GENERACION DE DATOS ELV

MODELO MARGULES

CONDICION ISOTERMICO

i
( 01 )
( 02 )

SISTEMA BINARIO
Nombre
Metanol
Agua

Temperatura (C)

Frmula
CH4O
H20

COD. TABLA

30
0

85.00 <---- Puede cambiar la Temperatura

x2
1.0000
0.9500
0.9000
0.8500
0.8000
0.7500
0.7000
0.6500
0.6000
0.5500
0.5000
0.4500
0.4000
0.3500
0.3000
0.2500
0.2000
0.1500
0.1000
0.0500
0.0000

g1
2.2626
2.0278
1.8361
1.6788
1.5491
1.4420
1.3534
1.2801
1.2195
1.1697
1.1289
1.0958
1.0693
1.0484
1.0322
1.0202
1.0115
1.0057
1.0022
1.0005
1.0000

P(mmHg)
g2
1.0000
433.64
1.0028
577.31
1.0109
691.87
1.0239
785.20
1.0415
863.04
1.0633
929.64
1.0892
988.14
1.1187
1040.90
1.1517
1089.64
1.1877
1135.69
1.2265
1180.02
1.2674
1223.35
1.3101
1266.23
1.3539
1309.03
1.3981
1352.02
1.4420
1395.39
1.4848
1439.24
1.5254
1483.60
1.5629
1528.48
1.5962
1573.80
1.6242
1619.44

y1
0.0000
0.2844
0.4298
0.5194
0.5814
0.6280
0.6654
0.6971
0.7250
0.7506
0.7746
0.7978
0.8205
0.8430
0.8655
0.8880
0.9105
0.9331
0.9557
0.9780
1.0000

CALCULO PUNTUAL
0.1400
0.8600

1.7078

1.0209

0.5042

x1
0.0000
0.0500
0.1000
0.1500
0.2000
0.2500
0.3000
0.3500
0.4000
0.4500
0.5000
0.5500
0.6000
0.6500
0.7000
0.7500
0.8000
0.8500
0.9000
0.9500
1.0000

767.93

Psat

Constantes de Antoine : P (kPa), t (C)

Ao

7.19730
7.07406

Bo

1574.990
1657.459

Co

Tmn

238.870
227.020

CTES. DE
MARGULES

Ing. Alfredo ARIAS JARA

-16
11

Tmx

(mmHg)

91 1619.442
168 433.6396

A12 =

0.8165

A21 =

0.485

DIAGRAMA DE COMPOSICION

DIAGRAMA PRESION / COMPOSICION

1800

0
1

1.0

0
1

1600

0.9

1400

0.7

1200

Presin (mmHg)

y (fraccin molar fase vapor)

0.8

0.6

0.5

0.4

1000

800

600
0.3

400
0.2

200

0.1

0.0
0.0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1.0

x (fraccin molar fase lquida)

0.0

0.1

0.2

0.3

0.4

0.5

x,y

Ing. Alfredo ARIAS JARA

0.6

0.7

0.8

0.9

1.0

GENERACION DE DATOS ELV

MODELO VAN LAAR

CONDICION ISOTERMICO
SISTEMA BINARIO
Nombre
Metanol

i
( 01 )
( 02 )

1,2 Dicloroetano

Temperatura (C)

Frmula
CH4O
C2H4Cl2

COD. TABLA

Tmn

P
Tmx

(mmHg)

7.19730

1574.990

238.870

-16

91

265.852

63

6.15020

1271.250

222.940

-33

100

155.076

40.00 <---- Puede cambiar la Temperatura

g1
7.8358
6.0793
4.8272
3.9165
3.2419
2.7341
2.3462
2.0462
1.8116
1.6266
1.4798
1.3627
1.2693
1.1950
1.1362
1.0904
1.0556
1.0302
1.0130
1.0032
1.0000

