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pH + Curvas de Titulao
Potenciomtrica:
Simulao e Anlise
Clculo de pH de solues aq
Anlise de dados de pH em fu
determinao de concentra
Aplicaes
Instalao
Observaes
Sugestes
http://www2.iq.usp.br/docente/gutz/Curtipot.html
Histrico
es de ensino e pesquisa
es e outras informaes:
.usp.br/docente/gutz
localizao automtica e precisa das inflexes das curvas (por interpolao com alisamento por splines
determinao de concentraes e pKas (inclusive de amostras diludas com mltiplos componentes) por
Simulao de curvas de titulao cido - base com o Titulador Virtual
titulaes simples ou de misturas complexas de cidos e bases multiprticos
simulao de disperso nas medidas de pH e de volume, para avaliar efeito nos resultados
Leia a licena (coloque o mouse na clula Q14) e, se estiver de acordo, utilize o programa gratuitamente somente no e
Permita a execuo de macros pelo Excel no Windows Vista ou Windows XP (Ferramentas / Macro/ Segurana / N
Ative ou instale o suplemento Solver do Excel (pr-instalado ou disponvel no disco do Office ) antes de usar Analise_
O mdulo pH realiza clculos de fora inica e coeficientes de atividade; o Simulador no (vez que os pontos estequiom
Para determinao de pKas com o mdulo Analise_II, os dados reais de pH devem ser isentos de erros de calibrao,
O autor no garante o funcionamento correto e exato do programa e se isenta de qualquer responsabilidade (mais deta
Favor comunicar erros e incompatibilidades do programa (testado em verses de 2003 a 2007 do Excel);
mais fcil comear com "CurTiPot para iniciantes", disponvel em www2.iq.usp.br/docente/gutz/Curtipot.html - pro
Em todas as planilhas, leia as instrues (a comear pelas da 1 linha) posicionando o mouse sobre clulas com sinal v
Comece pelo mdulo pH, depois siga para o Simulador, ambos preenchidos com exemplos tpicos
V direto para a Anlise_I para analisar os seus dados experimentais ou simulados
O mdulo Analise_II mais poderoso e seu uso requer aprendizado; guie-se pelas instrues locais e pelos Exemplo
Grave seus dados em arquivos curtipot_qualquer-nome.xls para preservar a cpia original do programa
A verso 1 do programa CurTiPot foi desenvolvida em 1991/1992 em Turbo Basic (Boreland) para DOS (Disk Operatin
A verso 2 (para DOS), datada de 1993 e distribuda pela AllChemy (http://allchemy.iq.usp.br) comporta anlise de titula
A verso 3 para Excel, com o novo mdulo de anlise por regresso no linear multiparamtrica, comeou a ser escrita
A verso 3.1 foi a 1 a ser traduzida para o ingls e distribuda a partir de 01/05/2006 no site www2.iq.usp.br/docente/g
A verso 3.2, lanada em 01/01/2007, inclui uma planilha especfica para clculos de pH, com estimativas das atividad
A verso 3.3, lanada em 15/01/2008, tem interface mais amigvel com a base de dados de pKa e gera diagrama loga
A verso 3.4, lanada em 14/10/2008, contempla clculos de fora inica e estimativas de coeficiente de atividade no m
Entre maio de 2006 e outubro de 2008, mais de 40 mil cpias foram extradas do site do autor, destinadas a mais de 10
Reportagem sobre o sucesso de CurTiPot foi publicada pela Agncia FAPESP em www.agencia.fapesp.br/boletim_den
o arquivo curtipot.xls
programa gratuitamente somente no ensino e em aplicaes no comerciais
vem ser isentos de erros de calibrao, erro alcalino e de potencial de juno (corrigir previamente)
ando o mouse sobre clulas com sinal vermelho; exemplos acima: Q2, Q3, Q6,...
om exemplos tpicos
asic (Boreland) para DOS (Disk Operating System, Microsoft) e lanada em 1992
o site do autor, destinadas a mais de 100 pases; outros 300 sites de redistribuem o software
em www.agencia.fapesp.br/boletim_dentro.php?id=7123
m todas as planilhas
pH de solues aquosas
um ou mais campos; Enter; clique em B18.
Composio da soluo - reagentes adicionados, Preencha
mol/L
cido / Base
protonao
cido actico
cido
clordrico
[B]
[HB]
[H2B]
cido
fosfrico
Alanina
0.061
0.0395
[H3B]
[H4B]
[H5B]
[H6B]
S[HiB]
0.1005
S[H]
0.14
SziCi
-0.1615
Eletrlito
Ci (mol/L)
ziCi
Na+
K+
Ca++
Cl-
NO3-
ClO4-
0.1615
0
Balano de carga
Correto
9.995E-08
pH
0.1615
0.2225
g H+
0.743
a H+
cido actico
cido
clordrico
cido
fosfrico
[B]
[HB]
1.206E-06
[H2B]
3.950E-02
[H3B]
4.123E-07
Alanina
6.100E-02
[H4B]
[H5B]
[H6B]
S[HiB]
0.000E+00
0.000E+00
1.005E-01
0.000E+00
0.000E+00
para pH = 7.000
0.000E+00
p[H] =
cido / Base
protonao
cido actico
cido
clordrico
%B
99.58
100.00
0.00
94.66
0.52
0.18
% HB
% H 2B
0.42
0.00
60.69
5.32
96.66
99.81
39.30
0.01
2.81
0.00
0.00
0.00
0.00
% H 3B
cido
fosfrico
% H 4B
0.00
% H 5B
0.00
% H 6B
% S[HiB]
Alanina
0.00
100.00
100.00
100.00
100.00
100.00
para pH = 7.000
100.00
e para I =
cido / Base
protonao
gB
g HB
g H 2B
g H 3B
g H 4B
g H 5B
g H 6B
Eletrlito
gi
cido actico
cido
clordrico
cido
fosfrico
0.743
0.743
0.069
0.069
0.009
0.743
1.000
1.000
0.304
0.304
0.069
1.000
0.743
0.743
0.304
0.743
1.000
1.000
0.743
Alanina
1.000
0.743
0.304
Na+
0.743
K+
0.743
Ca++
0.304
Cl0.743
cido actico
0.004
cido
clordrico
0.000
cido
fosfrico
1.393
NO30.743
ClO40.743
para pH = 7.000
cido ctrico cido EDTA
0.053
1.023
Alanina
0.998
13
cido / Base
cido actico
cido clordrico
cido fosfrico
Carga de B
pKa1
-1
-1
-3
4.757
-7.000
2.148
pKa2
7.199
pKa3
12.350
pKa4
pKa5
pKa6
SS
1.005E-01
Eletrlito
1.400E-01
Carga do on
Na+
1
-0.1615
pKw
13.997
K+
1
Ca++
2
0.1615
0.509
Mude crIterosament
0.300
7.000
pOH
6.997
p[H]
6.871
p[OH]
[H+]
cido / Base
cido actico
cido clordrico
cido fosfrico
1.35E-07
Carga de B
-1
-1
-3
pK'an = logK'p1
4.499
-7.258
11.575
[OH ]
1.36E-07
pK'an-1 = logK'p2
6.682
pK'an-2 = logK'p3
1.890
pK'an-3 = logK'p4
pK'an-4 = logK'p5
0.000E+00
6.871
cido ctrico
94.66
5.32
0.01
0.00
100.00
0.2225
SS
pK'an-5 = logK'p6
1.005E-01
pK'w
13.74
cido ctrico
0.069
0.304
0.743
1.000
cido ctrico
0.053
117
cido ctrico
cido EDTA
Alanina
cido ctrico
-3
-4
-1
-3
3.128
0.000
2.348
3.128
4.761
1.500
9.867
4.761
6.396
2.000
-1
5.715E+04
6.396
Kw
1.01E-14
10.170
-1
ClO4-1
b p1
b p2
b p3
b p4
b p5
b p6
6.110
NO3-1
Carga de B
2.680
Cl-
cdigo de cores
No
altere
Mude crIterosamente
Preencha, altere ou deixe em branco
6.868
"p[H]"
7.388
"p[OH]"
6.609
cido ctrico
cido EDTA
Alanina
cido ctrico
-3
-4
-1
-3
5.621
9.137
9.609
5.621
4.244
5.335
2.348
4.244
2.870
2.163
1.742
1.500
0.258
2.870
b'p1
b'p2
b'p3
b'p4
b'p5
b'p6
K'w
-1
3.15E+04
1.83E-14
cido
fosfrico
-1
1.000E-07
-3
2.239E+12
-3
2.489E+06
3.540E+19
4.977E+21
Alanina
cido ctrico
cido / Base
-4
1.479E+10
-1
7.362E+09
-3
2.489E+06
Carga de B
pKa1 = logKpn
1.435E+11
1.905E+16
1.641E+12
1.435E+11
pKa2 = logKpn-1
1.928E+14
9.120E+18
1.928E+14
pKa3 = logKpn-2
9.120E+20
pKa4 = logKpn-3
2.884E+22
pKa5 = logKpn-4
pKa6 = logKpn-5
2.884E+22
cido
fosfrico
-1
5.52E-08
-3
3.76E+11
-3
4.18E+05
1.81E+18
1.40E+20
Alanina
cido ctrico
-4
1.37E+09
-1
4.06E+09
-3
4.18E+05
7.33E+09
2.96E+14
9.05E+11
7.33E+09
5.43E+12
4.32E+16
2.38E+18
7.53E+19
1.36E+20
5.43E+12
cido
clordrico
cido EDTA
cido
tricloroactico
cido ctrico
-1
-1
-3
-3
-4
-1
-3
4.757
-7.000
2.148
3.128
0.000
0.660
3.128
7.199
4.761
1.500
4.761
12.350
6.396
2.000
6.396
2.680
6.110
10.170
cido
fosfrico
cido lglutmico
cido actico
Hidrxido de
amnio
cido
clordrico
0.005
0
0
cido forte
0.005
0.015
Base forte
0.1
0
0
c. carbnico
[HB]
[H2B]
S[HiB]
S[H]
0
0
"pH" inicial
1.806
0.1
0
0
0
0
0
SS
1.00E-01
0.00E+00
0
0
0
0
Volumes de titulado / titulante (mL)
Titulado
gua
Adicionado
adicionada
20
Vol. bureta
50.00
0
N de adies
50
14.0
12.0
10.0
pH
8.0
6.0
4.0
2.0
Ler dados nas curvas
Copiar curvas para
0.0
Mudar escalas
0.0
10.0
20.0
Volume de titulante (
Analisar os dados
V adic.
