the
1
crucible is heated strongly for a few minutes.
8. Cool the crucible and weigh the crucible,its lid and its 1
Content and record the mass.
9. The process of heating, cooling and weighing is repeated 1
until constant is obtained.
10. (Precaution step );
Close the crucible immediately to prevent loss of
1

9
Element Z O 1

Mass(g) 1.30 0.32

1
mol 1.30/65=0.02 0.32/16=0.02
1
Simplest 1 1
ratio 1

Empirical Formula ZO 1

TOTAL 20

10
 PAPER2 –SECTION C

No Rubric Mark

9 a Sample answer :
Zn + HNO3  Zn(NO3)2 + H2O
ZnCO3 + HNO3  Zn(NO3)2 + H2O + CO2
ZnO + HNO3  Zn(NO3)2 + H2O
Any two 2

b (i)  Methanoic acid partial ionizes in water 1

 produce low concentration of hydrogen ion 1
(ii)  Glacial ethanoic acid has (neutral) molecule 1
 Methanoic acid aqueous ionizes in water 1

 to produce free moving ion 1

c(i) Procedure :

1 100 cm3 of 0.1 moldm-3 sulphuric acid is poured into a beaker 1

and heated slowly.

2 zinc carbonate is added into the sulphuric acid until in excess/no 1

longer dissolves.

3 Stir the solution and filtered. 1

4 The filtrate is poured into an evaporating dish and heat until 1

saturated

5 The hot saturated salt solution is allowed to cool

1
6 The crystals formed are filtered out, rinsed with distilled water

7 dried between sheets of filter paper. 1

11
 (ii) ZnCO3 + H2SO4  ZnSO4 + H2O + CO2 1

Number of mole , H2SO4 = 0.1( 100 )/1000

1
= 0.01
1 mol of H2SO4 produce 1 mol of ZnSO4
1
Mole of ZnSO4 = 0.01
Mass of ZnSO4 = 0.01 X 161
1
= 16.1 g
d Sample answer :
1 ammonium chloride as a fertilizer
1
2 copper (II) sulphate as a pesticide
3 hydrated calcium sulphate to make plaster casts
1
4 sodium chloride food additive
Any 2 suitable anwers(1+1)

TOTAL
20
10a (i) catalyst 1
esterification
(ii) 1
(iii) CH3COOH + C3H7OH  CH3COOC3H7 + H2O
Correct reactant 1
Correct product
1
(iv)

Ethyl propanoate
Sweet smell/fruity smell/fragrant smell
//insoluble in water/soluble in organic solvent
//colourless
//less dense than water
2
any two properties (1+1)
(v)

12
  Bacteria will produce lactic acid/H+ ions which neutralize
b (i)
negatives charge of the protein membrane/ rubber molecules
1
 The rubber molecules will be collide with each other and
1
cause protein membrane broken
 Rubber polymer are released and lump together
1

 Hydroxide ions/OH- from ammonia solution will neutralise

1
H+ produced by acid
 The protein membrane remains negatively charged
1
 The rubber particles repel each others/ the rubber polymers
cannot combine and coagulate 1

 The presence of cross-linkage of sulphur atoms between

(ii)
the rubber molecule 1
 When vulcanized rubber is stretched and release, the cross-
linkage will pull the chain back to their original
arrangement
1
 Diagram
1
 Improves the elasticity and strength of the rubber / make
vulcanized rubbers more resistant to heat /organic solvent
1


or
Resistant to oxidation :
 The presence of cross-linkage of sulphur atoms between
the rubber molecule
1
 Diagram
1
 C=C in vulcanized rubber is less than C=C in the
unvulcanized rubber, 1
 so vulcanize rubber is more resistant to oxidation
1
TOTAL
20

13
 PAPER 3

1 (a) KK0503 – Measuring and using numbers

EXPLANATION SCORE
[Able to write all the times with units accurately] 3
Suggested answer:

t1 55.0 s, t2 48.0 s , t3 42.0 s , t4 37.0 s , t5 33.0 s

[Able to record all the times accurately but without units / no decimal place] 2
t1 55.0 , t2 48.0 , t3 42.0 , t4 37.0 , t5 33.0 //
// t1 55 s , t2 48.0 s , t3 42 s, t4 37s, t5 33s

[Able to write at least 3 readings of the times accurately] 1

No response given / wrong response 0

1 (b) KK0501- Observation

EXPLANATION SCORE
[Able to state the colour of sulphur and the rate of it is formed] 3
Suggested answer:

Pale / light yellow precipitate is slowly formed

[Able to state the colour of sulphur] 2
Pale / light yellow precipitate is formed.
[Able to state the formation of precipitate] 1
A precipitate is formed.
No response given / wrong response 0

1 (c) KK0506 – Communicating

EXPLANATION SCORE
[Able to construct a table correctly containing three labeled columns with
correct units and record all the time and 1/time accurately ]

Suggested answer:

Temperature, 30 35 40 45 50 3
o
C
Time , s 55.0 48.0 42.0 37.0 33.0
1 / time , s-1 0.018 0.021 0.024 0.027 0.030
[Able to construct a table correctly containing three labeled columns with 2
correct units and record all the time and 1/time but not accurately]

[Able to write at least 3 readings of the times accurately] 1

No response given / wrong response 0

1 (d) (i) KK0506 Communicating

14
 EXPLANATION SCORE
[Able to draw a graph accurately that consists of the following aspects] 3
Suggested answer:

1. Both axes labeled and units

( Y axis - temperature , X axis – 1/ time )
2. All points transferred correctly
3. Uniform scale, graph size covers at least half of the graph paper.
4. Straight line/ best fits drawn

[Able to draw a graph that consists of the following aspects] 2

1. Both axes labeled / units
( Y axis - temperature , X axis – 1/ time )
2. At least three points transferred correctly
3. Uniform scale, graph size covers at least half of the graph paper.
4. Straight line/ best fits drawn

[Able to draw a graph that consists of the following aspects] 1

1. Both axes labeled and units
( Y axis - temperature , X axis – 1/ time )
2. Draw a line

No response given / wrong response 0

1(d)(ii) KK0509 – To define Operationally

EXPLANATION SCORE
[Able to interpret the relationship between the rate of reaction and the 3
temperature of sodium thiosulphate solution from graph accurately]
Suggested answer:

The rate of reaction is directly proportional to the temperature of sodium

thiosulphate solution // As the temperature of sodium thiosulphate increases
the rate of reaction increases.
[Able to interpret the relationship between the rate of reaction and the 2
temperature of sodium thiosulphate solution from graph ]

The rate of reaction is proportional to the temperature // the temperature is

proportional to the rate of reaction // the rate of reaction increases when the
temperature increases.
[Able to state an idea of hypothesis 1
The temperature affects the rate of reaction.

No response given / wrong response 0

15
Temperature /oC

50 X

45 X

40 X

35 X

30
X
0.015 0.020 0.025 0.030 1/time , s-1

16
1(e) KK0510 - State variables

EXPLANATION SCORE
[Able to state three variables and three action to be taken]
Suggested answer:

Variable Action to be taken

Manipulated: Heat the sodium thiosulphate 3
Temperature solution at different temperature //
Use different temperature.
Responding: Record the time taken for “X” mark
Rate of reaction / time taken for “X” to disappear from view.
marks to disappear from view.
Controlled : Use the same concentration and
Concentration and volume of H2SO4, volume of H2SO4 /sodium
concentration and volume of sodium thiosulphate solution // Use same
thiosulphate solution, size of conical size conical flask.
flask.
[Able to state any two variables and any two action to be taken] 2

[Able to state any one variables and any one action to be taken] 1

No response given / wrong response 0

2 (a) KK0506 Communicating

EXPLAINATION SCORE
[Able to write the correct overall ionic equation] 3
Suggested answer:

Mg + Cu2+  Mg2+ + Cu
Mg + CuSO4  MgSO4 + Cu 2
Mg  Mg2+ + 2e // Cu2+ + 2e  Cu 1
No response given / wrong response 0

2(a)(i) KK 0504 – Making inference

EXPLANATION SCORE
[Able to state the correct inference] 3
Suggested answer:

Magnesium atom releases/donate/loses electrons to produce magnesium ion //

Magnesium is corrode.
Magnesium becomes thinner // mass of magnesium decreases 2
Magnesium dissolves 1
No response given / wrong response 0

17
2(b) KK 0505 - Predicting
EXPLANATION SCORE
[Able to state the voltage value] 3
0.65 V
0.63 – 0.64 V // 0.66 – 0.67 V 2
< 0.64 V // > 0.67 V 1
No response given / wrong response 0