P(mmHg)
g2
1.0000
155.08
1.0065
229.09
1.0254
271.45
1.0565
295.44
1.0996
308.80
1.1553
316.09
1.2243
320.03
1.3076
322.20
1.4067
323.53
1.5231
324.51
1.6592
325.35
1.8173
326.07
2.0003
326.56
2.2119
326.55
2.4559
325.70
2.7370
323.53
3.0606
319.43
3.4330
312.65
3.8614
302.26
4.3540
287.12
4.9205
265.85

y1
0.0000
0.3527
0.4728
0.5286
0.5582
0.5749
0.5847
0.5909
0.5955
0.5997
0.6046
0.6111
0.6200
0.6324
0.6492
0.6720
0.7028
0.7446
0.8019
0.8824
1.0000

CALCULO PUNTUAL
0.7000
0.3000

1.1362

2.4559

0.6492

325.70

30

x2
1.0000
0.9500
0.9000
0.8500
0.8000
0.7500
0.7000
0.6500
0.6000
0.5500
0.5000
0.4500
0.4000
0.3500
0.3000
0.2500
0.2000
0.1500
0.1000
0.0500
0.0000

x1
0.0000
0.0500
0.1000
0.1500
0.2000
0.2500
0.3000
0.3500
0.4000
0.4500
0.5000
0.5500
0.6000
0.6500
0.7000
0.7500
0.8000
0.8500
0.9000
0.9500
1.0000

sat

Constantes de Antoine : P (kPa), t (C)

A

CTES. DE VAN LAAR

Ing. Alfredo ARIAS JARA

A'12 =

2.059

A'21 =

1.593

DIAGRAMA PRESION / COMPOSICION

DIAGRAMA DE COMPOSICION

350

0
1

1.0

0
1
300

0.9

0.8

0.7

Presin (mmHg)

y (fraccin molar fase vapor)

250

0.6

0.5

0.4

200

150

100

0.3

0.2
50
0.1
0

0.0

0.0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1.0

0.0

0.1

0.2

0.3

0.4

0.5

x,y

x (fraccin molar fase lquida)

Ing. Alfredo ARIAS JARA

0.6

0.7

0.8

0.9

1.0

GENERACION DE DATOS ELV

MODELO WILSON

CONDICION ISOTERMICO

i
( 01 )
( 02 )

SISTEMA BINARIO
Nombre
Frmula
Cloroformo
CHCl3
Etanol
CH3CH2OH

Temperatura (C)

COD. TABLA

10
81

60.00 <---- Puede cambiar la Temperatura

x1
0.0000
0.0500
0.1000
0.1500
0.2000

x2
1.0000
0.9500
0.9000
0.8500
0.8000

g1
2.0860
1.9988
1.9152
1.8351
1.7584

g2
1.0000
1.0011
1.0046
1.0108
1.0200

P(mmHg)
351.15
405.75
455.05
499.39
539.11

y1
0.0000
0.1769
0.3023
0.3959
0.4685

0.2500
0.3000
0.3500
0.4000
0.4500
0.5000
0.5500
0.6000
0.6500
0.7000
0.7500
0.8000
0.8500
0.9000
0.9500
1.0000

0.7500
0.7000
0.6500
0.6000
0.5500
0.5000
0.4500
0.4000
0.3500
0.3000
0.2500
0.2000
0.1500
0.1000
0.0500
0.0000

1.6849
1.6147
1.5477
1.4838
1.4229
1.3651
1.3104
1.2588
1.2104
1.1653
1.1239
1.0864
1.0537
1.0268
1.0077
1.0000

1.0327
1.0495
1.0712
1.0987
1.1333
1.1767
1.2312
1.3001
1.3881
1.5021
1.6531
1.8583
2.1479
2.5773
3.2595
4.4565

574.52
605.90
633.56
657.76
678.76
696.83
712.19
725.07
735.66
744.11
750.51
754.75
756.42
754.24
744.80
718.23