(mL)
"pH"
simulado
0.000
1.806
V adic.
com "erro"
(no use)
0.027
"pH"
simulado
com "erro"
1.905
[H]
CHtot =
CHcalc
1.563E-02
1.500E-01
fatores de diluio
Titulado
(amostra)
1.000E+00
2.157
4.096
5.754
7.077
8.061
8.749
9.210
9.508
9.697
9.817
9.894
9.944
9.982
10.014
10.050
10.098
10.170
10.282
10.457
10.730
11.144
11.748
12.577
13.626
14.824
16.044
17.146
18.041
18.706
19.169
19.478
19.677
19.804
19.886
19.941
19.982
20.018
20.059
20.115
20.200
20.333
20.548
20.896
21.459
22.365
23.818
26.155
29.983
36.644
50.000
2.020
2.235
2.449
2.664
2.878
3.093
3.307
3.522
3.736
3.951
4.165
4.380
4.594
4.809
5.023
5.238
5.452
5.667
5.881
6.096
6.310
6.525
6.739
6.954
7.168
7.383
7.598
7.812
8.027
8.241
8.456
8.670
8.885
9.099
9.314
9.528
9.743
9.957
10.172
10.386
10.601
10.815
11.030
11.244
11.459
11.673
11.888
12.102
12.317
12.531
2.062
4.096
5.525
7.286
7.927
8.814
9.232
9.416
9.621
9.934
10.082
9.965
9.830
9.899
10.000
10.103
10.303
10.276
10.528
10.767
11.154
11.741
12.628
13.561
14.975
16.013
16.901
18.096
18.493
19.178
19.601
19.533
19.937
19.905
20.061
20.035
19.898
19.967
20.080
20.124
20.392
20.669
20.957
21.466
22.268
23.846
26.246
30.102
36.548
49.894
2.087
2.250
2.404
2.645
2.902
2.946
3.355
3.471
3.516
4.165
5.296
4.528
4.056
4.350
4.698
5.260
5.627
5.536
5.818
6.101
6.287
6.522
6.818
6.951
7.220
7.320
7.478
7.775
7.854
8.267
8.311
8.525
9.263
9.171
9.883
9.922
9.167
9.475
10.083
10.391
10.760
10.950
10.875
11.263
11.406
11.684
11.774
12.071
12.508
12.573
9.540E-03
5.822E-03
3.553E-03
2.168E-03
1.323E-03
8.073E-04
4.927E-04
3.006E-04
1.835E-04
1.120E-04
6.832E-05
4.169E-05
2.544E-05
1.552E-05
9.474E-06
5.781E-06
3.528E-06
2.153E-06
1.314E-06
8.017E-07
4.892E-07
2.985E-07
1.822E-07
1.112E-07
6.784E-08
4.140E-08
2.526E-08
1.542E-08
9.408E-09
5.741E-09
3.503E-09
2.138E-09
1.305E-09
7.961E-10
4.858E-10
2.965E-10
1.809E-10
1.104E-10
6.737E-11
4.111E-11
2.509E-11
1.531E-11
9.342E-12
5.701E-12
3.479E-12
2.123E-12
1.296E-12
7.906E-13
4.824E-13
2.944E-13
1.354E-01
1.245E-01
1.165E-01
1.108E-01
1.069E-01
1.044E-01
1.027E-01
1.017E-01
1.010E-01
1.006E-01
1.004E-01
1.002E-01
1.001E-01
9.995E-02
9.983E-02
9.967E-02
9.944E-02
9.907E-02
9.850E-02
9.763E-02
9.633E-02
9.450E-02
9.209E-02
8.922E-02
8.615E-02
8.323E-02
8.076E-02
7.886E-02
7.751E-02
7.659E-02
7.599E-02
7.561E-02
7.537E-02
7.521E-02
7.511E-02
7.503E-02
7.497E-02
7.489E-02
7.478E-02
7.463E-02
7.438E-02
7.399E-02
7.336E-02
7.236E-02
7.081E-02
6.846E-02
6.500E-02
6.002E-02
5.296E-02
4.286E-02
9.026E-01
8.300E-01
7.766E-01
7.386E-01
7.127E-01
6.957E-01
6.847E-01
6.778E-01
6.735E-01
6.708E-01
6.690E-01
6.679E-01
6.671E-01
6.664E-01
6.656E-01
6.645E-01
6.629E-01
6.605E-01
6.567E-01
6.508E-01
6.422E-01
6.300E-01
6.139E-01
5.948E-01
5.743E-01
5.549E-01
5.384E-01
5.258E-01
5.167E-01
5.106E-01
5.066E-01
5.041E-01
5.025E-01
5.014E-01
5.007E-01
5.002E-01
4.998E-01
4.993E-01
4.986E-01
4.975E-01
4.959E-01
4.932E-01
4.890E-01
4.824E-01
4.721E-01
4.564E-01
4.333E-01
4.001E-01
3.531E-01
2.857E-01
cido
carbnico
0
0
mes de titulado / titulante (mL)
Soma
(Vol inicial)
20.00
N de adies
SS
5.000E-03
1.500E-02
57
cido / Base
cido EDTA
cido fosfrico
cido l-glutmico
Carga de B
pKa1
pKa2
pKa3
pKa4
pKa5
pKa6
-4
0.000
1.500
2.000
2.680
6.110
10.170
13.997
-3
2.148
7.199
12.350
-2
2.230
4.420
9.950
pKw
Simulao de disperso
S pH=
S Vol=
0.100
0.100
Velocidade de titulao
Menor
Maior
0
pausa (s)
30.0
Volume de titulante (mL)
fatores de diluio
Titulante
(bureta)
0.000E+00
40.0
50.0
60.0
h1
h2
h3
h4
cido EDTA
cido fosfrico
cido l-glutmico
cido actico
2.6873
h5
Hidrxido de
amnio
9.735E-02
1.700E-01
2.234E-01
2.614E-01
2.873E-01
3.043E-01
3.153E-01
3.222E-01
3.265E-01
3.292E-01
3.310E-01
3.321E-01
3.329E-01
3.336E-01
3.344E-01
3.355E-01
3.371E-01
3.395E-01
3.433E-01
3.492E-01
3.578E-01
3.700E-01
3.861E-01
4.052E-01
4.257E-01
4.451E-01
4.616E-01
4.742E-01
4.833E-01
4.894E-01
4.934E-01
4.959E-01
4.975E-01
4.986E-01
4.993E-01
4.998E-01
5.002E-01
5.007E-01
5.014E-01
5.025E-01
5.041E-01
5.068E-01
5.110E-01
5.176E-01
5.279E-01
5.436E-01
5.667E-01
5.999E-01
6.469E-01
7.143E-01
2.5729
2.4501
2.3331
2.2336
2.1568
2.1019
2.0647
2.0403
2.0248
2.0149
2.0086
2.0043
2.0011
1.9981
1.9947
1.9900
1.9829
1.9718
1.9543
1.9270
1.8856
1.8252
1.7423
1.6374
1.5176
1.3956
1.2854
1.1960
1.1295
1.0831
1.0524
1.0325
1.0199
1.0119
1.0067
1.0032
1.0004
0.9977
0.9945
0.9899
0.9829
0.9719
0.9545
0.9274
0.8863
0.8262
0.7436
0.6390
0.5192
0.3973
cido actico
Hidrxido de
amnio
cido clordrico
cido carbnico
cido forte
-1
4.757
0
9.244
-1
-7.000
-2
6.352
10.329
-1
-6
h2 titulante
Base forte
h3 titulante
c. carbnico
cdigo de cores
No altere
Mude crIterosamente
Preencha, altere ou deixe em branco
h6
h7
cido clordrico
cido carbnico
h1 titulante
cido forte
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
0.9999
0.9999
0.9999
0.9998
0.9996
0.9994
Titulado
c. carbnico cido / Base
-2
6.352
10.329
Carga de B
bp1
bp2
bp3
bp4
bp5
bp6
Kw
-3
2.239E+12
3.540E+19
4.977E+21
cido lglutmico
-2
8.913E+09
2.344E+14
3.981E+16
cido actico
Hidrxido de
amnio
cido
clordrico
cido
carbnico
-1
5.715E+04
0
1.754E+09
-1
1.000E-07
-2
2.133E+10
4.797E+16
cido forte
Base forte
-1
1.000E-06
-1
5.559E+15
cido / Base
-2
2.133E+10
4.797E+16
Carga de B
pKa1 = logKpn
pKa2 = logKpn-1
pKa3 = logKpn-2
pKa4 = logKpn-3
pKa5 = logKpn-4
pKa6 = logKpn-5
-3
2.148
7.199
12.350
-1
3.831
-1
4.757
cido
clordrico
cido
carbnico
0
9.244
-1
-7.000
-2
6.352
10.329
3.164802
5.550821
7.204449
8.284732
8.963467
9.379517
9.6307
9.780957
9.870347
9.923351
9.954719
9.973262
9.984215
9.990683
9.994501
9.996755
9.998085
9.99887
9.999334
9.999609
9.999772
9.99987
9.99993
9.999971
10
10.00004
10.00008
10.00015
10.00026
10.00045
10.00076
10.00129
10.00219
10.00371
10.00628
10.01065
10.01805
10.0306
10.05188
10.08802
10.14946
10.25414
10.4332
10.74151
11.27848
12.23258
13.9896
17.44934
25.2575
50
Vol
2
pH
2
0 1.838538
Vol
3
pH
3
0
1.30103
Vol
4
pH
4
Vol
5
pH
5
1.530077
1.759125
1.988172
2.21722
2.446267
2.675315
2.904362
3.13341
3.362457
3.591505
3.820552
4.0496
4.278647
4.507695
4.736742
4.96579
5.194837
5.423885
5.652932
5.88198
6.111027
6.340075
6.569122
6.79817
7.027217
7.256265
7.485312
7.71436
7.943407
8.172455
8.401502
8.63055
8.859597
9.088645
9.317692
9.54674
9.775787
10.00483
10.23388
10.46293
10.69198
10.92102
11.15007
11.37912
11.60817
11.83721
12.06626
12.29531
12.52436
12.7534
2.049407
3.938869
5.618284
7.032329
8.170884
9.08299
9.858687
10.60375
11.41871
12.37769
13.50223
14.74101
15.98032
17.09362
17.99712
18.67074
19.14162
19.45613
19.65993
19.78955
19.87128
19.92293
19.95629
19.97918
19.99705
20.01421
20.0348
20.06374
20.10787
20.17736
20.28762
20.46167
20.73226
21.1421
21.7385
22.55746
23.59709
24.79377
26.02813
27.17152
28.14247
28.93161
29.59039
30.21046
30.91664
31.88401
33.38986
35.93712
40.57981
50
2.050888
2.263239
2.475589
2.687939
2.900289
3.112639
3.32499
3.53734
3.74969
3.96204
4.174391
4.386741
4.599091
4.811441
5.023791
5.236142
5.448492
5.660842
5.873192
6.085542
6.297893
6.510243
6.722593
6.934943
7.147293
7.359644
7.571994
7.784344
7.996694
8.209045
8.421395
8.633745
8.846095
9.058445
9.270796
9.483146
9.695496
9.907846
10.1202
10.33255
10.5449
10.75725
10.9696
11.18195
11.3943
11.60665
11.819
12.03135
12.2437
12.45605
3.165531
5.551868
7.205499
8.285625
8.964158
9.380021
9.631052
9.781198
9.870507
9.923457
9.954788
9.973306
9.984243
9.990701
9.994512
9.996762
9.99809
9.998873
9.999336
9.99961
9.999772
9.99987
9.999931
9.999971
10
10.00004
10.00008
10.00015
