PRE-ASSESSMENT TEST SEM 1 2013 / 14

Section A

[15 marks]

Four suggested answers labelled A, B, C and D are given for each question in this section. Choose one correct answer, and write it in the space provided at Page 6
1. Which one of the following pieces of information about an element cannot be obtained from mass spectra A B C D the relative atomic mass the relative masses of the isotopes the relative abundance of the isotopes the number of isotopes

2.

Which of the following contains 1 mol of the stated particles. A B C D Chlorine molecules in 35.5 g of chlorine gas Hydrogen atoms in 1 g of hydrogen gas Hydrogen ions in 1 dm3 of 1 mol dm3 aqueous sulphuric acid Oxygen atoms in 22.4 dm3 of oxygen gas at s.t.p.

3.

Which of the following electronic configurations represents an element that forms a simple ion with a charge of -3? A B C D 1s2 2s2 2p6 3s2 3p1 1s2 2s2 2p6 3s2 3p3 1s2 2s2 2p6 3s2 3p6 3d1 4s2 1s2 2s2 2p6 3s2 3p6 3d3 4s2

4.

Which diagram best shows the shapes and relative energies of 2s and 2p orbitals in carbon?

5.

MTBE is a constituent of petrol. What is the value of angle P and angle Q in a molecule of MTBE

CH3 Angle P CH3 C CH3

Angle Q O CH3

Angle A B C D

P 90 104.5 109 107

Q 180 180 104.5 109

PRE-ASSESSMENT TEST SEM 1 2013 / 14 6. Ethanol is much more soluble in water than is ethyl ethanoate. Which statement helps to account for this? A A hydrogen bond forms between the hydrogen of the-OH group in ethanol and the hydrogen of a watermolecule. B A hydrogen bond forms between the hydrogen of theOH group in ethanol and the oxygen of a watermolecule. C D Ethanol is a polar molecule, but ethyl ethanoate isnon-polar. Ethanol is able to dissociate into hydrogen ions and ethoxide ions but ethyl ethanoate is not able to dissociate

7.

The Lewis structures of molecules HF, H2O and NH3 are shown respectively below.

Which statement about the molecules is true? A B C D HF and H2O molecules are planar. H2O molecule is a stronger Lewis base than NH3 molecule. The boiling points of the molecules increase in the order of H2O, HF, NH3. The hydrgen bonds formed by the molecules decrease in the order of HF, H2O, NH3.

8.

A small spacecraft of capacity 10m3 is connected to another of capacity 30 m3. Before connection, the pressure inside the smaller craft is 50 kPa and that inside the larger is 100 kPa. If all measurements are made at the same temperature, what is the pressure in the combined arrangement after connection? A. 75 kPa B. 87.5 kPa C. 100 kPa D. 125kPa

9.

The phase diagram for iodine is shown below

Which of the following statements is true? A B C D The line OC represents the effect of pressure on the melting point of iodine. Point C is the critical temperature. At point B, solid iodine and liquid iodine exist in equilibrium. Iodine sublime when heated from room temperature to 120 C at constant pressure of 14 kPa. 3

PRE-ASSESSMENT ASSESSMENT TEST SEM 1 2013 / 14 10. The following reaction is first order with respect to [P] and zero order with respect to [Q]. P+Q products.

If the rate constant doubles for each 10 C rise in temperature, which of the following sets of conditions will give the greatest rate of reaction? A [P]/mol dm
-3 3

B 0.10 0.30 40.0

C 0.20 0.20 30.0

D 0.30 0.10 30.0

0.10 0.20 40.0

[Q] / mol dm

Temperature/C 11.

The reaction of acidified, aqueous potassium iodide with aqueous hydrogen peroxide 2 I- (aq) + H2O2 (aq) + 2 H+ (aq) is thought to involve the following steps: H2O2 + I- H2O + OI-(slow) OI- + H+ HOI (fast) + HOI + H + I I2 + H2O (fast) Which one of the following conclusions cannot be drawn from this information? A B C D The iodide ion is oxidised by the hydrogen peroxide. The acid acts as a catalyst. The reaction is first order with respect to the iodide ion. The rate determining step is H2O2 + IH2O + OI-. I2 (aq) + 2 H2O (l)

12.

The percentage of ammonia obtainable, if equilibrium were established during the Haber process, is plotted against the operating pressure for two temperatures, 400 C and 500 C. Which of the following correctly represents the two graphs?

13 (i)

Each of the following equilibria is subjected to two changes carried out separately: the pressure is s reduced at constant temperature; (ii) the temperature is increased at constant pressure.

For which equilibrium will both of these changes result in an increase in the proportion of products? A B C D H2 (g) + I2 (g) 4 NH3 (g) + 5 O2 (g) N2(g) + 3H2(g) N2O4 (g) 2 HI (g) 4 NO(g) + 6 H2O(g) 2 NH3 (g) 2 NO2 (g) 4 H = +53 kJ mol-1 H = - 95 kJ mol-1 H = -92 92 kJ mol-1 H H = + 57 kJ mol-1

PRE-ASSESSMENT ASSESSMENT TEST SEM 1 2013 / 14 14. In aqueous solution, chlorate(I) ions, ClO, ClO , are hydrolysed according to the equation ClO (aq) + H2O (g) HClO (aq) + OH(aq).