0.5266
0.5742
0.6141
0.6481
0.6775
0.7035
0.7268
0.7481
0.7681
0.7873
0.8066
0.8271
0.8504
0.8800
0.9232
1.0000

g1
1.6849
1.8828

g2
1.0327
1.0067

P(mmHg)
574.52
473.36

y1
0.5266
0.3428

CALCULO PUNTUAL
x1
x2
0.2500
0.7500
0.1200
0.8800

sat

Constantes de Antoine : P (kPa), t (C)

A

6.06200
7.33820

1171.200
1652.050

Tmn

227.000
231.480

-13
-3

P
Tmx

(mmHg)

97 718.2254
96 351.1544

CTES. DE WILSON

(l12 - l11) = -245.1521 cal/mol

(l21 - l22) = 1235.3932 cal/mol

VOL. MOLARES DE
LIQUIDOS PUROS

V1 =
V2 =

PARAMETROS DE
WILSON

Ing. Alfredo ARIAS JARA

L12 =
L21 =

80.67 mL/mol
58.68 mL/mol
1.05341
0.21272

DIAGRAMA PRESION / COMPOSICION

DIAGRAMA DE COMPOSICION
0
1

1.0

0
1

800

700
0.9

600

0.7
500
Presin (mmHg)

y (fraccin molar fase vapor)

0.8

0.6

0.5

400

300

0.4

0.3
200
0.2
100

0.1

0.0
0.0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1.0

0.0

0.1

0.2

0.3

0.4

0.5
x,y

x (fraccin molar fase lquida)

Ing. Alfredo ARIAS JARA

0.6

0.7

0.8

0.9

1.0

GENERACION DE DATOS ELV

MODELO NRTL

CONDICION ISOTERMICO

i
( 01 )
( 02 )

SISTEMA BINARIO
Nombre
Frmula
Etanol
CH3CH2OH
Agua
H20

Temperatura (C)

COD. TABLA

81
0

7.33820
7.07406

1652.050
1657.459

g1
5.5321
4.1474
3.2520
2.6480
2.2261
1.9228
1.6995
1.5319
1.4042
1.3059
1.2295
1.1699
1.1235
1.0874
1.0597
1.0386
1.0231
1.0122
1.0051
1.0012
1.0000

g2
1.0000
1.0073
1.0272
1.0576
1.0972
1.1447
1.1995
1.2609
1.3283
1.4014
1.4798
1.5632
1.6511
1.7432
1.8393
1.9389
2.0417
2.1474
2.2556
2.3658
2.4778

CALCULO PUNTUAL
0.3000
0.7000
0.1200
0.8800

1.6995
2.9829

1.1995
1.0382

P(mmHg)
433.64
619.11
721.05
780.89
818.95
845.55
866.05
883.25
898.59
912.78
926.08
938.54
950.05
960.46
969.55
977.10
982.90
986.73
988.39
987.71
984.51

y1
0.0000
0.3298
0.4440
0.5008
0.5352
0.5597
0.5796
0.5976
0.6154
0.6338
0.6535
0.6750
0.6986
0.7245
0.7532
0.7849
0.8198
0.8584
0.9010
0.9481
1.0000

866.05
748.59

0.5796
0.4708

-3
11

Tmx

(mmHg)

96 984.5094
168 433.6396

(g12 - g22) = -109.634 cal/mol

85.00 <---- Puede cambiar la Temperatura

x2
1.0000
0.9500
0.9000
0.8500
0.8000
0.7500
0.7000
0.6500
0.6000
0.5500
0.5000
0.4500
0.4000
0.3500
0.3000
0.2500
0.2000
0.1500
0.1000
0.0500
0.0000

Tmn

231.480
227.020

CTES. NRTL
x1
0.0000
0.0500
0.1000
0.1500
0.2000
0.2500
0.3000
0.3500
0.4000
0.4500
0.5000
0.5500
0.6000
0.6500
0.7000
0.7500
0.8000
0.8500
0.9000
0.9500
1.0000

sat

Constantes de Antoine : P (kPa), t (C)