10.00026
10.00045
10.00076
10.00129
10.00218
10.0037
10.00627
10.01063
10.01802
10.03054
10.0518
10.0879
10.14927
10.25386
10.43277
10.74088
11.27756
12.23125
13.98773
17.44677
25.25432
50
1.530137
1.759245
1.988352
2.21746
2.446567
2.675675
2.904782
3.13389
3.362997
3.592105
3.821212
4.05032
4.279427
4.508535
4.737642
4.96675
5.195857
5.424965
5.654072
5.88318
6.112287
6.341395
6.570502
6.79961
7.028717
7.257825
7.486932
7.71604
7.945147
8.174255
8.403362
8.63247
8.861577
9.090685
9.319792
9.5489
9.778007
10.00711
10.23622
10.46533
10.69444
10.92354
11.15265
11.38176
11.61087
11.83997
12.06908
12.29819
12.5273
12.7564
Vol
6
pH
6
Vol
7
pH
7
Vol
8
pH
8
Vol
9
pH
9
Vol
10
pH
10
Vol
11
pH
11
Vol
12
pH
12
Vol
13
pH
13
de protonao
pKa1 = logKpn
2.148
b1
do sistema cido/base
pKa2 = logKpn-1
7.199
b2
cido fosfrico
pKa3 = logKpn-2
12.350
b3
a) em funo do pH e b) sobrepostas
pKa4 = logKpn-3
b4
pKa5 = logKpn-4
b5
pKa6 = logKpn-5
b6
Carga de B
-3
>aHiB
n protonaes
a B <
1.00
0.80
ai
0.60
0.40
0.20
0.00
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
9.0
10.0
11.0
pH
Distribuio das espcies HiB
0.00
-1.00
log ai
-2.00
-3.00
-4.00
-5.00
-6.00
-7.00
< aHiB
aB>
-7.00
-8.00
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
9.0
10.0
11.0
12.0
11.0
12.0
pH
3.5
3.0
h mdio
2.5
2.0
1.5
1.0
0.5
0.0
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
pH
8.0
9.0
10.0
bp
aB
2.239E+12
a HB
3.540E+19
a H 2B
4.977E+21
a H 3B
a H 4B
a H 5B
a H 6B
3
1.00
0.80
ai
0.60
0.40
0.20
0.00
12.0
13.0
14.0
0.0
10.0
20.0
30.0
Volume (mL)
0.00
-1.00
-2.00
log ai
11.0
-3.00
-4.00
-5.00
-6.00
-7.00
<
-7.00
12.0
13.0
-8.00
14.0
0.0
10.0
20.0
30.0
Volume (mL)
11.0
1.5
1.0
0.5
0.0
12.0
13.0
14.0
0.0
10.0
20.0
30.0
Volume (mL)
< aHiB
pH
aB>
14
pH
7
30.0
40.0
50.0
60.0
Volume (mL)
< aHiB
aB>
14
pH
7
0.000
0.200
0.400
0.600
0.800
1.000
1.200
1.400
1.600
1.800
2.000
2.200
2.400
2.600
2.800
3.000
3.200
3.400
3.600
3.800
4.000
4.200
4.400
4.600
4.800
5.000
5.200
5.400
5.600
5.800
6.000
6.200
6.400
6.600
6.800
7.000
7.200
7.400
7.600
7.800
8.000
h mdio
2.993
2.989
2.982
2.972
2.957
2.934
2.899
2.848
2.779
2.690
2.584
2.470
2.359
2.261
2.182
2.123
2.081
2.053
2.034
2.021
2.013
2.008
2.004
2.001
1.998
1.995
1.991
1.985
1.976
1.962
1.941
1.909
1.863
1.799
1.715
1.613
1.499
1.386
1.284
1.200
1.136
alfa 0
alfa 1
HB
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
0.001
0.002
0.003
0.004
0.006
0.010
0.016
0.025
0.038
0.059
0.091
0.137
0.201
0.285
0.387
0.501
0.614
0.716
0.800
0.863
30.0
40.0
50.0
60.0
Volume (mL)
base na titulao
14
pH
7
30.0
Volume (mL)
40.0
50.0
60.0
8.200
8.400
8.600
8.800
9.000
9.200
9.400
9.600
9.800
10.000
10.200
10.400
10.600
10.800
11.000
11.200
11.400
11.600
11.800
12.000
12.200
12.400
12.600
12.800
13.000
13.200
13.400
13.600
13.800
14.000
1.091
1.059
1.038
1.024
1.015
1.009
1.005
1.002
1.000
0.997
0.994
0.990
0.983
0.973
0.957
0.934
0.899
0.849
0.780
0.691
0.586
0.471
0.360
0.262
0.183
0.124
0.082
0.053
0.034
0.022
0.000
0.000
0.000
0.000
0.000
0.001
0.001
0.002
0.003
0.004
0.007
0.011
0.017
0.027
0.043
0.066
0.101
0.151
0.220
0.309
0.414
0.529
0.640
0.738
0.817
0.876
0.918
0.947
0.966
0.978
0.909
0.941
0.962
0.975
0.984
0.989
0.993
0.994
0.995
0.994
0.992
0.988
0.982
0.972
0.957
0.934
0.899
0.849
0.780
0.691
0.585
0.471
0.360
0.262
0.183
0.124
0.082
0.053
0.034
0.022
da espcie em funo do pH
alfa 2
alfa 3
alfa 4
alfa 5
alfa 6
H2B
H3B
H4B
H5B
H6B
0.007
0.011
0.018
0.028
0.043
0.066
0.101
0.152
0.221
0.310
0.416
0.530
0.641
0.739
0.818
0.877
0.918
0.947
0.966
0.978
0.986
0.990
0.993
0.994
0.994
0.992
0.989
0.984
0.975
0.961
0.940
0.909
0.863
0.799
0.715
0.613
0.499
0.386
0.284
0.200
0.137
0.993
0.989
0.982
0.972
0.957
0.934
0.899
0.848
0.779
0.690
0.584
0.470
0.359
0.261
0.182
0.123
0.081
0.053
0.034
0.022
0.014
0.009
0.006
0.004
0.002
0.001
0.001
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Vol
pH
0.000
2.157
4.096
5.754
7.077
8.061
8.749
9.210
9.508
9.697
9.817
9.894
9.944
9.982
10.014
10.050
10.098
10.170
10.282
10.457
10.730
11.144
11.748
12.577
13.626
14.824
16.044
17.146
18.041
18.706
19.169
19.478
19.677
19.804
19.886
19.941
19.982
20.018
20.059
20.115
20.200
1.806
2.020
2.235
2.449
2.664
2.878
3.093
3.307
3.522
3.736
3.951
4.165
4.380
4.594
4.809
5.023
5.238
5.452
5.667
5.881
6.096
6.310
6.525
6.739
6.954
7.168
7.383
7.598
7.812
8.027
8.241
8.456
8.670
8.885
9.099
9.314
9.528
9.743
9.957
10.172
10.386
h mdio
2.687
2.573
2.450
2.333
2.234
2.157
2.102
2.065
2.040
2.025
2.015
2.009
2.004
2.001
1.998
1.995
1.990
1.983
1.972
1.954
1.927
1.886
1.825
1.742
1.637
1.518
1.396
1.285
1.196
1.129
1.083
1.052
1.032
1.020
1.012
1.007
1.003
1.000
0.998
0.994
0.990
0.091
0.059
0.038
0.024
0.016
0.010
0.006
0.004
0.002
0.002
0.001
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
20.333
20.548
20.896
21.459
22.365
23.818
26.155
29.983
36.644
50.000
10.601
10.815
11.030
11.244
11.459
11.673
11.888
12.102
12.317
12.531
0.983
0.972
0.955
0.927
0.886
0.826
0.744
0.639
0.519
0.397
titulao simulada
titulao da Anlise I
alfa 1
alfa 2
alfa 3
alfa 4
alfa 5
alfa 6
escala
HB
H2B
H3B
H4B
H5B
H6B
pH/14
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
0.001
0.001
0.002
0.004
0.007
0.011
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
0.001
0.002
0.002
0.004
0.007
0.011
0.018
0.029
0.046
0.073
0.114
0.175
0.258
0.363
0.482
0.604
0.715
0.804
0.870
0.917
0.947
0.967
0.979
0.987
0.991
0.994
0.995
0.994
0.992
0.989
0.313
0.427
0.550
0.667
0.766
0.843
0.898
0.935
0.959
0.975
0.984
0.990
0.993
0.994
0.994
0.992
0.988
0.982
0.971
0.954
0.927
0.885
0.825
0.742
0.637
0.518
0.396
0.285
0.196
0.129
0.083
0.052
0.033
0.020
0.012
0.008
0.005
0.003
0.002
0.001
0.001
0.687
0.573
0.450
0.333
0.234
0.157
0.102
0.065
0.041
0.025
0.015
0.010
0.006
0.004
0.002
0.001
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.129
0.144
0.160
0.175
0.190
0.206
0.221
0.236
0.252
0.267
0.282
0.298
0.313
0.328
0.343
0.359
0.374
0.389
0.405
0.420
0.435
0.451
0.466
0.481
0.497
0.512
0.527
0.543
0.558
0.573
0.589
0.604
0.619
0.635
0.650
0.665
0.681
0.696
0.711
0.727
0.742
0.017
0.028
0.046
0.073
0.114
0.174
0.256
0.361
0.481
0.603
0.982
0.971
0.954
0.927
0.886
0.826
0.744
0.639
0.519
0.397
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.757
0.773
0.788
0.803
0.818
0.834
0.849
0.864
0.880
0.895
n*pH/14
0.387
0.433
0.479
0.525
0.571
0.617
0.663
0.709
0.755
0.801
0.847
0.893
0.939
0.985
1.030
1.076
1.122
1.168
1.214
1.260
1.306
1.352
1.398
1.444
1.490
1.536
1.582
1.628
1.674
1.720
1.766
1.812
1.858
1.904
1.950
1.996
2.042
2.088
2.134
2.180
2.226
pH
0.000
0.200
0.400
0.600
0.800
1.000
1.200
1.400
1.600
1.800
2.000
2.200
2.400
2.600
2.800
3.000
3.200
3.400
3.600
3.800
4.000
4.200
4.400
4.600
4.800
5.000
5.200
5.400
5.600
5.800
6.000
6.200
6.400
6.600
6.800
7.000
7.200
7.400
7.600
7.800
8.000
pOH
14.000
13.800
13.600
13.400
13.200
13.000
12.800
12.600
12.400
12.200
12.000
11.800
11.600
11.400
11.200
11.000
10.800
10.600
10.400
10.200
10.000
9.800
9.600
9.400
9.200
9.000
8.800
8.600
8.400
8.200
8.000
7.800
7.600
7.400
7.200
7.000
6.800
6.600
6.400
6.200
6.000
log alfa 0
log alfa 1
log alfa 2
log alfa 3
log alfa 4
HB
H2B
H3B
H4B
-21.700
-21.102
-20.505
-19.909
-19.316
-18.727
-18.143
-17.568
-17.005
-16.458
-15.930
-15.425
-14.942
-14.480
-14.036
-13.606
-13.186
-12.773
-12.364
-11.959
-11.555
-11.153
-10.752
-10.352
-9.952
-9.552
-9.154
-8.756
-8.360
-7.966
-7.576
-7.190
-6.813
-6.446
-6.095
-5.762
-5.450
-5.162
-4.895
-4.647
-4.414
-9.350
-8.952
-8.555
