1

: 1
2011/2012

:
2

7.5 : 45 .

. C50

.
:
P.V.C
: .

) (

:
+

+
Na aq + HOaq + C 4 H 8 O2( ) C 2 H 6 O( ) + CH 3 CO2( aq ) + Na aq
:
C20 :+
Na

5,0.10 3
) ( S .m 2 .mol 1

HO

2,0.10 2

CH3CO2

4,1.10 3

M = 88( g .mol 1 ) :
= 0,90( g .ml 1 ) :

0.25
0.25
1.25
1
0.25
1

1.25
0.5
1.25
0.5

3
1
V
=
200
(
mL
)
0 C 0 = 1,00.10 mol.L

.
) t = 0(min ) V1 = 1,0(mL .
S .
. C20
-1 n0 . V0
-2 n1 V1
-3 .
-4 V1 V0 V . S
4-1 0 t = 0 f . C 0
4-2 t = 0 .
4-2 t t :
x
(
)

HO
V CH 3CO2

t = 0 +

-5 S ) - x = f (t
5-1
t = 4 min t = 12 min
.
5-2 . t1 / 2
5-3 t1 / 2
-6
= 40C . t '1 / 2
t1 / 2 . t '1 / 2 .

7.5 : 1 45 .
, .
100m
h . 4000m
.
). ( 0,5h