What is the pH value of a 2.00 x 102 mol dm3 solution of sodium chlorate(I), NaClO, at 25 C? [At 25C, base dissociation constant, Kb, of ClO is 3.30 x 107 mol dm3 [Ionic product of water, Kw, is 1.00 x 1014 mol2 dm6.] A 15. 4.09 B 7.52 C 9.22 D 9.91 The following equilibrium quilibrium exists in a mixture of concentrated nitric acid and sulphuric acid.

Which statement about this equilibrium is correct? A B C D Addition of H2O will reduce the NO2+ concentration. HNO3 and NO2+ are a conjugate acid-base acid pair. The nitric acid acts as an oxidising agent. The sulphuric acid acts as a dehydrating agent.

PRE-ASSESSMENT TEST SEM 1 2013 / 14 Name : ____________________________________ Tingkatan : LOWER 6 ____________

Section A 1 2 3 4 5 6 7 8 9 10 Section B [15 marks] 11 12 13 14 15

Answer all questions in this section on the spaces provided 16. (a) Using Rydberg's Equation, the wavelength and the frequency of hydrogen emission spectrum can be calculated quantitatively. Given the Rydberg Equation is

1 1 = RH 2 2 n1 n2 1

where RH = 1.097 107 m 1

[2 marks]

i. Based on the equation above, calculate the wavelength of last line in Balmer series.

ii.

Based on you answer given in (a) i, compare the wavelength given off by the last line in Lyman Series and explain your answer [2 marks]

............................................................................................................................................................................... ............................................................................................................................................................................... (b) Diagram below shows the emission spectra of hydrogen atom in Lyman series.

P i. Draw a labelled diagram showing how spectrum P was formed [3 marks]

PRE-ASSESSMENT TEST SEM 1 2013 / 14 17. Grape juice has a pH of 3.75. ....................................................................................................................... [1 mark] [1 mark]

(a) i. Define pH.

ii. Calculate the molar concentration of hydrogen ions in grape juice.

(b)

Grape juice can be titrated with standard alkali. A 25.0 cm3 sample of grape juice was exactly neutralised by 27.5 cm3 of 0.100 mol dm-3 sodium hydroxide using phenolphthalein as indicator. Assuming that the acid inside grape juice is monobasic acid, calculate the concentration of acid in the juice.

[2 marks] (c) (i) How can you explain the difference between the two results you have obtained in (a) (ii) and (b)

.................................................................................................................................................................. .................................................................................................................................................................. [2 marks] (iii) Calculate the dissociation constant of acid. [2 marks]

Section C

[30 marks]

Answer any two questions in this section. 18. (a) The major acidic component of soured milk is lactic acid: CH3CH(OH)COOH. When 10.0 cm3 of a solution of lactic acid was titrated against 0.050 mol dm-3 sodium hydroxide the following pH readings were obtained: Volume of NaOH added /cm3 pH (i) 0 2.5 2 3.1 4 3.4 6 3.7 8 3.9 10 4.1 12 4.4 14 4.7 15.9 5.0 16 9.1 16.1 11.4 18 11.6 20 11.8

Plot a graph of these results with pH on the y-axis and volume added on the x-axis.Suggest an indicator, giving a reason for your choice. [5 marks] [2 marks] [1 marks]

(ii) (iii)

Calculate the concentration of the lactic acid in the solution. Deduce the Ka value from the graph for lactic acid 7

PRE-ASSESSMENT TEST SEM 1 2013 / 14 (b) The mass spectrum of rhombic sulphur is shown below

(i) (ii) (iii) (iv)

Explain why the mass spectrum of rhombic sulphur consists of a number of peaks Identify the species which is most abundant in the sample of sulphur vapour. From the mass spectrum, deduce the molecular mass and formula of rhombic sulphur. State the other allotrope of rhombic sulphur

[2 marks] [2 marks] [2 marks] [1 mark]

19. (a) Bromide ions are slowly oxidised by bromate (V) ions under acidic condition according to the following equation below BrO3- (aq) + 6 H+ (aq) + 5 Br- (aq) 3 Br2 (aq) + 3 H2O (l) Table below shos the results of four experiments under constant temperature Experiment 1 2 3 4 i. ii. (b) [BrO3-] / mol dm-3 0.400 0.600 0.600 0.400 [Br -] / mol dm-3 0.280 0.280 0.560 0.280 [H+] / mol dm-3 0.031 0.031 0.031 0.062 Initial rate / mol dm-3 s-1 1.29 x 10-3 1.94 x 10-3 3.87 x 10-3 5.16 x 10-3 [7 marks] [2 marks]

Calculate the order of reaction with respect to BrO3- , Br- and H+ Write the rate equation and calculate the rate constant of the reaction