-8.159
-7.766
-7.377
-6.993
-6.618
-6.255
-5.908
-5.580
-5.275
-4.992
-4.730
-4.486
-4.256
-4.036
-3.823
-3.614
-3.409
-3.205
-3.003
-2.802
-2.602
-2.402
-2.202
-2.004
-1.806
-1.610
-1.416
-1.226
-1.041
-0.863
-0.697
-0.545
-0.412
-0.301
-0.212
-0.145
-0.097
-0.064
-2.151
-1.953
-1.756
-1.560
-1.367
-1.178
-0.994
-0.819
-0.656
-0.509
-0.381
-0.276
-0.193
-0.131
-0.087
-0.057
-0.037
-0.024
-0.015
-0.010
-0.006
-0.004
-0.003
-0.003
-0.003
-0.003
-0.005
-0.007
-0.011
-0.017
-0.027
-0.042
-0.064
-0.098
-0.146
-0.213
-0.302
-0.413
-0.546
-0.698
-0.865
-0.003
-0.005
-0.008
-0.012
-0.019
-0.030
-0.046
-0.071
-0.108
-0.161
-0.233
-0.328
-0.445
-0.583
-0.739
-0.909
-1.089
-1.276
-1.467
-1.662
-1.858
-2.056
-2.255
-2.455
-2.655
-2.855
-3.057
-3.259
-3.463
-3.669
-3.879
-4.093
-4.316
-4.550
-4.798
-5.065
-5.353
-5.665
-5.998
-6.350
-6.717
2.272
2.318
2.363
2.409
2.455
2.501
2.547
2.593
2.639
2.685
8.200
8.400
8.600
8.800
9.000
9.200
9.400
9.600
9.800
10.000
10.200
10.400
10.600
10.800
11.000
11.200
11.400
11.600
11.800
12.000
12.200
12.400
12.600
12.800
13.000
13.200
13.400
13.600
13.800
14.000
5.800
5.600
5.400
5.200
5.000
4.800
4.600
4.400
4.200
4.000
3.800
3.600
3.400
3.200
3.000
2.800
2.600
2.400
2.200
2.000
1.800
1.600
1.400
1.200
1.000
0.800
0.600
0.400
0.200
0.000
-4.191
-3.977
-3.767
-3.561
-3.357
-3.155
-2.953
-2.752
-2.552
-2.353
-2.153
-1.955
-1.758
-1.562
-1.369
-1.180
-0.996
-0.821
-0.658
-0.510
-0.382
-0.277
-0.194
-0.132
-0.088
-0.057
-0.037
-0.024
-0.015
-0.010
-0.041
-0.027
-0.017
-0.011
-0.007
-0.005
-0.003
-0.002
-0.002
-0.003
-0.003
-0.005
-0.008
-0.012
-0.019
-0.030
-0.046
-0.071
-0.108
-0.160
-0.232
-0.327
-0.444
-0.582
-0.738
-0.907
-1.087
-1.274
-1.465
-1.660
-1.042
-1.228
-1.418
-1.612
-1.808
-2.006
-2.204
-2.403
-2.603
-2.804
-3.004
-3.206
-3.409
-3.613
-3.820
-4.031
-4.247
-4.472
-4.709
-4.961
-5.233
-5.528
-5.845
-6.183
-6.539
-6.908
-7.288
-7.675
-8.066
-8.461
-7.094
-7.480
-7.870
-8.264
-8.660
-9.058
-9.456
-9.855
-10.255
-10.656
-11.056
-11.458
-11.861
-12.265
-12.672
-13.083
-13.499
-13.924
-14.361
-14.813
-15.285
-15.780
-16.297
-16.835
-17.391
-17.960
-18.540
-19.127
-19.718
-20.312
H5B
H6B
Vol
pH
log alfa 0
log alfa 1
log alfa 2
log alfa 3
HB
H2B
H3B
-16.442
-15.878
-15.339
-14.826
-14.337
-13.866
-13.410
-12.963
-12.523
-12.087
-11.654
-11.223
-10.792
-10.363
-9.934
-9.505
-9.078
-8.652
-8.228
-7.806
-7.390
-6.981
-6.582
-6.199
-5.837
-5.498
-5.186
-4.898
-4.633
-4.384
-4.147
-3.918
-3.694
-3.474
-3.257
-3.040
-2.825
-2.610
-2.395
-2.182
-1.969
-5.898
-5.548
-5.224
-4.925
-4.651
-4.395
-4.153
-3.921
-3.695
-3.474
-3.255
-3.038
-2.822
-2.607
-2.393
-2.179
-1.966
-1.754
-1.545
-1.338
-1.136
-0.941
-0.757
-0.589
-0.441
-0.317
-0.219
-0.146
-0.095
-0.060
-0.038
-0.023
-0.015
-0.009
-0.006
-0.004
-0.003
-0.002
-0.003
-0.003
-0.005
-0.505
-0.369
-0.260
-0.176
-0.116
-0.074
-0.047
-0.029
-0.018
-0.011
-0.007
-0.005
-0.003
-0.003
-0.003
-0.003
-0.005
-0.008
-0.013
-0.020
-0.033
-0.053
-0.083
-0.129
-0.196
-0.286
-0.403
-0.544
-0.708
-0.888
-1.080
-1.280
-1.486
-1.695
-1.906
-2.118
-2.332
-2.546
-2.761
-2.976
-3.192
-0.163
-0.242
-0.347
-0.477
-0.632
-0.805
-0.992
-1.189
-1.392
-1.600
-1.810
-2.022
-2.235
-2.449
-2.664
-2.879
-3.095
-3.312
-3.532
-3.754
-3.981
-4.215
-4.460
-4.721
-5.002
-5.307
-5.638
-5.994
-6.372
-6.766
-7.173
-7.587
-8.008
-8.431
-8.857
-9.284
-9.712
-10.140
-10.570
-10.999
-11.430
-1.757
-1.548
-1.341
-1.139
-0.944
-0.760
-0.591
-0.442
-0.318
-0.220
-0.008
-0.013
-0.020
-0.033
-0.052
-0.083
-0.129
-0.195
-0.285
-0.401
-3.409
-3.629
-3.851
-4.078
-4.312
-4.557
-4.817
-5.098
-5.402
-5.733
-11.862
-12.296
-12.732
-13.174
-13.622
-14.082
-14.557
-15.052
-15.571
-16.116
H4B
H5B
H6B
escala
pH (-8 a 0)
-6.968
-6.845
-6.723
-6.600
-6.478
-6.355
-6.233
-6.110
-5.987
-5.865
-5.742
-5.620
-5.497
-5.375
-5.252
-5.129
-5.007
-4.884
-4.762
-4.639
-4.517
-4.394
-4.271
-4.149
-4.026
-3.904
-3.781
-3.659
-3.536
-3.413
-3.291
-3.168
-3.046
-2.923
-2.801
-2.678
-2.555
-2.433
-2.310
-2.188
-2.065
-1.943
-1.820
-1.697
-1.575
-1.452
-1.330
-1.207
-1.085
-0.962
-0.839
2.230
2.230
2.280
2.490
2.640
2.870
3.060
3.240
3.430
3.690
3.870
4.080
4.240
4.430
4.660
4.880
5.040
5.250
5.420
5.650
5.840
6.010
6.190
6.400
6.580
6.770
6.960
7.180
7.420
7.710
7.850
8.010
8.240
8.430
8.610
8.810
8.980
9.150
9.330
9.510
9.690
9.870
10.060
10.170
10.350
Vol interp.
pH ajust
dpH/dV
0.0000
0.6977
1.3953
2.0930
2.7907
3.4884
4.1860
4.8837
5.5814
6.2791
6.9767
7.6744
8.3721
9.0698
9.7674
10.4651
11.1628
11.8605
12.5581
13.2558
13.9535
14.6512
15.3488
16.0465
16.7442
17.4419
18.1395
18.8372
19.5349
20.2326
20.9302
21.6279
22.3256
23.0233
23.7209
24.4186
25.1163
25.8140
26.5116
27.2093
27.9070
28.6047
29.3023
30.0000
2.2149
2.2580
2.3084
2.3672
2.4353
2.5137
2.6064
2.7225
2.8792
3.0991
3.4081
3.8155
4.2929
4.8016
5.2906
5.6964
5.9997
6.2236
6.3977
6.5425
6.6733
6.8004
6.9309
7.0707
7.2253
7.4035
7.6184
7.8836
8.2093
8.5823
8.9544
9.2711
9.5148
9.6947
9.8269
9.9277
10.0087
10.0758
10.1340
10.1854
10.2316
10.2738
10.3134
10.3518
0.0592
0.0665
0.0781
0.0908
0.1047
0.1208
0.1468
0.1907
0.2637
0.3735
0.5157
0.6441
0.7155
0.7308
0.6530
0.5061
0.3700
0.2794
0.2244
0.1943
0.1829
0.1831
0.1924
0.2097
0.2356
0.2785
0.3409
0.4225
0.5081
0.5493
0.5022
0.4019
0.2999
0.2197
0.1631
0.1286
0.1047
0.0891
0.0781
0.0696
0.0630
0.0584
0.0556
0.0546
d pH/dV
0.0000
0.0082
0.0087
0.0095
0.0104
0.0144
0.0229
0.0418
0.0638
0.0928
0.1050
0.0722
0.0331
-0.0181
-0.0912
-0.1087
-0.0813
-0.0496
-0.0294
-0.0141
-0.0038
0.0037
0.0095
0.0152
0.0238
0.0377
0.0517
0.0645
0.0515
0.0004
-0.0621
-0.0781
-0.0658
-0.0491
-0.0321
-0.0201
-0.0141
-0.0088
-0.0070
-0.0053
-0.0040
-0.0027
-0.0013
0.0000
95
n ptos. interpolados
44
dados experimentais
12.000
10.000
8.000
pH
0.000
0.500
1.000
3.200
4.300
5.500
6.200
6.700
7.100
7.500
7.750
8.050
8.300
8.600
8.900
9.200
9.400
9.650
9.900
10.300
10.700
11.200
11.800
12.600
13.500
14.500
15.500
16.500
17.500
18.400
18.800
19.200
19.650
20.000
20.300
20.600
20.900
21.300
21.700
22.300
23.000
24.100
25.700
27.000
30.000
pH
(0 a 100%)
6.000
4.000
2.000
0.000
0.000
5.000
dpH/dV
Volume
Intensidade do alisamento
0.30
0.20
0.10
0.00
0.0000
5.0000
-0.10
-0.20
Vol. inflexo
1 8.8805
2 20.238
3
4
5
6
7
8
9
10
Resultado do exemplo:
0,0501 mol/L de H3PO4 e 0,0499 mol/L d
Isto porque metade do H2PO4- encontrad
Intervalo a analisar
Volume inicial
Volume final
dados experimentais
0.000
mximo
50.000
mnimo
cdigo de cores
Volume
dpH/dV
8.880458 0.734195
No
altere
Mude crIterosamente
Preencha, altere ou deixe em branco
dados alisados
15.000
20.000
25.000
30.000
35.000
25.0000
30.0000
35.0000
Volume (mL)
derivada dados alisados
10.0000
derivada 2
15.0000
20.0000
Volume (mL)
ambas as escalas)
n (mols)
0.000888046
0.00202376
delta n
0.000888
0.001136
[espcie]
0.0444023
0.0567857
Resultado do exemplo:
0,0501 mol/L de H3PO4 e 0,0499 mol/L de NaH2PO4
Isto porque metade do H2PO4- encontrado provm do H3PO4
cdigo de cores
No
altere
Mude crIterosamente
cido fosfrico
cido ascrbico
cido actico
1.25749E-09
1.63937E-05
0.004952765
0.034835294
0
0
0
0
0
0
0
0
0
0
1.41194E-13
0.000456023
0.030071735
0
0
0
0
0
0
0
0
0
0
0
S[HiB]
S[H] ligado
0.039804454
0.030527758
0.114427807
0.060599493
max. H livre
0.004985556
0.000456023
Titulante
cido forte
Base forte
c. carbnico
Espcie
[B]
[HB]
[H2B]
[H3B]
[H4B]
[H5B]
[H6B]
0.1
[B]
[HB]
Amostra
20
SS
[H2B]
S[HiB]
0.1
0.1
S[H]
14.00
12.00
10.00
pH
8.00
6.00
4.00
2.00
0.00
0.0
10.0
20.0
30.0
40.0
Vol. Adicion.