A

(g21 - g11) =1332.313 cal/mol

a =
0.3031

t12 =
PARAMETROS DEL t21 =
MOD. NRTL
G12 =
G21 =

Ing. Alfredo ARIAS JARA

-0.15404
1.871965
1.04780
0.56700

DIAGRAMA DE COMPOSICION
0
1

DIAGRAMA PRESION / COMPOSICION

0
1

1200

1.0

0.9
1000

0.7

800

Presin (mmHg)

y (fraccin molar fase vapor)

0.8

0.6

0.5

0.4

600

400
0.3

0.2

200

0.1

0.0
0.0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1.0

0.0

0.1

0.2

0.3

0.4

0.5

x,y

x (fraccin molar fase lquida)

Ing. Alfredo ARIAS JARA

0.6

0.7

0.8

0.9

1.0

GENERACION DE DATOS ELV

MODELO UNIQUAC

CONDICION ISOTERMICO
i
( 01 )
( 02 )

SISTEMA BINARIO
Nombre
Tetracloruro Carbono
2-Butanol

CTES. DEL MOD. (u12 - u22) =

UNIQUAC
(u21 - u11) =

Temperatura (C)

519.3032 cal/mol
-157.8161 cal/mol

x2
1.0000
0.9500
0.9000
0.8500
0.8000
0.7500
0.7000
0.6500
0.6000
0.5500
0.5000
0.4500
0.4000
0.3500
0.3000
0.2500
0.2000
0.1500
0.1000
0.0500
0.0000

CALCULO PUNTUAL
0.6460 0.3540
0.1200 0.8800

COD. TABLA

Psat

Constantes de Antoine : P (kPa), t (C)

A

Tmn

Tmx

(mmHg)

6.01900

1219.580

227.170

-20

101

838.9233

173

6.59920

1314.190

186.510

25

120

349.291

PARAM.
VOLUMETRICOS

r1 =
r2 =

3.3900
3.4535

PARAM.
SUPERFICIALES

q1 =

2.9100

q2 =

3.0480

PARAMETROS
DEL MOD.
UNIQUAC

t12 =
t21 =

0.477125
1.252171

l1 =
l2 =

-0.42600

0.01000

80.00 <---- Puede cambiar la Temperatura

Fracc. Volum. Prom

x1
0.0000
0.0500
0.1000
0.1500
0.2000
0.2500
0.3000
0.3500
0.4000
0.4500
0.5000
0.5500
0.6000
0.6500
0.7000
0.7500
0.8000
0.8500
0.9000
0.9500
1.0000

Frmula
CCl4
C4H10O

Fracc. Superf. Prom

Efecto Combinatorial

Efecto Residual

F1
0.0000
0.0491
0.0983
0.1476
0.1970
0.2465
0.2961
0.3458
0.3956
0.4454
0.4954
0.5454
0.5955
0.6458
0.6961
0.7465
0.7970
0.8476
0.8983
0.9491
1.0000

F2
1.0000
0.9509
0.9017
0.8524
0.8030
0.7535
0.7039
0.6542
0.6044
0.5546
0.5046
0.4546
0.4045
0.3542
0.3039
0.2535
0.2030
0.1524
0.1017
0.0509
0.0000

q1
0.0000
0.0478
0.0959
0.1442
0.1927
0.2414
0.2904
0.3395
0.3889
0.4386
0.4884
0.5385
0.5888
0.6394
0.6902
0.7412
0.7925
0.8440
0.8958
0.9478
1.0000

q2
1.0000
0.9522
0.9041
0.8558
0.8073
0.7586
0.7096
0.6605
0.6111
0.5614
0.5116
0.4615
0.4112
0.3606
0.3098
0.2588
0.2075
0.1560
0.1042
0.0522
0.0000

g1C
1.0055
1.0050
1.0045
1.0040
1.0036
1.0031
1.0027
1.0024
1.0020
1.0017
1.0014
1.0011
1.0009
1.0007
1.0005
1.0004
1.0002
1.0001
1.0001
1.0000
1.0000

