3E

Product: Quality: Use: Supplier:

Material Safety Data Sheet

(02/02/05)

1 Product and company identification

3E All shades Used for making joints, sealing and gluing. (For further information, refer to the product technical data sheet). Henkel Building Systems Henkel Loctite Adhesives Limited Winsford, Cheshire, CW7 3QY 01606 594600 01606 863762 technical.services@henkel.co.uk 01865 407333

Telephone: Fax: E-mail: Emergency Telephone:

2. Composition / information on ingredients

Preparation Chemical nature: Components presenting hazards: EC Classification: Blend based on: Polydimethylsiloxanes , amorphous silica ,additive & crosslinker Distillates (petroleum), hydrotreated middle; gasoil unspecified (CAS: 64742-46-7) : < 30 % EC N :265-148-2. Xn - R65 Silanetriol, ethyl-, triacetate (CAS: 17689-77-9) : < 5 % EC N :200-580-7. R14 ; C-R34 ; Xn-R22 Silanetriol, methyl-, triacetate (CAS: 4253-34-3) : < 5 % EC N :224-221-9. R14 ; C-R34 ; Xn-R22.

Self-classification:

Self-classification:

3. Hazards Identification
Most important hazards Adverse human health effects: Environmental effects: Physical and chemical hazards Fire or explosion: Further hazards: Specific hazards: Further information: Combustible. On contact with humidity: Irritating vapours are released. According to EC criteria, this product is not classified as a "hazardous preparation". After drying, may stick to the skin. During use, acetic acid is released (CAS: 64-19-7). Slightly irritating to eyes, respiratory system and skin. Presents no particular risk to the environment, provided the disposal requirements (see section 13) and national or local regulations are complied with.

4. First Aid Measures

Inhalation: Skin contact: Not specifically applicable. Remove all contaminated clothing and footwear. Wash with soap and water. Wash immediately and thoroughly for a prolonged period (at least 15 minutes). In case of inflammation (redness, irritation, ...) obtain medical attention. Show this sheet to the doctor. Use appropriate protective equipment when treating a contaminated person. Immediately rinse with plenty of running water for a prolonged period, (at least 15 minutes) whilst keeping the eyes wide open. If irritation persists, consult a doctor. Show this sheet to the doctor. Never attempt to induce vomiting. Do not give anything to drink. If necessary seek medical advice. Show this sheet to the doctor. Place contaminated clothing in a sealed bag for disposal. Use appropriate protective equipment when treating a contaminated person.

Eye contact:

Ingestion: Further information:

5. Fire Fighting Measures

Extinguishing media Suitable: Carbon dioxide (CO2). Foam. Powders. Water spray. None to our knowledge. If there is a fire close by, use suitable extinguishing agents. Combustible. For further information, refer to section 10: "Stability and Reactivity". Cool down the containers/equipment exposed to heat with a water spray. Self-contained breathing apparatus.

Not suitable: Specific hazards: Specific fire fighting methods: Protection of fire-fighters:

6. Accidental Release Measures

Personal precautions: Protective equipment: Mechanically ventilate the spillage area. Environmental precautions: Methods for cleaning up Recovery: Scrape up the product with a spatula or similar instrument. Collect up the product and place it in a spare container: - suitably labelled. Tightly closed. Absorb residues with: Inert absorbent material. Decontaminate and wash the floor with: An appropriate solvent.(cf. : 9). Then wash with plenty of water. For disposal of solid materials refer to section 13 "Disposal considerations". This product does not present any particular risk for the environment. Avoid contact with skin and eyes. Do not breathe vapours. For further information refer to section 8 "Exposure-controls/personal protection".

Neutralization: Cleaning/Decontamination:

Disposal:

7. Handling and Storage

Handling Technical measures: Measures: Safe handling advice: Storage Technical measures: Storage conditions Recommended: Keep: Only in the original container. The container tightly closed and dry. Strong oxidizing agents. Polyethylene liner in a metal drum varnished with epikote. Polyethylene cartridges (outer packaging - cardboard box). Does not require any specific or particular technical measures. Ventilation. Do not exceed the occupational exposure limits (OEL). Comply with instructions for use (refer to technical sheet). Work outside or in a well-ventilated room.

Incompatible products: Packaging: Packaging materials Recommended: Further information:

Polyethylene. Coated metals. The product polymerises on contact with air.

8. Exposure Controls and Personal Protection

Engineering measures: Control parameters Occupational exposure limits Limits (France): Limits (U.S.A./A.C.G.I.H.): Limits (UK): Acetic acid: VLE: 25 mg/m3 (10 ppm). Petroleum distillate: VLE: 200 ppm. Acetic acid: TLV ( TWA ) : 25 mg/m3 (10 ppm). : TLV ( STEL ) : 37 mg/m3 (15 ppm). Acetic acid: OES: 10 ppm (25 mg/m3). (Long term exposure limit - 8h TWA reference period). OES: 15 ppm (37 mg/m3). (Short term exposure limit - 15 minute reference period). Measure the concentration in the atmosphere. Ensure good ventilation of the work station.

Surveillance procedures: Personal protective equipment Respiratory protection: Hand protection: Eye protection: Collective emergency equipment:

In the event of insufficient ventilation: Respiratory protective device with a gas filter. Protective gloves made of rubber. Safety spectacles. Eye fountain.