(mL)
0.000
0.897
1.864
2.961
4.198
5.548
6.970
8.440
9.958
11.528
13.142
14.769
16.357
17.845
19.182
20.352
21.384
22.343
23.297
24.292
25.326
26.348
27.280
28.063
28.670
29.112
29.419
29.625
29.761
29.849
29.906
29.944
29.969
29.988
30.004
30.021
30.043
30.073
30.120
30.192
30.304
30.479
30.749
31.161
31.777
32.681
33.983
35.846
38.567
42.781
50.000
pH medido
pH ajustado
por regresso
[H]
mol/L
dpH/dV
ou dimulado
2.2808
2.4714
2.6625
2.8606
3.0950
3.2735
3.4831
3.6744
3.8778
4.0878
4.2595
4.4838
4.6824
4.8894
5.0960
5.2953
5.5012
5.6876
5.8781
6.0934
6.3069
6.4902
6.6985
6.8921
7.0866
7.3027
7.5183
7.7039
7.9083
8.1150
8.2506
8.5723
8.6735
8.9492
9.1846
9.2019
9.5546
9.7397
9.9213
10.1181
10.3403
10.5265
10.7167
10.9218
11.1236
11.3351
11.5157
11.7421
11.9191
12.1346
12.3300
2.2699
2.4715
2.6733
2.8750
3.0766
3.2779
3.4790
3.6798
3.8803
4.0807
4.2811
4.4816
4.6823
4.8829
5.0835
5.2841
5.4851
5.6867
5.8889
6.0913
6.2936
6.4957
6.6975
6.8993
7.1010
7.3027
7.5045
7.7066
7.9090
8.1121
8.3161
8.5212
8.7271
8.9322
9.1337
9.3312
9.5273
9.7241
9.9221
10.1213
10.3212
10.5216
10.7223
10.9232
11.1243
11.3254
11.5268
11.7283
11.9302
12.1324
12.3347
5.24E-03
3.38E-03
2.18E-03
1.38E-03
8.04E-04
5.33E-04
3.29E-04
2.12E-04
1.32E-04
8.17E-05
5.50E-05
3.28E-05
2.08E-05
1.29E-05
8.02E-06
5.07E-06
3.15E-06
2.05E-06
1.32E-06
8.06E-07
4.93E-07
3.23E-07
2.00E-07
1.28E-07
8.19E-08
4.98E-08
3.03E-08
1.98E-08
1.24E-08
7.67E-09
5.62E-09
2.68E-09
2.12E-09
1.12E-09
6.54E-10
6.28E-10
2.79E-10
1.82E-10
1.20E-10
7.62E-11
4.57E-11
2.97E-11
1.92E-11
1.20E-11
7.52E-12
4.62E-12
3.05E-12
1.81E-12
1.20E-12
7.34E-13
4.68E-13
2.12E-01
2.05E-01
1.89E-01
1.85E-01
1.60E-01
1.40E-01
1.39E-01
1.32E-01
1.34E-01
1.20E-01
1.22E-01
1.32E-01
1.32E-01
1.46E-01
1.62E-01
1.84E-01
1.97E-01
1.97E-01
2.08E-01
2.11E-01
1.93E-01
2.00E-01
2.34E-01
2.79E-01
3.91E-01
5.76E-01
7.81E-01
1.14E+00
1.84E+00
2.36E+00
4.84E+00
6.74E+00
8.55E+00
1.47E+01
7.63E+00
9.60E+00
1.03E+01
4.75E+00
3.19E+00
2.27E+00
1.42E+00
8.46E-01
5.80E-01
3.96E-01
2.72E-01
1.78E-01
1.29E-01
8.80E-02
5.66E-02
3.59E-02
2.71E-02
o II Regresso
cido carbnico
cido clordrico
cido / Base
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
SS
Carga de B
pKa1
pKa2
pKa3
pKa4
pKa5
pKa6
7.033E-02
SS[bases]
1.750E-01
SS[H] ligado
5.442E-03
5.027E-05
Total
20.00
-p[H]
SS[HiB]
pH
12.996
[H]=10
[OH]=Kw/[H]
5.238E-03
CHcalc inicial
1.803E-01
CHRNL inicial
1.805E-01
1.293E-06
S(CHR-CHcalc) W
expoente a
1.922E-12
2.000
2.281
11.716
expoente b
6.0E-04
4.0E-04
CHReg-CHcalc
2.0E-04
0.0E+00
-2.0E-04
-4.0E-04
-6.0E-04
0.0
10.0
20.0
30.0
Vol. titulante (mL)
1.0E-01
5.0E-02
pHReg-pH
SS [H]
0.0E+00
-5.0E-02
-1.0E-01
-1.5E-01
50.0
60.0
0.0
10.0
20.0
30.0
Vol. titulante (mL)
Planilha preparada para 100 pontos. Estender colunas da linha 141 at 200 para at 160 pontos (mais lento) e trocar 141 por 200
Resduo
CHReg-CHcalc
CHRNL
ponderado
mol/L
mol/L
CHcalc
mol/L
6.440E-08
8.885E-12
6.589E-08
1.352E-07
2.472E-07
1.431E-08
1.222E-08
1.968E-08
3.935E-09
3.272E-08
2.799E-07
2.585E-09
1.102E-11
1.456E-08
3.942E-08
2.260E-08
3.569E-08
9.438E-11
1.420E-08
5.686E-10
2.263E-08
3.408E-09
7.277E-11
2.662E-09
5.963E-09
5.640E-15
1.175E-09
2.058E-11
6.090E-13
3.970E-12
9.866E-10
2.069E-10
1.335E-10
7.869E-12
6.829E-11
5.219E-10
5.161E-11
3.582E-11
2.200E-13
7.931E-12
7.237E-10
1.117E-10
3.220E-10
4.864E-11
1.929E-11
9.528E-09
2.291E-08
6.786E-08
7.917E-08
6.367E-09
6.234E-08
2.538E-04
-2.981E-06
-2.567E-04
-3.677E-04
4.972E-04
-1.196E-04
1.105E-04
-1.403E-04
-6.273E-05
1.809E-04
-5.291E-04
5.084E-05
3.319E-06
1.207E-04
1.985E-04
1.503E-04
1.889E-04
9.715E-06
-1.191E-04
2.385E-05
1.504E-04
-5.838E-05
8.530E-06
-5.160E-05
-7.722E-05
7.510E-08
3.428E-05
-4.537E-06
-7.804E-07
1.992E-06
-3.141E-05
1.438E-05
-1.155E-05
2.805E-06
8.263E-06
-2.285E-05
7.184E-06
5.985E-06
-4.691E-07
-2.816E-06
2.690E-05
1.057E-05
-1.794E-05
-6.975E-06
-4.392E-06
9.761E-05
-1.514E-04
2.605E-04
-2.814E-04
7.979E-05
-2.497E-04
1.81E-01
1.73E-01
1.65E-01
1.57E-01
1.49E-01
1.41E-01
1.34E-01
1.27E-01
1.21E-01
1.15E-01
1.09E-01
1.04E-01
9.93E-02
9.54E-02
9.21E-02
8.95E-02
8.72E-02
8.53E-02
8.34E-02
8.15E-02
7.97E-02
7.79E-02
7.64E-02
7.51E-02
7.42E-02
7.35E-02
7.31E-02
7.28E-02
7.26E-02
7.24E-02
7.23E-02
7.23E-02
7.23E-02
7.22E-02
7.22E-02
7.22E-02
7.21E-02
7.21E-02
7.20E-02
7.19E-02
7.18E-02
7.15E-02
7.11E-02
7.06E-02
6.97E-02
6.85E-02
6.69E-02
6.46E-02
6.16E-02
5.75E-02
5.16E-02
1.80E-01
1.73E-01
1.65E-01
1.58E-01
1.49E-01
1.41E-01
1.34E-01
1.27E-01
1.21E-01
1.14E-01
1.09E-01
1.04E-01
9.93E-02
9.53E-02
9.19E-02
8.93E-02
8.71E-02
8.53E-02
8.35E-02
8.15E-02
7.95E-02
7.80E-02
7.64E-02
7.52E-02
7.43E-02
7.35E-02
7.30E-02
7.28E-02
7.26E-02
7.24E-02
7.24E-02
7.23E-02
7.23E-02
7.22E-02
7.22E-02
7.22E-02
7.21E-02
7.21E-02
7.20E-02
7.19E-02
7.17E-02
7.15E-02
7.12E-02
7.06E-02
6.97E-02
6.84E-02
6.70E-02
6.44E-02
6.19E-02
5.74E-02
5.18E-02
24
cido ctrico
cido fosfrico
cido ascrbico
cido actico
Hidrxido de
amnio
-3
3.128
4.761
6.396
-3
2.148
7.199
12.350
-2
4.100
11.790
-1
4.757
0
9.244
"pOH" inicial
A
b
+ opcionalmente, pKas
b
0.000
W =(dpH/dVol)
CH,calc)
40.0
50.0
60.0
20 para atualizar
40.0
Vol. titulante (mL)
50.0
60.0
para at 160 pontos (mais lento) e trocar 141 por 200 na frmula de I19
Dil ttlante.
0.0000
0.0429
0.0853
0.1289
0.1735
0.2172
0.2584
0.2968
0.3324
0.3656
0.3965
0.4248
0.4499
0.4715
0.4896
0.5044
0.5167
0.5277
0.5381
0.5485
0.5588
0.5685
0.5770
0.5839
0.5891
0.5928
0.5953
0.5970
0.5981
0.5988
0.5992
0.5995
0.5998
0.5999
0.6000
0.6002
0.6003
0.6006
0.6010
0.6015
0.6024
0.6038
0.6059
0.6091
0.6137
0.6204
0.6295
0.6419
0.6585
0.6814
0.7143
Dil ttlado.
1.0000
0.9571
0.9147
0.8711
0.8265
0.7828
0.7416
0.7032
0.6676
0.6344
0.6035
0.5752
0.5501
0.5285
0.5104
0.4956
0.4833
0.4723
0.4619
0.4515
0.4412
0.4315
0.4230
0.4161
0.4109
0.4072
0.4047
0.4030
0.4019
0.4012
0.4008
0.4005
0.4002
0.4001
0.4000
0.3998
0.3997
0.3994
0.3990
0.3985
0.3976
0.3962
0.3941
0.3909
0.3863
0.3796
0.3705
0.3581
0.3415
0.3186
0.2857
den1
den2
den3
cido ctrico
cido fosfrico
cido ascrbico
3.165E+07
9.072E+06
2.669E+06
7.812E+05
1.947E+05
7.119E+04
2.318E+04
8.784E+03
3.298E+03
1.267E+03
6.045E+02
2.442E+02
1.164E+02
5.742E+01
3.028E+01
1.732E+01
1.028E+01
6.717E+00
4.547E+00
3.101E+00
2.263E+00
1.820E+00
1.504E+00
1.321E+00
1.205E+00
1.124E+00
1.076E+00
1.049E+00
1.031E+00
1.019E+00
1.014E+00
1.007E+00
1.005E+00
1.003E+00
1.002E+00
1.002E+00
1.001E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.687E+15
5.956E+14
2.188E+14
8.031E+13
2.544E+13
1.080E+13
4.004E+12
1.633E+12
6.332E+11
2.391E+11
1.081E+11
3.839E+10
1.537E+10
5.932E+09
2.296E+09
9.205E+08
3.593E+08
1.539E+08
6.502E+07
2.483E+07
9.720E+06
4.429E+06
1.867E+06
8.688E+05
4.210E+05
1.993E+05
1.004E+05
5.812E+04
3.305E+04
1.927E+04
1.369E+04
6.249E+03
4.908E+03
2.562E+03
1.480E+03
1.421E+03
6.281E+02
4.098E+02
2.698E+02
1.718E+02
1.033E+02
6.763E+01
4.399E+01
2.781E+01
1.784E+01
1.135E+01
7.829E+00
5.054E+00
3.697E+00
2.642E+00
2.047E+00
2.162E+11
9.063E+10
3.808E+10
1.560E+10
5.508E+09
2.531E+09
1.042E+09
4.782E+08
2.179E+08
1.022E+08
5.742E+07
2.860E+07
1.616E+07
9.247E+06
5.442E+06
3.323E+06
2.022E+06
1.299E+06
8.299E+05
5.023E+05
3.061E+05
2.003E+05
1.238E+05
7.917E+04
5.057E+04
3.073E+04
1.870E+04
1.220E+04
7.617E+03
4.733E+03
3.464E+03
1.652E+03
1.309E+03
6.941E+02
4.041E+02
3.883E+02
1.730E+02
1.133E+02
7.490E+01
4.798E+01
2.917E+01
1.934E+01
1.284E+01
8.383E+00
5.638E+00
3.850E+00
2.881E+00
2.117E+00
1.743E+00
1.452E+00
1.288E+00
Constantes cumulativas de
Titulante
cido carbnico
cido clordrico
cido forte
Base forte
-2
6.352
10.329
-1
-7.000
-1
-6
-1
15.745
-2
6.352
10.329
Titulado
Titulante
0.000000
0.000000
0.000000
0.000000
bp1
bp2
bp3
pKw
13.9970
alibrao do sensor de pH
7.0000
100.00%
Carga de B
bp1
bp2
bp3
bp4
bp5
bp6
(z = carga do on)
1/2.SCkzk = Ik
0.000000
0.000000
SzjCj
2
1/2.SCjzj = Ij
0.000204
0.099822
0.509
Mnimo
de contra-ons
0.000102
0.049911
0.300
para cidos/bases
carga contra-on
bp4
bp5
bp6
ons de cidos/bases
SziCi
-0.005442
0.000000
SziCi
= Ii
0.002737
0.000000
Szi Ci
I Total
I = Ii+Ij+Ik+IH
0.005458
0.099822
I aplicado
I em uso
0.000000
0.000000
1.000
1.000
[H ]
5.2381E-03
1.0087E-13
1.9223E-12
9.9822E-02
2.281
12.996
no pH da soluo
1/2.SCizi
gH
Coef. de ativid.