g2C
1.0000
1.0000
1.0001
1.0001
1.0002
1.0003
1.0005
1.0007
1.0009
1.0011
1.0014
1.0017
1.0020
1.0023
1.0027
1.0031
1.0036
1.0041
1.0046
1.0051
1.0057

g1R
2.3802
2.2605
2.1459
2.0363
1.9317
1.8322
1.7378
1.6484
1.5640
1.4848
1.4107
1.3419
1.2783
1.2203
1.1678
1.1214
1.0813
1.0481
1.0226
1.0060
1.0000

g2R
1.0000
1.0013
1.0056
1.0132
1.0246
1.0405
1.0616
1.0890
1.1239
1.1679
1.2234
1.2930
1.3809
1.4923
1.6350
1.8201
2.0640
2.3917
2.8430
3.4829
4.4231

g1
2.3933
2.2718
2.1555
2.0444
1.9386
1.8380
1.7425
1.6523
1.5672
1.4873
1.4127
1.3434
1.2795
1.2211
1.1684
1.1218
1.0815
1.0482
1.0227
1.0060
1.0000

P(mmHg)
g2
1.0000
349.29
1.0014
427.57
1.0056
496.96
1.0133
558.11
1.0248
611.63
1.0408
658.14
1.0621
698.24
1.0897
732.54
1.1249
761.64
1.1692
786.12
1.2250
806.53
1.2952
823.44
1.3836
837.35
1.4958
848.73
1.6395
857.96
1.8258
865.25
2.0714
870.55
2.4014
873.29
2.8560
871.91
3.5007
862.93
4.4481
838.92

y1
0.0000
0.2229
0.3639
0.4610
0.5318
0.5857
0.6281
0.6623
0.6905
0.7143
0.7347
0.7528
0.7691
0.7845
0.7998
0.8157
0.8338
0.8559
0.8856
0.9292
1.0000

0.6417
0.1181

0.3583
0.8819

0.6353
0.1152

0.3647
0.8848

1.0007
1.0043

1.0023
1.0001

1.2247
2.1014

1.4824
1.0082

1.2256
2.1104

1.4858
1.0083

0.7833
0.4067

Ing. Alfredo ARIAS JARA

847.91
522.38

0
DIAGRAMA0 DE COMPOSICION
1

DIAGRAMA PRESION / COMPOSICION

1000

1.0
900

0.9
800

0.8
700

Presin (mmHg)

y (fraccin molar fase vapor)

0.7

0.6

0.5

600

500

400

0.4
300

0.3
200

0.2
100

0.1

0.0

0.0

0.0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1.0

x (fraccin molar fase lquida)

Ing. Alfredo ARIAS JARA

0.1

0.2

0.3

0.4

0.5

x,y

0.6

0.7

0.8

0.9

1.0

Temp (C) P (mmHg)

80
760

i
( 01 )
( 02 )

SISTEMA BINARIO
Nombre
Tetracloruro Carbono
2-Butanol

Tetracloruro Carbono
2-Butanol
DECHEMA
Tetracloruro Carbono
2-Butanol

Frmula
CCl4
C4H10O

COD. TABLA

1
173

Constantes de Antoine : P (kPa), t (C)

A

6.01900
6.59920

1219.580
1314.190

227.170
186.510

Tmn

Tmx

-20
25

101
120

Psat (mmHg)

Tsat (C)

838.92
349.29

CCl4
C4H10O

Constantes de Antoine : P (mmHg), T (K)

1 15.874245 2808.187
-45.980
-20
173 17.210205 3026.034
-86.640
25

Psat (mmHg) Tsat (C)

101
838.92
120
349.29

CCl4
C4H10O

Constantes de Antoine : P (mmHg), T (C)

7.23703
1483.18
263.785
77
7.47429 1314.188
186.500
25

Psat (mmHg) Tsat (C)

251
837.07
120
349.14