SR.NEON Chemistry 30. 0.

Eamcet Grand Test (On 2nd Year)

Date :

SRI CHAITANYA EDUCATIONAL INSTITUTIONS, A.P.

SR.NEON 30.10.13 SUB : Chemistry M!#.M!r$s : %0 121. 122. The vapour pressure is least for 1) pure water 2) 0.1m aqueous urea 3) 0.2m aqueous urea 4) 0.3m aqueous urea 250 ml of a solution contains 6.3 g of oxalic acid (MW=126). What is the volume of water to be added to this solution make it a 0.1 N solution 1) 750 Lit 123. 2) 7.5 Lit 3) 0.75 Lit 4) 75 ml The vapour pressure of two pure liquids (A) and (B) are 100 & 80 torr . The total pressure of the solution obtained by mixing 2 mol of (A) and 3 mole of (B) would be 1) 20 torr 124. Reason 2) 36 torr (R) : Glass is a pseudo solid 3) 88 torr 4) 180 torr Assertion (A) : Glass posses sharp melting point 1) A and R are true and R is the correct explanation of A. 2) A and R are true and R is not the correct explanation of A. 3) A is true, R is false. 125. pattern 1) 24 % 126. 1) 290 300 k 127. 2) 26% 2) 300 310 k 3) 34% 3) 310 320 k 4) 74% 4) 320 330 k The increase in rate constant of a reaction is more when the temperature increases from 1 is given below. Here x is equal to T
logk
slo pe =x

EAMCET GRAND TEST (On 2nd e!r"

DATE :

4) A is false, R is true.

The percentage of void space of a metallic element crystallizing in ABCABC type lattice

The graph of log k verses

1) 128. 129.

- Ea 2.303

2)

- Ea 2.303R

3)

- 2.303 EaR

4)

- 2.303R Ea

After electrolysis of aqueous solution of NaCl using Pt electrodes, the pH of the solution 1) increases 1) ohm cm 3) S.cm-2 2) decreases 3) remains constant 4) becomes zero The unit of equivalent conductivity is 2) ohm-1 cm2. gm equivalent -1 4) ohm cm2. gm equivalent -1
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SR.NEON Chemistry 30. 0. 2

Eamcet Grand Test (On 2nd Year)

Date :

130.

on passing current through molten KCl , 19.5g of K is deposited. The amount of Al deposited by the same quantity of electricity when passes through molten AlCl3 is 1) 4.5 g 2) 9 g 3) 13.5 g 4) 2.7 g

131.

The standard emf for the cell reaction ; Zn + Cu +2 Cu + Zn 2+ is 1.1 volt at 250C. The EMF for the cell reaction, when 0.1M Cu+2 and 0.1M Zn+2 solution are used, at 250C is 1) 1.1 V 2) 0.1 V 3) -1.1 V 4) 1.23 V

132.

When 0.1M CH3COOH solution is shaken with activated charcoal and the charcoal is filtered out . The concentration of acid 1) Increases 2) No change 3) Decreases 4) Cant say

133.

On addition of 1 ml solution of 10% NaCl to 10 ml gold sol in the presence of 0.0250gm of starch, the coagulation is just prevented the gold number of starch is 1) 0.025 2) 0.25 2) Electro dialysis 2) NH3 2) H3PO5 , H4P2O7 3) 2.5 3) Electro phorisis 3) BiH3 3) H3PO3 , H3PO2 4) 25 4) Ultra filtration 4) AsH3 4) H3PO2 , HPO3

134. 135. 136. 137.

Colloidal sols are not purified by 1) Dialysis 1) PH3 1) H3PO4 , H3PO3 Reason Most volatile hydride is Which pair of oxy acids contain P H bonds Assertion (A) : Direct absorption of SO3 in H2O commercially not possible (R) : Direct absorption of SO3 in water form a mist of corrosive vapour 1) A and R are true and R is the correct explanation of A. 2) A and R are true and R is not the correct explanation of A. 3) A is true, R is false. 4) A is false, R is true. 2) H2O, H2Se 2) SP3 3) H2Se, H2Te 3) SP3d 2) Br2 + 2I- 2Br - + I 2 4) Cl 2 + 2Br - 2Cl- + Br2 2) Dipole induced dipole 4) London dispersions 2) [ XeF3 ] [ PF6 ]
+ -

138. 139. 140.