9. Physical and Chemical Properties

Appearance Physical state: Colour: Odour: pH: Specific temperatures Decomposition temperature: Flammability characteristics Flash point: Oxidizing properties: Specific gravity: Solubility In water: In organic solvents: Practically insoluble. Insoluble in: Acetone. Alcohol (ethanol). Petrol. White-spirit. Aromatic hydrocarbons (toluene, xylene). Chlorinated solvents. > 120 C (Closed cup, according to method Afnor T 60103). Non oxidizing material according to EC criteria. Approx. 970 kg/m3 at 25C. > 200C. Thixotropic paste. Translucent or pigmented. Of vinegar. Not applicable.

Dispersible (partial solubilisation) in:

10. Stability and Reactivity

Stability: Hazardous reactions Conditions to avoid: Hazardous decomposition products: On combustion forms: No dangerous reactions known under normal conditions of use. See technical data sheet. During vulcanisation, acetic acid is released. (Quantity potentially released : < 3 % of product weight). (Carbon oxides (CO + CO2). amorphous silica Stable at room temperature provided it is not on contact with air. Vulcanises at room temperature on contact with moisture in the air.

11. Tolicological Information

Acute toxicity: Not classified as harmful by inhalation. Not classified as harmful by contact with skin. Not classified as harmful if swallowed (by calculation according to the conventional method). Slightly irritating to the skin. Slightly irritating to the eyes. Not classified as irritating to skin and eyes (by calculation according to the conventional method). Not classified as sensitising by skin contact (by calculation according to the conventional method).

Local effects:

Sensitisation: Specific effects Mutagenicity: Further information:

No information available. At high concentrations, the vapours can be irritating to the respiratory system.

12. Ecological Information

Biodegradability Ultimate aerobic biodegradability: Bioaccumulation Bioconcentration factor: Ecotoxicity Effects on the aquatic environment: The preparation has not been tested. According to the data on the components: The product does not have any known adverse effects on the aquatic organisms tested. Not classified as Dangerous for the Environment, according to EC criteria (by calculation according to the conventional method). According to the data on the components: To be considered to be: Not potentially bioaccumulable. (Internal evaluation) According to the data on the components: To be considered to be: Not biodegradable. (Internal evaluation)

Further information:

13. Disposal
Residues from product Destruction/Disposal: Contaminated packaging Decontamination/cleaning: Destruction/Disposal: Separate the different packaging components and treat them separately. Incinerate plastic packaging at a licensed installation. Entrust the uncontaminated packaging to a licensed waste contractor. Following decontamination, re-use or recycle metal packaging. Incinerate at a licensed installation. The user's attention is drawn to the possible existence of local regulations regarding disposal. Dispose of at a licensed waste collection point.

Disposable containers: Note:

14. Transport Information

International regulations Land Rail/road (RID/ADR): Sea (IMO/IMDG): Air (ICAO-IATA): Other regulations United Kingdom: Rail/road: Note: Not restricted. The above regulatory prescriptions are those valid on the date of publication of this sheet. Given the possible evolution of transport regulations for hazardous materials, it would be advisable to check their validity with your sales office. Not restricted. Not restricted. Not restricted.

15. Regulatory Information

Labelling EC regulations: Applicable Identification of the hazardous product: R phrases: S phrases: Additional phrases: Further regulations United Kingdom: Handle in accordance with relevant British legislation: Control of Substances Hazardous to Health Regulations Not applicable. No R phrases. No S phrases. Safety Data Sheet available on request for professional users. Mandatory labelling of preparations not classified as hazardous.

15. Regulatory Information continued

Environmental Hygiene Guidance: Note: EH/40 Occupational. Exposure Limits (revised annually). The regulatory information given above only indicates the principal regulations specifically applicable to the product described in the Safety Data Sheet. The user's attention is drawn to the possible existence of additional provisions which complete these regulations. Refer to all applicable national, international and local regulations or provisions.

16. Other Information

Uses Prohibited uses: Registration numbers: This product is only intended for industrial use. The polymers are not listed in the EINECS inventory. The monomers corresponding to the polymer(s) in this preparation are registered in the EINECS inventory All the other constituents of this preparation are registered in the EINECS inventory. All the components of this preparation are registered in the TSCA inventory. Registered on the AICS inventory. Registered in the Canadian inventory (CEPA DSL). Registered in the Korean inventory. Registered in the Philippine inventory (PICCS) Registered in the Chinese inventory

R Phrases of 2 & 3: R 14: R 22: R 34: R 65: Harmful: Reacts violently with water. Harmful if swallowed. Causes burns. May cause lung damage if swallowed.

This safety data sheet should be used in conjunction with technical data sheets. It does not replace them. The information given is based on our knowledge of this product, at the time of publication. It is given in good faith. The attention of the user is drawn to the possible risks incurred by using the product for any other purpose than that for which it was intended. This does not in any way excuse the user from knowing and applying all the regulations governing his activity. It is the sole responsibility of the user to fulfil his obligations regarding the use of hazardous products. This information is not exhaustive. This does not exonerate the user from ensuring that legal obligations, other than those mentioned, relating to the use and storage of the product, do not exist. This is solely his/her responsibility.

Henkel Building Systems Henkel Loctite Adhesives Limited Winsford, Cheshire, CW7 3QY Tel: 01606 594600 Fax: 01606 863762 E-Mail: technical.services@uk.henkel.com
ISO Registration Henkel Loctite Adhesives Ltd is part of Henkel KGaA who are certified by DQS (Certificate Registration number: 003052 QM/UM) as a company operating a Quality Management System to BS EN ISO 9001:2000, and BS EN 14001.