[OH ]
pH
"p[H]"
cdigo de cores
No
altere
Mude crIterosamente
Preencha, altere ou deixe em branco
Constantes cumu
den4
den5
den6
cido actico
Hidrxido de amnio
cido carbnico
3.003E+02
1.940E+02
1.253E+02
7.978E+01
4.692E+01
3.144E+01
1.979E+01
1.309E+01
8.571E+00
5.668E+00
4.144E+00
2.876E+00
2.187E+00
1.737E+00
1.458E+00
1.290E+00
1.180E+00
1.117E+00
1.076E+00
1.046E+00
1.028E+00
1.018E+00
1.011E+00
1.007E+00
1.005E+00
1.003E+00
1.002E+00
1.001E+00
1.001E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
9.187E+06
5.924E+06
3.815E+06
2.418E+06
1.409E+06
9.343E+05
5.766E+05
3.712E+05
2.324E+05
1.433E+05
9.649E+04
5.757E+04
3.644E+04
2.263E+04
1.406E+04
8.886E+03
5.532E+03
3.602E+03
2.323E+03
1.415E+03
8.662E+02
5.683E+02
3.522E+02
2.258E+02
1.447E+02
8.835E+01
5.417E+01
3.568E+01
2.266E+01
1.446E+01
1.085E+01
5.696E+00
4.719E+00
2.971E+00
2.147E+00
2.102E+00
1.489E+00
1.319E+00
1.210E+00
1.134E+00
1.080E+00
1.052E+00
1.034E+00
1.021E+00
1.013E+00
1.008E+00
1.005E+00
1.003E+00
1.002E+00
1.001E+00
1.001E+00
1.316E+12
5.473E+11
2.271E+11
9.119E+10
3.099E+10
1.362E+10
5.192E+09
2.153E+09
8.448E+08
3.219E+08
1.464E+08
5.238E+07
2.115E+07
8.260E+06
3.254E+06
1.339E+06
5.445E+05
2.460E+05
1.123E+05
4.841E+04
2.220E+04
1.192E+04
6.195E+03
3.524E+03
2.070E+03
1.182E+03
6.917E+02
4.416E+02
2.718E+02
1.675E+02
1.223E+02
5.845E+01
4.645E+01
2.504E+01
1.497E+01
1.442E+01
6.952E+00
4.886E+00
3.557E+00
2.625E+00
1.974E+00
1.635E+00
1.410E+00
1.255E+00
1.160E+00
1.099E+00
1.065E+00
1.039E+00
1.026E+00
1.016E+00
1.010E+00
den7
cido
clordrico
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
den1 tlante.
den2 tlante.
cido forte
Base forte
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
1.000E+00
2.912E+13
1.878E+13
1.209E+13
7.663E+12
4.467E+12
2.961E+12
1.828E+12
1.176E+12
7.365E+11
4.541E+11
3.058E+11
1.825E+11
1.155E+11
7.172E+10
4.456E+10
2.816E+10
1.753E+10
1.141E+10
7.360E+09
4.483E+09
2.742E+09
1.798E+09
1.113E+09
7.127E+08
4.554E+08
2.769E+08
1.685E+08
1.099E+08
6.866E+07
4.266E+07
3.122E+07
1.488E+07
1.179E+07
6.248E+06
3.634E+06
3.492E+06
1.550E+06
1.012E+06
6.663E+05
4.236E+05
2.539E+05
1.654E+05
1.067E+05
6.656E+04
4.182E+04
2.570E+04
1.696E+04
1.007E+04
6.698E+03
4.079E+03
2.601E+03
cido fosfrico
cido
ascrbico
cido actico
Hidrxido de
amnio
cido
carbnico
-3
2.489E+06
1.435E+11
1.928E+14
10E-10
10E-10
10E-10
-3
2.239E+12
3.540E+19
4.977E+21
10E-10
10E-10
10E-10
-2
6.166E+11
7.762E+15
10E-10
10E-10
10E-10
10E-10
-1
5.715E+04
10E-10
10E-10
10E-10
10E-10
10E-10
0
1.754E+09
10E-10
10E-10
10E-10
10E-10
10E-10
0.000000
-2
2.133E+10
4.797E+16
10E-10
10E-10
10E-10
10E-10
+
egH =
1.75E+09
2.13E+10
2.24E+12
6.17E+11
1.44E+11
3.54E+19
7.76E+15
5.71E+04
1.93E+14
4.98E+21
-0.004986
0.000000
-0.000456
0.000000
0.000000
0.000000
0.005018
0.000000
0.000456
0.000000
0.000000
0.000000
4.80E+16
den3 tlante.
c. carbnico
1.316E+12
5.473E+11
2.271E+11
9.119E+10
3.099E+10
1.362E+10
5.192E+09
2.153E+09
8.448E+08
3.219E+08
1.464E+08
5.238E+07
2.115E+07
8.260E+06
3.254E+06
1.339E+06
5.445E+05
2.460E+05
1.123E+05
4.841E+04
2.220E+04
1.192E+04
6.195E+03
3.524E+03
2.070E+03
1.182E+03
6.917E+02
4.416E+02
2.718E+02
1.675E+02
1.223E+02
5.845E+01
4.645E+01
2.504E+01
1.497E+01
1.442E+01
6.952E+00
4.886E+00
3.557E+00
2.625E+00
1.974E+00
1.635E+00
1.410E+00
1.255E+00
1.160E+00
1.099E+00
1.065E+00
1.039E+00
1.026E+00
1.016E+00
1.010E+00
h1
h2
2.424
2.322
2.234
2.162
2.101
2.070
2.044
2.029
2.018
2.011
2.007
2.003
2.000
1.997
1.993
1.988
1.981
1.970
1.955
1.927
1.886
1.837
1.760
1.670
1.564
1.441
1.324
1.238
1.163
1.108
1.081
1.040
1.032
1.017
1.010
1.009
1.003
1.000
0.998
0.995
0.991
0.986
0.978
0.964
0.944
0.912
0.872
0.802
0.730
0.622
0.512
h3
cido
ascrbico
1.985
1.977
1.965
1.946
1.910
1.870
1.805
1.727
1.625
1.507
1.409
1.292
1.207
1.140
1.092
1.060
1.038
1.025
1.016
1.010
1.006
1.004
1.003
1.002
1.001
1.001
1.000
1.000
1.000
1.000
1.000
0.999
0.999
0.999
0.998
0.997
0.994
0.991
0.987
0.979
0.966
0.948
0.922
0.881
0.823
0.740
0.653
0.528
0.426
0.311
0.224
h4
cido actico
0.997
0.995
0.992
0.987
0.979
0.968
0.949
0.924
0.883
0.824
0.759
0.652
0.543
0.424
0.314
0.225
0.153
0.105
0.070
0.044
0.027
0.018
0.011
0.007
0.005
0.003
0.002
0.001
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
h5
Hidrxido de
amnio
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
0.999
0.999
0.998
0.997
0.996
0.993
0.989
0.982
0.972
0.956
0.931
0.908
0.824
0.788
0.663
0.534
0.524
0.328
0.242
0.174
0.118
0.074
0.050
0.033
0.021
0.013
0.008
0.005
0.003
0.002
0.001
0.001
cido forte
Base forte
c. carbnico
cido / Base
cido ctrico
-1
1.000E-06
10E-10
-1
5.559E+15
10E-10
-2
2.133E+10
4.797E+16
Carga de B
pKa1 = logKpn
pKa2 = logKpn-1
pKa3 = logKpn-2
pKa4 = logKpn-3
pKa5 = logKpn-4
pKa6 = logKpn-5
-3
3.128
4.761
6.396
Kw
1.01E-14
recalc. para g H =
1.000
1.00E-06
5.56E+15
2.13E+10
1.00E-09
1.00E-09
4.80E+16
0.000000
0.000000
0.000000
1.000
1.00E-07
0.000000
Titulado
0.000000
Kw
Kw
1.007E-14
1.007E-14
h6
cido
carbnico
2.000
2.000
2.000
2.000
1.999
1.999
1.999
1.998
1.997
1.995
1.992
1.987
1.979
1.967
1.947
1.919
1.876
1.822
1.749
1.645
1.526
1.421
1.310
1.223
1.155
1.100
1.062
1.040
1.023
1.011
1.004
0.989
0.983
0.962
0.935
0.932
0.857
0.796
0.719
0.619
0.494
0.388
0.291
0.203
0.138
0.090
0.061
0.037
0.025
0.015
0.010
h7
cido
clordrico
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
h1 ttlante.
h2 ttlante.
h3 ttlante.
I1
cido forte
Base forte
c. carbnico
cido ctrico
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
2.000
2.000
2.000
2.000
1.999
1.999
1.999
1.998
1.997
1.995
1.992
1.987
1.979
1.967
1.947
1.919
1.876
1.822
1.749
1.645
1.526
1.421
1.310
1.223
1.155
1.100
1.062
1.040
1.023
1.011
1.004
0.989
0.983
0.962
0.935
0.932
0.857
0.796
0.719
0.619
0.494
0.388
0.291
0.203
0.138
0.090
0.061
0.037
0.025
0.015
0.010
2.509E-03
3.509E-03
4.781E-03
6.359E-03
8.508E-03
1.008E-02
1.197E-02
1.362E-02
1.550E-02
1.773E-02
1.969E-02
2.300E-02
2.613E-02
2.955E-02
3.289E-02
3.595E-02
3.912E-02
4.205E-02
4.535E-02
4.963E-02
5.412E-02
5.773E-02
6.157E-02
6.442E-02
6.663E-02
6.846E-02
6.966E-02
7.030E-02
7.080E-02
7.112E-02
7.123E-02
7.146E-02
7.148E-02
7.155E-02
7.158E-02
7.156E-02
7.156E-02
7.153E-02
7.146E-02
7.137E-02
7.121E-02
7.097E-02
7.059E-02
7.002E-02
6.919E-02
6.800E-02
6.636E-02
6.415E-02
6.117E-02
5.706E-02
5.118E-02
cido
ascrbico
cido
actico
-3
2.148
7.199
12.350
-2
4.100
11.790
-1
4.757
Hidrxido
cido
de amnio carbnico
0
9.244
-2
6.352
10.329
cido
clordrico
-1
-7.000
I2
cido
fosfrico
I3
cido
ascrbico
2.280E-04
3.357E-04
4.919E-04
7.244E-04
1.135E-03
1.551E-03
2.203E-03
2.929E-03
3.820E-03
4.774E-03
5.442E-03
6.213E-03
6.656E-03
6.939E-03
7.077E-03
7.112E-03
7.095E-03
7.028E-03
6.935E-03
6.823E-03
6.694E-03
6.560E-03
6.441E-03
6.342E-03
6.266E-03
6.213E-03
6.176E-03
6.152E-03
6.136E-03
6.127E-03
6.122E-03
6.123E-03
6.123E-03
6.133E-03
6.150E-03
6.150E-03
6.206E-03
6.258E-03
6.335E-03
6.463E-03
6.693E-03
6.986E-03
7.421E-03
8.102E-03
9.033E-03
1.031E-02
1.154E-02
1.321E-02
1.418E-02
1.491E-02
1.452E-02
I4
cido
actico
I5
I6
Hidrxido
cido
de amnio carbnico
I7
cido
clordrico
I1 ttlante.
I2 ttlante.
I3 ttlante.
c.
