Document No: BUL.MSDS.

05_en

MATERIAL SAFETY DATA SHEET DENACTIVE BLUE DENF

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name
General Use Product Description

Date of issue : 07.05.2008 Revision No: 0

DENACTIVE BLUE DENF REACTIVE DYESTUFF / REACTIVE BLUE DENF Reactive Dyestuff (Mixture)

Safety Signs

DENGE KMYA & TEKSTL SAN. TC. LTD. T. Factory: erkezky Yolu zeri Akbayr Mevkii Velimee Ky 59850 orlu Tekirda / TURKIYE Company Identification Phone: +90 (0282) 674 54 00 (Pbx) Fax :+90 (0282) 674 54 01 Web: www.dengekimya.com E-mail: info@dengekimya.com

2. COMPOSITION/INFORMATION ON INGREDIENTS
Component Denactive BLUE DENF (Mixture) CAS No: 93912-64-2 2580-78-1

3. HAZARDS IDENTIFICATION
Emergency Overview Potential Health Effects Dust can be a nuisance. Based on similar products, material may cause Inhalation Eye contact Skin contact Ingestion sensitization by inhalation. Non-irritating Non-irritating. Practically non-toxic in normal industrial use. Practically non-toxic in normal industrial use. No known effects Blue powder that presents little or no immediate hazard. Avoid contact with skin and eyes.

Chronic

4. EMERGENCY AND FIRST AID MEASURES

Ingestion Inhalation If swallowed get medical attention. If exposure to dust causes irritation or distress, remove person to fresh air. Give oxygen or artificial respiration if needed. Get medical attention. Immediately flush skin with soap and plenty of water. Remove clothing Wash clothing before reuse. Get medical attention. Eye Contact Immediately flush eyes with plenty of water for at least 15 minutes and contact a physician.

Skin Contact

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Document No: BUL.MSDS.05_en

MATERIAL SAFETY DATA SHEET DENACTIVE BLUE DENF

5. FlRE-FIGHTING MEASURES AND EXPLOSION HAZARD DATA
Flash Point Flammable limit Extinguishing media Autoignition temperature Special Fire-Fighting Measures: Not known (Material is a powder) Not applicable

Date of issue : 07.05.2008 Revision No: 0

Use carbondioxide or dry chemical for small fires; Universal foam or water spray for large fires. About 300C Fire fighters should be provided with normal protective equipment and positive-pressure self contained breathing apparatus. For small fires make one quick attempt to extinguish. If unsuccessful or fire is too big, call experts who should use self contained breathing apparatus.. To reduce potential explosion hazard, avoid dispersion of dust in air. May generate SOx, NOx or CO when heated to burning

Explosion Hazards Hazardous decomposition products:

6. ACCIDENTAL RELEASE MEASURES

General Very fine particles can cause a fire or explosion. Eliminate all ignition sources. Consult an expert on disposal of the recovered material. Ensure disposal is in compliance with government requirements and ensure conformity with local disposal regulations. Notify the appropriate authorities immediately. Take all additional action necessary to prevent and remedy the adverse affects of the spill.

Land Spill

Collect in a dustless manner such as a vacuum cleaner or soak up with saw dust, then wash away any remaining traces. Prevent washings from entering waterways.

7. HANDLING AND STORAGE

Avoid breathing dust. Avoid contact with eyes. Avoid prolonged or repeated contact with skin. Use with adequate ventilation. May form explosive dust-air mixtures. Ground and bond containers when transfening material. Store at room temperature. Keep containers closed when not in use.

PRECAUTIONS

8. EXPOSURE CONTROLS AND PERSONAL PROTECTION

Ventilation Use local ventilation at places where dust can be released into the workplace air. Keep dust concentrations below recommended TLV. ACGIH TLV for "Particles otherwise not classified"= 10mg/m Personal Protection:
3

Respiratory

Not required for occasional handling if adequate ventilation is available. A dust respirator is recommended for prolonged handling or exposure.

Protective Gloves Eye Protection Other Work/Hygenic Practices

Wear rubber gloves. Wear safety goggles or equivalent eye protection. Wear appropriate protective clothing to prevent skin contact. Always clean protective equipment and workplace.

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Document No: BUL.MSDS.05_en

MATERIAL SAFETY DATA SHEET DENACTIVE BLUE DENF

9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance- Odor Melting Point Boiling Point Vapor Density Percent Volatile Vapour Pressure Evaporation rate pH Solubility Specific Gravity Blue Powder Odorless Not known Not known Not Known Not applicaple Not known Not applicable pH = 5 ~ 6 at 0,1 g/l > 100 g/l at 25C -

Date of issue : 07.05.2008 Revision No: 0

10. STABILITY AND REACTIVITY

Stability Conditionsto avoid Hazardous Decomposition Products Hazardous Polymerisation Incompatibility Stable at normal condition Avoid exposure to direct sunlight See section 5 Will not occur Oxidizing materials

11. TOXICOLOGICAL INFORMATION

Acute Inhalation Effects: Eye effects Skin Effects Acute Oral effects Chronic effects/Carcinogenicity No data available but similar products have caused sensitization and irritation. Non-irritant based on rabbits testing according to EEC standards Non-irritant based on rabbits testing according to EEC standards The oral LD50 in rats is > 2000 mg/kg No data available. Not listed by IARC, NTP or OSHA

12. ECOLOGICAL INFORMATION

AOX cautions, Product does not contain any organic binded halogens which causes increase of the AOX value of the media Does not contain formaldehite and any azo dyestuff listed in MAK group III 1,2,3

13. DISPOSAL CONSIDERATIONS

May be incinerated by adequate methods. Disposal in accordance with federal, state and local regulations. The owner of the material is responsible for proper waste disposal.

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Document No: BUL.MSDS.05_en

MATERIAL SAFETY DATA SHEET DENACTIVE BLUE DENF

14. TRANSPORT INFORMATION
Not regulated.

Date of issue : 07.05.2008 Revision No: 0

15. REGULATORY INFORMATION

To the best of our knowledge the substance: is NOT listed on the black list 2455/2001/EG It does NOT require labeling with any R phrases; R27, 29, 35, 39, 40, 45, 46, 48, 49, 50, 51, 52 , 53, 59, 60, 62, 63, 68

R phrases R 22 Harmful if swallowed. R 34 Causes burning. R 36/38 Irritate eyes and skin. R 41 Causes dangerous and important irritation at eyes.

16. GENERAL INFORMATION

The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

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