2(c)KK 0508 – Interpreting Data

EXPLANATION SCORE
[Able to arrange the position of all metals in an ascending order based on 3
tendency to release electrons correctly]
Copper > Lead > Iron > Zinc > Magnesium

[Able to arrange the position of all metals in descending order based on 2

tendency to release electrons]
Magnesium > Zinc > Iron > Lead > copper

[Able to arrange the position of at least four metals in ascending order based 1
on tendency to release electrons correctly]

No response given / wrong response 0

2(d) KK0509 – Operational definition

EXPLANATION SCORE
[Able to state the correct and complete operational definition] 3
Suggested answer:

The further the metal is from copper in the electrochemical series, the greater
is their voltage reading. //

[Able to give incomplete relationship] 2

Suggested answer:

The further apart the metal is in the electrochemical series, the greater the
potential difference / voltage reading.

[Able to state an idea] 1

Suggested answer:

The position of metal influence the voltage reading //

Type of metal influence the voltage reading.

No response given / wrong response 0

18
3.(a) KK051021 – Statement of problem
EXPLANATION SCORE
[Able to make a suitable statement of problem] 3
Suggested answer:

How to differentiate between magnesium nitrate solution and calcium nitrate

solution // How to differentiate between magnesium ion and calcium ion
[Able to make a suitable aim] 2
Suggested answer:

To differentiate the presence of magnesium ion and calcium ion by using

aqueous ammonia solution.
[Able to state an idea of statement of problem or aim] 1

No response given / wrong response 0

3(b) KK051202 – Stating hypothesis

EXPLANATION SCORE
[Able to state the relationship between manipulated variable and responding 3
variable correctly]
Suggested answer:

If the addition of aqueous ammonia solution forms white precipitate which is

insoluble in excess ammonia aqueous solution, then the solution tested is
magnesium nitrate. // If aqueous ammonia solution is added and no change
occur then the solution tested is calcium nitrate.
[Able to state the relationship between manipulated variable and responding 2
variable]
[Able to state an idea of the hypothesis] 1

No response given / wrong response 0

3 (c) KK051202 – Stating variables

EXPLANATION SCORE
[Able to state all the three variables correctly]
Suggested answer:

Manipulated variable : magnesium nitrate and calcium nitrate // Mg2+ and Ca2+
Responding variable: formation of white precipitate
Controlled variable : aqueous ammonia solution
[Able to state any two of the variables correctly]

[Able to state one of the variables correctly or state idea regarding variable]

No response given / wrong response

19
3(d) KK051205 – List of substances and apparatus
EXPLANATION SCORE
[Able to state the list of substances and apparatus correctly and completely] 3
Suggested answer:

Test tube, dropper, test tube rack

0.5 mol dm-3 magnesium nitrate solution, 0.5 mol dm-3 calcium nitrate
solution, aqueous ammonia solution.
[Able to state the list of substances and apparatus correctly but not 2
completely]
Suggested answer:

Test tube
0.5 mol dm-3 magnesium nitrate solution, 0.5 mol dm-3 calcium nitrate
solution, aqueous ammonia solution.
[Able to state an idea about the list of substances and apparatus] 1
Suggested answer:

Test tube
magnesium nitrate, calcium nitrate
No response given / wrong response 0

3(e) KK051204 – Technique /Precedure

EXPLANATION SCORE
[Able to state a complete experimental procedure] 3
Suggested answer:
1. 2 cm3 of solution A is poured into a test tube.
2. A few drops of aqueous ammonia solution are added into the test tube
using a dropper and the test tube is shaken well.
3. If the precipitate is formed, aqueous ammonia solution is added
continuously until no further change occurred / until excess
4. The mixture is shaken well.
5. The changes occur is recorded in a table.
6. Steps 1 to 4 are repeated using solution B.

[Able to state a complete experimental procedure] 2

1,2,3,4,5

[Able to state a complete experimental procedure] 1

1,2,3,5
No response given / wrong response 0

20
3(f) Tabulation of data
EXPLANATION SCORE
[Able to exhibit the tabulation of data correctly ]

Reagent Observation
Test tube/Solution A Test tube/Solution B
Aqueous
ammonia solution 3

[Able to exhibit the tabulation of data less accurately ] 2

Reagent Test tube /Solution A Test tube/Solution B

Aqueous
ammonia solution

[Able state an idea about the tabulation of data] 1

No response given / wrong response 0

END OF MARKING SCHEME

21