carbnico
I Ac./Base
calculado
mol/L
5.356E-03
5.533E-03
6.361E-03
7.772E-03
1.004E-02
1.189E-02
1.433E-02
1.665E-02
1.938E-02
2.255E-02
2.516E-02
2.922E-02
3.279E-02
3.650E-02
3.997E-02
4.307E-02
4.622E-02
4.908E-02
5.229E-02
5.645E-02
6.082E-02
6.429E-02
6.801E-02
7.076E-02
7.290E-02
7.467E-02
7.583E-02
7.646E-02
7.693E-02
7.724E-02
7.736E-02
7.759E-02
7.761E-02
7.769E-02
7.774E-02
7.771E-02
7.778E-02
7.781E-02
7.784E-02
7.790E-02
7.801E-02
7.812E-02
7.827E-02
7.854E-02
7.889E-02
7.940E-02
7.956E-02
8.015E-02
7.954E-02
7.884E-02
7.647E-02
IA/B/CI
calculado
mol/L
5.458E-03
7.773E-03
1.071E-02
1.430E-02
1.879E-02
2.281E-02
2.731E-02
3.153E-02
3.604E-02
4.086E-02
4.502E-02
5.048E-02
5.531E-02
6.009E-02
6.446E-02
6.829E-02
7.206E-02
7.546E-02
7.919E-02
8.387E-02
8.875E-02
9.271E-02
9.685E-02
9.995E-02
1.023E-01
1.043E-01
1.056E-01
1.063E-01
1.068E-01
1.072E-01
1.073E-01
1.076E-01
1.076E-01
1.077E-01
1.077E-01
1.077E-01
1.078E-01
1.078E-01
1.079E-01
1.080E-01
1.081E-01
1.083E-01
1.086E-01
1.090E-01
1.096E-01
1.104E-01
1.110E-01
1.122E-01
1.124E-01
1.129E-01
1.121E-01
IA/B/CI
aplicado
mol/L
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
I total
aplicado
mol/L
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
g H+
pH - pHRNL
6.13E+01
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
0.0109
-0.0001
-0.0108
-0.0144
0.0184
-0.0044
0.0041
-0.0054
-0.0024
0.0072
-0.0216
0.0022
0.0001
0.0065
0.0125
0.0112
0.0160
0.0009
-0.0108
0.0021
0.0133
-0.0055
0.0009
-0.0072
-0.0144
0.0000
0.0138
-0.0027
-0.0007
0.0029
-0.0654
0.0511
-0.0536
0.0171
0.0509
-0.1293
0.0273
0.0156
-0.0008
-0.0032
0.0191
0.0049
-0.0056
-0.0014
-0.0006
0.0097
-0.0111
0.0138
-0.0111
0.0022
-0.0047
pH - pHRNL
FALSEdpH/dV
FALSEdpH/dV
FALSEdpH/dV
14
12
10
pH
8
6
4
2
0
0.0
10.0
20.0
30.0
Volume Titulante (mL)
Titulante (mL)
Vol
40.0
50.0
60.0
0
2.12965
4.047664
5.693839
7.015282
8.005077
8.703493
9.174377
9.481985
9.679055
9.804296
9.88443
9.937449
9.975641
10.00802
10.04229
10.08653
10.15101
10.25014
10.4049
10.6452
11.01084
11.54818
12.2975
13.26889
14.41542
15.62783
16.76964
17.73349
18.47478
19.00523
19.36573
19.60256
19.75526
19.85347
19.91806
19.96352
20.00041
20.03749
20.08365
20.14997
20.25233
20.41504
20.6763
21.09645
21.77041
22.84708
24.56286
27.31445
31.86091
40
Simulador
pH
1.805933
2.017575
2.229217
2.440859
2.652501
2.864144
3.075786
3.287428
3.49907
3.710712
3.922355
4.133997
4.345639
4.557281
4.768923
4.980565
5.192208
5.40385
5.615492
5.827134
6.038776
6.250419
6.462061
6.673703
6.885345
7.096987
7.308629
7.520272
7.731914
7.943556
8.155198
8.36684
8.578483
8.790125
9.001767
9.213409
9.425051
9.636693
9.848336
10.05998
10.27162
10.48326
10.6949
10.90655
Vol_
1.078546
3.126565
4.925
6.415524
7.568945
8.405026
8.979395
9.358681
9.602655
9.757391
9.855484
9.919032
9.962955
9.997827
10.03215
10.07425
10.13421
10.22589
10.36936
10.59341
10.93683
11.44571
12.16204
13.10116
14.22513
15.43412
16.59477
17.59316
18.37322
18.93755
19.32336
19.57724
19.74067
19.84535
19.91379
19.96161
20.00019
20.03892
20.08734
20.15739
20.26627
20.44051
20.72202
dpH/dVol Vol
0.099441
0.110628
0.12938
0.162118
0.218053
0.311576
0.46601
0.719145
1.130898
1.790557
2.807972
4.23036
5.775489
6.579003
5.953094
4.451801
2.990169
1.92183
1.223416
0.78639
0.518021
0.355334
0.258747
0.204438
0.178943
0.175928
0.194643
0.239735
0.322384
0.462977
0.695755
1.075494
1.683486
2.617143
3.907013
5.265199
5.889436
5.226234
3.844444
2.544527
1.607214
0.997606
0.616372
Analise Inicial
pH
2.200676
2.391679
2.69706
2.878141
3.053583
3.207016
3.46169
3.631131
3.790307
4.076724
4.162303
4.27497
4.758719
5.168723
5.082678
5.112615
5.443185
5.605886
5.83998
6.023505
6.173876
6.376543
6.627543
6.820057
7.032317
7.26773
7.433136
7.651831
7.799735
7.972317
8.210496
8.338675
8.641195
8.756468
8.942605
9.366374
9.45561
9.778101
9.946603
9.872647
10.15136
10.42055
10.68804
10.87965
11.11819
11.32983
11.54147
11.75312
11.96476
12.1764
12.38804
21.17732
21.91164
23.09147
24.98648
28.06894
33.31351
43.3219
0.381271
0.23675
0.147563
0.09181
0.056027
0.032205
0.01606
31.42984
32.24327
33.50071
35.43031
38.37481
42.88566
50
11.06226
11.13366
11.42751
11.59687
11.82194
11.95825
12.19936
Analise Inicial
Vol_
Analise
pH
Vol_
dpH/dVol Vol
Valores de pKa de ~250 cidos e bases comuns encontram-se compilados abaixo. Para alguns cidos no s
Adies podem ser feitas no final ou em qualquer ponto, neste caso, inserindo novas linhas e renumerando sequencialmente
Compilaes de Constantes e breve bibliografia sobre equilbrios cido-base
Martell, A. E., Smith, R. M., Critical Stability Constants, Vol. 14. Plenum Press: New York, 1976.
Perrin, D. D., Dissociation Constants of Organic Bases in Aqueous Solution, Butterworths, London, 1965; Supplement, 1972.
Serjeant, E. P., and Dempsey, B., Ionization Constants of Organic Acids in Aqueous Solution, Pergamon, Oxford, 1979.
Albert, A., "Ionization Constants of Heterocyclic Substances", in Physical Methods in Heterocyclic Chemistry, Katritzky, A. R., E
Perrin, D. D., Dempsey, B., and Serjeant, E. P., pKa Prediction for Organic Acids and Bases, Chapman & Hall, London, 1981.
Dawson, R. M. C., Elliot, D. C., Elliot, W. H., and Jones, K. M., Data for Biochemical Research, Oxford Science Publications, O
Extensa compilao de pKas de cidos e bases inorgnicas e orgnicas (33 pginas)
Constantes de cidos e bases orgnicas (>600 compostos)
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
Carga,
inteiramente
desprotonado
USO FREQENTE
cido actico
cido carbnico
cido ctrico
cido clordrico
cido EDTA
cido fosfrico
Hidrxido de amnio
Hidrxido de sdio
O R D E M A L F A B T I C A (em ingls)
Acetamida
cido actico
cido acetoactico
cido acrlico
cido adpico
cido 4-aminobenzico
cido 2-aminobenzico
cido 2-aminobutanico
cido 6-aminohexanico
cido 5-aminopentanico
cido arsnico
cido arsenoso
cido ascrbico
cido asprtico
cido barbitrico
cido benzenosulfnico
cido benzico
cido brico
cido bromdrico
pKa1
-1
-2
-3
-1
-4
-3
0
-1
0
0
4.757
6.352
3.128
-7
0
2.148
9.244
15.745
0
-1
-1
-1
-2
-1
-1
-1
-1
-1
-3
-1
-2
-2
-1
-1
-1
-3
-1
0.63
4.757
3.58
4.25
4.43
2.501
2.108
2.29
4.373
4.27
2.24
9.22
4.1
1.99
4.01
0.7
4.19
9.236
-9
pKa2
10.329
4.761
1.5
7.199
5.41
4.874
4.946
9.83
10.804
10.766
6.96
11.79
3.9
12.74
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
78
79
80
81
82
83
84
85
86
cido butanico
cido 3-butenico
cido carbnico
cido ciandrico
cido ciandrico
cido ctrico
cido clordrico
cido cloroactico
cido 2-clorobenzico
cido 3-clorobenzico
cido 4-clorobenzico
cido crmico
cido 2,4-diaminobutanico
cido dicloroactico
cido dnicotnico
cido dipicolnico
cido etilenodiaminatetraactico (EDTA)
cido fenilactico
cido fluordrico
cido frmico
cido fosfrico
cido m- ftlico
cido o-ftlico
cido p-ftlico
cido fumrico
cido glicrico
cido gliclico
cido glioxlico
cido l-glutmico
cido heptanodiico
cido heptanico
cido hexanico
cido hidrazico
cido m-hidroxibenzico
cido p-hidroxibenzico
cido 3-hidroxipropanico
cido hipobromoso
cido hipocloroso
cido hipoiodoso
cido idico
cido isoctrico
cido ltico
cido maleico
cido mlico
cido malnico
cido 2-metilbutanico
cido 3-metilbutanico
cido metilmalnico
cido 4-metilpentanico
cido nitrilotriactico
cido 2-nitrobenzico
cido 3-nitrobenzico
cido 4-nitrobenzico
cido nitroso
cido octanico
cido octenodiico
-1
-1
-2
-1
-1
-3
-1
-1
-1
-1
-1
-2
-1
-1
-1
-2
-4
-1
-1
-1
-3
-2
-2
-2
-2
-1
-1
-1
-2
-1
-1
-1
-1
-2
-2
-1
-1
-1
-1
-1
-3
-1
-2
-2
-2
-1
-1
-2
-1
-3
-1
-1
-1
-1
-1
-1
4.83
4.34
6.352
9.21
3.46
3.128
-7
2.865
2.92
3.82
3.98
0,2
1.85
1.3
2.8
2.16
0
4.28
3.17
3.745
2.148
3.54
3.51
2.95
3.053
3.52
3.831
3.18
2.23
4.71
4.89
4.85
4.72
4.06
4.48
4.51
8.63
7.53
10.64
0.77
3.29
3.86
1.91
3.459
2.847
4.8
4.77
3.07
4.84
1.1
2.179
3.449
3.442
3.15
4.89
4.52
10.329
4.761
6.51
8.24
4.76
1.5
7.199
4.6
4.82
5.408
4.494
4.42
9.92
9.32
4.71
6.332
5.097
5.696
5.76
1.65
87
88
89
90
91
92
93
94
95
96
97
98
99
100
101
102
103
104
105
106
107
108
109
110
111
112
113
114
115
116
117
118
119
120
121
122
123
124
125
126
127
128
129
130
131
132
133
134
135
136
137
138
139
140
141
142
cido oxlico
cido oxaloactico
cido pentanico
cido perclrico
cido p-peridico
cido picolnico
cido pcrico
cido 3-piridinocarboxlico
cido 4-piridinocarboxlico
cido pirofosfrico
cido pirvico
cido propanico
cido saliclico
cido selnico
cido selenoso
cido m-silcico
cido o-silcico
cido succnico
cido sulfdrico
cido sulfrico
cido sulfuroso
cido meso-tartrico
cido d-tartrico
cido tereftlico
cido tioactico
cido tiocinico
cido tiossulfrico
cido m-tolico
cido o-tolico
cido p-tolico
cido tricloroactico
cido trimetilactico
