Professional Documents
Culture Documents
Nuclear fuel cycles of non-power reactors and batteries The Economics of Nuclear Power
CANDU fuel cycle cost
High-Level Waste Managements properties of irradiated fuel classification of radioactive wastes Fuel bay storage Dry fuel storage spent fuel management Decommissioning of Nuclear Power Plants Final review
Introduction
Nuclear Reactor: a
Nuclear generating stations avoid
component in which nuclear chain reaction initiated, controlled and sustained in a steady rate
In nuclear weapon a chain
emissions of 3.2 billion tonnes of greenhouse gas emissions annually (source: Cameco Co.)
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Introduction
Nuclear energy is an important source of electricity throughout the
globe
Currently 435 reactors are operating ( about 374 GWe), 65 under
REACTORS URANIUM PROPOSED REQUIRED Jan 2013 2012 No. MWe gross tonnes U
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13.5
435 374,108
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65,139
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2006 IAEA report indicates 441 nuclear power plants, with total
installed capacity of 369 GW(e), were in operation worldwide, generating about 16% of global electricity.
France 74.1% Europe dominant source In Japan and Korea become increasingly important UK about 15.7%
to be in the range of 0.9% up to the year 2025 by which time the total installed nuclear power would be some 438 GW(e).
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From OECD (Organization of Economic Cooperation and Development); includes about 25 industrialized democracies
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From OECD (Organization of Economic Cooperation and Development); includes about 25 industrialized democracies
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neutron; e.g., 235U,233U,239Pu, and 241Pu fertile: isotopes that can be converted to fissile materials by the capture of neutron; e.g., 238U,232Th transmutation: the conversion of one element into another by absorbing a neutron and emitting a beta particle to increase by one atomic number unit enrichment: the process of increasing the ratio of the 235U isotope to that of the 238U isotope burnup: the energy produced by the fuel expressed in MWD/MTU (MegaWatt Days per Metric Ton of Uranium
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Fuel cycles
Progression of nuclear fuel in different stages of its life
cycle, or, The way in which fuel gets to nuclear reactors and what happens to it when it comes out. Unlike coal, uranium ore cannot be fed directly into a power station; it has to be purified, isotopically concentrated (usually) and made up into special fuel rods.
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can be used
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Natural uranium
Natural uranium contains 99% U-238 and only about
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Natural uranium
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control mechanisms structural shielding other material present or predominant 238U it forms neptunium-239 plutonium-239
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for breeding human-made fissile isotope 233U efficiently in a thermal neutron reactor has been recognized
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Concentrate is 85% U, enrichment to 4% U-235 with 0.25% tails assay - hence 140,000 SWU required, core load 72 tU, refuelling so that 24 tU/yr is replaced. Operation: 45,000 MWday/t (45 GWd/t) burn-up, 33% thermal efficiency. (In fact a 1000 MWe reactor cannot be expected to run at 100% load factor - 90% is more typical best, so say 7.75 TWh/yr, but this simply means scaling back the inputs accordingly.) Uranium concentrations are sometimes expressed in terms of U3O8 content (U3O8 is a mixture of two uranium oxides approximately as they occur in nature). Pure U3O8 product contains about 85% uranium metal.
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-UO2 use of the fuel in nuclear power, research, or naval propulsion reactors used fuel and low level waste (LLW) uranium and plutonium recycling high level waste (HLW) disposal
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Fuel Cycle
Once-through cycle Breeder reactor fuel cycle
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Service period
in-core fuel management
Back end
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Uranium history
From WNA Pocket Guide (www.world-nuclear.org) In 1789 Martin Klaproth, a German chemist, isolated an oxide of uranium while
for tinting in early photography. Uranium was produced in Bohemia, Cornwall, Portugal and Colorado and total production amounted to about 300-400 tonnes. he discovery of radium in 1898 by Marie Curie led to the construction of a number of radium extraction plants processing uranium ore (radium is a decay product of uranium). Prized for its use in cancer therapy, radium reached a price of 750,000 gold francs per gram in 1906(US$10 million). It is estimated that 754 grams were produced worldwide between 1898 and 1928.Uranium itself was simply a waste material. With the discovery of nuclear fission in 1939, the uranium industry entered a new era. On 2 December 1942, the first controlled nuclear chain reaction was achieved in Chicago. The first nuclear explosion in 1945 demonstrated the enormous power potential of nuclear fission. From a small beginning in 1951, when four light bulbs were lit with nuclear electricity, the nuclear power industry now supplies over 13% of world electricity