Ozone, O3, may be used as a bactericide in the treatment of waste water. The concentration of ozone in water may be determined using the following equation: O3(g) + 3 I(aq)+ 2H+(aq) O2(g) + I3-(aq) + H2O (l) In an experiment, 500.0 cm3 of a waste water sample was treated with an excess of iodide ions. The volume of oxygen gas collected from the reaction at 25.0 C and 101.3 kPa was 10.0 cm3. Calculate the concentration of ozone in the waste water sample under the above conditions of temperature and pressure. 8 [6 marks]

PRE-ASSESSMENT TEST SEM 1 2013 / 14 20.(a) The key reaction during the Contact process for manufacturing sulphuric acid is as follows. 2 SO2 (g) + O2 (g) 2 SO3 (g) ; H = - 197 kJ mol-1

When a 2:1 ratio of sulphur dioxide and oxygen at a total initial pressure of 3 atm is passed over a catalyst at 430 C, the partial pressure of sulphur trioxide at equilibrium is found to be 1.9 atm. i. Calculate the partial pressures of SO2 and O2 at equilibrium ii. Calculate the equilibrium constant of partial pressure, Kp of the reaction above. (b) By drawing Lewis structure, compare the shape and polar properties of sulphur dioxide, SO2 and sulphur trioxide, SO3. [8] [4] [3]

============END OF QUESTION PAPER ===========

Prepared by

Approved by

___________________________ [Chew Chin Kuen]

____________________________

PRE-ASSESSMENT TEST SEM 1 2013 / 14 Section A 1 2 3 4 5

16 a) 1
1 1 = 1.097 10 7 2 2 2

A B B A C
[1]

6 7 8 9 10

B D B A D

11 12 13 14 15
20 a) i. 2 SO2 + O2 2 SO3 Initial : 2 atm 1 atm At eq : - 1.9 - (1.9 x ) + 1.9 Px 0.10 atm [1] 0.050 atm [1] ii. [1] (1.9) 2 ( PSO ) 2
3

B A D D B

= 365 nm [1] ii. last line of Balmer series has a shorter wavelength compare to Lyman series [1] -since the energy level difference between n=2 to n = is shorter [1] X Axis labelled [1] Show at least 4 energy level n = 1 to n = 4 [1] Draw the arrow down from n = 4 to n = 1 [1] b) 17. a) i. pH = -lg or (insist [ ]) @ explain by words ii. 1.78 x 10-4 mol dm-3 (3 s.f. with unit) b) Ma(25.0) / (0.100)(27.5) = 1/1 Ma = 0.110 mol dm3 (3 s.f. with unit) c) - Grape juice is weak acid / dissociate partially in water - however, it react completely with NaOH d) Ka = [H3O+]2 / c or subst Ka = 2.88 x 10-7mol dm-3 (3 s.f. with unit) [H+] [H3O+]

19 a) i. rate = k [BrO3-]x [Br-]y [H+]z [1] (show all 4 substituted rate equation = [3] show 3 substituted rate equation = [2] show 2 substituted rate equation = [1] Exp 1 :1.29 x 10-3 = k (0.400)x (0.280)y(0.031)z Exp 2 :1.94 x 10-3 = k (0.600)x (0.280)y(0.031)z Exp 3 :3.87 x 10-3 = k (0.600)x (0.560)y(0.031)z Exp 4: 5.16 x 10-3 = k (0.400)x (0.280)y(0.062)z Divide Exp 2 / Exp 1 ; x = 1 [1] Divide Exp 3 / Exp 2 ; y = 1 [1] Divide Exp 4 / Exp 1 ; z = 2 [1] ii. rate = k [BrO3-] [Br-] [H+]2 [1] k = = 12.0 mol-3 dm9 s-1 (3 s.f. with unit) [1] b) m1 : PV = nRT m2 : (101.3 x 103) (10.0 x 10-6) = n (8.31) (273 + 25.0) m3 : n = 4.09 x 10-4 mol m4 : Since 1 mol of O3 1 mol of O2 m5 : [O3] = 4.09 x 10-4 / (500/1000) m6: = 8.18 x 10-4 mol dm-3 [1] [1] [1] [1] [1] [1]

[1] [1] [1]

KP =

( PSO2 ) ( PO2 )

KP =

(0.10) (0.050)

Kp = 7220

atm-1

(2/3 s.f. with unit)

[1]

[1] [1] [1] [1] [1] [1] [1] [1]

20 b) Each correct comparison = 1 SO2 Lewis Shape No of electron Polar properties Bent 2 bond pair and 1 lone pair Polar molecule Trigonal planar 3 bond pair Non-polar molecule SO3

Section C 18 a) i. refer graph [3] [Axis = 1] [Point plotted = 1] [Curves = 1] - Suitable indicator : phenolphthalein / bromothymol blue [1] - The effective pH range intercepted the end point of titration [1] ii. Ma(10.0) / (0.050)(16) = 1/1 [1] Ma = 0.080 mol dm3 (2 s.f. with unit) [1] iii. Ka = (check graph) (1/2 V of end point) [1] b) i. Since sulphur exist as molecules [1] - Each peak represent fragment of sulphur ion with different molecular mass (or m/e) [1] ii. most abundant = m/e 64 [1] molecular ion = S2+ (ins : +) [1] iii. RMM = 256 [1] molecular formula : S8 [1] iv. monoclinic sulphur / -sulphur [1]

10