The pair of exothermic hydrides of VIA group are 1) H2O, H2S 1) SP3d3 4) H2S, H2Te 4) Sp3d2 The hybridisation in ClF7 is Which of the following reaction does not takes place 1) F2 + 2Cl- 2F- + Cl 2 3) Cl 2 + 2F- 2Cl- + F2

141.

The forces that make the molecules of a noble gas in liquid state. 1) Dipole dipole 3) Repulsive dipole

142.

Xenon difluoride reacts with PF5 , they give 1) [ XeF ] [ PF6 ]

+ -

3) [ XeF5 ] [ PF6 ]

4) [ XeF7 ] [ PF6 ]

143.

- 350k 50- 70k !" + C# 330 !" ( C#) !" + C# ; This sequence of reactions involved in

1) Zone refining 144.

Sri Ch!it!ny!

2) Distillation

3) Van arkel method

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4) Monds process
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Heating mixture of Cu2O and Cu2S will give

SR.NEON Chemistry 30. 0. 2

Eamcet Grand Test (On 2nd Year)

Date :

1) Cu + SO3 145. 146. 147. 148. 1) 7 1) Co+2 1) CoCl3.6NH3 1) Co ( en ) 2 Cl 2 149. List I A) Phenol + CH2O B) Terephthalic acid C) Caprolactum
+

2) Cu2SO3 2) 8 2) Co+3 2) CoCl3.5NH3 2) Co ( !$ 3 ) 5 Cl

+2

3) Cu + SO2 3) 9 3) Mn+2 3) CoCl3.4NH3 3) Co ( !$ 3 ) Cl 2 List II 1) synthetic rubber 2) Bakelite 3) Nylon 6 4) Terylene

+

4) CuO + CuS 4) 10 4) Sc+3 4) CoCl3.3NH3 4) Cr ( #X ) 3

- 3

The number of electrons in 4d sub shells of Pd is Which one of the following is diamagnetic Example of neutral complex is Both geometrical and optical isomerism are shown by

D) Butadiene + Styrene A 1) 3) 150. 2 2 B 3 4 C 4 3 D 1 1

A 2) 4) 3 1

B 1 2

C 2 3

D 4 4

Histamine causes 1) Allergic response to pollen 3) Nasal congestion

C$2C$2!$!$2

2) Secretion of acid in stomach 4) All

151. 1) Nardil 152. 153. 154. 155. 156. 157. 1) B1 1) Cortisone 1) 4 1) fluoro benzene 1) C2H5Cl

%"s 2) Iproniazid 2) B2 2) Thyroxine 2) 1 2) Benzene 2) CH3CH3 3) Valium 3) B12 3) Progestrone 3) 2 3) Aniline 3) C2H5OH 4) Prontosil 4) B6 4) Estrone 4) 3 4) Phenol 4) CH3COOH Convulsion is due to deficiency of vitamin The sex hormone which controls the development and maintenance of pregnancy is Aniline can react with maximum moles of CH3I Benzene diazonium fluoroborate on heating to dryness yields Which of the following posses highest boiling point C2H5CHO and CH3COCH3 can be distinguished by 1) Phenyl hydrazine 3) Fehling solution 2) 2, 4 di nitro phenyl hydrazine 4) Sodium bisulphate

158.

Tert-butyl methyl ether on heating with HI of one molar concentration gives

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SR.NEON Chemistry 30. 0. 2

Eamcet Grand Test (On 2nd Year)

Date :

1) C$ 3#$ +( C$ 3 ) 3 CI 3) C$ 3I +( C$ 3 ) 3 CI 159. a) 2, 4, 6 trinitrophenol c) m nitro phenol 1) a > b > c > e > d 160. 2) d > e > c > b > a
Cl

2) C$ 3I +( C$ 3 ) 3 C#$ 4) None

Arrange the following compound in the decreasing order of their pKa values. b) 3, 4 dinitrophenol d) p cresol 3) a > b > c > d > e
C$2Cl

e) Phenol 4) e > d > c > b > a

Which of the following will be the least reactive towards nucleophilic substitution ?
Cl

1) C2H5Cl

2)

3&%

&%

C$3

Key Sheet

1) 11) 21) 31)

4 1 4 1

2) 12) 22) 32)

3 3 1 4

3) 13) 23) 33)

3 4 4 3

4) 14) 24) 34)

4 3 3 4

5) 15) 25) 35)

2 1 4 1

6) 16) 26) 36)

1 3 4 4

7) 17) 27) 37)

2 1 4 3

8) 18) 28) 38)

1 1 1 1

9) 19) 29) 39)

2 1 3 2

10) 20) 30) 40)

1 3 4 4

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