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Airborne Survey
satellites- preliminary Landsat-I launched by NASA by beaming electromagnetic waves onto the surface and receiving the reflected signal radiometric survey by small airplane or helicopter more detailed investigation detection of gamma rays gamma-ray counter can detect the photons emitted by uranium daughters notably radon and bismuth can detect uranium ore in areas as small as 50m2 with ore grades of 0.2 U3O8
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detect the delayed fission neutron produced by the uranium in the ore
measurement helium from a borehole uranium and thorium and their
Botanical methods existence of high concentrations of certain elements indicates the presence of uranium
for example Astrofilus pattersons needs selenium to grow http://www.cameco.com/common/flash/fuelcycle/index.html#/Exploration
/Candu/
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Mineable deposits
Minerals
Uraninite Davidite Brannerite Carnotite Tyuyaminite Autunite Torbernite Uranophane
Chemical Composition
UO2 (Fe,Ce,La,Y,U,Ca,Zr,Th)(Ti,Fe,Cr,V)3(O,OH) (U,Ca,Fe,Th,Y)3Ti5O16 K2 (UO2)2 (VO4)2.3H2O Ca (UO2)2 (VO4)2.5-8H2O Ca (UO2)2 (PO4)2.10-12H2O Cu (UO2)2 (PO4)2.8-12H2O Ca (UO2)2 SiO3(OH)2.5H2O
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surface about less than 100 meters deep depending on the nature of the ore body drilling holes at 50-ft centre may be required for ore bed topsoil is stockpiles for backfilling pits after the shutdown slope 0.75 to 1 with shallow surface berm to prevent slippage
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A schematic
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disadvantages
potential for contamination of underground lower recovery rate
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Hope
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Precautions
Precautions taken at a uranium mine Dust control
to minimize inhalation of gamma or alpha-emitting minerals main source of radiation exposure in a uranium mine
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Open pit
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that can be recovered at less that stated cost with currently proven mining Resources
probable possible speculative
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15%
10% 8% 7%
Australia Kazakhstan Canada South Africa Namibia 5% Brasil Russian Fed. Uzbekistan United States
17%
4% 30%
4%
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tonnes U 1,143,000 816,000 444,000 342,000 341,000 282,000 279,000 225,000 172,000 116,000 90,000 79,000 67,000 60,000 287,000 4,743,000
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(1998)
Company CAMECO COGEMA Vostgok Anglogold Kazatomprom Western Mining Navoi Priargunsky Rio Tinto ERA 31% 17% 2% 2% 4% 4% 6% 6% 8% 10% Shareholder Canada,USA Canada,USA,France.Gabon,Niger,Australia Ukraine South Africa Kazakhstan Australia Uzbekistan Russia Namibia and South Africa Australia
10% 31%
CAMECO COGEMA Vostgok Anglogold Kazatomprom Western Mining Navoi Priargunsky Rio Tinto 17% ERA
8% 6% 6% 4% 4% 2% 2%
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deposits of high-grade uranium ore in the world are found in northern Saskatchewan.
About 14 per cent of the
world's known uranium reserves are located in northern Saskatchewan where four mines produce about 30 per cent of the world's supply.
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uranium
average concentration of about 3x10-3 ppm marine mud concentration is about 1 ppm approach hydrogen titanium oxide (HTiO) is used to absorb the uranium from
seawater
ammonium carbonate (NH4CO3H2O) is used to separate the uranium
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the solution
stage estimate of amount of uranium that could be produced from all of these by-product sources is 119000 tons of uranium for the rest of this century
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Reserves availability
Example: (a) How many 1000MWe LWRyears can the world reserves of uranium service? Use the reserves information in Table 2.7 in the Textbook and add all the categories for world resources. (b) If the current capacity of the World nuclear fleet is 350GWe, and that capacity grows at 2% per year, how many years can be served by these resources? (c) If advanced reactors are introduced in 2025 that have a plant efficiency of 45% instead of 33%, how long will the reserves last?
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Uranium commodity
of U
stockpiles, degraded
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mineral could limit the nuclear power industry's plans to develop 168 new nuclear plants worldwide by 2020 Radiation levels at these mines also are far more concentrated than in lower-grade deposits,
work remotely or in protective clothing and equipment.
source: www.bloomberg.com
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rock
danger at Cigar Lake emerged slowly, 11 days after the blasting. company couldn't control the water initial leak in the tunnel's ceiling of 340 cubic meters an hour was
within the mine's pumping capacity of 500 cubic meters an hour, the company said in its accident report and in testimony to regulators three hours later, the situation was much worse. Groundwater was gushing into the mine at the rate of almost 1,500 cubic meters an hour - three times the pumps' capacity - filling the shaft, the company report states. regulator pledges were to install more underground pumps
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