Acid Base Worksheet Chemistry 1B Name ___________________ 1.

Fill in the following table acid HCN HSO4HF base NH3 HCO3BrFormula of conjugate base Name of conjugate base

Formula of conjugate acid

Name of conjugate acid

2. Several acids are listed here with their respective equilibrium constants: C6H5OH(aq) + H2O(l) <=> H3O+(aq) + C6H5O-(aq) HCO2H(aq) + H2O(l) <=> H3O+(aq) + HCO2-(aq) HC2O4- + H2O(l) <=> H3O+(aq) + C2O42-(aq) a. Which is the strongest acid? __________________ b. Which is the weakest acid? ___________________ c. Which is the weakest conjugate base?____________ d. Which is the strongest conjugate base?___________ 3. If each of the salts listed here were dissolved in water to give 0.10 M solution: Na2S, Na3PO4, NaH2PO4, NaF, NaCH3CO2H, AlCl3 a. which solution would have the highest pH?______________ b. Which would have the lowest pH? __________________ 4. Which is the stronger of the two acids below? a. Benzoic acid C6H5CO2H pKa = 4.20 Ka = 1.3x10-10 Ka = 1.8 x 10-4 Ka=6.4 x 10-5

b. 2-chlorobenzoic acid ClC6H4CO2H pKa= 2.8

5. For each of the following reactions, predict whether the equilibrium lies predominantly to the left or to the right. Explain your prediction (briefly). You can use Ka tables in your book. a. NH4+ (aq) + Br-(aq) <=> NH3(aq) + HBr(aq) b. HPO42-(aq) + CH3CO2-(aq) <=> PO43-(aq) + HCH3CO2(aq) c. Fe(H2O)63+(aq) + HCO3- <=> Fe(H2O)5(OH)2+ (aq) + H2CO3(aq)

6. Calculate the hydronium ion concentration and pH of the solution that results when 22.0 mL of 0.15 M acetic acid is mixed with 22.0 mL of 0.15 M NaOH. 7. Solutions with equal molar quantities of acetic acid and sodium mono hydrogen phosphate are mixed. a. Write a balanced, et ionic equation for an acid-base reaction that occurs. b. Is the resulting solution acidic, basic, or neutral?

7. A 0.015 M solution of hydrogen cyanate, HOCN, has a pH of 2.67. a. What is the hydronium ion concentration in the solution? b. What is the ionization constant, Ka, for the acid

8. Calculate the hydronium ion concentration and pH in 0.20 M ammonium chloride solution 9. For each of the following cases, decide whether the pH is less than, equal to, or greater than 7. a. Equal volumes of 0.10 M acetic acid and 0.10 M KOH are mixed. b. 25 mL of 0.015 M NH3 is mixed with 25 mL of 0.015 M HCl c. 150 mL of 0.20 M HNO3 is mixed with 75 mL of 0.40 M NaOH 9. Write two equations: one to show the ionization of HPO42- as an acid and one to show its ionization (hydrolysis) as a base. Would you expect an aqueous solution of Na2HPO4 to be acidic or basic?

Acid Base Worksheet Chemistry 1B Name ___________________ 1. Fill in the following tables acid HCN HSO4HF base NH3 HCO3BrFormula of conjugate base CNSO43FFormula of conjugate acid NH4+ H2CO3 HBr Name of conjugate base Cyanide ion Sulfate ion Fluoride ion Name of conjugate acid Ammonium ion Carbonic acid Hydrobromic acid

2. Several acids are listed here with their respective equilibrium constants: C6H5OH(aq) + H2O(l) <=> H3O+(aq) + C6H5O-(aq) HCO2H(aq) + H2O(l) <=> H3O+(aq) + HCO2-(aq) HC2O4- + H2O(l) <=> H3O+(aq) + C2O42-(aq) a. Which is the strongest acid? ___HCO2H_______________ b. Which is the weakest acid? _____ C6H5OH ______________ c. Which is the weakest conjugate base?___ HCO2-_________ d. Which is the strongest conjugate base?__ C6H5O-_________ 3. If each of the salts listed here were dissolved in water to give 0.10 M solution: Na2S, Na3PO4, NaH2PO4, NaF, NaCH3CO2H, AlCl3 a. which solution would have the highest pH?__ Na2S ____________ b. Which would have the lowest pH? _____ AlCl3__ 4. Which is the stronger of the two acids below? 2-chlorobenzoic acid has the smaller pKa value a. Benzoic acid C6H5CO2H pKa = 4.20 Ka = 1.3x10-10 Ka = 1.8 x 10-4 Ka=6.4 x 10-5

b. 2-chlorobenzoic acid ClC6H4CO2H pKa= 2.8

5. For each of the following reactions, predict whether the equilibrium lies predominantly to the left or to the right. Explain your prediction (briefly). You can use Ka tables in your book. a. NH4+ (aq) + Br-(aq) <=> NH3(aq) + HBr(aq) LEFT b. HPO42-(aq) + CH3CO2-(aq) <=> PO43-(aq) + HCH3CO2(aq) LEFT c. Fe(H2O)63+(aq) + HCO3- <=> Fe(H2O)5(OH)2+ (aq) + H2CO3(aq)RIGHT 6. Calculate the hydronium ion concentration and pH of the solution that results when 22.0 mL of 0.15 M acetic acid is mixed with 22.0 mL of 0.15 M NaOH.[H3O+] = 1.5x10-9; pH = 8.81 7. Solutions with equal molar quantities of acetic acid and sodium mono hydrogen phosphate are mixed. a. Write a balanced, et ionic equation for an acid-base reaction that occurs.
CH3CO2H(aq) + HPO4 (aq) <=>H2PO4 (aq) + CH3CO2 (aq)
2-

b. Is the resulting solution acidic, basic, or neutral? acetic acid is stronger so the equilibrium will lie to the right. The
solution will be acidic

8. A 0.015 M solution of hydrogen cyanate, HOCN, has a pH of 2.67. a. What is the hydronium ion concentration in the solution?2.1x10-3 M b. What is the ionization constant, Ka, for the acidKa = 3.5 x 10-4

9. Calculate the hydronium ion concentration and pH in 0.20 M ammonium chloride solution [H3O+]=1.1x10-15, pH = 4.98 10. For each of the following cases, decide whether the pH is less than, equal to, or greater than 7. a. Equal volumes of 0.10 M acetic acid and 0.10 M KOH are mixed.rxn produces acetate ion, conjugate base of
acetic acid, solution is weakly basic

b. 25 mL of 0.015 M NH3 is mixed with 25 mL of 0.015 M HClproduces ammonium ion, weakly acidic c. 150 mL of 0.20 M HNO3 is mixed with 75 mL of 0.40 M NaOH produces equal molar amounts of strong base and
acid. solution will be neutral

9. Write two equations: one to show the ionization of HPO42- as an acid and one to show its ionization (hydrolysis) as a base. Would you expect an aqueous solution of Na2HPO4 to be acidic or basic?
HPO4 + H2O <=> PO4 + H3O
223+ -

Ka = 4.2 x 10 Kb= 2.4 x 10

-13

HPO4 + H2O <=> H2PO4 + OH

-2

based on Kb>Ka it would be basic