cido rico
Alanina
b-Alanina
Aminobenzeno = anilina
2-Aminofenol
Amonia
Anilina
Arginina
Asparagina
Barbital
Benzilamina
2-Benzilpiridina
Betana
Butilamina
sec-Butilamina
terc-Butilamina
Cadaverina
Catecol
Cistena
2-Cloroanilina
3-Cloroanilina
4-Cloroanilina
2-Clorofenol
3-Clorofenol
-2
-2
-1
-1
-2
-2
-1
-1
-1
-4
-1
-1
-2
-1
-2
-2
-2
-2
-2
-2
-2
-2
-2
-1
-1
-1
-2
-1
-1
-1
-1
-1
-1
-1
-1
0
-1
0
0
-1
-1
0
0
0
-1
0
0
0
0
-2
-2
0
0
0
-1
-1
1.252
2.22
4.84
-10
1.55
1.07
0.38
4.96
4.85
1.52
2.39
4.874
2.97
1.92
2.64
9.7
9.66
4.207
7.02
-3
1.91
3.22
3.036
3.51
3.33
0.9
0.6
4.27
3.91
4.36
0.66
5.03
3.89
2.348
3.55
4.6
4.78
9.244
4.63
1.823
2.14
7.43
9.33
5.13
1.83
10.77
10.56
10.68
10.05
9.4
1.71
2.65
3.46
4.15
8.49
8.85
4.266
3.89
8.28
5.25
2.36
13.74
8.28
12
11.7
5.636
13.9
1.99
7.18
4.82
4.366
1,6 3
9.867
10.24
9.97
8.991
8.72
10.93
12.8
8.36
143
144
145
146
147
148
149
150
151
152
153
154
155
156
157
158
159
160
161
162
163
164
165
166
167
168
169
170
171
172
173
174
175
176
177
178
179
180
181
182
183
184
185
186
187
188
4-Clorofenol
Codeina
Colina
Creatinina
m-Cresol
o-Cresol
p-Cresol
Cupferron
Decilamina
2,3-Diclorofenol
Dietilamina
Difenilamina
Dimetilamina
Dimetilglioxima
2,3-Dimetilpiridina
2,4-Dimetilpiridina
2,5-Dimetilpiridina
3,4-Dimetilpiridina
3,5-Dimetilpiridina
3,6-Dimetilpiridina
Disopropilamina
Dopamina
d-Efedrina
l-Efedrina
Etanolamina
Etilamina
Etilenodiamina
Etilenoimina
2-Etilpiridina
1,10-Fenantrolina
Fenilalanina
Feniletilamina
Fenilglicina
Fenol
m-Fenotidina
o-Fenotidina
p-Fenotidina
Glicerol
Glicina
l-Glutamina
l-Glutationa
Heptilamina
Hexametilenodiamina
Hexilamina
Hidrazina
Hidrogeno cromato, on
-1
0
0
0
-1
-1
-1
-1
0
-1
0
0
0
-2
0
0
0
0
0
0
0
-1
0
0
0
0
0
0
0
0
-1
0
-1
-1
0
0
0
-1
-2
-1
-2
0
0
0
0
-1
9.18
8.21
13.9
4.83
10.01
10.2
10.17
4.16
10.64
7.46
10.933
0.79
10.774
10.66
6.58
6.99
6.4
6.65
6.46
6.15
11.05
8.9
10.139
9.958
9.5
10.636
6.848
8.01
5.89
4.84
2.2
9.84
1.83
9.98
4.18
4.43
5.2
14.15
2.35
2.17
2.12
10.67
11.857
10.56
8.07
6.52
189
190
191
192
193
194
195
196
197
198
Hidrogeno selenato, on
Hidroquinona
Hidroxilamina
8-Hidroxiquinolina
Histamina
Histidina
Imidazol
Isoleucina
l-Leucina
Lisina
-1
0
0
-1
0
-1
0
-1
-1
-1
1.66
10.35
5.96
4.91
6.04
1.7
6.953
2.319
2.328
2.04
9.2
12
10.6
9.928
9.31
4.39
9.778
9.13
3.59
10.762
9.81
9.75
6.02
9.754
9.744
9.08
199
200
201
202
203
204
205
206
207
208
209
210
211
212
213
214
215
216
217
218
219
220
221
222
223
224
225
226
227
228
229
230
231
232
233
234
235
236
237
238
239
240
241
242
243
244
245
246
247
248
249
250
251
252
253
254
Melamina = 1,3,5-triazina-2,4,6-triamina
0
5
Metil-1-naftilamina
0
3.67
Metilamina
0
10.63
2-Metilanilina = o-touidina = amino-1-metilbenzeno
0
4.447
4-Metilanilina = p-toluidina = 4-amino-1-metilbenzeno
0
5.084
2-Metilbenzimidazol
0
6.19
2-Metilfenol = o-cresol
-1
10.28
4-Metilfenol = p-cresol
-1
10.26
1-Metilpiperidina
0
10.08
2-Metilpiridina
0
5.97
3-Metilpiridina
0
5.68
4-Metilpiridina
0
6.02
Metionina = cido (S)-2-amino-4-(metilssulfanilo)-butanico
-1
2.13
Morfina
0
8.21
Morfolina
0
8.33
1-Naftol
-1
9.34
2-Naftol
-1
9.51
Nicotina
0
8.02
2-Nitroanilina
0
-0.26
3-Nitroanilina
0
2.466
4-Nitroanilina
0
1
2-Nitrofenol
-1
7.21
3-Nitrofenol
-1
8.39
4-Nitrofenol
-1
7.15
Noradrenalina
-1
8.64
Octadecilamina
0
10.6
Papaverina
0
6.4
Perxido de hidrognio
-1
11.65
Pilocarpina
0
6.87
Piperazina
0
9.83
Piperidina
11.123
0
Piridina
0
5.229
Pirimidina
0
6.35
Pirocatecol
-2
9.4
Pirrolidina
0
11.27
Prolina
-1
1.952
Propilamina
0
10.566
Purina
0
2.3
Quinina
0
8.52
Quinolina
0
4.9
Resorcinol
-2
9.3
Sacarina
-1
11.68
Serina
-1
2.19
Stricnina
0
8.26
Tiazol
0
2.44
Tiramina
0
9.74
Tirosina
-1
2.17
Treonina
-1
2.088
Trietanolamina
0
7.762
Trietilamina
0
10.715
Trimetilamina
0
9.8
Triptofano
-1
2.35
Tris(hidroximetil)-aminometano = tris
0
8.075
Uria
0
0.1
Valina
-1
2.286
9.27
3.12
9.7
5.56
7.53
12.8
10.64
8.96
4.13
11.06
9.05
10.52
9.19
9.1
9.33
9.718
255
256
257
258
259
260
261
262
263
264
265
266
267
268
269
270
271
272
273
274
275
276
277
278
279
280
compilados abaixo. Para alguns cidos no se encontrou pKas para fora inica zero, requeridos mdulo pH
do novas linhas e renumerando sequencialmente a coluna B (de 1 a 280)
http://www.beloit.edu/~chem/Chem220/indicator/
rquivo Ionic St_effects.pdf contido no pacote: http://www.iupac.org/projects/2000/Aq_Solutions.zip
Sendo a fora inica:
pKa4
pKa5
pKa6
6.396
2
12.35
11.5
10.002
13.8
2.68
6.11
10.17
Temperat.
C
Fora
inica
Formula
25
25
25
0
0
0
CH3COOH
H2CO3
H3C6H5O7
25
25
25
25
0.1
0
0
0
25
25
18
25
25
25
25
25
25
25
25
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
24
25
25
25
25
20
C10H16N2O8
H3PO4
NH3
NaOH
C2H5NO
CH3COOH
C4H6O3
C3H4O2
C6H10O4
C7H7NO2
C7H7NO2
C4H9NO2
C6H13NO2
C5H11NO2
H3AsO4
H3AsO3
C6H8O6
C4H7NO4
C4H4N2O3
C6H6O3S
C7H6O2
H3BO3
HI
6.396
10.44
2.68
12.35
9.95
6.4
2.94
10.334
6.11
10.17
25
25
25
25
0
0
0
0
25
25
25
25
25
20
25
25
25
25
25
18
25
20
25
25
25
25
25
25
25
25
25
25
25
25
0
0
0
0
0
0
0
0
0
0.1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
19
19
25
25
25
25
25
25
0
0
0
0
0
0
0
0
25
25
25
25
25
25
18
20
25
25
25
25
25
25
0
0
0
0
0
0
0
0
0
0
0
0
0
0
C4H8O2
C4H6O2
H2CO3
HCN
HCNO
H3C6H5O7
HCl
ClCH2COOH
C7H5CIO2
C7H5CIO2
C7H5CIO2
H2CrO4
C4H10N2O2
Cl2CHCOOH
C7H5NO4
C7H5NO4
C10H16N2O8
C8H8O2
HF
HCOOH
H3PO4
C8H6O4
C8H6O4
C8H6O4
C4H4O4
C3H6O4
HOCH2COOH
C2H2O3
C5H9NO4
C7H12O4
C7H14O2
C6H12O2
HN3
C7H6O3
C7H6O3
C3H6O3
HOBr
HOCl
HOI
HIO3
C6H8O7
HC3H5O3
C4H4O4
C4H6O5
HOOCCH2COOH
C5H10O2
C5H10O2
C4H6O4
C6H12O2
C7H5NO4
C7H5NO4
C7H5NO4
HNO2
C8H16O2
C8H14O4
13.03
6.6
12.48
10.77
25
25
25
0
0
0
25
25
25
0
0
25
25
25
25
0
0
0
0
0
25
25
25
25
25
25
25
25
25
25
25
25
25
25
12
25
25
25
20
25
25
25
25
25
25
25
0
20
25
25
25
25
25
25
25
25
25
25
0
0
0
0
0
0
0
0
0
0
0
0
0.1
0
0
0
0
0
0
0
0
0
0.1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
9.25
C2H2O4
C4H4O5
C5H10O2
HClO4
H5IO6
C6H5NO2
C6H3N3O7
C6H5NO2
C6H5NO2
H4P2O7
C3H4O3
CH3CH2COOH
C7H6O3
H2SeO4
H2SeO3
H2SiO3
H4SiO4
HOOCCH2CH2COO
H2S
H2SO4
H2SO3
C4H6O6
C4H6O6
C8H6O4
C2H4OS
HSCN
H2S2O3
C8H8O2
C8H8O2
C8H8O2
Cl3CCOOH
C5H10O2
C5H4N4O3
C3H7NO2
C3H7NO2
C6H7N
C6H7NO
NH3
C6H7N
C6H14N4O2
C4H8N2O3
C8H12N2O3
C7H9N
C12H11N
C5H11NO2
C4H11N
C4H11N
C4H11N
C5H14N2
C6H4(OH)2
C3H7NO2S
C6H6CIN
C6H6CIN
C6H6CIN
C6H5CIO
C6H5CIO
8.75
9.08
10.69
9.65
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
10
10
25
25
25
25
25
25
25
25
25
25
25
28
28
25
25
25
25
25
0
25
30
20
25
25
25
25
25
25
25
25
0
0
0
0
0
0
0
0.1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.1
0
0
0
0.1
C6H5CIO
C18H21NO3
C5H14NO
C4H7N3O
C7H8O
C7H8O
C7H8O
C6H6N2O
C10H23N
C6H4Cl2O
(CH3CH2)2NH
C12H11N
(CH3)2NH
C4H12O2N2
C7H9N
C7H9N
C7H9N
C7H9N
C7H9N
C7H9N
C6H15N
C8H11NO2
C10H15NO
C10H15NO
C2H7NO
CH3CH2NH2
H2NCH2CH2NH2
C2H5N
C7H9N
C12H8N2
C9H11NO2
C8H11N
C8H9NO2
HC6H5O
C8H11NO
C8H11NO
C8H11NO
C3H8O3
H2NCH2COOH
C5H10N2O3
C10H17N3O6S
C7H17N
C6H16N2
C6H15N
N2H4
HCrO4
HSeO4C6H6O2
NH2OH
C5H9N3
C6H9N3O2
C3H4N2
C6H13NO2
C6H13NO2
C6H14N2O2
10.47
25
27
25
25
25
25
25
25
25
20
20
20
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
30
23
25
25
20
20
25
25
25
20
25
20
25
18
25
25
20
25
25
25
25
25
25
25
25
21
25
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.1
0
0
0
C3H6N6
C11H11N
CH5N
C7H9N
C7H9N
C8H8N2
C7H8O
C7H8O
C6H13N
C6H7N
C6H7N
C6H7N
C5H11NO2S
C17H19NO3
C4H9NO
C10H8O
C10H8O
C10H14N2
C6H6N2O2
C6H6N2O2
C6H6N2O2
C6H5NO3
C6H5NO3
C6H5NO3
C8H11NO3
C18H39N
C20H21NO4
H2O2
C11H16N2O2
C4H10N2
C5H11N
C5H5N
C11H8N2
C6H6O2
C4H9N
C5H9NO2
CH3CH2CH2NH2
C5H4N4
C20H24N2O2
C9H7N
C6H6O2
C7H5NO3S
C3H7NO3
C21H22N2O2
C3H3NS
C8H11NO
C9H11NO3
C4H9NO3
(HOCH2CH2)3NH
(CH3CH2)3NH
(CH3)3NH
C11H12N2O2
(HOCH2)3CNH3
CH4N2O
C5H11NO2
Massa molecular
g/mol
60.052
192.027
292.09
97.976
17.026
59.067
60.052
102.089
72.063
146.143
137.138
137.138
128.09
http://achpc50.chemie.uni-karlsruhe.de/Cours%20de%20Chris
http://ptcl.chem.ox.ac.uk/MSDS/msds-searcher.html
http://www.iupac.org/publications/pac/2002/pdf/7411x2169.pdf
http://nvl.nist.gov/pub/nistpubs/jres/081/1/V81.N01.A03.pdf
http://nvl.nist.gov/pub/nistpubs/jres/066/2/V66.N02.A06.pdf
166.14
166.14
116.07
147.13
177.98
88.06
138.12
118.09
98.08
82.07
150.09
150.09
89.094
93.13
17.026
184.19
110.1
153.18
165.23
165.23
180.3
75.07
146.15
68.08
131.18
31.1
107.17
107.17
108.14
108.14
208.259
85.15
79.1
110.1
115.13
120.11
324.42
129.16
110.1
105.09
334.41
119.12
50.chemie.uni-karlsruhe.de/Cours%20de%20Chris%20Anson/OHP8acids.doc
em.ox.ac.uk/MSDS/msds-searcher.html
upac.org/publications/pac/2002/pdf/7411x2169.pdf
t.gov/pub/nistpubs/jres/081/1/V81.N01.A03.pdf
t.gov/pub/nistpubs/jres/066/2/V66.N02.A06.pdf